Thallium(III) acetate

Names
IUPAC name

Thallium(III) acetate

Identifiers

CAS Number

* 2570-63-0 Y

3D model (JSmol)

* Interactive image

ChemSpider |

* 10667701

EC Number |

* 219-913-2

PubChem CID

* 16685266

UNII |

* 24Z9A6MS8G

InChI

* InChI=1S/3C2H4O2.Tl/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3

Key: SMRRYUGQTFYZGD-UHFFFAOYSA-K

SMILES

* CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Tl+3]

Properties

Chemical formula

| Tl(C2H3O2)3
Molar mass | 381.52

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Thallium(III) acetate  is the acetate salt of thallium, with the chemical formula Tl(CH3COO)3. As a selective culture medium in microbiology,[1] thallium acetate is toxic,[2] but it can also be used as a hair loss agent. A dose of 8 mg/kg will cause acute poisoning, and the minimum lethal dose for adults is 12 mg/kg.[3]

## Preparation

Thallium acetate can be obtained by reacting 80% acetic acid with thallium(III) oxide, and the product crystallizes in acetic anhydride.[4]

## Properties

Anhydrous thallium(III) acetate crystallises in the monoclinic system with space group C2/c. The unit cell dimensions are a = 15.54 Å b = 8.630 Å and c = 7.848 Å with β = 113.92°. There are four formula per unit cell. and density is 2.57. Three acetate ions are chellated to each thallium ion.[5]

Thallium(III) acetate monohydrate also crystallises in the monoclinic system with space group C2/c, a = 9.311 Å, b = 14.341 Å, c = 9.198 Å, β = 119.69 °. Unit cell volume is V = 1067.0 Å3 Z = 4, density is 2.49.[6]

## References

1. ↑ Bulich, Anthony A.; Hartman, Paul A. (Nov 1969). "Evaluation of Thallium Acetate-Citrate Medium for Isolation of Enterococci". Applied Microbiology 18 (5): 944–945. doi:10.1128/am.18.5.944-945.1969. ISSN 0003-6919. PMID 5370465. PMC 378124. http://dx.doi.org/10.1128/am.18.5.944-945.1969.
2. ↑ World Health Organization (2008). Anthrax in humans and animals. World Health Organization. pp. 139–. ISBN 978-92-4-154753-6. https://books.google.com/books?id=EKYihvnaA7oC&pg=PA139. Retrieved 23 February 2011.
3. ↑ "铊、玻璃和人——从两桩铊中毒事件说起". 中国科学院上海硅酸盐研究所. http://119.78.242.243:8080/kexie/news.asp?id=144. Retrieved 2015-05-20.
4. ↑ Kolling, Orland W.; Mawdsley, Elizabeth A. (1971). "Anhydrous Thallium(III) Acetate". Transactions of the Kansas Academy of Science 74 (1): 38. doi:10.2307/3627666. https://www.jstor.org/stable/3627666.
5. ↑ Faggiani, R.; Brown, I. D. (1 September 1978). "Thallium(III) triacetate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 34 (9): 2845–2846. doi:10.1107/S0567740878009358. Bibcode: 1978AcCrB..34.2845F.
6. ↑ Faggiani, R.; Brown, I. D. (15 September 1982). "Thallium triacetate monohydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 38 (9): 2473–2475. doi:10.1107/S0567740882009091. Bibcode: 1982AcCrB..38.2473F.

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Thallium compounds

Thallium(I)|

* TlN3
* TlOH
* TlI
* TlBr
* Tl2CO3
* TlCl
* TlF
* Tl2O
* Tl2SO4
* Tl2S
* Tl2Te
* TlI3
* TBCCO

| Organothallium(I)|

* Tl(C2H3O2)3
* Tl2C3H2O4
* TlC5H5

|

Thallium(III)|

* TlH3
* Tl(OH)3
* Tl2O3
* Tl(NO3)3

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Acetyl halides and salts of the acetate ion

AcOH |  |  |  | He
LiOAc | Be(OAc)2
BeAcOH | B(OAc)3 | AcOAc
ROAc | NH4OAc | AcOOH | FAc | Ne
NaOAc | Mg(OAc)2 | Al(OAc)3
ALSOL
Al(OAc)2OH
Al2SO4(OAc)4 | Si  | P  | S  | ClAc | Ar
KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2
Cr(OAc)3 | Mn(OAc)2
Mn(OAc)3 | Fe(OAc)2
Fe(OAc)3 | Co(OAc)2,
Co(OAc)3 | Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge  | As(OAc)3 | Se  | BrAc | Kr
RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb  | Mo(OAc)2 | Tc  | Ru(OAc)2
Ru(OAc)3
Ru(OAc)4 | Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In  | Sn(OAc)2
Sn(OAc)4 | Sb(OAc)3 | Te  | IAc | Xe
CsOAc | Ba(OAc)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt(OAc)2 | Au  | Hg2(OAc)2,
Hg(OAc)2 | TlOAc
Tl(OAc)3 | Pb(OAc)2
Pb(OAc)4 | Bi(OAc)3 | Po  | At  | Rn
Fr  | Ra  |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(OAc)3 | Ce(OAc)x | Pr  | Nd  | Pm  | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb  | Dy(OAc)3 | Ho(OAc)3 | Er  | Tm  | Yb(OAc)3 | Lu(OAc)3
Ac  | Th  | Pa  | UO2(OAc)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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