Titanium yellow

Short description: Nickel antimony titanium yellow pigment

Titanium yellow

Commercial pigment

Color coordinates
Hex triplet| #EEE600
Source| [Unsourced]
Titanium yellow  Names

IUPAC name

* Titanium yellow
* nickel antimony titanium yellow
* nickel antimony titanium yellow rutile
* CI Pigment Yellow 53
* C.I. 77788

Identifiers

CAS Number

* 8007-18-9

3D model (JSmol)

* Interactive image

EC Number |

* 232-353-3

InChI

* InChI=1S/Ni.44O.2Sb.20Ti.12H/q+2;44*-2;2*+3;20*+4;;;;;;;;;;;;

Key: KTGGHEZYKTWVFJ-UHFFFAOYSA-N

SMILES

* [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ni+2].[Sb+3].[Sb+3].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4]

Properties

Chemical formula

| NiO·Sb2O3·20TiO2
Appearance  | Yellow pigment

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Titanium yellow is a yellow pigment with the chemical composition NiO·Sb2O3·20TiO2. It is considered a complex inorganic color pigment (CICP)[1][2], formerly known as a mixed phase metal oxide[2]. The pigment has a rutile crystal lattice[1], with 2-5% of titanium ions replaced with nickel(II) and 9-12% of them replaced with antimony(III).

## Contents

* 1 Properties
* 2 Production
* 3 Use
* 4 Safety
* 5 See also
* 6 References
* 7 External links

## Properties

As other CICPs, it has excellent heat stability and good chemical stability.[2]

## Production

CICPs such as titanium yellow are manufactured by calcining fine powders of metal oxides, hydroxides, or carbonates in solid state at temperatures between 650 and 1300 °C.[1]

## Use

Titanium yellow is used primarily as a pigment for plastics[3] and ceramic glazes[2], and in art painting.

It also finds use in high-end applications such as automotive and coil coatings.[2]

## Safety

While titanium yellow contains antimony and nickel, it is considered relatively inert and can be regarded as "physiologically and environmentally harmless."[2]

## See also

* List of colors
* List of inorganic pigments

## References

1. ↑ 1.0 1.1 1.2 Faulkner, Edwin B., ed (2009-01-14) (in en). High Performance Pigments. Wiley. pp. 44-45. doi:10.1002/9783527626915. ISBN 978-3-527-31405-8. https://onlinelibrary.wiley.com/doi/book/10.1002/9783527626915.
2. ↑ 2.0 2.1 2.2 2.3 2.4 2.5 Lambourne, R.; Strivens, T. A. (1999-08-23) (in en). Paint and Surface Coatings: Theory and Practice. Elsevier. pp. 137-138. ISBN 978-1-85573-700-6. https://books.google.com/books?id=cRKkAgAAQBAJ.
3. ↑ Sarvis, Harrey E. (1993). "The coloring of PVC" (in en). Journal of Vinyl Technology 15 (3): 150. doi:10.1002/vnl.730150307. ISSN 1548-0585. https://onlinelibrary.wiley.com/doi/abs/10.1002/vnl.730150307.

## External links

* Database of Painting Pigments
* chemicalbook.com

* v
* t
* e

Shades of yellow

| Amber| Apricot| Arylide yellow| Aureolin| Beige| Buff| Champagne| Chartreuse| Citron| Citrine

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|  |  |  |  |  |  |  |  |
Cosmic latte| Cream| Dark goldenrod| Ecru| Flax| Gamboge| Gold| Gold (metallic)| Goldenrod| Harvest gold
|  |  |  |  |  |  |  |  |
Ivory| Jasmine| Jonquil| Khaki| Lemon chiffon| Lemon-lime| Light yellow| Lion| Maize| Mikado yellow
|  |  |  |  |  |  |  |  |
Mindaro| Mustard| Naples yellow| Navajo white| Old gold| Papaya whip| Peach-yellow| Pear| Saffron| School bus yellow
|  |  |  |  |  |  |  |  |
Selective yellow| Stil de grain yellow| Straw| Sunglow| Sunset| Vanilla| Wheat| Yellow
|  |  |  |  |  |  |

A typical sample is shown for each name; a range of color-variations is commonly associated with each color-name.

* v
* t
* e

Nickel compounds

Nickel(0)|

* Ni(CO)4
* Ni(COD)2

Nickel(II)|

* NiBr2
* NiCO3
* NiCl2
* NiCrO4
* NiF2
* NiI2
* Ni(NO2)2
* Ni(NO3)2
* NiO
* Ni(OH)2
* Ni3(PO4)2
* NiS
* NiSO4
* NiTiO3
* Ni(acac)2
* xNi(NO2)6
* xNiF4
* xNiCl4
* xNiBr4
* xNiI4

Nickel(III)|

* Ni2O3
* NiOOH

Nickel(IV)|

* K2NiF6
* MNiOx

* v
* t
* e

Antimony compounds

* SbBr3
* Sb(C2H3O2)3
* SbCl3
* SbCl5
* SbF3
* SbF5
* SbH3
* SbI3
* Sb2O3
* Sb2O4
* Sb2O5
* Sb2S3
* Sb2S5
* Sb2(SO4)3
* Sb2Se3
* Sb2Te3

* v
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* e

Titanium compounds

Titanium(II)|

* TiCl2
* TiH2
* TiO
* TiS
* TiSi2

| Organotitanium(II) compounds|

[(C5H5)2Ti(CO)2]

|

Titanium(III)|

* TiAl
* TiBr3
* TiCl3
* TiF3
* TiI3
* TiN
* TiP
* Ti2O3
* Ti2S3

| Organotitanium(III) compounds|

[(C5H5)2TiCl]2

|

Titanium(IV)|

* TiB2
* TiBr4
* TiC
* TiCl4
* Ti(ClO4)4
* TiF4
* H2TiF6
* TiH4
* TiI4
* Ti(NMe2)4
* Ti(NO3)4
* TiO2
* H4TiO4
* Ti4(OCH2CH3)16
* Ti(OCH(CH3)2)4
* Ti(OCH2CH2CH2CH3)4
* KTiOPO4
* NiO*Sb2O3*20TiO2
* TiS2
* TiSe2
* TiSi2

| Titanate compounds|

* BaTiO3
* Ba2TiO4
* Bi4Ti3O12
* CaTiO3
* CaCu3Ti4O12
* CaZrTi2O7
* Cs2TiO3
* Dy2Ti2O7
* EuBaTiO4
* FeTiO3
* Ho2Ti2O7
* Li2TiO3
* MnTiO3
* Na2Ti3O7
* Na0.5Bi0.5TiO3
* NiTiO3
* PbTiO3
* Pb(Zr,Ti)O3
* SrTiO3
* ZnTiO3

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Organotitanium(IV) compounds|

* [(C5H5)2TiCl2]
* [(C5H5)2Ti(CH3)2]
* [(C5H5)2TiS5]
* [(C5H5)2Ti(μ-Cl)(μ-CH2)Al(CH3)2]
* [(η5-C5H4-CH2C6H4OCH3)2TiCl2]

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