Telluride iodide

Short description: Class of chemical compounds

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.[1]

Tellurium does not normally bond with iodine, but can form many different units with bonds to other tellurium atoms.

## List

name  | formula  | system  | space group | unit cell | volume  | density  | properties  | ref

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Copper telluride iodide  | CuTeI  | tetrahedral  | I41/amd | a = 17.170, c = 4.876, and Z = 16  |  |  | Cu+1 ion conductor; metallic grey  | [2][3]
| (CuI)3Cu2TeS3 |  | P3121  |  |  |  |  | [1]
gallium telluride iodide  | GaTeI  | orthorhombic  |  |  |  |  | band gap 2.55  | [1]
| Ge40.0Te5.3I8 | cubic  | Pm3n | a=10.815 Z = 1  | 1265.0  | 6.023  | band gap 0.8 eV; clathrate  | [4]
α-Arsenic telluride iodide  | AsTeI  | monoclinic  | P21 | a=8.965 b=4.042 c=10.341 β=90.75 Z=4  |  | 5.84  | melt 281 °C black  | [5]
β-Arsenic telluride iodide  | AsTeI  | cubic  | Fm3m  | a=5.791 Z=2  |  | 5.63  | black metallic  | [5]
| As4Te5I2 | monoclinic  |  | a=14.58 b=4.00 c=12.26 β=95.0 Z=2  |  | 5.51  | melt 303 °C metallic  | [5]
triniobium telluride heptaiodide  | Nb3TeI7 |  |  |  |  |  |  | [1]
| NbTe4I  |  | P21/c | a=7.695 b=15.393 c=13.438 β=100.84 Z=8  | 1563.2  | 6.205  | black metallic  | [6]
diniobium hexatelluride iodide  | Nb2Te6I  |  | P21/c | a=9.197 b=13.387 c=9.651 β=112.36  | 1093.8  | 6.548  |  | [1][7]
| Nb4Te12I  | monoclinic  | C12/c1  | a=21.957 b=6.147 c=19.925 β=122.40 Z=4  | 2270.6  | 5.8  | black  | [8]
| Nb4Te17I4 | monoclinic  | C2/c | a = 16.199 b = 8.128 c = 27.355 β = 110.84°, Z = 4  |  |  | black metallic  | [9]
| Mo3Tel0Il0 |  |  |  |  |  |  | [1]
| [Mo3Se7(TeI3)I2]I  | monoclinic  | P23/n | a=10.4969 b=13.029 c=16.567 β =102.921° Z=4  | 2208.3  | 5.202  |  | [1][10]
| [Mo3Te7(TeI3)3]2(I)(TeI3)  | triclinic  | P1 | a=11.2148 b=11.6550 c=16.6798 α=92.124 β=102.223 γ=117.427 Z=  | 1868.4  | 5.374  |  | [1][10]
Palladium telluride iodide  | PdTeI  |  |  | a=7.821 c=5.659  |  |  | brass yellow  | [11][12]
| Ag23Te12I  | orthorhombic  | Pnnm |  |  |  | honeycomb Te  | [1]
| Ag19Te6Br5.4I1.6 | orthorhombic  | Pnma |  |  |  | electric conductor  | [1]
indium telluride iodide  | InTeI  | monoclinic  | P21/c |  |  |  |  | [13]
Antimony telluride iodide  | SbTeI  | triclinic  | P1 |  |  |  |  | [1]
| (Sb2Te2)I[AlI4]  | monoclinic  | P21/n |  |  |  |  | [1]
| La2TeI2 | rhombohedral  | R3m | a = 4.5074 c = 32.528 Z = 3  |  |  | metallic  | [1][14]
| Er17.3Te24I8 |  | Fd3m | a=12.020  |  |  |  | [15]
| Ta3TeI7 | hexagonal  | P63mc |  |  |  |  | [1]
| [TaTe4]4[PtI6]I2 | triclinic  | P1 | a=16.831 b=17.740 c=19.018 α=93.57 β=94.08 γ=102.09 Z=1  | 977.65  |  |  | [16]
| TaTe4I  | triclinic  | P1 | a=6.679 b=7.787 c=8.581 α=112.76 β=102.60 γ=101.25 Z=2  | 381.8  | 7.118  | black  | [6]
| W2Cl12Te6I2 |  |  |  |  |  |  | [17]
Gold telluride iodide  | AuITe  | monoclinic  |  | a=7.317 b=7.626 c=7.249 β=106.33  |  | 7.73  | semiconductor band gap 0.9 grey melt 360 °C  | [18]
Gold telluride diiodide  | AuITe2 | orthorhombic  | Pmmb | a = 4.056 Å, b = 12.579 Å, c = 4.741 Å, Z = 2  | 241.9  | 7.989  | silvery white conductor melt 440 °C  | [19]
| Hg3Te2I2 |  |  |  |  |  | greyish red  | [1]
| Hg3Te2BrI  | monoclinic  | C2  | 18.376 b=9.587 c=10.575 β=100.11°  |  |  |  | [20]
| Hg3TeI4 | cubic  | F43m | a=6.244 Z=(80% partial occupancy)  | 243.4  | 7.03  | decompose 273 °C dark ruby red  | [21]
Bismuth telluride iodide  | BiTeI  |  | P3m1 / Pnma |  |  |  | over 3.9 GPa Weyl semimetal; under semimetal  | [1]
| ThTe2I2 | monoclinic  | C2/m | a = 7.642 b = 14.336 c = 7.727 and β = 111.27° Z = 4  |  |  |  | [22]
| [Ta7(Se2)14][U2I10]2 | orthorhombic  | Cccm | a = 21.5134 b = 22.1619 and c = 16.7834 Z=4  |  |  |  | [23]

## References

1. ↑ 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.14 1.15 Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
2. ↑ Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride" (in en). Journal of Solid State Chemistry 18 (2): 183–189. doi:10.1016/0022-4596(76)90094-3. Bibcode: 1976JSSCh..18..183C.
3. ↑ Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" (in de). Zeitschrift für anorganische und allgemeine Chemie 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313.
4. ↑ Kovnir, Kirill A.; Abramchuk, Nikolay S.; Zaikina, Julia V.; Baitinger, Michael; Burkhardt, Ulrich; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I. et al. (2006-05-01). "Ge 40.0 Te 5.3 I 8: synthesis, crystal structure, and properties of a new clathrate-I compound" (in en). Zeitschrift für Kristallographie - Crystalline Materials 221 (5–7): 527–532. doi:10.1524/zkri.2006.221.5-7.527. ISSN 2196-7105. Bibcode: 2006ZK....221..527K. https://www.degruyter.com/document/doi/10.1524/zkri.2006.221.5-7.527/html.
5. ↑ 5.0 5.1 5.2 Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic" (in en). Angewandte Chemie International Edition in English 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833.
6. ↑ 6.0 6.1 Tremel, Wolfgang (October 1992). "NbTe4I und TaTe4I, zwei neue Tellurid-Iodide mit Kettenstruktur" (in de). Chemische Berichte 125 (10): 2165–2170. doi:10.1002/cber.19921251002.
7. ↑ Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group" (in en). Inorganic Chemistry 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669.
8. ↑ Deng, S.; Zhuang, H.; Lu, C.; Huang, Jinshun; Huang, Jingling (1993-06-15). "A new type of one-dimensional compound: structure of Nb4(Te2)4Te4I". Acta Crystallographica Section C Crystal Structure Communications 49 (6): 1135–1137. doi:10.1107/S010827019201285X. Bibcode: 1993AcCrC..49.1135D. http://scripts.iucr.org/cgi-bin/paper?S010827019201285X.
9. ↑ Tremel, Wolfgang (January 1994). "Nb4Te17I4, a New Pseudo One-Dimensional Solid-State Polytelluride" (in de). Chemische Berichte 127 (1): 11–14. doi:10.1002/cber.19941270103.
10. ↑ 10.0 10.1 Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10, Mo 3 Se 7 TeI 6, and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †" (in en). Inorganic Chemistry 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
11. ↑ Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study" (in en). Physical Review B 91 (24). doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. Bibcode: 2015PhRvB..91x5204G.
12. ↑ Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal" (in en). Angewandte Chemie International Edition in English 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.
13. ↑ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials 18 (10): 2538–2544. doi:10.1021/cm060226m.
14. ↑ Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2: A New Layered Telluride Iodide with Unusual Electrical Properties" (in en). Inorganic Chemistry 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429.
15. ↑ Stöwe, K (August 1998). "Nonstoichiometry in Er–Te Binary and Er–Te–I Ternary Systems" (in en). Journal of Solid State Chemistry 139 (1): 57–65. doi:10.1006/jssc.1998.7807.
16. ↑ Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117.
17. ↑ Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides" (in en). Angewandte Chemie International Edition in English 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
18. ↑ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold" (in en). Journal of the Less Common Metals 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3.
19. ↑ Haendler, H.M.; Mootz, D.; Rabenau, A.; Rosenstein, G. (June 1974). "The crystal structures of AuTe2Cl and AuTe2I" (in en). Journal of Solid State Chemistry 10 (2): 175–181. doi:10.1016/0022-4596(74)90024-3. Bibcode: 1974JSSCh..10..175H.
20. ↑ Minets, Yu.V; Voroshilov, Yu.V; Pan'ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2" (in en). Journal of Alloys and Compounds 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.
21. ↑ Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4" (in en). Zeitschrift für anorganische und allgemeine Chemie 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313.
22. ↑ Rocker, Frank; Tremel, Wolfgang (2001). "Synthesis and Structure of ThTe2I2" (in en). Zeitschrift für anorganische und allgemeine Chemie 627 (6): 1305–1308. doi:10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J.
23. ↑ Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2) 14 ][U 2 I 10 ] 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 636 (3–4): 440–442. doi:10.1002/zaac.200900416.

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Tellurides

| H2Te |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

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Li2Te | BeTe |  |  |  |  |  |  |  |  |  |  | B  | CTe2
(CH3)2Te | (NH4)2Te | O  | F  | Ne
Na2Te | MgTe |  |  |  |  |  |  |  |  |  |  | Al2Te | Si  | P2Te5 | S  | Cl  | Ar
K2Te | CaTe | Sc2Te3 | Ti  | VTe2 | CrTe
Cr2Te3 | MnTe
MnTe2 | FeTe | CoTe | NiTe | CuTe | ZnTe | GaTe
Ga2Te3 | GeTe | As2Te3
As4Te3 | Se  | Br  | Kr
Rb2Te | SrTe | Y2Te3 | Zr  | NbTe2 | MoTe2 | Tc  | Ru  | Rh  | Pd  | Ag2Te | CdTe | In2Te3 | SnTe
SnTe2 | Sb2Te3 | Te2- | I  | Xe
Cs2Te | BaTe | *  | Hf  | TaTe2 | WTe2
WTe3 | ReTe2 | Os  | Ir  | Pt  | AuxTey | HgTe | Tl2Te | PbTe | Bi2Te3 | Po  | At  | Rn
Fr  | Ra  | **  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og  |  |  |  |  |  |  |  |
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | La2Te3 | Ce2Te3 | Pr2Te3 | Nd2Te3 | Pm  | Sm2Te3 | Eu2Te3 | Gd  | Tb  | Dy  | Ho  | Er2Te3 | Tm2Te3 | Yb  | Lu  |
| ** | Ac  | ThTe2 | Pa  | UTe2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr  |

HI |  |  |  | He

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LiI | BeI2 | BI3 | CI4 | NI3 | I2O4,
I2O5,
I4O9 | IF,
IF3,
IF5,
IF7 | Ne
NaI | MgI2 | AlI3 | SiI4 | PI3,
P2I4 | S  | ICl,
ICl3 | Ar
KI | CaI2 | Sc  | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2,
GeI4 | AsI3 | Se  | IBr | Kr
RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo  | Tc  | Ru  | Rh  | Pd  | AgI | CdI2 | InI3 | SnI4,
SnI2 | SbI3 | TeI4 | I  | Xe
CsI | BaI2 |  | HfI4 | TaI5 | W  | Re  | Os  | Ir  | Pt  | AuI | Hg2I2,
HgI2 | TlI | PbI2 | BiI3 | Po  | AtI | Rn
Fr  | RaI2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La  | Ce  | Pr  | Nd  | Pm  | SmI2 | Eu  | Gd  | TbI3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac  | ThI4 | Pa  | UI3,
UI4 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | EsI3 | Fm  | Md  | No  | Lr

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