Yttrium(III) nitrate

Names
Other names

Yttrium nitrate

Identifiers

CAS Number

* anhydrous: 10361-93-0 Y
* hexahydrate: 13494-98-9 Y

3D model (JSmol)

* anhydrous: Interactive image

EC Number |

* anhydrous: 233-802-6

PubChem CID

* anhydrous: 159283
* hexahydrate: 166833

UNII |

* anhydrous: 0XR81865O4

InChI

* InChI=1S/3NO3.Y/c3*2-1(3)4;/q3*-1;+3

Key: BXJPTTGFESFXJU-UHFFFAOYSA-N

SMILES

* anhydrous: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Y+3]

Properties

Chemical formula

| Y(NO3)3
Molar mass | 274.927
Appearance  | Colorless crystals

Solubility in water

| Soluble

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Yttrium(III) nitrate is an inorganic compound, a salt with the formula Y(NO3)3. The hexahydrate is the most common form commercially available.

## Contents

* 1 Preparation
* 2 Properties
* 3 Uses
* 4 References

## Preparation

Yttrium(III) nitrate can be prepared by dissolving corresponding metal oxide in 6 mol/L nitric acid:[1]

Y2O3 \+ 6 HNO3 → 2 Y(NO3)3 \+ 3 H2O

## Properties

Yttrium(III) nitrate hexahydrate loses crystallized water at relatively low temperature. Upon further heating, basic salt YONO3 is formed.[2] At 600 C, the thermal decomposition is complete. Y2O3 is the final product.[3]

Y(NO3)3·3TBP is formed when tributyl phosphate is used as the extracting solvent.[4]

## Uses

Yttrium(III) nitrate is mainly used as a source of Y3+ cations. It is a precursor of some yttrium-containing materials, such as Y4Al2O9,[3] YBa2Cu3O6.5+x[2] and yttrium-based metal-organic frameworks. [5] It can also be used as a catalyst in organic synthesis.[6]

## References

1. ↑ Dong, Bin; Hua, Rui N.; Cao, Bao S.; Li, Zhi P.; He, Yang Y.; Zhang, Zhen Y.; Wolfbeis, Otto S. (2014). "Size dependence of the upconverted luminescence of NaYF4:Er,Yb microspheres for use in ratiometric thermometry". Physical Chemistry Chemical Physics 16 (37): 20009–12. doi:10.1039/C4CP01966K. ISSN 1463-9076. PMID 25123272. Bibcode: 2014PCCP...1620009D.
2. ↑ 2.0 2.1 Zhuang, R.F.; Qiu, J.B.; Zhu, Y.P. (1990). "A study on reaction mechanism in preparation of Y-Ba-Cu-O superconducting material from the thermoreaction method of nitrates". Journal of Solid State Chemistry 86 (1): 125–128. doi:10.1016/0022-4596(90)90122-E. ISSN 0022-4596.
3. ↑ 3.0 3.1 Xu, F.M.; Zhang, Z.J.; Shi, X.L.; Tan, Y.; Yang, J.M. (2011). "Effects of adding yttrium nitrate on the mechanical properties of hot-pressed AlN ceramics". Journal of Alloys and Compounds 509 (35): 8688–8691. doi:10.1016/j.jallcom.2011.05.110. ISSN 0925-8388.
4. ↑ Scargill, D.; Alcock, K.; Fletcher, J.M.; Hesford, E.; McKay, H.A.C. (1957). "Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates—II Yttrium and the lower lanthanide nitrates". Journal of Inorganic and Nuclear Chemistry 4 (5–6): 304–314. doi:10.1016/0022-1902(57)80012-8. ISSN 0022-1902.
5. ↑ Duan, Tian-Wei; Yan, Bing (2014). "Hybrids based on lanthanide ions activated yttrium metal–organic frameworks: functional assembly, polymer film preparation and luminescence tuning". J. Mater. Chem. C 2 (26): 5098–5104. doi:10.1039/C4TC00414K. ISSN 2050-7526.
6. ↑ Bhanushali, Mayur J.; Nandurkar, Nitin S.; Jagtap, Sachin R.; Bhanage, Bhalchandra M. (2008). "Y(NO3)3·6H2O catalyzed aza-Michael addition of aromatic/hetero-aromatic amines under solvent-free conditions". Catalysis Communications 9 (6): 1189–1195. doi:10.1016/j.catcom.2007.11.002. ISSN 1566-7367.

* v
* t
* e

Yttrium compounds

* YAs
* YAl3(BO3)4
* Y3Al5O12
* Y3Fe5O12
* YB6
* YBr3
* YCl3
* YF3
* YN
* Y(NO3)3
* YOF
* YP
* YPO4
* YSb
* YVO4
* Y2O3
* Y2S3

* v
* t
* e

Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

|
|
|
|

LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Yttrium(III) nitrate. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Yttrium(III)_nitrate&oldid=811294"
*[CID]: Compound ID
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template