Sulfanyl

Sulfur, S

Hydrogen, H

Names
Systematic IUPAC name

Sulfanyl[2] (substitutive)
Hydridosulfur(•)[2] (additive)

Other names

λ1-Sulfane[1]

Identifiers

CAS Number

* 13940-21-1 N

3D model (JSmol)

* Interactive image

ChEBI |

* CHEBI:29312 Y

ChemSpider |

* 4574111 Y

Gmelin Reference

| 299

PubChem CID

* 5460613

InChI

* InChI=1S/HS/h1H Y

Key: PXQLVRUNWNTZOS-UHFFFAOYSA-N Y

SMILES

* [SH]

Properties

Chemical formula

| HS•
Molar mass | 33.073 g mol−1

Solubility in water

| Reacts
Thermochemistry

Std molar
entropy (S ~~o~~ 298)

| 195.63 J K−1 mol−1

Std enthalpy of
formation (ΔfH⦵298)

| 139.33 kJ mol−1
Related compounds

Related radicals

| Hydroxyl

Related compounds

| Hydrogen sulfide

Hydrogen disulfide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is YN ?)
Infobox references

Tracking categories (test):

* SizeSet

Sulfanyl (HS•), also known as the mercapto radical, hydrosulfide radical, or hydridosulfur, is a simple radical molecule consisting of one hydrogen and one sulfur atom. The radical appears in metabolism in organisms as H2S is detoxified. Sulfanyl is one of the top three sulfur-containing gasses in gas giants such as Jupiter and is very likely to be found in brown dwarfs and cool stars. It was originally discovered by Margaret N. Lewis and John U. White at the University of California in 1939.[3] They observed molecular absorption bands around 325 nm belonging to the system designated by 2Σ+ ← 2Πi. They generated the radical by means of a radio frequency discharge in hydrogen sulfide.[4] HS• is formed during the degradation of hydrogen sulfide in the atmosphere of the Earth. This may be a deliberate action to destroy odours or a natural phenomenon.[5]

The organic analogue of sulfanyl is thiyl radical with the formula RS•
, where R is some organic group (e.g., alkyl or aryl).

## Contents

* 1 Natural occurrence
* 2 Formation
* 3 Reactions
* 4 Properties
* 5 Related molecules
* 6 References
* 7 External links

## Natural occurrence

Absorption lines of sulfanyl in space were first detected in the infrared by Yamamura (2000) in a star R And. In the sun •SH was detected at several ultraviolet wavelengths: 326.0459, 327.5468, 328.9749, 330.0892 and 330.1112 nm.[6]

Sulfanyl has been detected in interstellar gas,[7] and it is possibly present in comets.[8]

Various theoretical studies have examined HS• in atmospheres. In Earth's atmosphere HS• reacts with NO2 to make two products HSNO2 and HSONO. HSONO decomposes to HSO and NO. HS• also reacts with O2 and N2O.[9] HS• can also react with Cl2 producing HSCl and a Cl• atom.[10] HS• destroys ozone producing HSO• and oxygen.[11] HS• is formed in the Earth's atmosphere by the reaction of HO•, the hydroxyl radical, on carbon disulfide, carbon oxysulfide and hydrogen sulfide with side products of carbon dioxide and water. Photodissociation of hydrogen sulfide also produces the radical in air.[12]

In a planetary atmosphere that contains H2S, HS• will be formed if the temperature and pressure are high enough. The ratio of H2S and HS• is given by:

log(XH2S/XHS) = −3.37 + 8785/T \+ 0.5 log PT \+ 0.5 log XH2

For a hydrogen dominated atmosphere in a gas giant or star: H2S has the same level as HS• at

log⁡PT=6.82−17570/T.

At higher temperatures HS• breaks up into sulfur vapour and H2. The line of equal S and HS concentration follows the line

log⁡PT=4.80−14522/T.

The lines of equal concentration cross at 1509 K and 1.51 Pa, with HS• being left out of the mix at lower temperatures and pressures. •SH is expected to be the second or third most common sulfur containing gas in gas giants or brown dwarfs.[13]

## Formation

Thermal decomposition of mercaptans, such as ethyl mercaptan yields HS•.[14]

The radical can be formed by the action of ultraviolet radiation on hydrogen sulfide, which splits off a hydrogen atom. A wavelength of 190 nm gives maximum absorption.[15]

In humans superoxide dismutase [Cu-Zn] converts the hydrosulfide ion (HS−) to HS•. This happens as the Cu2+ ion in the enzyme is converted to Cu+.[16]

Sulfide dehydrogenase as found in sulfur bacteria catalyses the oxidation of HS− to HS•, by removing a single electron.[17]

When sulfur minerals are leached with ferric ions HS• is formed in this way:

MS + Fe3+ \+ 2H+ → M2+ \+ Fe2+ \+ H2S•+

with the H2S•+ radical then passing a proton to water to make the HS• radical. M is a metal such as zinc or copper.[18] This has potential for bioleaching in metallic ore extraction.

The hydrosulfide ion HS− can be oxidized to HS• with cerium (IV) sulfate.[19]

## Reactions

Being a radical, HS• is quite reactive. In water HS can react with O2 producing SO2− and H+. SO2− reacts further with O2 to make SO2 and superoxide O2−. In water HS• has an equilibrium with S− • and H+. The hydroxyl radical •OH combines with H2S to form HS• and water.[20] Other reactions investigated by Tiee (1981) are HS• \+ ethylene, HS• \+ O2 → HO• \+ SO, and reactions with itself HS• \+ HS• → H2S2 or H2 and S.[21] The disulfide can further react with HS• to make the disulfide radical HS–S• and H2S.[18]

## Properties

The ionization energy of HS is 10.4219 eV.[22] The reduction potential to go to HS− is 0.92 eV.[23] HS• in water can ionize to S•− and H+. The S•− can catalyze a cis-trans conversion in lipids.[24]

The interatomic distance between sulfur and hydrogen in the radical is 0.134 nm.[25]

HS• reacts with carboxylic acids to make carbonyl sulfide (COS) and probably is the main source of this substance in the atmosphere of Earth.[19]

## Related molecules

HS—S• is called disufanyl with lengthening chains as trisulfanyl, tetrasulfanyl and pentasulfanyl HSSSSS•. S−* is termed sulfanidyl. HS+ is known as sulfanylium, and the common hydrosulfide ion HS− is also known as sulfanido for a ligand or sulfanide as an anion. Further down the periodic table, HSe• is known as selanyl, and HTe• is termed tellanyl.

## References

1. ↑ "Mercapto radical – Compound summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and related records. https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=5460613&loc=ec_rcs.
2. ↑ 2.0 2.1 "sulfanyl (CHEBI:29312)". Chemical entities of biological interest. UK: European Bioinformatics Institute. 6 November 2006. Main. http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:29312.
3. ↑ Lewis, Margaret; John U. White (1939). "The band spectrum of HS". Physical Review 55 (10): 894–898. doi:10.1103/PhysRev.55.894. Bibcode: 1939PhRv...55..894L.
4. ↑ Harrison, Jeremy J.; Bryce E. Williamson (November 2005). "Magnetic circular dichroism of the mercapto radical in noble-gas matrices". Journal of the Indian Institute of Science 85: 391–402. http://journal.library.iisc.ernet.in/vol200506/paper6/391-402.pdf.
5. ↑ Mercado-Cabrera, Antonio; B. Jaramillo-Sierra (29 April 2009). "Environmental odour control by atmospheric dielectric barrier discharge". ISPC. http://www.ispc-conference.org/ispcproc/papers/275.pdf.
6. ↑ Sveta V. Berdyugina; W.C. Livingston (May 2002). "Detection of the mercapto radical SH in the solar atmosphere". Astronomy and Astrophysics 387: L6–L9. doi:10.1051/0004-6361:20020364. Bibcode: 2002A&A...387L...6B.
7. ↑ Palca, Joe (1 October 2011). "Flying telescope makes an out-of-this-world find". NPR. https://www.npr.org/2011/10/01/140877924/flying-telescope-makes-an-out-of-this-world-find.
8. ↑ "The cosmic ice laboratory – Cometary molecules". http://science.gsfc.nasa.gov/691/cosmicice/cometary.html.
9. ↑ Resende, Stella M. (2007). "The atmospheric oxidation of the HS radical: Reaction with NO2". Journal of Atmospheric Chemistry 56 (1): 21–32. doi:10.1007/s10874-006-9040-z. Bibcode: 2006JAtC...56...21R.
10. ↑ Resende, Stella M.; Fernando R Ornellas (25 February 2000). "Atmospheric reaction between the HS radical and chlorine". Chemical Physics Letters 318 (4–5): 340–344. doi:10.1016/S0009-2614(00)00019-1. Bibcode: 2000CPL...318..340R.
11. ↑ Yoshimura, Yasunori; Toshio Kasai, Hiroshi Ohoyama and Keiji Kuwata; Ohoyama, Hiroshi; Kuwata, Keiji (1995). "Nascent HF + and HSO(2A') formations in the elementary reactions of F + H2S and HS + O3 and the internal energy distributions". Canadian Journal of Chemistry 73 (2): 204–221. doi:10.1139/v95-029.
12. ↑ Furones, Maikel Yusat Ballester (2008). "A theoretical study on the HSO2 molecular system". Coimbra: Universidade de Coimbra. pp. 1, 37. https://estudogeral.sib.uc.pt/jspui/bitstream/10316/7489/3/thesis-MYBF.pdf.
13. ↑ Visscher, Channon; Lodders, Katharina; Fegley, Bruce Jr. (10 September 2006). "Atmospheric chemistry in giant planets, brown dwarfs, and low-mass dwarf stars. II. Sulfur and phosphorus". The Astrophysical Journal 648 (2): 1181–1195. doi:10.1086/506245. Bibcode: 2006ApJ...648.1181V.
14. ↑ Sehon, A. H.; B. deB. Darwent (October 1954). "The thermal decomposition of mercaptans". Journal of the American Chemical Society 76 (19): 4806. doi:10.1021/ja01648a011.
15. ↑ Hollaender, Alexander; Livingston, Robert (1955). "1". Radiation Biology. McGraw Hill. p. 27. https://archive.org/stream/radiationbiology02holl/radiationbiology02holl_djvu.txt.
16. ↑ Lyons, Thomas J.; Edith Butler Gralla; Joan Selverstone Valentine (1999). Biological chemistry of copper-zinc superoxide dismutase and its link to amyotrophic lateral sclerosis. 36. Basel, Switzerland: Marcel Decker Inc. 139. ISBN 978-0-8247-1956-2. http://www.ffame.org/tlyons/mibs36.125-177.pdf. Retrieved 10 October 2011.
17. ↑ Sorokina, Dimitry Yu; Govardus A.H de Jong; Lesley A. Robertson; Gijs J. Kuenen (1 May 1998). "Purification and characterization of sulfide dehydrogenase from alkaliphilic chemolithoautotrophic sulfur-oxidizing bacteria". FEBS Letters 427 (1): 11–14. doi:10.1016/S0014-5793(98)00379-2. PMID 9613590.
18. ↑ 18.0 18.1 Schippers, Axel; Wolfgang Sand (January 1999). "Bacterial leaching of metal sulfides proceeds by two indirect mechanisms via thiosulfate or via polysulfides and sulfur". Applied and Environmental Microbiology 65 (1): 319–321. doi:10.1128/AEM.65.1.319-321.1999. PMID 9872800. Bibcode: 1999ApEnM..65..319S.
19. ↑ 19.0 19.1 Pos, Willer H.; Daniel D. Riemer; Rod G. Zika (1998). "Carbonyl sulfide (OCS) and carbon monoxide (CO) in natural waters: evidence of a coupled production pathway". Marine Chemistry 62 (1–2): 89–101. doi:10.1016/S0304-4203(98)00025-5. Bibcode: 1998MarCh..62...89P.
20. ↑ Fang, Hao Jie; Dong Wen Bo; Zhang Ren Xi; Hou, Hui Qi (June 2006). "水相中·HS 的光谱表征及其与氧气的反应研究" (in zh). Acta Physico-Chimica Sinica 22 (6): 761–763. doi:10.3866/PKU.WHXB20060623. http://www.whxb.pku.edu.cn/EN/abstract/abstract22924.shtml. Retrieved 12 October 2011.
21. ↑ Tiee, J.J. (1981). "Spectroscopy and reaction kinetics of HS radicals". Kinetics Database (NIST) 82 (1): 80–84. doi:10.1016/0009-2614(81)85111-1. Bibcode: 1981CPL....82...80T. http://kinetics.nist.gov/kinetics/Detail?id=1981TIE/WAM80:0. Retrieved 13 October 2011.
22. ↑ Cheng, B. M.; Chew, E. P.; Hung, Wen-Ching; Eberhard, Jürg; Lee, Yuan-Pern (May 1998). "Photoionization studies of sulfur radicals and products of their reactions". Journal of Synchrotron Radiation 5 (3): 1041–3. doi:10.1107/S0909049597016075. PMID 15263738. Bibcode: 1998JSynR...5.1041C. http://journals.iucr.org/s/issues/1998/03/00/mz3378/mz3378.pdf.
23. ↑ Das, T. N.; R. E. Huie; P. Neta; S. Padmaja (11 June 1999). "Reduction potential of the sulfhydryl radical: pulse radiolysis and laser flash photolysis studies of the formation and reactions of •SH and HS–SH•− in aqueous solutions". The Journal of Physical Chemistry A 103 (27): 5221–5226. doi:10.1021/jp9907544. Bibcode: 1999JPCA..103.5221D.
24. ↑ Lykakis, Ioannis N.; Carla Ferreri; Chryssostomos Chatgilialoglu (19 January 2007). "The sulfhydryl radical (HS•/S•−): A contender for the isomerization of double bonds in membrane lipids". Angewandte Chemie 46 (11): 1914–1916. doi:10.1002/anie.200604525. PMID 17450618.
25. ↑ Ellingson, Benjamin A.; Donald G. Truhlar (1 August 2007). "Explanation of the unusual temperature dependence of the atmospheric important •OH + H2S → H2O + •SH reaction and prediction of the rate constant at combustion temperatures" (reprint). J. Am. Chem. Soc. 129 (42): 12765–12771 [12769]. doi:10.1021/ja072538b. PMID 17910447. http://static.msi.umn.edu/rreports/2007/267.pdf. Retrieved 20 October 2011.

## External links

* Mercapto radical from NIST
* Milan, J. B.; W. J. Buma; C. A. de Lange (22 October 1996). "Two-photon resonance enhanced multiphoton ionization photoelectron spectroscopy of the SH (SD) radical below and above the lowest ionization threshold". Journal of Chemical Physics 105 (16): 6688–6712. doi:10.1063/1.471850. Bibcode: 1996JChPh.105.6688M. http://dare.uva.nl/document/10542. Retrieved 11 October 2011.
* Burma, W.J.; J. B. Milan; C.A. de Lange; C. M. Western.; N.M.R. Ashfold (1995). "Two-photon resonance enhanced MPI-PES above the lowest ionization threshold: observation of the [a E1delta5p pi E2phi state of the SH (SD) radical"]. Chemical Physics Letters 239 (4–6): 326–331. doi:10.1016/0009-2614(95)00488-P. Bibcode: 1995CPL...239..326M. http://dare.uva.nl/record/129549.
* Nourbakhsh, Omid (August 2015). Manipulation of the motion of polyatomic molecules by AC and DC Stark deceleration (PDF) (Thesis). Vancouver: THE UNIVERSITY OF BRITISH COLUMBIA. Sulfur deuteride radical SD• microwave spectrum

* v
* t
* e

Molecules detected in outer space

Molecules|

| Diatomic|

* Aluminium monochloride
* Aluminium monofluoride
* Aluminium monoxide
* Argonium
* Carbon monophosphide
* Carbon monosulfide
* Carbon monoxide
* Carborundum
* Cyanogen radical
* Diatomic carbon
* Fluoromethylidynium
* Helium hydride ion
* Hydrogen chloride
* Hydrogen fluoride
* Hydrogen (molecular)
* Hydroxyl radical
* Iron(II) oxide
* Magnesium monohydride cation
* Methylidyne radical
* Nitric oxide
* Nitrogen (molecular)
* Nitrogen monohydride
* Nitrogen sulfide
* Oxygen (molecular)
* Phosphorus monoxide
* Phosphorus mononitride
* Potassium chloride
* Silicon carbide
* Silicon mononitride
* Silicon monoxide
* Silicon monosulfide
* Sodium chloride
* Sodium iodide
* Sulfur monohydride
* Sulfur monoxide
* Titanium oxide

|
|

Triatomic|

* Aluminium hydroxide
* Aluminium isocyanide
* Amino radical
* Carbon dioxide
* Carbonyl sulfide
* CCP radical
* Chloronium
* Diazenylium
* Dicarbon monoxide
* Disilicon carbide
* Ethynyl radical
* Formyl radical
* Hydrogen cyanide (HCN)
* Hydrogen isocyanide (HNC)
* Hydrogen sulfide
* Hydroperoxyl
* Iron cyanide
* Isoformyl
* Magnesium cyanide
* Magnesium isocyanide
* Methylene radical
* N2H+
* Nitrous oxide
* Nitroxyl
* Ozone
* Phosphaethyne
* Potassium cyanide
* Protonated molecular hydrogen
* Sodium cyanide
* Sodium hydroxide
* Silicon carbonitride
* c-Silicon dicarbide
* SiNC
* Sulfur dioxide
* Thioformyl
* Thioxoethenylidene
* Titanium dioxide
* Tricarbon
* Water

Four
atoms|

* Acetylene
* Ammonia
* Cyanic acid
* Cyanoethynyl
* Cyclopropynylidyne
* Formaldehyde
* Fulminic acid
* HCCN
* Hydrogen peroxide
* Hydromagnesium isocyanide
* Isocyanic acid
* Isothiocyanic acid
* Ketenyl
* Methylene amidogen
* Methyl radical
* Propynylidyne
* Protonated carbon dioxide
* Protonated hydrogen cyanide
* Silicon tricarbide
* Thioformaldehyde
* Tricarbon monoxide
* Tricarbon sulfide
* Thiocyanic acid

Five
atoms|

* Ammonium ion
* Butadiynyl
* Carbodiimide
* Cyanamide
* Cyanoacetylene
* Cyanoformaldehyde
* Cyanomethyl
* Cyclopropenylidene
* Formic acid
* Isocyanoacetylene
* Ketene
* Methane
* Methoxy radical
* Methylenimine
* Propadienylidene
* Protonated formaldehyde
* Protonated formaldehyde
* Silane
* Silicon-carbide cluster

Six
atoms|

* Acetonitrile
* Cyanobutadiynyl radical
* E-Cyanomethanimine
* Cyclopropenone
* Diacetylene
* Ethylene
* Formamide
* HC4N
* Ketenimine
* Methanethiol
* Methanol
* Methyl isocyanide
* Pentynylidyne
* Propynal
* Protonated cyanoacetylene

Seven
atoms|

* Acetaldehyde
* Acrylonitrile
* Vinyl cyanide
* Cyanodiacetylene
* Ethylene oxide
* Glycolonitrile
* Hexatriynyl radical
* Methylacetylene
* Methylamine
* Methyl isocyanate
* Vinyl alcohol

Eight
atoms|

* Acetic acid
* Aminoacetonitrile
* Cyanoallene
* Ethanimine
* Glycolaldehyde
* Heptatrienyl radical
* Hexapentaenylidene
* Methylcyanoacetylene
* Methyl formate
* Propenal

Nine
atoms|

* Acetamide
* Cyanohexatriyne
* Cyanotriacetylene
* Dimethyl ether
* Ethanol
* Methyldiacetylene
* Octatetraynyl radical
* Propene
* Propionitrile

Ten
atoms
or more|

* Acetone
* Benzene
* Benzonitrile
* Buckminsterfullerene (C60, C60+, fullerene, buckyball)
* C70 fullerene
* Cyanodecapentayne
* Cyanopentaacetylene
* Cyanotetra-acetylene
* Ethylene glycol
* Ethyl formate
* Methyl acetate
* Methyl-cyano-diacetylene
* Methyltriacetylene
* Propanal
* n-Propyl cyanide
* Pyrimidine

Deuterated
molecules|

* Ammonia
* Ammonium ion
* Formaldehyde
* Formyl radical
* Heavy water
* Hydrogen cyanide
* Hydrogen deuteride
* Hydrogen isocyanide
* Methylacetylene
* N2D+
* Trihydrogen cation

Unconfirmed|

* Anthracene
* Dihydroxyacetone
* Ethyl methyl ether
* Glycine
* Graphene
* H2NCO+
* Linear C5
* Naphthalene cation
* Phosphine
* Pyrene
* Silylidine

Related|

* Abiogenesis
* Astrobiology
* Astrochemistry
* Atomic and molecular astrophysics
* Chemical formula
* Circumstellar envelope
* Cosmic dust
* Cosmic ray
* Cosmochemistry
* Diffuse interstellar band
* Earliest known life forms
* Extraterrestrial life
* Extraterrestrial liquid water
* Forbidden mechanism
* Homochirality
* Intergalactic dust
* Interplanetary medium
* Interstellar medium
* Photodissociation region
* Iron–sulfur world theory
* Kerogen
* Molecules in stars
* Nexus for Exoplanet System Science
* Organic compound
* Outer space
* PAH world hypothesis
* Panspermia
* Polycyclic aromatic hydrocarbon (PAH)
* RNA world hypothesis
* Spectroscopy
* Tholin

* Category:Astrochemistry
*   *   *

* v
* t
* e

Binary compounds of hydrogen

Alkali metal (Group 1) hydrides|

* LiH
* NaH
* KH
* RbH
* CsH

Lithium hydride, LiH
ionic metal hydride

Beryllium hydride
Left (gas phase): BeH2
covalent metal hydride
Right: (BeH2)n (solid phase)
polymeric metal hydride

Borane and diborane
Left: BH3 (special conditions), covalent metalloid hydride
Right: B2H6 (standard conditions), dimeric metalloid hydride

Methane, CH4
covalent nonmetal hydride

Ammonia, NH3
covalent nonmetal hydride

Water, H2O
covalent nonmetal hydride

Hydrogen fluoride, HF
covalent nonmetal hydride

Alkaline (Group 2) earth hydrides|

| Monohydrides|

* BeH
* MgH
* CaH
* SrH
* BaH

|

Dihydrides|

* BeH2
* MgH2
* CaH2
* SrH2
* BaH2

|

Group 13 hydrides|

| Boranes|

* BH3
* B2H6
* B2H2
* B2H4
* B4H10
* B5H9
* B5H11
* B6H10
* B6H12
* B10H14
* B18H22

|

Alanes|

* AlH3
* Al2H6

|

Gallanes|

* GaH3
* Ga2H6

|

Indiganes|

* InH3
* In2H6

|

Thallanes|

* TlH3
* Tl2H6

|

Group 14 hydrides|

| Linear alkanes|

* CH4
* C2H6
* C3H8
* C4H10
* C5H12
* C6H14
* C7H16
* C8H18
* C9H20
* C10H22
* more...

|

Linear alkenes|

* C2H4
* C3H6
* C4H8
* C5H10
* C6H12
* C7H14
* C8H16
* C9H18
* C10H20
* more...

|

Linear alkynes|

* C2H2
* C3H4
* C4H6
* C5H8
* C6H10
* C7H12
* C8H14
* C9H16
* C10H18
* more...

|

Silanes|

* SiH4
* Si2H6
* Si3H8
* Si4H10
* Si5H12
* Si6H14
* Si7H16
* Si8H18
* Si9H20
* Si10H22
* more...

|

Silenes|

* Si2H4

|

Silynes|

* Si2H2
* SiH

|

Germanes|

* GeH4
* Ge2H6
* Ge3H8
* Ge4H10
* Ge5H12

|

Stannanes|

* SnH4
* Sn2H6

|

Plumbanes|

* PbH4

|

* CH
* CH2
* CH3
* C2H
* Cycloalkanes
* Cycloalkenes
* Annulenes
* Many more

Pnictogen (Group 15) hydrides|

| Azanes|

* NH3
* N2H4
* N3H5
* N4H6
* N5H7
* N6H8
* N7H9
* N8H10
* N9H11
* N10H12
* more...

|

Azenes|

* N2H2
* N3H3
* N4H4

|

Phosphanes|

* PH3
* P2H4
* P3H5
* P4H6
* P5H7
* P6H8
* P7H9
* P8H10
* P9H11
* P10H12
* more...

|

Phosphenes|

* P2H2
* P3H3
* P4H4

|

Arsanes|

* AsH3
* As2H4

|

Stibanes|

* SbH3

|

Bismuthanes|

* BiH3

|

* HN3
* NH
* radical

Hydrogen chalcogenides (Group 16 hydrides)|

| Polyoxidanes|

* H2O
* H2O2
* H2O3
* H2O4
* H2O5
* H2O6
* H2O7
* H2O8
* H2O9
* H2O10
* more...

|

Polysulfanes|

* H2S
* H2S2
* H2S3
* H2S4
* H2S5
* H2S6
* H2S7
* H2S8
* H2S9
* H2S10
* more...

|

Selanes|

* H2Se
* H2Se2

|

Tellanes|

* H2Te
* H2Te2

|

Polanes|

* PoH2

|

* HO
* HO2
* HO3
* H2O+–O–
* H2S=S
* (HS)2S+–S–
* HS
* HDO
* D2O
* T2O

Hydrogen halides (Group 17 hydrides)|

* HF
* HCl
* HBr
* HI
* HAt

Transition metal hydrides|

* ScH2
* YH2
* YH3
* TiH2
* ZrH2
* HfH2
* VH
* VH2
* NbH
* NbH2
* TaH
* CrH
* CrH2
* CrHx
* NiH
* PdHx (x < 1)
* FeH
* FeH2
* FeH5
* CuH
* ZnH2
* CdH2
* HgH2

Lanthanide hydrides|

* LaH2
* LaH3
* LaH10
* CeH2
* CeH3
* PrH2
* PrH3
* NdH2
* NdH3
* SmH2
* SmH3
* EuH2
* GdH2
* GdH3
* TbH2
* TbH3
* DyH2
* DyH3
* HoH2
* HoH3
* ErH2
* ErH3
* TmH2
* TmH3
* YbH2
* YbH2.5
* LuH2
* LuH3

Actinide hydrides|

* AcH2
* ThH2
* Th4H15
* PaH3
* UH3
* NpH2
* NpH3
* PuH2
* PuH3
* AmH2
* AmH3
* CmH2

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Original source: https://en.wikipedia.org/wiki/Sulfanyl. Read more

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