Thiophosphoryl Iodide

Thiophosphoryl iodide
Names
	Other names Phosphorothioic triiodide; Phosphorus thioiodide; Thiophosphoryl triiodide;
Identifiers
CAS Number	63972-04-3;
3D model (JSmol)	Interactive image;
PubChem CID	21517233;
	InChI InChI=1S/I3PS/c1-4(2,3)5 Key: CVHICNBAVVKDQW-UHFFFAOYSA-N;
	SMILES S=P(I)(I)I;
Properties
Chemical formula	PSI; 3
Molar mass	443.75 g·mol−1
Appearance	red-brown solid
Melting point	48 °C (118 °F; 321 K)
Boiling point	decomposes
Structure
Molecular shape	Tetrahedral at the P atom
Related compounds
Related compounds	Phosphorus triiodide; Phosphoryl iodide; Thiophosphoryl fluoride; Thiophosphoryl chloride; Thiophosphoryl bromide; Phosphorothioic chloride difluoride;
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Thiophosphoryl iodide is an inorganic compound with the formula PSI
3.^[1]

Preparation

Thiophosphoryl iodide can be prepared by reacting phosphorus triiodide with sulfur in carbon disulfide at 10–15 °C in the dark for several days.^[1]^[2]

Attempts to synthesise PSI
3 by the reaction of lithium iodide with thiophosphoryl bromide lead to the mixed thiophosphoryl halides PSBr
2I and PSBrI
2 instead.^[3]

References

↑ ^1.0 ^1.1 ^1.2 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 501–503. ISBN 978-0-08-037941-8.
↑ Arthur D. F. Toy (1975). The Chemistry of Phosphorus. Permanon Texts in Inorganic Chemistry. 3. Permanon Press. p. 438. ISBN 9781483139593.
↑ Dillon, K. B.; Craveirinha Dillon, M. G.; Waddington, T. C. (1977). "The identification of some new thiophosphoryl compounds containing P–I bonds by means of ³¹P N.M.R. spectroscopy". Inorg. Nucl. Chem. Lett. 13 (8): 349–353. doi:10.1016/0020-1650(77)80109-8.

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[G&E-1] 1.0 ^1.1 ^1.2 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 501–503. ISBN 978-0-08-037941-8.

[Toy-2] Arthur D. F. Toy (1975). The Chemistry of Phosphorus. Permanon Texts in Inorganic Chemistry. 3. Permanon Press. p. 438. ISBN 9781483139593.

[3] Dillon, K. B.; Craveirinha Dillon, M. G.; Waddington, T. C. (1977). "The identification of some new thiophosphoryl compounds containing P–I bonds by means of ³¹P N.M.R. spectroscopy". Inorg. Nucl. Chem. Lett. 13 (8): 349–353. doi:10.1016/0020-1650(77)80109-8.

Names

Other names Phosphorothioic triiodide Phosphorus thioiodide Thiophosphoryl triiodide
Identifiers
CAS Number	63972-04-3
3D model (JSmol)	Interactive image
PubChem CID	21517233
InChI InChI=1S/I3PS/c1-4(2,3)5 Key: CVHICNBAVVKDQW-UHFFFAOYSA-N
SMILES S=P(I)(I)I
Properties
Chemical formula	PSI 3
Molar mass	443.75 g·mol⁻¹
Appearance	red-brown solid^[1]
Melting point	48 °C (118 °F; 321 K)
Boiling point	decomposes
Structure
Molecular shape	Tetrahedral at the P atom
Related compounds
Related compounds	Phosphorus triiodide Phosphoryl iodide Thiophosphoryl fluoride Thiophosphoryl chloride Thiophosphoryl bromide Phosphorothioic chloride difluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references