Nitrate nitrite

Short description: Class of chemical compounds

A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO−
2) and nitrate (NO−
3) anions. They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.[citation needed]

## Contents

* 1 Production
* 2 Properties
* 3 Related
* 4 List
* 5 References

## Production

Mercury(II) nitrate and potassium nitrate in water solution produce the salt tripotassium tetranitratomercurate(II) nitrate K
3[Hg(NO

4]NO
3.[1]

## Properties

On heating, nitrate nitrites lose NO2 and NO and yield metal oxides.

## Related

Other compounds having an element in two different anion states include the sulfate sulfites, the phosphate phosphites, arsenate arsenites and the selenate selenites.

## List

name  | formula  | ratio

NO3:NO2

| mw | system  | space group | unit cell Å  | volume  | density  | properties  | references

|
|
|
|
|
|
|
|
|
|

| [Cr(NH3)5(NO2)] ·(NO3)2 |  |  |  |  |  |  |  |  | [2]
trans-dinitrotetraamminecobalt(III) nitrate monohydrate  | [Co(NO2)2(NH3)4]NO3•H2O  | 1:2  |  | orthorhombic  | P212121 | a=10.02, b=6.02, c=16.84, Z=4  |  | 1.84  |  | [3]
cis-dinitrotetraamminecobalt(III) nitrate  | [Co(NO2)2(NH3)4]NO3 | 1:2  |  | orthorhombic  | P212121 | a=12.19, b=7.18, c=10.92, Z=4  |  | 1.95  |  | [4]
| [cis-β-Co(trien)(NO2)2]NO3 | 1:2  |  | monoclinic  | P21/n | a = 7.604, b = 13.019, c = 14.472, β = 98.13°, Z = 4  | 1418.26  | 1.682  | racemate  | [5]
| [cis-α-Co(tren)(NO2)2]NO3•13H2O  | 1:2  |  |  | P21/c |  |  |  |  | [6]
| trans-Co[(en2)(NO2)2]NO3 | 1:2  |  |  |  |  |  |  |  | [7]
| trans-[Co(2,3,2-tet)(NO2)2]NO3 | 1:2  | 373.21  |  | P21/n | a=8.490, b=8.884, c=18.580 and β=95.08°;, Z=4  | 1395.89  | 1.776  |  | [8]
| trans-[Co(2,3,2-tet)(NO2)2]NO3 |  | 373.21  |  | Pn  | a=6.493, b=11.731, c=9.325 β=100.13°; M.W.=373.21, Z=2)=  | 699.21  | 1.773  |  | [8]
| cis-[Co(Hao)2(NO2)2]NO3 (Hao = 3-amino-3-methyl-2-butanone oxime)  |  |  | monoclinic  | P21/n | a= 8.1 60, b= 17.250, c= 13.745, β= 104.77°  |  |  |  | [9]
| [Co(pic)2(NO2)2]NO3.½H2O pic=2-picolylamine  |  |  |  |  |  |  |  |  | [10]
| cis-[Co(phen)2(NO2)2]NO3 · 2 H2O phen=1,10-phenanthroline  |  |  |  |  |  |  |  |  | [11]
Sparteine copper(II) nitrate nitrite  | Cu(C15H26N2)(NO3)(NO2)  | 1:1  |  |  |  |  |  |  | green  | [12]
trans-diammine-cis-dinitratonitronitrosyl ruthenium(II)  | RuNO(NH3)2(NO3)2(NO2)  |  |  |  |  |  |  |  |  |
bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate  | [Pd(NO2)(NH3)3]2[Pd(NH3)4](NO3)4 | 4:1  | 829.20  | tetragonal  | I42m  | a=7.637 c=21.610 Z=2  |  | 2.18  | bright yellow  | [13]
bis(1,10-Phenanthroline)-(nitroso-O)-(nitrato-O,O')-cadmium(ii)  | Cd(phen)2(NO3)(NO2)  |  |  | monoclinic  | P21/c  | a 6.872 b 9.690 c 20.852 β 93.59°  |  |  |  | [14]
catena-((μ2-Nitroso-O,O')-aqua-(nitrato-O,O')-(1,10-phenanthroline)-cadmium(ii))  | [Cd(phen)(NO3)(NO2)(H2O)]n |  |  | monoclinic  | Cc | a 11.703Å b 15.242 c 13.451 β 106.321°  |  |  |  | [14]
| [NO2(NH3)2Pt(C5H4NO)2Pt(NH3)2NO2](NO3)2.H2O  |  |  |  |  |  |  |  | yellow  | [15]
| K3[Hg(NO2)4]NO3 | 1:4  |  | orthorhombic  | Pnma | a=12.12 b=10.58 c=9.28 Z=4  |  | 3.14  | pale yellow  | [1]
| Pb2(NO2)(NO3)(SeO3)  | 1:1  |  | orthorhombic  | Pmn21 | a=5.529, b=10.357, c=6.811, Z=2  | 390  |  | colourless  | [16]
| K2Pb(NO2)3(NO3)  | 1:3  | 503.4  | orthorhombic  | Pbca | a = 6.766, b = 11.999, c = 26.61, Z = 8  | 2160  | 3.095  | yellow orange  | [17]
| [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O  | 1:4  |  | orthorhombic  | Pbca | a = 8.9414, b = 14.5330, c = 24.9383, Z = 8  | 3240.6  |  |  |

## References

1. ↑ 1.0 1.1 Hall, D.; Holland, R.V. (January 1969). "The crystal structure of K3[Hg(NO2)4NO3"] (in en). Inorganica Chimica Acta 3: 235–238. doi:10.1016/S0020-1693(00)92486-1. https://linkinghub.elsevier.com/retrieve/pii/S0020169300924861.
2. ↑ Shepard, Whiting N.; Forster, Leslie S. (1971). "The2 E?4 A 2 transition in tetragonal Cr3+ complexes" (in en). Theoretica Chimica Acta 20 (2): 135–142. doi:10.1007/BF00569260. ISSN 0040-5744. https://link.springer.com/10.1007/BF00569260.
3. ↑ Oonishi, Isao; Muto, Fumio; Komiyama, Yoshimichi (October 1969). "The Molecular and Crystal Structure of trans -Dinitrotetramminecobalt(III) Nitrate Monohydrate" (in en). Bulletin of the Chemical Society of Japan 42 (10): 2791–2796. doi:10.1246/bcsj.42.2791. ISSN 0009-2673.
4. ↑ Oonishi, Isao; Fujimaki, Hiroto; Muto, Fumio; Komiyama, Yoshimichi (March 1970). "The Crystal Structure of cis -Dinitrotetraamminecobalt (III) Nitrate" (in en). Bulletin of the Chemical Society of Japan 43 (3): 733–739. doi:10.1246/bcsj.43.733. ISSN 0009-2673.
5. ↑ Bernal, Ivan; Cetrullo, James (October 1986). "The phenomenon of conglomerate crystallization. VII. Clavic dissymmetry in coordination compounds.V. An investigation of the crystallization behavior of [cis-β-Co(triethylenetetramine)(NO2)2X (X = I, NO3) and the crystal structure of racemic [cis-β-Co(trien)(NO2)2]NO3"] (in en). Inorganica Chimica Acta 120 (2): 109–117. doi:10.1016/S0020-1693(00)86096-X. https://linkinghub.elsevier.com/retrieve/pii/S002016930086096X.
6. ↑ Bernal, Ivan; Cetrullo, James; Myrczek, Jozef (October 1993). "The phenomenon of conglomerate crystallization Part XXXI. The crystallization behavior of [cis-Co(en)2(NO2)2Br and of : counter-ion effects on crystallization pathway of racemate solutions" (in en). Materials Chemistry and Physics 35 (3–4): 290–300. doi:10.1016/0254-0584(93)90145-C. https://linkinghub.elsevier.com/retrieve/pii/025405849390145C.
7. ↑ Charpeutier, T.; Virlet, J. (October 1998). "Triple quantum MQMAS spectroscopy of (I=7/2) in Na3Co(NO2)6 and trans-Co[(en2)(NO2)2NO3 interplay between the quadrupole coupling and anisotropic shielding tensors"] (in en). Solid State Nuclear Magnetic Resonance 12 (4): 227–242. doi:10.1016/S0926-2040(98)00051-4. PMID 9800268. https://linkinghub.elsevier.com/retrieve/pii/S0926204098000514.
8. ↑ 8.0 8.1 Bernal, Ivan; Somoza, Fernando; Chen, Ya-Chen; Massoud, Salah S. (April 1997). "The Phenomenon of Conglomerate Crystallization. Part 48. Two Polymorphs of Racemic Trans-[Co(2,3,2-Tet) (No2)2]No3(I and Ii)" (in en). Journal of Coordination Chemistry 41 (3): 233–247. doi:10.1080/00958979708023574. ISSN 0095-8972. http://www.tandfonline.com/doi/abs/10.1080/00958979708023574.
9. ↑ Murray, Don E.; Schlemper, Elmer O.; Siripaisarnpipat, Sutatip; Murmann, R. Kent (1986). "A structural and isotopic NO 2 – exchange rate comparison of trans-[Co(ao–H–ao)(NO 2 ) 2  and cis-[Co(Hao) 2 (NO 2 ) 2 ]NO 3"] (in en). J. Chem. Soc., Dalton Trans. (9): 1759–1765. doi:10.1039/DT9860001759. ISSN 0300-9246. https://xlink.rsc.org/?DOI=DT9860001759.
10. ↑ Sutton, Gj (1960). "Some Studies in Inorganic Complexes. VIII. Cobalt(II) and Cobalt(III) with 2-Picolylamine" (in en). Australian Journal of Chemistry 13 (4): 473. doi:10.1071/CH9600473. ISSN 0004-9425. http://www.publish.csiro.au/?paper=CH9600473.
11. ↑ Ghaschghaie, Natascha (2010). "HETEROLEPTISCHE COBALT(III)-CHELATKOMPLEXE MIT BIOLIGANDEN". https://edoc.ub.uni-muenchen.de/12126/1/Ghaschghaie_Natascha.pdf.
12. ↑ Lee, Yong-Min; Kim, Yong-Kyu; Jung, Hee-Cheul; Kim, Young-Inn; Choi, Sung-Nak (2002-03-20). "Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes". Bulletin of the Korean Chemical Society 23 (3): 404–412. doi:10.5012/BKCS.2002.23.3.404.
13. ↑ Boer, F. Peter; Carter, Virginia B.; Turley, June W. (April 1971). "Single-crystal x-ray and Raman studies of bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate" (in en). Inorganic Chemistry 10 (4): 651–661. doi:10.1021/ic50098a001. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic50098a001.
14. ↑ 14.0 14.1 Fan, Ruiqing; Zhang, Yanjiao; Yin, Yanbin; Su, Qing; Yang, Yulin; Hasi, Wuliji (June 2009). "Syntheses, structures, and luminescent properties of cadmium (II) complexes: 3D supramolecular [Cd(phen)(NO3)(NO2)(H2O)n and Cd(phen)2(NO3)(NO2) constructed by π–π stacking interactions"] (in en). Synthetic Metals 159 (11): 1106–1111. doi:10.1016/j.synthmet.2009.04.007. https://linkinghub.elsevier.com/retrieve/pii/S037967790900188X.
15. ↑ Hollis, L. Steven; Lippard, Stephen J. (May 1982). "Effect of axial ligands on the platinum-platinum bond in binuclear .alpha.-pyridonate-bridged platinum(III) complexes. Structures of [X(NH3)2Pt(C5H4NO)2Pt(NH3)2X(NO3)2.H2O, X = NO3, NO2"] (in en). Inorganic Chemistry 21 (5): 2116–2117. doi:10.1021/ic00135a087. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00135a087.
16. ↑ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)". Monatshefte für Chemie 118 (2): 211–216. doi:10.1007/BF00810054.
17. ↑ Nardelli, Mario; Pelizzi, Giancarlo (January 1980). "Crystal structure of K2Pb(NO2)3(NO3)·H2O" (in en). Inorganica Chimica Acta 38: 15–19. doi:10.1016/S0020-1693(00)91928-5. https://linkinghub.elsevier.com/retrieve/pii/S0020169300919285.

* v
* t
* e

Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

|
|
|
|

LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

Template:Nitrites

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Nitrate nitrite. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Nitrate_nitrite&oldid=4179488"
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template