Neodymium tantalate

The structure of Neodymium tanatalate. Atoms are: O(red), Ta(blue) and Nd(green)

Identifiers

CAS Number

* 12344-26-2 Y

3D model (JSmol)

* Interactive image

PubChem CID

* 157362626

InChI

* InChI=1S/Nd.4O.Ta/q+3;4*-2;+5

Key: BIUUBSDKMPQKED-UHFFFAOYSA-N

SMILES

* [O-2].[O-2].[O-2].[O-2].[Nd+3].[Ta+5]

Properties

Chemical formula

| NdTaO4
Molar mass | 389.19
Appearance  | gray-purple solid[1]

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Neodymium tantalate is an inorganic compound with the chemical formula NdTaO4. It is prepared by reacting neodymium oxide and tantalum pentoxide at 1200 °C.[1] It reacts with a mixture of tantalum pentoxide and chlorine gas at high temperature to obtain Nd2Ta2O7Cl2.[2] It is ammonolyzed at high temperature to obtain oxynitrides of Nd-Ta.[3]

## Contents

* 1 Properties
* 2 See also
* 3 References
* 4 External links

## Properties

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Neodymium tantalate forms violet crystals of the monoclinic system, with space group I2/a, unit cell dimensions a = 0.55153 nm, b = 1.12388 nm, c = 0.51184 nm, β = 95.731°, with formulas per unit cell Z = 4.[4]

There is a metastable high-pressure phase of the monoclinic system, space group P21/c, cell parameters a = 0.75920 nm, b = 0.54673 nm, c = 0.77022 nm, β = 100.032°, Z = 4.[5]

## See also

* Neodymium
* Tantalum
* Tantalate

## References

1. ↑ 1.0 1.1 Krylov, E. I.; Strelina, M. M. Praseodymium and neodymium orthotantalates. Zhurnal Neorganicheskoi Khimii, 1961. 6: 235-235. ISSN 0044-457X.
2. ↑ U. Schaffrath, R. Gruehn (1988-12-01). "Nd7,33Ta8O28CI6 — ein Zwischenprodukt des thermischen Abbaus von Nd2Ta2O7Cl2: Präparation, Struktur und magnetische Eigenschaften / Nd7,33Ta8O28Cl6 — an Intermediate Product of the Thermal Decomposition of Nd2Ta2O7Cl2: Preparation, Crystal Structure and Magnetic Properties". Zeitschrift für Naturforschung B 43 (12): 1567–1574. doi:10.1515/znb-1988-1208. ISSN 1865-7117.
3. ↑ Pascal Maillard, Franck Tessier, Emmanuelle Orhan, François Cheviré, Roger Marchand (January 2005). "Thermal Ammonolysis Study of the Rare-Earth Tantalates RTaO4" (in en). Chemistry of Materials 17 (1): 152–156. doi:10.1021/cm040131p. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm040131p. Retrieved 2021-06-06.
4. ↑ Kaijie Ning, Qingli Zhang, Deming Zhang, Jintai Fan, Dunlu Sun, Xiaofei Wang, Yin Hang (2014). "Crystal growth, characterization of NdTaO4: A new promising stoichiometric neodymium laser material". Journal of Crystal Growth 388: 83–86. doi:10.1016/j.jcrysgro.2013.10.030. Bibcode: 2014JCrGr.388...83N.
5. ↑ Titov Yu. A., Sych A. M., Sokolov A. N., Kapshuk A. A., Markiv V. Ya., Belyavina N. M. (2000). Crystal structure of the high-pressure modification of NdTaO4. 311 (Journal of alloys and compounds ed.). pp. 252–255. http://cat.inist.fr/?aModele=afficheN&cpsidt=1506065.

## External links

* Patrick N. Walsh, Harold W. Goldstein, David White (May 1960). "Vaporization of Rare-Earth Oxides" (in en). Journal of the American Ceramic Society 43 (5): 229–233. doi:10.1111/j.1151-2916.1960.tb14589.x. ISSN 0002-7820. http://doi.wiley.com/10.1111/j.1151-2916.1960.tb14589.x. Retrieved 2021-06-06.

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Neodymium compounds

* NdAl3(BO3)4
* NdBr3
* NdCl3
* NdF3
* Nd(OH)3
* NdNiO3
* NdN
* Nd(NO3)3
* Nd2O3
* Nd2(SO4)3

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Tantalum compounds

Tantalum(II)|

* TaB2

Tantalum(III)|

* TaAl3
* TaN

Tantalum(IV)|

* TaS2
* TaC
* TaTe2
* Ta4HfC5

Tantalum(V)|

* TaF5
* TaCl5
* TaBr5
* TaI5
* Ta2O5
* LiTaO3
* LuTaO4
* K2TaF7
* H2TaF7
* K2Ta2O3F6

| Organotantalum(V)|

* Ta2(OC2H5)10
* TaC5H15
* Ta(C2H6N)5

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