Oxalate sulfate

Short description: Mixed anion compounds

Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.

Related compounds include the sulfite oxalates[1] and oxalate selenates.[2]

## Contents

* 1 Production
* 2 Properties
* 3 List
* 4 References

## Production

Oxalate sulfates may be deposited from a solution in water of the metal anions and sulfate with oxalic acid when evaporated. Crystals formed this way may be hydrates.[3]

## Properties

Many crystal forms are non-centrosymmetric and have non-linear optical properties.[3]

When heated, oxalate sulfates will first dehydrate, and then give off carbon dioxide.[3]

## List

name  | formula  | system  | space group | unit cell Å  | volume  | density  | comment  | ref

|
|
|
|
|
|
|
|

lithium sulfate monohydrate oxalate  | ?  | triclinic  | P1  | a = 3.4014 b = 5.0397 c = 6.120 α = 78.62° β= 84.95°

γ = 81.14°

| 101.45  |  | band gap 4.57 eV

dielectric constant 29.7 stable below 83°C piezoelectric coefficient 6pC/N

| [3]
homopiperazinium dimagnesium dioxalate sulfate dihydrate  | C5H14N2•Mg2•[C2O4]2•SO4•2H2O  | monoclinic  | Ia | a=11.5673 b=27.3352 c=16.6097 β=95.255° Z=12  | 5229.8  | 1.749  | colourless  | [4]
piperazinium magnesium oxalate sulfate hydrate  | C4H12N2•Mg•[C2O4]•SO4•H2O  | monoclinic  | P21/c | a=12.7330 b=8.9240 c=11.8172 β=115.502° Z=4  | 1211.95  | 1.724  | colourless  | [4]
potassium sulphato oxalate  | ?  | triclinic  |  | a = 6.37 b = 7.03 c = 10.61 α = 93.96 ̊ β = 101.37 ̊ γ = 100.1 ̊  |  |  | colourless > 300nm; SHG 1.6×KDP  | [5]
bapp = 1,4-bis(3-aminopropyl)piperazine  | (H4bapp)0.5·VO(SO4)(C2O4)  | triclinic  | P1 | a=6.2031 b=8.6599 c=12.1853 α=77.130° β=76.207° γ=82.987°  |  |  |  | [6]
bipy=4,4′-bipyridine; (μ2-Oxalato-O,O',O'',O''')-tetrakis(2,2'-bipyridine)-di-chromium(iii) disulfate 2,2'-bipyridine solvate monohydrate  | [Cr2(bipy)4(C2O4)](SO4)·(bipy)0.5·H2O  | triclinic  | P1 | a=11.610 b=12.668 c=17.155 α=77.297° β=83.957° γ=85.458°  |  |  |  | [7]
depa = 3-(diethylamino)propylamine  | H2depa⋅Mn2(SO4)(C2O4)2(H2O)⋅H2O  | orthorhombic  | Pbca | a=14.6293 b=15.6671 c=17.3579  |  |  |  | [6]
hpip = homopiperazine  | H2hpip·Mn2(SO4)(C2O4)2(H2O)  | orthorhombic  | P212121 | a=9.9066 b=12.4496 c=13.6640  |  |  |  | [8]
pip = piperazine; piperazinediium (μ-oxalato)-bis(μ-sulfato)-diaqua-di-manganese(ii) dihydrate  | H2pip·Mn2(SO4)2(C2O4)(H2O)4 | triclinic  | P1 | a 6.6501(4)Å b 7.7034(4)Å c 9.6810(5)Å, α 69.850(4)° β 70.553(5)° γ 83.921(4)°  |  |  |  | [9]
ipa = 3,3′-iminobis(N,N-dimethylpropylamine) bis(3-dimethylammoniopropyl)ammonium pentakis(μ-oxalato)-bis(μ-sulfato)-tetra-manganese(ii) dihydrate  | H3ipa⋅Mn2(SO4)(C2O4)2.5·H2O  | triclinic  | P1 | a 9.9379(6)Å b 11.2423(6)Å c 11.6390(7)Å, α 86.793(5)° β 81.644(5)° γ 74.481(5)°  |  |  |  | [9]
dpta = dipropylenetriamine; bis(3-ammoniopropyl)ammonium tris(μ-oxalato)-bis(μ-sulfato)-bis(sulfato)-hexa-aqua-tetra-manganese(ii)  | H3dpta⋅Mn2(SO4)2(C2O4)1.5(H2O)3 | triclinic  | P1 | a 8.6819(3)Å b 10.1689(3)Å c 13.7456(5)Å, α 70.197(3)° β 73.406(3)° γ 87.636(3)°  |  |  |  | [9]
dmen = N,N-dimethylethylenediamine  | H2dmen·Mn(SO4)(C2O4)  | monoclinic  | P21/n | a=9.8603 b=12.6525 c=10.0837 β=113.002°  |  |  |  | [10]
bis(N,N-dimethylpropane-1,3-diaminium) bis(μ-oxalato)-bis(μ-sulfato)-di-manganese  |  | triclinic  | P1 | a=8.5307 b=9.0432 c=9.6913 α=69.632° β=64.639° γ=88.148°  |  |  |  | [11]
butane-1,4-diaminium bis(μ-oxalato)-(μ-sulfato)-aqua-di-manganese  |  | triclinic  | P1 | a=8.5468 b=10.0050 c=10.6532 α=75.445° β=79.787° γ=71.848°  |  |  |  | [11]
| Na2Fe(C2O4)SO4⋅H2O  |  |  |  |  |  | orange; most air sensitive  | [12]
(μ-oxalato)-(μ-sulfato)-iron-di-potassium  | K2[Fe(C2O4)(SO4)]  | monoclinic  | P21/c | a=5.8735 b=10.2169 c=13.1491 β=91.226°  |  |  |  | [13]
tris(μ-oxalato)-bis(μ-sulfato)-tri-iron-tetra-potassium  | K4[Fe3(C2O4)3(SO4)2]  | monoclinic  | P21/c | a 13.739 b 5.496 c 12.774 β 97.677°  |  |  |  | [13]
acid oxalo-bisulfate of roseocobalt ??  | Co2(HN3)10(C2O4)(SO4)2 ·H2O·H2C2O4 |  |  |  |  |  | speculative  | [14]
| [Co(NH3)4(C2O4)]2SO4·2H2O  |  |  |  |  |  |  | [15]
| [Co(NH3)4(C2O4)]2S2O6  |  |  |  |  |  |  | [15]
tris(μ-aqua)-tris(μ-oxalato)-tris(μ-sulfato)-tri-cobalt-hexa-sodium  | Na2[Co(C2O4)(SO4)]·H2O  | hexagonal  | P62m | a=10.2322 c=6.4774  |  |  |  | [13]
tris(μ-oxalato)-bis(μ-sulfato)-bis(2-((2-aminoethyl)amino)ethanaminium)-tetraaqua-tetra-cobalt  |  | triclinic  | P1 | a=8.6065 b=9.5595 c=9.5987 α=77.884° β=82.744° γ=87.356°  |  |  |  | [16]
bis(μ-oxalato)-bis(μ-sulfato)-bis(4-(2-aminoethyl)piperazin-1-ium)-tri-cobalt  |  | triclinic  | P1 | a=8.4331 b=9.4691 c=9.5144 α=71.522° β=64.356° γ=89.622°  |  |  |  | [16]
1,4-dimethylpiperazinedi-ium bis(μ-oxalato)-hepta-aqua-tri-cobalt bis(sulfate)  | (H2dmp)(SO4)3Co3(C2O4)2(H2O)7 | orthorhombic  | Pnma | a=11.1050 b=16.4221 c=13.9815  |  |  | violet  | [17]
Bis[tris(oxamide dioxime-2N,N')cobalt(III)] oxalate bis(sulfate) dodecahydrate  | [Co(C2H6N4O2)3]2(C2O4)(SO4)212H2O  | triclinic  | P1 | a = 9.430 b = 11.782 c = 12.812 α = 65.494° β = 83.088° γ = 86.735° Z=1  | 1285.7  | 1.698  | at 193K; red  | [18]
homopiperazinium dizinc dioxalate sulfate hydrate  | C5H14N2•Zn2•[C2O4]2•SO4•H2O  | monoclinic  | P21 | a=15.8356 b=13.5022 c=15.9578 β=109.075° Z=8  | 3224.7  | 2.154  | colourless  | [4]
homopiperazinium dizinc dioxalate sulfate dihydrate  | C5H14N2•Zn2•[C2O4]2•SO4•2H2O  | monoclinic  | Ia | a=11.5681 b=27.1755 c=16.5979 β=94.946° Z=12  | 5198.4  | 2.074  | colourless  | [4]
bis(4-(2-aminoethyl)piperazin-1-ium)-bis(μ-oxalato)-bis(μ-sulfato)-tri-zinc  |  | triclinic  | P1 | a=8.407 b=9.523 c=9.543 α=108.39° β=115.52° γ=90.17°  |  |  |  | [11]
1,4-dimethylpiperazinedi-ium bis(sulfate) bis(μ-oxalato)-hepta-aqua-tri-zinc  | (H2dmp)(SO4)3Zn3(C2O4)2(H2O)7 | orthorhombic  | Pnma | a 11.1058 b 16.3449 c 14.0064  |  |  | colourless  | [17]
| (Hgly)2·Zn(SO4)(C2O4)  | monoclinic  | C2  | a 19.1509 b 5.4000 c 12.8206 β 102.878°  |  |  |  | [19]
| RbFe(SO4)(C2O4)0.5·H2O  | monoclinic  | P21/c | a = 7.9193, b = 9.4907, c = 8.8090, β = 95.180°, Z = 4  |  |  |  | [20]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-yttrium diammonium  | [NH4][Y(H2O)(SO4)(C2O4)]  | monoclinic  | P21/n | a=6.534 b=8.527 c=13.745 β=92.87°  |  |  |  | [21]
bis(μ3-Sulfato-O,O,O',O'',O''')-(μ2-oxalato-O,O',O'',O''')-(μ2-piperazine-diium-1,4-diacetato-O,O')-diaqua-di-yttrium(iii)  | Y2(H2pda)(C2O4)(SO4)2(H2O)2]  | monoclinic  | C2/c | a 19.392 b 6.2757 c 16.999 β 108.279°  |  |  |  | [22]
levinsonite-(Y)  | (Y,Nd,Ce)Al(SO4)2(C2O4) · 12H2O  | monoclinic  | P2/n | a = 10.289 Å, b = 9.234, c = 11.015

β = 108.50°

| 992.4  | 2.181  | Biaxial (+) Refractive index:

nα = 1.480 nβ = 1.490 nγ = 1.550

| [23][24]
thfa = tetrahydrofurfurylamine; bis(tetrahydrofurfurylammonium) tris(μ-oxalato)-(μ-sulfato)-di-indium(iii) dihydrate  | (Hthfa)2·In2(SO4)(C2O4)3·2H2O  | monoclinic  | P21/c | a=10.7581 b=12.9985 c=19.9093 β=92.876°  |  |  |  | [8]
bapp = N,N′-bis(3-aminopropyl)piperazine  | H4bapp·[In2(SO4)3(C2O4)2(H2O)2]·H2O  | monoclinic  | I2/a | a=13.8931 b=14.6792 c=15.2418 β=111.153°  |  |  |  | [10]
bis(1-ethylpiperazinedi-ium) tris(μ-oxalato)-bis(sulfato)-di-indium  | H2epip·[In2(SO4)2(C2O4)3]  | tetragonal  | I41/a | a=26.0767 c=8.9467  |  |  | colourless  | [17]
Piperazinediium bis(μ2-oxalato-O,O',O'',O''')-bis(μ2-sulfato-O,O')-diaqua-di-indium dihydrate  | [C4N2H12]0.5InSO4C2O4·2H2O  | monoclinic  | P21/c | a=6.478 b=11.067 c=14.317 β=100.302°  |  |  |  | [25]
| Hgly·In(SO4)(C2O4)(gly)  | monoclinic  | P21 | a 6.5179(2)Å b 10.9928(3)Å c 18.0301(6)Å, α 90° β 93.9700(10)°  |  |  |  | [19]
| CsMn(SO4)(C2O4)0.5·H2O  | monoclinic  | P21/c | a = 8.065, b = 9.610, c = 9.219, β = 94.564°, Z = 4  |  |  |  | [20]
| CsFe(SO4)(C2O4)0.5·H2O  | monoclinic  | P21/c | a = 7.9377, b = 9.5757, c = 9.1474, β = 96.104°, Z = 4  |  |  |  | [20]
| La2(C2O4)(SO4)2(H2O)3 | monoclinic  | P21/n | a=9.838 b=9.817 c=13.111 β=104.258°  |  |  |  | [26]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-lanthanum diammonium  | [NH4][La(H2O)(SO4)(C2O4)]  | monoclinic  | P21/n | a=6.629 b=8.673 c=13.867 β=93.35°  |  |  |  | [21]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-cerium(iii) dihydrate  | Ce2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O  | monoclinic  | C2/c | a 19.353 b 6.836 c 16.400 β 94.312°  |  |  |  | [22]
coskrenite-(Ce)  | (Ce,Nd,La)2(C2O4)(SO4)2 · 12H2O  | triclinic  |  | a = 6.007(1) Å, b = 8.368(2) Å, c = 9.189(2) Å

α = 99.90(2)°, β = 105.55(2)°, γ = 107.71(2)°

|  | 2.881  | Biaxial (-) refractive indices: nα = 1.544 nβ = 1.578 nγ = 1.602; Birefringence: δ = 0.058  | [27][28]
zugshunstite-(Ce)  | (Ce,Nd,La)Al(SO4)2(C2O4) · 12H2O  | Monoclinic  | C2/c | a = 8.718 b = 18.313 c = 13.128

β = 93.90°

| 2091  | 2.121  | Large REE; pink in incandescent light; blue in fluorescent light; Biaxial (+) refractive index: nα = 1.455 nβ = 1.485 nγ = 1.528;  | [29][24]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-praseodymium(iii) dihydrate  | Pr2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O  | monoclinic  | C2/c | a 19.295 b 6.8100 c 16.377 β 94.369°  |  |  |  | [22]
heptakis(μ-oxalato)-bis(μ-sulfato)-tetradecaaqua-hexa-neodymium dihydrate  | Nd6(SO4)2(C2O4)7(H2O)14·H2O  | triclinic  | P1 | a=6.0817 b=11.8807 c=16.0749 α=73.230° β=80.873° γ=88.976°  |  |  |  | [30]
N,N'-dimethylethane-1,2-diaminium tetrakis(μ-sulfato)-tris(μ-oxalato)-octaaqua-tetra-neodymium  | [C4H14N2]·Nd4(SO4)4(C2O4)3(H2O)8 | triclinic  | P1 | a=7.0649 b=11.2771 c=11.8318 α=67.370° β=80.035° γ=82.821°  |  |  |  | [30]
bis(μ3-Sulfato-O,O,O',O'',O''')-(μ2-oxalato-O,O',O'',O''')-(μ2-piperazine-diium-1,4-diacetato-O,O')-diaqua-di-neodymium(iii)  | Nd2(H2pda)(C2O4)(SO4)2(H2O)2]  | monoclinic  | C2/c | a=19.702 b=6.348 c=17.352 β=109.973°  |  |  |  | [22]
bis(1,4-Diazoniabicyclo[2.2.2]octane) tetrakis(μ2-oxalato-O,O',O'',O''')-tetrakis(μ2-sulfato-O,O',O'')-octa-aqua-tetra-neodymium(iii) dihydrate  | [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O  | monoclinic  | P21/c | a=8.523 b=28.628 c=9.306 β=96.497°  |  |  |  | [31]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-europium(iii) dihydrate  | Eu2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O  | monoclinic  | C2/c | a=19.143 b=6.722 c=16.323 β=94.58°  |  |  |  | [22]
(μ5-Oxalato)-(μ3-sulfato)-(μ2-aqua)-aqua-europium-silver  | AgEu(μ5-C2O4)(SO4)(H2O)2 | monoclinic  | P21/c | a=6.627 b=13.848 c=8.983 β=96.985°  |  |  |  | [32]
tetrakis(μ2-oxalato)-bis(μ2-sulfato)-dodeca-aqua-tetra-erbium monohydrate  | Er4(SO4)2(C2O4)4(H2O)12·H2O  | monoclinic  | P21/c | a=10.5598 b=12.8404 c=12.0835 β=93.327°  |  |  |  | [30]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-samarium diammonium  | [NH4][Sm(H2O)(SO4)(C2O4)]  | monoclinic  | P21/n | a=6.619 b=8.660 c=13.853 β=93.30°  |  |  |  | [21]
(μ5-Oxalato)-(μ3-sulfato)-(μ2-aqua)-aqua-samarium-silver  | AgSm(μ5-C2O4)(SO4)(H2O)2 | monoclinic  | P21/c | a=6.630 b=13.829 c=9.001 β=97.128°  |  |  |  | [32]
| (NH4)[Gd(C2O4)(SO4)(H2O)]  |  |  |  |  |  | large magnetocaloric effect | [33]
| K[Gd(C2O4)(SO4)(H2O)]  | monoclinic  | P21/c | a = 6.5849 b = 8.5660 c = 14.7660(2) Å, β = 112.470° Z=4  | 769.66  | 3.439  | colourless  | [34]
potassium aquaterbium(III) oxalate sulfate  | KTb(C2O4)(SO4)(H2O)  | monoclinic  |  | a = 6.527 b = 8.507 c = 14.591 β = 112.65° Z=4  | 747.7  |  | at 113K; colourless  | [35]
(μ6-Oxalato)-(μ4-oxalato)-bis(μ3-sulfato)-diaqua-di-silver-di-terbium  | AgTb(μ4-C2O4)0.5(μ6-C2O4)0.5(SO4)(H2O)  | monoclinic  | C2/m | a=13.693 b=6.889 c=9.0885 β=116.73°  |  |  |  | [32]
(μ6-Oxalato)-(μ4-oxalato)-bis(μ3-sulfato)-diaqua-di-dysprosium-di-silver  | AgDy(μ4-C2O4)0.5(μ6-C2O4)0.5(SO4)(H2O)  | monoclinic  | C2/m | a=13.683 b=6.881 c=9.080 β=116.731°  |  |  |  | [32]
bis(1-ethyl-3-methyl-1H-imidazol-3-ium) (μ-oxalato)-bis(μ-sulfato)-tetraoxo-di-uranium monohydrate  |  | monoclinic  | P21/c | a=11.579 b=17.312 c=13.694 β=108.178°  |  |  | yellow  | [36]
| (NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2]⋅6H2O  | orthorhombic  | Pbam | a = 12.0177 b = 18.6182 c = 6.757 Z=2  |  |  |  | [37]
Tetrapotassium bis(μ2-oxalato)-tetraoxo-bis(sulfato)-di-uranium(vi) hexahydrate  | K2[UO2(C2O4)SO4] · 3H2O  | triclinic  | P1 | a=5.743 b=9.544 c=11.845 α=89.49° β=84.95° γ=83.01°  |  |  |  | [38]
| K4[(UO2)2C2O4(SO4)2(NCS)2]  | orthorhombic  | Pbam | a = 11.5548 b = 7.0847 c = 13.5172 β = 93.130° Z=2  | 1104.90  |  |  | [39]
Di-rubidium dioxo-(oxalato-O,O')-(μ3-sulfato)-uranium monohydrate  | Rb2[UO2SO4(C2O4)] · H2O  | orthorhombic  | Pna21 | a=9.720 b=17.037 c=6.852  |  |  |  | [38][40]
| Rb4[(UO2)2C2O4(SO4)2(NCS)2]  | orthorhombic  | Pbam | a = 11.5854 b = 7.3841 c = 13.9072 β = 95.754 V = Z=2  | 1183.7  |  |  | [39]
| Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] · 4H2O  | orthorhombic  | Pbam | a = 11.6539 b = 18.379 c = 6.7216 Z=2  |  |  |  | [37]
Tetracesium dioxo-bis(oxalato-O,O')-(sulfato-O)-uranium(vi) hydrate  | Cs4[UO2(C2O4)2SO4] · 2.7H2O  | orthorhombic  | Pbca | a=9.546 b=21.119 c=21.499  |  |  |  | [38]

## References

1. ↑ Tiwari, Ranjay K.; Kumar, Jitendra; Behera, J. N. (2017). "Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures" (in en). Dalton Transactions 46 (45): 15939–15946. doi:10.1039/C7DT03073H. ISSN 1477-9226. PMID 29119180. http://xlink.rsc.org/?DOI=C7DT03073H.
2. ↑ Medrish, I. V.; Peresypkina, E. V.; Virovets, A. V.; Serezhkina, L. B. (August 2008). "Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4) · 1.33H2O"] (in en). Russian Journal of Coordination Chemistry 34 (8): 629–634. doi:10.1134/S1070328408080125. ISSN 1070-3284. http://link.springer.com/10.1134/S1070328408080125.
3. ↑ 3.0 3.1 3.2 3.3 Yadav, Harsh; Sinha, Nidhi; Kumar, Binay (April 2015). "Growth and characterization of new semiorganic nonlinear optical and piezoelectric lithium sulfate monohydrate oxalate single crystals" (in en). Materials Research Bulletin 64: 194–199. doi:10.1016/j.materresbull.2014.12.065. https://linkinghub.elsevier.com/retrieve/pii/S0025540814008228.
4. ↑ 4.0 4.1 4.2 4.3 Wen, Xuemei; Long, Ying; Luo, Daibing; Huang, Ling; Zeng, Hongmei; Wang, Xin; Zou, Guohong; Lin, Zhien (2023-04-24). "Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route" (in en). Inorganic Chemistry 62 (16): 6202–6206. doi:10.1021/acs.inorgchem.3c00412. ISSN 0020-1669. PMID 37027523. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c00412.
5. ↑ Punniyamoorthy, R.; Manimekalai, R.; Uma, K.; Pasupathi, G. (March 2019). "Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals" (in en). Crystal Research and Technology 54 (3): 1800203. doi:10.1002/crat.201800203. https://onlinelibrary.wiley.com/doi/10.1002/crat.201800203.
6. ↑ 6.0 6.1 Zhang, Ying; Lin, Longzhen; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (August 2019). "Organically templated metal sulfate-oxalates: Solvent-free synthesis, crystal structure, and proton conduction" (in en). Journal of Solid State Chemistry 276: 1–5. doi:10.1016/j.jssc.2019.04.031. Bibcode: 2019JSSCh.276....1Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459619302087.
7. ↑ Chen, Xu-Fang; Liu, Li; Ma, Jian-Gong; Yi, Long; Cheng, Peng; Liao, Dai-Zheng; Yan, Shi-Ping; Jiang, Zong-Hui (August 2005). "Synthesis, reaction and structure of a series of chromium(III) complexes containing oxalate ligand" (in en). Journal of Molecular Structure 750 (1–3): 94–100. doi:10.1016/j.molstruc.2005.04.020. Bibcode: 2005JMoSt.750...94C. https://linkinghub.elsevier.com/retrieve/pii/S0022286005003170.
8. ↑ 8.0 8.1 Li, Ting; Chen, Cheng; Guo, Furong; Li, Jing; Zeng, Hongmei; Lin, Zhien (July 2018). "Extra-large-pore metal sulfate-oxalates with diamondoid and zeolitic frameworks" (in en). Inorganic Chemistry Communications 93: 33–36. doi:10.1016/j.inoche.2018.05.003. https://linkinghub.elsevier.com/retrieve/pii/S1387700318302673.
9. ↑ 9.0 9.1 9.2 Shi, Jingyu; Guo, Furong; Yang, Meng; Zeng, Hongmei; Lin, Zhien (January 2018). "Solvent-free synthesis of three layered manganese sulfate-oxalates with different pore apertures" (in en). Solid State Sciences 75: 77–81. doi:10.1016/j.solidstatesciences.2017.07.011. Bibcode: 2018SSSci..75...77S. https://linkinghub.elsevier.com/retrieve/pii/S1293255816310159.
10. ↑ 10.0 10.1 Guo, Caihong; Chen, Cheng; Wang, Kangcai; Zeng, Hongmei; Lin, Zhien (November 2017). "Solvent-free synthesis of open-framework metal sulfate oxalates with dia and ths topologies" (in en). Inorganic Chemistry Communications 85: 96–99. doi:10.1016/j.inoche.2017.07.007. https://linkinghub.elsevier.com/retrieve/pii/S1387700317303970.
11. ↑ 11.0 11.1 11.2 Guo, Furong; Xiao, Kang; Yang, Meng; Luan, Lindong; Lin, Zhien (January 2016). "Solvent-free synthesis of new metal sulfate–oxalates containing chain-like building blocks" (in en). Inorganic Chemistry Communications 63: 20–23. doi:10.1016/j.inoche.2015.11.005. https://linkinghub.elsevier.com/retrieve/pii/S1387700315301337.
12. ↑ Song, Tianyi; Yao, Wenjiao; Kiadkhunthod, Pinit; Zheng, Yongping; Wu, Nanzhong; Zhou, Xiaolong; Tunmee, Sarayut; Sattayaporn, Suchinda et al. (2020-01-07). "A Low‐Cost and Environmentally Friendly Mixed Polyanionic Cathode for Sodium‐Ion Storage" (in en). Angewandte Chemie International Edition 59 (2): 740–745. doi:10.1002/anie.201912272. ISSN 1433-7851. PMID 31591806. https://onlinelibrary.wiley.com/doi/10.1002/anie.201912272.
13. ↑ 13.0 13.1 13.2 Cheng, Fang-Fang; Zhu, Jian-Nan; Zhao, Ming-Yu; Ma, Zhong-Jie; Xiong, Wei-Wei (October 2019). "Preparing transition metal-organic frameworks based on oxalate-sulfate anions in deep eutectic solvents" (in en). Journal of Solid State Chemistry 278: 120904. doi:10.1016/j.jssc.2019.120904. Bibcode: 2019JSSCh.27820904C. https://linkinghub.elsevier.com/retrieve/pii/S0022459619304050.
14. ↑ Gibbs, Wolcott (1875). "Researches on the Hexatomic Compounds of Cobalt (Continued)" (in en). Proceedings of the American Academy of Arts and Sciences 11: 1–51. doi:10.2307/20021454. https://www.jstor.org/stable/20021454.
15. ↑ 15.0 15.1 Schramm, Walter (1929-04-08). "Die Einwirkung von Oxalsäure und Malonsäure auf die Tetrammin-kobaltikomplexe und ihre Analogen" (in en). Zeitschrift für anorganische und allgemeine Chemie 180 (1): 161–183. doi:10.1002/zaac.19291800119. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19291800119.
16. ↑ 16.0 16.1 Wang, Kangcai; Luo, Daibing; Xu, Dingguo; Guo, Furong; Liu, Lin; Lin, Zhien (2014). "New open-framework cobalt sulfate-oxalates based on molecular and chain-like building blocks" (in en). Dalton Trans. 43 (36): 13476–13479. doi:10.1039/C4DT01503G. ISSN 1477-9226. PMID 25110964. http://xlink.rsc.org/?DOI=C4DT01503G.
17. ↑ 17.0 17.1 17.2 Guo, Furong; Chen, Cheng; Wang, Kangcai; Zhang, Qinghua; Lin, Zhien (2016-08-15). "Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates" (in en). Inorganic Chemistry 55 (16): 7817–7819. doi:10.1021/acs.inorgchem.6b01341. ISSN 0020-1669. PMID 27454425. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01341.
18. ↑ Belombe, Michel M.; Nenwa, Justin; Bebga, Gouet; Fokwa, Boniface P. T.; Dronskowski, Richard (2007-08-15). "Bis[tris(oxamide dioxime-κ 2 N , N ′)cobalt(III) oxalate bis(sulfate) dodecahydrate"]. Acta Crystallographica Section E 63 (8): m2037–m2038. doi:10.1107/S1600536807031169. ISSN 1600-5368. https://scripts.iucr.org/cgi-bin/paper?S1600536807031169.
19. ↑ 19.0 19.1 Li, Ying; Luo, Miao; Long, Ying; Huang, Ling; Gao, Daojiang; Zou, Guohong; Lin, Zhien; Zhao, Yan (2023-05-24). "Host–Guest Symmetry and Charge Matching in Glycine-Templated Metal Sulfate–Oxalates Obtained by a Solvent-Free Method" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c01469. ISSN 0020-1669. PMID 37222550. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01469.
20. ↑ 20.0 20.1 20.2 Becker, G.; Eschbach, B.; Mundt, O.; Reti, M.; Niecke, E.; Issberner, K.; Nieger, M.; Thelen, V. et al. (1998). "Bis(1,2-dimethoxyethan-O,O′)lithium-phosphanid, -arsanid und -chlorid – drei neue Vertreter des Bis(1,2-dimethoxyethan-O,O′)lithium-bromid-Typs". Zeitschrift für Anorganische und Allgemeine Chemie 624 (3): 469–482. doi:10.1002/(SICI)1521-3749(199803)624:3<469::AID-ZAAC469>3.0.CO;2-F.
21. ↑ 21.0 21.1 21.2 Li, Li; Yu, Ranbo; Wang, Dan; Lai, Xiaoyong; Mao, Dan; Yang, Mei (July 2010). "Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate–oxalates" (in en). Inorganic Chemistry Communications 13 (7): 831–833. doi:10.1016/j.inoche.2010.04.004. https://linkinghub.elsevier.com/retrieve/pii/S1387700310001425.
22. ↑ 22.0 22.1 22.2 22.3 22.4 Yang, Juan; Lu, Ning; Zhang, Gong; Cheng, Lin; Gou, Shao-Hua (June 2008). "The first hybrid organic–inorganic frameworks based on lanthanide(III) sulfate chains, in situ generated oxalate and organic pillars of 1,4-piperazinediacetic acid" (in en). Polyhedron 27 (9–10): 2119–2126. doi:10.1016/j.poly.2008.04.003. https://linkinghub.elsevier.com/retrieve/pii/S0277538708001940.
23. ↑ "Levinsonite-(Y)". https://www.mindat.org/min-7024.html.
24. ↑ 24.0 24.1 Rouse, R.C.; Peacor, D.R.; Essene, E.J.; Coskren, T.D.; Lauf, R.J. (April 2001). "The new minerals levinsonite-(Y) [(Y, Nd,Ce)Al(SO4)2(C2O4) · 12H2O and zugshunstite-(Ce) [(Ce,Nd,La)Al(SO4)2(C2O4) · 12H2O]: Coexisting oxalates with different structures and differentiation of LREE and HREE>"] (in en). Geochimica et Cosmochimica Acta 65 (7): 1101–1115. doi:10.1016/S0016-7037(00)00568-8. Bibcode: 2001GeCoA..65.1101R. https://linkinghub.elsevier.com/retrieve/pii/S0016703700005688.
25. ↑ Ramaswamy, Padmini; Hegde, Nayana N.; Prabhu, Ramanath; Vidya, V. M.; Datta, Ayan; Natarajan, Srinivasan (2009-12-21). "Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium" (in en). Inorganic Chemistry 48 (24): 11697–11711. doi:10.1021/ic901744m. ISSN 0020-1669. PMID 19911816. https://pubs.acs.org/doi/10.1021/ic901744m.
26. ↑ Yuan, Yan-Ping; Song, Jun-Ling; Mao, Jiang-Gao (January 2004). "Hydrothermal synthesis, crystal structure and characterizations of a lanthanum(III) sulfate oxalate with a 3D network structure" (in en). Inorganic Chemistry Communications 7 (1): 24–26. doi:10.1016/j.inoche.2003.09.018. https://linkinghub.elsevier.com/retrieve/pii/S1387700303003319.
27. ↑ "Coskrenite-(Ce)". https://www.mindat.org/min-6890.html.
28. ↑ Alpers, Charles N.; Jambor, John L.; Nordstrom, D. (17 December 2018) (in en). Sulfate Minerals: Crystallography, Geochemistry, and Environmental Significance. Walter de Gruyter GmbH & Co KG. pp. 89–90. ISBN 978-1-5015-0866-0. https://books.google.com/books?id=ya96DwAAQBAJ&dq="sulfate+oxalate"+crystal&pg=PA89.
29. ↑ "Zugshunstite-(Ce)". https://www.mindat.org/min-7023.html.
30. ↑ 30.0 30.1 30.2 Wang, Kangcai; Wang, Yu; Xu, Dingguo; Luo, Daibing; Lin, Zhien (October 2013). "New lanthanide sulfate–oxalate hybrid solids containing different inorganic building blocks" (in en). Inorganic Chemistry Communications 36: 146–149. doi:10.1016/j.inoche.2013.08.040. https://linkinghub.elsevier.com/retrieve/pii/S1387700313003511.
31. ↑ Xu, Ning; Xing, Yan; Liu, Xianchun; Song, Danhui; Ma, Ling; Sun, Xiujuan (March 2009). "Synthesis, Structure and Photoluminescent Properties of [C 6 N 2 H 14 [Nd 2 (C 2 O 4 ) 2 (SO 4 ) 2 (H 2 O) 4 ]·H 2 O, a New Organically Templated Neodymium(III) Oxalate-sulfate"] (in en). Zeitschrift für anorganische und allgemeine Chemie 635 (3): 558–562. doi:10.1002/zaac.200801309. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200801309.
32. ↑ 32.0 32.1 32.2 32.3 Xiao, Xueying; Wei, Yongqin; Zheng, Wenxu; Wu, Kechen (May 2011). "Organic-inorganic Hybrid Lanthanide-Silver Heterometallic Coordination Frameworks Constructed from Oxalate and Sulfate Anion: Syntheses, Structures, and Photoluminescent Properties" (in en). Zeitschrift für anorganische und allgemeine Chemie 637 (6): 741–747. doi:10.1002/zaac.201000427. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201000427.
33. ↑ Li, Jin-Hua; Liu, Ai-Ju; Ma, Yu-Juan; Han, Song-De; Hu, Ji-Xiang; Wang, Guo-Ming (2019). "A large magnetocaloric effect in two hybrid Gd-complexes: the synergy of inorganic and organic ligands towards excellent cryo-magnetic coolants" (in en). Journal of Materials Chemistry C 7 (21): 6352–6358. doi:10.1039/C9TC01475F. ISSN 2050-7526. http://xlink.rsc.org/?DOI=C9TC01475F.
34. ↑ Wang, Ning; Yue, Shan-Tang; Liu, Ying-Liang (2009-06-20). "One new lanthanide complex with mixed sulfate and oxalate ligands: hydrothermal synthesis, crystal structure, and magnetic properties" (in en). Journal of Coordination Chemistry 62 (12): 1914–1920. doi:10.1080/00958970902736780. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958970902736780.
35. ↑ Sun, Ya-Guang; Guo, Mei-yan; Xiong, Gang; Jiang, Bing; Wang, Lei (2009-07-15). "Potassium aquaterbium(III) oxalate sulfate". Acta Crystallographica Section E 65 (7): i48. doi:10.1107/S1600536809019679. ISSN 1600-5368. PMID 21582643. PMC 2969189. https://scripts.iucr.org/cgi-bin/paper?S1600536809019679.
36. ↑ Kohlgruber, Tsuyoshi A.; Felton, Daniel E.; Perry, Samuel N.; Oliver, Allen G.; Burns, Peter C. (2021-02-03). "Effect of Ionothermal Conditions on the Crystallization of Organically Templated Uranyl Sulfate Compounds" (in en). Crystal Growth & Design 21 (2): 861–868. doi:10.1021/acs.cgd.0c01198. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/acs.cgd.0c01198.
37. ↑ 37.0 37.1 Medrish, I. V.; Virovets, A. V.; Peresypkina, E. V.; Serezhkina, L. B. (July 2008). "Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2 · 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2] · 6H2O"] (in en). Russian Journal of Inorganic Chemistry 53 (7): 1034–1039. doi:10.1134/S0036023608070103. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023608070103.
38. ↑ 38.0 38.1 38.2 Serezhkin, V. N.; Medrish, I. V.; Serezhkina, L. B. (February 2008). "18-Electron rule and structure of uranyl sulfate complexes" (in en). Russian Journal of Coordination Chemistry 34 (2): 146–155. doi:10.1134/S1070328408020103. ISSN 1070-3284. http://link.springer.com/10.1134/S1070328408020103.
39. ↑ 39.0 39.1 Medrish, I. V.; Peresypkina, E. V.; Virovets, A. V.; Serezhkina, L. B. (May 2008). "Crystal structure of M4[(UO2)2C2O4(SO4)2(NCS)2 (M = K+, Rh+) and K4[(UO2)2C2O4(SeO4)2(NCS)2]"] (in en). Crystallography Reports 53 (3): 462–465. doi:10.1134/S1063774508030139. ISSN 1063-7745. Bibcode: 2008CryRp..53..462M. http://link.springer.com/10.1134/S1063774508030139.
40. ↑ MISTRYUKOV, V. E; MIKHAILOV, YU N.; KANISHCHEVA, A. S.; SEREZHKINA, L. B.; SEREZHKIN, V. N. (1993). "The crystal structure of Rb2UO2(SO4)C2O4.H2O". The Crystal Structure of Rb2UO2(SO4)C2O4.H2O 38 (9): 1413–1415. ISSN 0036-0236. https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3802489.

* v
* t
* e

Oxalates

* (NH4)2C2O4
* BaC2O4
* CaC2O4
* Ce2(C2O4)3
* CrC2O4
* CoC2O4
* CuC2O4
* FeC2O4
* Fe2(C2O4)3
* PbC2O4
* MgC2O4
* Ag2C2O4
* Na2C2O4
* SrC2O4
* Th(C2O4)2

* v
* t
* e

Compounds containing the sulfate group

H2SO4 |  |  |  | He

|
|
|
|

Li2SO4 | BeSO4 | B  | esters
ROSO3−
(RO)2SO2 | (NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4 | HOSO4 | F  | Ne
Na2SO4
NaHSO4 | MgSO4 | Al2(SO4)3
Al2SO4(OAc)4 | Si  | P  | SO42−
HSO3HSO4
(HSO4)2 | Cl  | Ar
K2SO4
KHSO4 | CaSO4 | Sc2(SO4)3 | TiOSO4 | VSO4
V2(SO4)3
VOSO4 | CrSO4
Cr2(SO4)3 | MnSO4 | FeSO4
Fe2(SO4)3 | CoSO4 | NiSO4 | CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4 | ZnSO4 | Ga2(SO4)3 | Ge  | As  | Se  | Br  | Kr
RbHSO4
Rb2SO4 | SrSO4 | Y2(SO4)3 | Zr(SO4)2 | Nb  | Mo  | Tc  | Ru  | Rh2(SO4)3 | PdSO4 | Ag2SO4 | CdSO4 | In2(SO4)3 | SnSO4
Sn(SO4)2 | Sb2(SO4)3 | Te  | I  | Xe
Cs2SO4
CsHSO4 | BaSO4 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | AuSO4
Au2(SO4)3 | Hg2SO4
HgSO4 | Tl2SO4
Tl2(SO4)3 | PbSO4 | Bi2(SO4)3 | Po  | At  | Rn
Fr  | Ra  |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La  | Ce2(SO4)3
Ce(SO4)2 | Pr2(SO4)3 | Nd  | Pm  | Sm  | Eu  | Gd  | Tb  | Dy  | Ho  | Er  | Tm  | Yb2(SO4)3 | Lu
Ac  | Th  | Pa  | U(SO4)2
UO2SO4 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Oxalate sulfate. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Oxalate_sulfate&oldid=2621521"
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template