Ruthenium(III) nitrate

Ruthenium(III) nitrate  Names

Other names

Rhuthenium trinitrate, Ruthenium nitrate

Identifiers

CAS Number

* 15825-24-8

3D model (JSmol)

* Interactive image

ChemSpider |

* 146478

EC Number |

* 239-923-0

PubChem CID

* 167436

InChI

* InChI=1S/3NO3.Ru/c3*2-1(3)4;/q3*-1;+3

Key: GTCKPGDAPXUISX-UHFFFAOYSA-N

SMILES

* [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Ru+3]

Properties

Chemical formula

| Ru(NO3)3
Molar mass | 287.1
Appearance  | Yellow crystals (hydrate)

Solubility in water

| Soluble
Hazards
GHS pictograms |
GHS Signal word | Danger

GHS hazard statements

| H272, H302, H317, H318, H411

GHS precautionary statements

| P210, P220, P221, P261, P264, P270, P272, P273, P280, P301+312, P302+352, P305+351+338, P310, P321, P330, P333+313, P363, P370+378, P391, P501
Related compounds

Related compounds

| Americium(III) nitrate, Einsteinium(III) nitrate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Ruthenium(III) nitrate is an inorganic compound, a salt of ruthenium and nitric acid with the chemical formula Ru(NO3)3.[1][2]

## Contents

* 1 Physical properties
* 2 Chemical properties
* 3 Applications
* 4 References

## Physical properties

Ruthenium(III) nitrate dissolves in water. It forms a crystalline hydrate with the composition Ru(NO

3 * 6H2O in the form of yellow crystals.

## Chemical properties

Ruthenium(III) nitrate reacts with silicon oxide in a carbon monoxide atmosphere to form Ru(CO)
2(OSi)
2, Ru(CO)
3(OSi)
2, or Ru
3(CO)
12.[3]

## Applications

Ruthenium(III) nitrate is used for the manufacture of ruthenium-carbon catalysts.[4]

## References

1. ↑ "Ruthenium Nitrate" (in en). American Elements. https://www.americanelements.com/ruthenium-nitrate-34513-98-9.
2. ↑ Becker, Harry; Dalpe, Claude; Walker, Richard J. (29 May 2002). "High-precision Ru isotopic measurements by multi-collector ICP-MS". The Analyst 127 (6): 775–780. doi:10.1039/b200596d. PMID 12146910. Bibcode: 2002Ana...127..775B.
3. ↑ Huang, Lin; Xu, Yide (November 2001). "Surface-mediated reductive carbonylation of SiO2-supported RuCl3 and Ru(NO)(NO3)3 studied by IR spectroscopy". Journal of Molecular Catalysis A: Chemical 176 (1–2): 267–280. doi:10.1016/S1381-1169(01)00267-9. https://www.sciencedirect.com/science/article/abs/pii/S1381116901002679. Retrieved August 21, 2021.
4. ↑ Kawaguchi, T; Sugimoto, W; Murakami, Y; Takasu, Y (1 January 2005). "Particle growth behavior of carbon-supported Pt, Ru, PtRu catalysts prepared by an impregnation reductive-pyrolysis method for direct methanol fuel cell anodes" (in en). Journal of Catalysis 229 (1): 176–184. doi:10.1016/j.jcat.2004.10.020. ISSN 0021-9517. https://www.sciencedirect.com/science/article/abs/pii/S0021951704005123. Retrieved 21 August 2021.

* v
* t
* e

Ruthenium compounds

Ru(0)|

* Ru3(CO)12
* Ru(P(C6H5)3)3(CO)2

Ru(I)|

* (C5(C6H5)4O)2H(Ru(CO)2)2H

Ru(II)|

* RuB2
* Na4Ru(N2C12H6(C6H4SO3)2)3
* (Ru((NC5H4)2)3)Cl2
* Ru(P(C6H5)3)3Cl2
* Ru(SO(CH3)2)4Cl2
* (RuCl2C6H4CH3CH(CH3)2)2
* RuClC5H5(P(C6H5)3)2
* C43H72Cl2P2Ru
* (C5H5)2Ru

Ru(III)|

* RuCl3

Ru(IV)|

* RuO2
* Sr2RuO4

Ru(V)|

* RuF5

Ru(VI)|

* RuF6

Ru(VII)|

* N(C3H7)4RuO4

Ru(VIII)|

* RuO4

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* t
* e

Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

|
|
|
|

LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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*[CID]: Compound ID
*[H272]: May intensify fire: oxidizer
*[H302]: Harmful if swallowed
*[H317]: May cause an allergic skin reaction
*[H318]: Causes serious eye damage
*[H411]: Toxic to aquatic life with long lasting effects
*[P210]: Keep away from heat/sparks/open flames/hot surfaces – No smoking
*[P220]: Keep/Store away from clothing/…/combustible materials
*[P221]: Take any precaution to avoid mixing with combustibles
*[P261]: Avoid breathing dust/fume/gas/mist/vapours/spray
*[P264]: Wash … thoroughly after handling
*[P270]: Do not eat, drink or smoke when using this product
*[P272]: Contaminated work clothing should not be allowed out of the workplace
*[P273]: Avoid release to the environment
*[P280]: Wear protective gloves/protective clothing/eye protection/face protection
*[P301+312]: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
*[P302+352]: IF ON SKIN: Wash with soap and water
*[P305+351+338]: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
*[P310]: Immediately call a POISON CENTER or doctor/physician
*[P321]: Specific treatment (see … on this label)
*[P330]: Rinse mouth
*[P333+313]: If skin irritation or a rash occurs: Get medical advice/attention
*[P363]: Wash contaminated clothing before reuse
*[P370+378]: In case of fire: Use … for extinction
*[P391]: Collect spillage
*[P501]: Dispose of contents/container to …
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