Thallium trifluoride

Identifiers

CAS Number

* 7783-57-5 Y

3D model (JSmol)

* Interactive image

ChemSpider |

* 74194

EC Number |

* 232-010-8

PubChem CID

* 53443050

UNII |

* ZJ85SF5XFJ Y

InChI

* InChI=1S/3FH.Tl/h3*1H;/q;;;+3/p-3

Key: BOUDEKXATYHWHY-UHFFFAOYSA-K

SMILES

* [F-].[F-].[F-].[Tl+3]

Properties

Chemical formula

| F3Tl
Molar mass | 261.38 g·mol−1
Appearance  | white solid
Density | 8.65 g/cm3
Hazards
GHS pictograms |
GHS Signal word | Danger

GHS hazard statements

| H300, H330, H373, H411

GHS precautionary statements

| P260, P264, P270, P271, P273, P284, P301+310, P304+340, P310, P314, P320, P321, P330, P391, P403+233, P405, P501
Related compounds

Other anions

| Thallium(III) chloride

Other cations

| Aluminum fluoride
Gallium(III) fluoride
Thallium(I) fluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Thallium trifluoride is the inorganic compound with the formula TlF3. It is a white solid. Aside from being one of two thallium fluorides, the compound is only of theoretical interest. It adopts the same structure as bismuth trifluoride, featuring eight-coordinate Tl(III) centers.[1] Some evidence exists for a second polymorph.

## References

1. ↑ Christoph Hebecker (1972). "Die Kristallstruktur von Thalliumtrifluorid (Crystal Structure of Thalliumtrifluorides)". Zeitschrift für Anorganische und Allgemeine Chemie 393: 223–229. doi:10.1002/zaac.19723930305.

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Thallium compounds

Thallium(I)|

* TlN3
* TlOH
* TlI
* TlBr
* Tl2CO3
* TlCl
* TlF
* Tl2O
* Tl2SO4
* Tl2S
* Tl2Te
* TlI3
* TBCCO

| Organothallium(I)|

* Tl(C2H3O2)3
* Tl2C3H2O4
* TlC5H5

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Thallium(III)|

* TlH3
* Tl(OH)3
* Tl2O3
* Tl(NO3)3

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Fluorine compounds

| HF |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

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LiF | BeF2 |  |  |  |  |  |  |  |  |  |  | BF3
B2F4 | CF4 | NF3 | OF2 | F− | Ne
NaF | MgF2 |  |  |  |  |  |  |  |  |  |  | AlF3 | SiF4 | PF3
PF5 | SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF2 | ScF3 | TiF3
TiF4 | VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5 | MnF2
MnF3 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF3 | GeF4 | AsF3
AsF5 | SeF4
SeF6 | BrF3
BrF5 | KrF2
RbF | SrF2 | YF3 | ZrF4 | NbF4
NbF5 | MoF5
MoF6 | TcF6 | RuF3
RuF4
RuF5
RuF6 | RhF6 | PdF2 | AgF
AgF2
Ag2F | CdF2 | InF3 | SnF2
SnF4 | SbF3
SbF5 | TeF4 | IF
IF3
IF5
IF7 | XeF2
XeF4
XeF6
CsF | BaF2 | *  | HfF4 | TaF5 | WF4
WF6 | ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF3
IrF5
IrF6 | PtF4
PtF6 | AuF3
Au2F10
AuF5·F2
| HgF2
Hg2F2 | TlF
TlF3 | PbF2
PbF4 | BiF3
BiF5 | Po | At | RnF2
Fr | Ra | **  | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | LaF3 | CeF3 | Pr | NdF3 | PmF3 | SmF3
| Eu | Gd | Tb | DyF3 | Ho | Er | Tm | YbF3
| Lu |
| ** | AcF3 | ThF4 | Pa | UF3
UF4
UF5
UF6 | NpF3
NpF4
NpF5
NpF6
| PuF3
PuF4
PuF5
PuF6 | AmF3
AmF4 | CmF3 | Bk | Cf | Es | Fm | Md | No | Lr |

Other|

* AgBF4
* AgPF6
* Cs2AlF5
* K3AlF6
* Na3AlF6
* KAsF6
* LiAsF6
* NaAsF6
* HBF4
* KBF4
* LiBF4
* NaBF4
* RbBF4
* Ba(BF4)2
* Ni(BF4)2
* Pb(BF4)2
* Sn(BF4)2
* BaClF
* BaSiF6
* BaGeF6
* BrOF3
* BrO2F
* CBrF3
* CBr2F2
* CBr3F
* CClF3
* CCl2F2
* CCl3F
* CFN
* CF2O
* CF3I
* CHF3
* CH2F2
* CH3F
* C2Cl3F3
* C2H3F
* C6H5F
* C7H5F3
* C15F33N
* ClFO2
* CrFO4
* CrF2O2
* CsBF4
* NH4F
* FNO
* FNO2
* FNO3
* KHF2
* NaHF2
* ThOF2
* NH5F2
* (NH4)2SiF6
* F2OS
* F3OP
* PSF3
* HPF6
* HSbF6
* NH4PF6
* KPF6
* KSbF6
* LiPF6
* NaPF6
* NaSbF6
* Na2SiF6
* Na2TiF6
* Na2ZrF6
* TlPF6
* IOF3
* K2NbF7
* K2TaF7
* IO3F
* UO2F2

Chemical formulas

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*[CID]: Compound ID
*[H300]: Fatal if swallowed
*[H330]: Fatal if inhaled
*[H373]: May cause damage to organs through prolonged or repeated exposure
*[H411]: Toxic to aquatic life with long lasting effects
*[P260]: Do not breathe dust/fume/gas/mist/vapours/spray
*[P264]: Wash … thoroughly after handling
*[P270]: Do not eat, drink or smoke when using this product
*[P271]: Use only outdoors or in a well-ventilated area
*[P273]: Avoid release to the environment
*[P284]: Wear respiratory protection
*[P301+310]: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
*[P304+340]: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
*[P310]: Immediately call a POISON CENTER or doctor/physician
*[P314]: Get Medical advice/attention if you feel unwell
*[P320]: Specific treatment is urgent (see … on this label)
*[P321]: Specific treatment (see … on this label)
*[P330]: Rinse mouth
*[P391]: Collect spillage
*[P403+233]: Store in a well ventilated place. Keep container tightly closed
*[P405]: Store locked up
*[P501]: Dispose of contents/container to …
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