Enthalpy of neutralization

Short description: Change in enthalpy during an acid-base reaction

In chemistry and thermodynamics, the enthalpy of neutralization (ΔHn) is the change in enthalpy that occurs when one equivalent of an acid and a base undergo a neutralization reaction to form water and a salt. It is a special case of the enthalpy of reaction. It is defined as the energy released with the formation of 1 mole of water. When a reaction is carried out under standard conditions at the temperature of 298 K (25 degrees Celsius) and 1 atm of pressure and one mole of water is formed, the heat released by the reaction is called the standard enthalpy of neutralization (ΔHn⊖).

The heat (Q) released during a reaction is

[math]\displaystyle{ Q = mc_p \Delta T }[/math]

where m is the mass of the solution, cp is the specific heat capacity of the solution, and ∆T is the temperature change observed during the reaction. From this, the standard enthalpy change (∆H) is obtained by division with the amount of substance (in moles) involved.

[math]\displaystyle{ \Delta H = - \frac{Q}{n} }[/math]

When a strong acid, HA, reacts with a strong base, BOH, the reaction that occurs is

[math]\ce{ H+ + OH^- -> H2O }[/math]

as the acid and the base are fully dissociated and neither the cation B+
nor the anion A−
are involved in the neutralization reaction.[1] The enthalpy change for this reaction is -57.62 kJ/mol at 25 °C.

For weak acids or bases, the heat of neutralization is pH-dependent.[1] In the absence of any added mineral acid or alkali, some heat is required for complete dissociation. The total heat evolved during neutralization will be smaller.

e.g. [math]\displaystyle{ \ce{HCN + NaOH -\gt NaCN + H2O};\ \Delta H = -12 \mathrm{kJ/mol} }[/math] at 25°C

The heat of ionization for this reaction is equal to (–12 + 57.3) = 45.3 kJ/mol at 25 °C.[2]

## References

1. ↑ 1.0 1.1 Clark, Jim (July 2013). "Enthalpy Change of Neutralization". https://www.chemguide.co.uk/physical/energetics/neutralisation.html.
2. ↑ "Enthalpy of Neutralization". Community College of Rhode Island. http://faculty.ccri.edu/aahughes/GenChemII/Lab Experiments/Enthalpy_of_Neutralization.pdf. Retrieved 24 February 2014.

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