Phosphate phosphite

Short description: Class of chemical compounds

A phosphate phosphite is a chemical compound or salt that contains both phosphate and phosphite anions (PO3−
4 and PO3−
3). These are mixed anion compounds or mixed valence compounds. Some have third anions.

Phosphate phosphites frequently occur as metal-organic framework compounds which are of research interest for gas storage, detection or catalysis. In these phosphate and phosphite form bridging ligands to hard metal ions. Protonated amines are templates.[1]

## Contents

* 1 Naming
* 2 Production
* 3 Related
* 4 List
* 5 References

## Naming

A phosphate phosphite compound may also be called a phosphite phosphate.

## Production

Phosphate phosphite compounds are frequently produced by hydrothermal synthesis, in which a water solution of ingredients is enclosed in a sealed container and heated. Phosphate may be reduced to phosphite or phosphite oxidised to phosphate in this process.

## Related

Related to these are the nitrite nitrates and arsenate arsenites.

## List

name  | formula  | ratio PO4:PO3 | mw | system  | space group | unit cell (Å)  | volume  | density  | properties  | references

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1,4-Diammoniumbutane  | [(H3N(CH2)4NH3)2][Sc5F4(HPO3)6(H2PO3)2(PO4)]  | 1:8  | 1300.8  | monoclinic  | C2/m | a = 12.888,
b = 14.835,
c = 10.531,
β = 103.093°,
Z = 2 (at 93 K)  | 1961.2  |  |  | [2]
Imidazole  | [C3N2H5]2[VIII4(H2O)3(HPO3)4(HPO4)3]  | 3:4  | 1003.766  | trigonal  | P3c1  | a = 13.499,
c = 18.120,
Z = 12  | 2280.35  | 2.143  | green  | [3]
| (C3H10NO)6[V8(H2O)6(PO4)2(HPO3)12]  | 2:12  |  | trigonal  | P3c1  | a = 13.5393,
c = 18.2283  | 2893.8  |  | green  | [4]
| (C4H8N2)3[V8(H2O)6(PO4)2(HPO3)12]  | 2:12  |  | trigonal  | P3c1  | a = 13.4922,
c = 18.3589  | 2894.3  |  | green  | [4]
L=cyclopentylammonium  | (L)4[V9(H2O)6(HPO3)10.5(HPO4)3.5(H2PO4)3]  |  |  | hexagonal  | P63/m | a=13.4107 c =27.5678 Z=1  | 4293.7  | 1.81  |  | [5]
| Mn5(μ-OH2)2(PO4)2(HPO3)2·2H2O  | 2:2  |  |  |  |  |  |  |  | [6]
Iron(III) 2,2′-bipyridine phosphite−phposphate  | [FeIII(2,2′-bipyridine)(HPO3)(H2PO4)]  | 1:1  |  | monoclinic  |  | a = 10.5407,
b = 6.4298,
c = 10.6172,
β = 113.890°,
Z = 2  |  | 1.878  | colourless  | [7]
| FeIII(1,10-phenanthroline)(HPO3)(H2PO3)  | 1:1  |  | monoclinic  | P21/m | a = 10.180,
b = 6.424,
c = 11.6668,
β = 115.59°,
Z = 4  | 668.2  | 1.880  | yellow  | [8]
| {[C3H4N2]2[C5NH5]14[H15(Mo2O4)8Co16(PO4)14(HPO3)10(OH)3]}·5H2O  | 14:10  | 6685.09  | monoclinic  | C2/m | a = 29.724,
b = 24.623,
c = 20.687,
β = 126.760°,
Z = 2  | 12130  | 1.830  | red  | [9]
Tris(4-pyridyl)triazine zinc phosphate–phosphite  | C54H60N18O42P10Zn9 | ?  | 2531.23  | hexagonal  | P63 | a = 15.6464,
c = 19.788,
Z = 2  | 4195.2  |  | yellow  | [10]
1-(2-Aminoethyl)piperazine tetrazinc diphosphate diphosphite  | (C6H17N3)[Zn4(PO4)2(HPO3)2]  | 2:2  |  | monoclinic  | Cc | a = 5.327,
b = 17.146,
c = 22.071,
β = 94.58°,
Z = 4  | 2009.5  |  |  | [11]
Zinc phosphate-phosphite  | trans-(C6H15N2)2Zn4(PO4)2(HPO3)2 | 2:2  | 841.78  | monoclinic  | P21/n | a = 9.706,
b = 9.993,
c = 27.557,
β = 96.795°,
Z = 4  | 2654.0  | 2.107  |  | [12]
1,3-Cyclohexanebis(methylamine)  | [H2CHBMA][Zn1.5Mn(HPO3)2.5(PO4)]·5H2O  | 1:5  |  | monoclinic  | C2/c | a = 33.929,
b = 13.045,
c = 8.971,
β = 104.37°,
Z = 2  | 3846.5  |  |  | [13]
2-Hydroxypropylammonium dizinc hydrogenphosphite phosphate  | [C3H6(OH)NH3][Zn2(HPO3)(PO4)]  | 1:1  |  | triclinic  | P1 | a = 5.302,
b = 8.934,
c = 12.686,
α = 74.35°,
β = 88.54°,
γ = 73.94°  |  |  |  | [14]

(Bis(Cyclohexane-1,3-bis(methylammonium)) bis(μ4-phosphato)-tetrakis(μ3-hydrogen phosphito)-manganese-tetra-zinc dihydrate)

| [H2CHBMA][Zn2Mn0.5(PO4)(HPO3)2]·H2O  | 1:2  |  | monoclinic  | C2/c | a = 33.929,
b = 13.045,
c = 8.971,
β = 104.37°,
Z = 4  | 3846  |  |  | [15]
Triethylenetetramine  | [C6N4H22]0.5[Zn3(PO4)2(HPO3)]  | 2:1  |  |  |  |  |  |  |  | [16]
Zinc potassium phosphite phosphate  |  |  |  |  |  |  |  |  |  | [17]
N,N,N′,N′-tetramethylenediamine (TMEDA)  | (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O  | 14:6  |  |  | P3 | a = 19.046,
c = 8.331,
Z = 1  | 2617.1  |  |  | [18]
Zirconium phosphate phosphite  | γ-ZrPO4·HPO2(OH)·2H2O  | 1:1  |  |  |  |  |  |  | layered  | [19]
Cadmium 1,10-phenanthroline phosphate phosphite oxalate  | Cd2(phen)2(H2PO4)(H2PO3)(C2O4)  | 1:1  |  |  |  |  |  |  | chains  | [20]
catena-(Tris(hexane-1,6-diaminium) octakis(μ3-phosphonato)-hexakis(μ3-phosphato)-tris(μ2-hydrogen phosphato)hexaaqua-nonaindium  | [In9(H2O)6(HPO3)13(H2PO3)2(PO4)(HPO4)][(C6N2H18)3]  | 2:15  |  | hexagonal  | P63/m | a = 13.7676,
c = 28.062  |  |  |  | [21]
4-Bipyridine  | (C10H10N2)1.5(H3O)3[In18(H2O)12(HPO4)12(HPO3)16(H2PO3)6]  | 12:16  |  | hexagonal  | P63/m | a = 13.784,
c = 28.058  | 4617  |  |  | [22]
catena-(Bis(propane-1,3-diammonium)-octakis(μ3-phosphito)-pentakis(μ2-hydrogen phosphito)-(μ2-dihydrogenphosphato)-hexaindium)  | [In6(HPO3)8(H2PO3)5(H2PO4)]·(C3N2H12)2 | 1:11  |  | orthorhombic  | Pna21 | a = 26.7974,
b = 9.8459,
c = 18.5441,
Z = 4  | 4892.8  |  |  | [23]
| Pb2Al(HPO3)3(H2PO4)  | 1:3  |  | orthorhombic  | Cmcm |  |  |  |  | [24]
| Pb2Ga(HPO3)3(H2PO4)  | 1:3  |  | orthorhombic  | Cmcm |  |  |  |  | [24]
| Pb2Al(HPO3)2(HPO4)(H2PO4)  | 2:2  |  | orthorhombic  | Cmcm |  |  |  |  | [24]
Rubidium uranium(VI,IV) phosphate-phosphite  | Rb2[(UO2)2(UIV)(PO4)2(HPO3)2(H2O)]  | 2:2  | 1316.94  | monoclinic  | C2/c | a = 16.2421,
b = 10.5049,
c = 11.0936,
β = 98.745°  | 1870.8  | 4.702  | orange-yellow  | [25]
Caesium uranium(IV) phosphate-phosphite  | Cs2[UIV3(PO4)2(HPO3)4]  | 2:4  | 1489.76  | monoclinic  | C2/m | a = 25.7396
b = 5.5906,
c = 7.6334,
β = 98.964°,
Z = 2  | 1085.03  | 4.560  | blue-green  | [25]
Caesium uranium(VI,IV) phosphate-phosphite  | Cs2[(UO2)(UIV)(HPO4)2(HPO3)2]  | 2:2  | 1123.78  | triclinic  | P1 | a = 6.8571,
b = 11.1190,
c = 12.0391,
α = 63.861°,
β = 77.481°,
γ = 79.331°,
Z = 2  | 800.22  | 4.664  | yellow-orange  | [25]
| Cs4[(UO2)8(HPO4)5(HPO3)5]·4H2O  | 5:5  |  | monoclinic  | C2/c | a = 18.5005,
b = 10.971,
c = 14.4752,
β = 104.513°  |  |  | yellow  | [26]
| Cs4[UIV6(PO4)8(HPO4)(HPO3)]  | 9:1  |  | orthorhombic  | Pmmn | a = 6.9321,
b = 26.935,
c = 10.9137  |  |  | pale green  | [26]
| Cs10[UIV10(PO4)4(HPO4)14(HPO3)5]·H2O  | 15:5  |  | monoclinic  | C2/m | a = 19.2966,
b = 20.2914,
c = 13.9293,
β = 126.839°  |  |  | green  | [26]
| Tl3[(UO2)2(H1.5PO4)(H0.5PO4)(H1.5PO3)2]  | 2:2  | 1503.07  | tetragonal  | P42/mbc | a = 13.5382,
c = 19.4008,
Z = 8  | 3555.8  | 5.615  | yellow-green  | [27]
| Tl2[(UO2)2(UIV)(H2O)(PO4)2(HPO3)2]  | 2:2  | 1550.71  | monoclinic  | C2/c | a = 16.2360,
b = 10.4995,
c = 11.0003,
β = 99.027°,
Z = 4  | 1851.99  | 5.562  | light green  | [27]

## References

1. ↑ Petrosyants, S. P. (December 2013). "Coordination polymers of indium, scandium, and yttrium" (in en). Russian Journal of Inorganic Chemistry 58 (13): 1605–1624. doi:10.1134/S0036023613130032. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023613130032.
2. ↑ Miller, Stuart R. (2007-12-17). Scandium bearing open framework materials (Thesis thesis). University of St Andrews. hdl:10023/570.
3. ↑ Ramaswamy, Padmini; Mandal, Sukhendu; Hegde, Nayana N; Prabhu, Ramanath; Banerjee, Debmalya; Bhat, S. V.; Natarajan, Srinivasan (April 2010). "Synthesis, Structure, and Magnetic Properties of Amine-Templated Transition-Metal Phosphites" (in en). European Journal of Inorganic Chemistry 2010 (12): 1829–1838. doi:10.1002/ejic.200901206. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200901206.
4. ↑ 4.0 4.1 曉文, 鄭 (18 July 1991). "亞磷酸釩及磷酸鉬的合成,結構鑑定及性質研究". p. 28. http://ir.lib.ncu.edu.tw:88/thesis/pdf/2002/GC89223009.pdf.
5. ↑ Orive, Joseba; Larrea, Edurne S.; Fernández de Luis, Roberto; Iglesias, Marta; Mesa, José L.; Rojo, Teófilo; Arriortua, María I. (2013). "Amine templated open-framework vanadium(iii) phosphites with catalytic properties" (in en). Dalton Transactions 42 (13): 4500. doi:10.1039/c2dt32286b. ISSN 1477-9226. https://xlink.rsc.org/?DOI=c2dt32286b.
6. ↑ "Mn（II）取代磷酸铝和磷酸锰微孔化合物的水热合成与表征--《吉林大学》2005年博士论文". https://cdmd.cnki.com.cn/Article/CDMD-10183-2005107315.htm.
7. ↑ Mandal, Sukhendu; Pati, Swapan K.; Green, Mark A.; Natarajan, Srinivasan (February 2005). "The First One-Dimensional Iron Phosphite−Phosphate, [FeIII(2,2′-bipyridine)(HPO3)(H2PO4): Synthesis, Structure, and Magnetic Properties"] (in en). Chemistry of Materials 17 (3): 638–643. doi:10.1021/cm049064p. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm049064p.
8. ↑ Mandal, Sukhendu; Green, Mark A.; Natarajan, Srinivasan (2005-12-10). "Synthesis, structure and magnetic properties of a new one-dimensional iron phosphite, [FeIII(1,10-phenanthroline)(HPO3)(H2PO3)"] (in en). Current Science 89 (11): 1899–1903. ISSN 0011-3891. http://www.ias.ac.in/currsci/dec102005/1899.pdf.
9. ↑ Miao, Hao; Wan, Hong-Xiang; Liu, Ming; Zhang, Yu; Xu, Xiao; Ju, Wei-Wei; Zhu, Dun-ru; Xu, Yan (2014). "Two novel organic–inorganic hybrid molybdenum(V) cobalt/nickel phosphate compounds based on isolated nanosized Mo/Co(Ni)/P cluster wheels" (in en). J. Mater. Chem. C 2 (32): 6554–6560. doi:10.1039/C4TC00944D. ISSN 2050-7526. http://xlink.rsc.org/?DOI=C4TC00944D.
10. ↑ Zhang, Jie; Yao, Zhenguo; Liao, Shijun; Dai, Jingcao; Fu, Zhiyong (2013). "A hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties" (in en). Journal of Materials Chemistry A 1 (16): 4945. doi:10.1039/c3ta10478h. ISSN 2050-7488. http://xlink.rsc.org/?DOI=c3ta10478h.
11. ↑ Chen, Xiaoxin; Wang, Yu; Yu, Jihong; Zou, Yongchun; Xu, Ruren (July 2004). "(C6H17N3)[Zn4(PO4)2(HPO3)2: a new layered zinc phosphate–phosphite templated by 1-(2-Aminoethyl) piperazine"] (in en). Journal of Solid State Chemistry 177 (7): 2518–2522. doi:10.1016/j.jssc.2004.03.039. Bibcode: 2004JSSCh.177.2518C. https://linkinghub.elsevier.com/retrieve/pii/S0022459604001458.
12. ↑ Wang, Yu; Yu, Jihong; Du, Yu; Shi, Zhan; Zou, Yongcun; Xu, Ruren (2002). "Hydrothermal synthesis and characterization of a new inorganic–organic hybrid layered zinc phosphate–phosphite (C6H15N2)2Zn4(PO4)2(HPO3)2" (in en). J. Chem. Soc., Dalton Trans. (21): 4060–4063. doi:10.1039/B204876K. ISSN 1472-7773. http://xlink.rsc.org/?DOI=B204876K.
13. ↑ "Synthesis and Structure of Manganese Zinc Phosphate-phosphite with Extra Large Twenty-membered Ring Channels–《Chemical Journal of Chinese Universities》2007年12期". https://en.cnki.com.cn/Article_en/CJFDTotal-GDXH200712007.htm.
14. ↑ Fu, Zhiyong; Zhang, Jie; Tan, Yi; Song, Desheng; Liu, Changchun; Wu, Jiaqi (2011-11-10). "Synthesis, structure, and base-catalytic performance of a laminar zinc phosphite-phosphate" (in en). Journal of Coordination Chemistry 64 (21): 3808–3816. doi:10.1080/00958972.2011.631533. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958972.2011.631533.
15. ↑ Chen, Guangyan; Su, Hao; Yu, Jianguo; Yang, Yang; Zhao, Yongnan; Fu, Zhifeng (July 2009). "Separation of 1,3-Cyclohexanebis(methylamine) Isomers by Template Synthesis of Open-Framework Bimetallic Phosphites" (in en). Zeitschrift für anorganische und allgemeine Chemie 635 (9–10): 1463–1469. doi:10.1002/zaac.200801317.
16. ↑ Rao, C. N. R. (2003-09-12) (in en). Advances In Chemistry: A Selection Of C N R Rao's Publications (1994–2003). World Scientific. pp. 478. ISBN 978-981-4485-05-0. https://books.google.com/books?id=cRTJCgAAQBAJ&pg=PA478.
17. ↑ "Studies on polymerization of zinc potassium phosphite-phosphate the non-toxic anticorrosive pigment--《JOURNAL OF SHANTOU UNIVERSITY(NATURAL SCIENCE EDITION)》1995年01期". https://en.cnki.com.cn/Article_en/CJFDTotal-STDX501.008.htm.
18. ↑ Zhou, Guangpeng; Yang, Yulin; Fan, Ruiqing; Liu, Xinrong; Hong, Hengwu; Wang, Fuping (July 2010). "Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate–phosphite (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O" (in en). Solid State Sciences 12 (7): 1103–1106. doi:10.1016/j.solidstatesciences.2010.04.013. Bibcode: 2010SSSci..12.1103Z. https://linkinghub.elsevier.com/retrieve/pii/S1293255810001664.
19. ↑ Alberti, G.; Costantino, U.; Vivani, R.; Biswas, R.K. (June 1992). "Preparation and some preliminary investigations of ion exchange and intercalation properties of γ-zirconium phosphate phosphite" (in en). Reactive Polymers 17 (3): 245–253. doi:10.1016/0923-1137(92)90271-3. https://linkinghub.elsevier.com/retrieve/pii/0923113792902713.
20. ↑ Li, Jing; Li, Ting; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (September 2018). "Solvent-free synthesis of inorganic-organic hybrid solids with chainlike, layered, and open-framework structures" (in en). Inorganic Chemistry Communications 95: 8–11. doi:10.1016/j.inoche.2018.06.022. https://linkinghub.elsevier.com/retrieve/pii/S1387700318304623.
21. ↑ Dong, Zhaojun; Yan, Yan; Li, Yi; Li, Jiyang; Yu, Jihong; Xu, Ruren (May 2011). "A new open-framework indium phosphate–phosphite containing intersecting extra-large 16-ring channels" (in en). Inorganic Chemistry Communications 14 (5): 727–730. doi:10.1016/j.inoche.2011.02.019. https://linkinghub.elsevier.com/retrieve/pii/S1387700311000943.
22. ↑ Li, Hui Duan (June 2014). "Construction of a Novel 3D Indium Phosphate–Phosphite with Extra-Large 16-MRs Channels: Synthesis, Structure and Fluorescence Property". Advanced Materials Research 936: 901–904. doi:10.4028/www.scientific.net/AMR.936.901. ISSN 1662-8985. https://www.scientific.net/AMR.936.901.
23. ↑ Huang, Liangliang; Song, Tianyou; Fan, Yong; Yang, Lei; Wang, Liping; Zhang, Hua; Wang, Li; Xu, Jianing (August 2010). "Hydrothermal syntheses, characterizations of novel three-dimensional indium phosphite and indium phosphite–phosphate with intersecting 8-membered ring channels: [In3(H2PO3)3(HPO3)4·(trans-C6N2H16) and [In6(HPO3)8(H2PO3)5(H2PO4)]·(C3N2H12)2"] (in en). Microporous and Mesoporous Materials 132 (3): 409–413. doi:10.1016/j.micromeso.2010.03.020. https://linkinghub.elsevier.com/retrieve/pii/S1387181110000892.
24. ↑ 24.0 24.1 24.2 李, 天予 (2020-07-17). "含鉛離子和三價金屬陽離子之混亞磷酸 -磷酸鹽化合物合成及結構和性質探討". http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=107223037.
25. ↑ 25.0 25.1 25.2 Villa, Eric M.; Marr, Connor J.; Jouffret, Laurent J.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-06-18). "Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates" (in en). Inorganic Chemistry 51 (12): 6548–6558. doi:10.1021/ic3000735. ISSN 0020-1669. PMID 22646238. https://pubs.acs.org/doi/10.1021/ic3000735.
26. ↑ 26.0 26.1 26.2 Villa, Eric M.; Marr, Connor J.; Diwu, Juan; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-01-18). "From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates" (in en). Inorganic Chemistry 52 (2): 965–973. doi:10.1021/ic302198w. ISSN 0020-1669. PMID 23301654. https://pubs.acs.org/doi/10.1021/ic302198w.
27. ↑ 27.0 27.1 Villa, Eric M.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-04-03). "Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate" (in en). Crystal Growth & Design 13 (4): 1721–1729. doi:10.1021/cg400046a. ISSN 1528-7483. Bibcode: 2013CrGrD..13.1721V. https://pubs.acs.org/doi/10.1021/cg400046a.

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Phosphates

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Li3PO4 | Be |  |  |  |  |  |  |  |  |  |  | BPO4 | C | (NH4)3PO4 | O | F | Ne
Na3PO4 | Mg3(PO4)2 |  |  |  |  |  |  |  |  |  |  | AlPO4 | Si | P | S | Cl | Ar
K3PO4 | Ca3(PO4)2 | ScPO4 | Ti | V | Cr | Mn3(PO4)2 | Fe3(PO4)2
FePO4 | Co3(PO4)2 | Ni3(PO4)2 | Cu3(PO4)2 | Zn3(PO4)2 | GaPO4 | Ge | As | Se | Br | Kr
Rb3PO4 | Sr3(PO4)2 | YPO4 | Zr3(PO4)4 | Nb | Mo | Tc | Ru | Rh | Pd | Ag3PO4 | Cd3(PO4)2 | InPO4 | Sn | Sb | Te | I | Xe
Cs3PO4 | Ba3(PO4)2 | *  | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl3PO4 | Pb3(PO4)2 | BiPO4 | Po | At | Rn
Fr | Ra | **  | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og |  |  |  |  |  |  |  |
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | LaPO4 | CePO4 | PrPO4 | NdPO4 | Pm | Sm | Eu | Gd | Tb | Dy | Ho | ErPO4 | TmPO4 | Yb | Lu |
| ** | Ac | Th3(PO4)4 | Pa | U(PO4)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |

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