Phosphinane

Names
Preferred IUPAC name

Phosphinane

Other names

Phosphacyclohexane

Identifiers

CAS Number

* 4743-40-2

3D model (JSmol)

* Interactive image

PubChem CID

* 138339

InChI

* InChI=1S/C5H11P/c1-2-4-6-5-3-1/h6H,1-5H2

Key: VXTFGYMINLXJPW-UHFFFAOYSA-N

SMILES

* C1CCPCC1

Properties

Chemical formula

| C5H11P
Molar mass | 102.117 g·mol−1
Appearance  | colorless liquid
Boiling point |  118–121 °C (244–250 °F; 391–394 K)

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Tracking categories (test):

* SizeSet

Phosphinane is the organophosphorus compound with the formula (CH2)5PH. This colorless liquid is the parent member of a family of six-membered, saturated rings containing phosphorus. These compounds are mainly of academic interest. The ring adopts a flexible cyclohexane-like chair conformation.[1]

Phosphinane can be prepared via the Arbuzov reaction of triethylphosphite and 1,5-dibromopentane followed by cyclization and reduction steps.[1] Phosphinane can also be prepared by reduction of 1-chlorophosphinane, which in turn is obtained by the reaction of 1-phenylphosphinane and phosphorus trichloride.[2]

## References

1. ↑ 1.0 1.1 Michael J. Gallagher (2001). "Six-membered rings: Phosphinanes, Dihydro- and Tetrahydro-phosphinines". Phosphorus-Carbon Heterocyclic Chemistry The Rise of a New Domain. pp. 463–483. doi:10.1016/B978-008043952-5/50012-7.
2. ↑ K. Sommer (1970). "Zur Spaltung tertiärer Phosphine. II". Zeitschrift für Anorganische und Allgemeine Chemie 379: 56–62. doi:10.1002/zaac.19703790110.

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*[CID]: Compound ID