Polyester

Polyester is a category of polymers that contain one or two ester linkages in every repeat unit of their main chain.[1] As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include some naturally occurring chemicals, such as those found in plants and insects. Natural polyesters and a few synthetic ones are biodegradable, but most synthetic polyesters are not. Synthetic polyesters are used extensively in clothing.

Polyester fibers are sometimes spun together with natural fibers to produce a cloth with blended properties. Cotton-polyester blends can be strong, wrinkle- and tear-resistant, and reduce shrinking. Synthetic fibers using polyester have high water, wind, and environmental resistance compared to plant-derived fibers. They are less fire-resistant and can melt when ignited.[2]

Liquid crystalline polyesters are among the first industrially used liquid crystal polymers. They are used for their mechanical properties and heat-resistance. These traits are also important in their application as an abradable seal in jet engines.[3]

## Contents

* 1 Types
* 1.1 Natural
* 1.2 Synthetic
* 1.3 Aliphatic vs. aromatic polymers
* 2 Uses and applications
* 3 Production
* 3.1 Polyester processing
* 4 Synthesis
* 4.1 Alcoholic transesterification
* 4.2 Acylation
* 4.3 Silyl method
* 4.4 Acetate method (esterification)
* 4.5 Ring-opening polymerization
* 4.6 Other methods
* 4.7 Thermodynamics of polycondensation reactions
* 5 History
* 6 Environmental impact
* 6.1 Biodegradation
* 6.2 Cross-linking
* 6.3 Pollution of freshwater and seawater habitats
* 6.4 Carbon footprint
* 7 Safety
* 7.1 Fertility
* 8 Recycling
* 9 See also
* 10 References
* 11 Further reading
* 12 External links

## Types

A polyester shirt Close-up of a polyester shirt SEM picture of a bend in a high-surface area polyester fiber with a seven-lobed cross section A drop of water on a water resistant polyester

Polyesters can contain one ester linkage per repeat unit of the polymer, as in polyhydroxyalkanoates like polylactic acid, or they may have two ester linkages per repeat unit, as in polyethylene terephthalate (PET).

Polyesters are one of the most economically important classes of polymers, driven especially by PET, which is counted among the commodity plastics; in 2019 around 30.5 million metric tons were produced worldwide.[4] There is a great variety of structures and properties in the polyester family, based on the varying nature of the R group (see first figure with blue ester group).[1]

### Natural

Polyesters occurring in nature include the cutin component of plant cuticles, which consists of omega hydroxy acids and their derivatives, interlinked via ester bonds, forming polyester polymers of indeterminate size. Polyesters are also produced by bees in the genus Colletes, which secrete a cellophane-like polyester lining for their underground brood cells[5] earning them the nickname "polyester bees".[6]

### Synthetic

The family of synthetic polyesters comprises[1]

* Linear aliphatic high molecular weight polyesters (Mn >10,000) are low-melting (m. p. 40 – 80 °C) semicrystalline polymers and exhibit relatively poor mechanical properties. Their inherent degradability, resulting from their hydrolytic instability, makes them suitable for applications where a possible environmental impact is a concern, e.g. packaging, disposable items or agricultural mulch films[7]⁠ or in biomedical and pharmaceutical applications.[8]
* Aliphatic linear low-molar-mass (Mn < 10,000) hydroxy-terminated polyesters are used as macromonomers for the production of polyurethanes.
* hyperbranched polyesters are used as rheology modifiers in thermoplastics or as crosslinkers in coatings[9] due to their particularly low viscosity, good solubility and high functionality[10]
* Aliphatic–aromatic polyesters, including poly(ethylene terephthalate) (PET) and poly(butylene terephthalate) (PBT), poly(hexamethylene terephthalate)(PHT), poly(propylene terephthalate) (PTT, Sorona), etc. are high-melting semicrystalline materials (m. p. 160–280 °C) that and have benefited from engineering thermoplastics, fibers and films.
* Wholly aromatic linear copolyesters present superior mechanical properties and heat resistance and are used in a number of high-performance applications.
* Unsaturated polyesters are produced from multifunctional alcohols and unsaturated dibasic acids and are cross-linked thereafter; they are used as matrices in composite materials. Alkyd resins are made from polyfunctional alcohols and fatty acids and are used widely in the coating and composite industries as they can be cross-linked in the presence of oxygen. Also rubber-like polyesters exist, called thermoplastic polyester elastomers (TPEE). Unsaturated polyesters (UPR) are thermosetting resins. They are used in the liquid state as casting materials, in sheet molding compounds, as fiberglass laminating resins and in non-metallic auto-body fillers. They are also used as the thermoset polymer matrix in pre-pregs. Fiberglass-reinforced unsaturated polyesters find wide application in bodies of yachts and as body parts of cars.

Depending on the chemical structure, polyester can be a thermoplastic or thermoset. There are also polyester resins cured by hardeners; however, the most common polyesters are thermoplastics.[11] The OH group is reacted with an Isocyanate functional compound in a 2 component system producing coatings which may optionally be pigmented. Polyesters as thermoplastics may change shape after the application of heat. While combustible at high temperatures, polyesters tend to shrink away from flames and self-extinguish upon ignition. Polyester fibers have high tenacity and E-modulus as well as low water absorption and minimal shrinkage in comparison with other industrial fibers.

Increasing the aromatic parts of polyesters increases their glass transition temperature, melting temperature, thermostability, chemical stability, and solvent resistance.

Polyesters can also be telechelic oligomers like the polycaprolactone diol (PCL) and the polyethylene adipate diol (PEA). They are then used as prepolymers.

### Aliphatic vs. aromatic polymers

Thermally stable polymers, which generally have a high proportion of aromatic structures, are also called high-performance plastics. This application-oriented classification compares such polymers with engineering plastics and commodity plastics. The continuous service temperature of high-performance plastics is generally stated as being higher than 150 °C,[12] whereas engineering plastics (such as polyamide or polycarbonate) are often defined as thermoplastics that retain their properties above 100 °C.[13]⁠ Commodity plastics (such as polyethylene or polypropylene) have in this respect even greater limitations, but they are manufactured in great amounts at low cost.

Poly(ester imides) contain an aromatic imide group in the repeat unit, the imide-based polymers have a high proportion of aromatic structures in the main chain and belong to the class of thermally stable polymers. Such polymers contain structures that impart high melting temperatures, resistance to oxidative degradation and stability to radiation and chemical reagents. Among the thermally stable polymers with commercial relevance are polyimides, polysulfones, polyetherketones, and polybenzimidazoles. Of these, polyimides are most widely applied.[14] The polymers' structures result also in poor processing characteristics, in particular a high melting point and low solubility. The named properties are in particular based on a high percentage of aromatic carbons in the polymer backbone which produces a certain stiffness.[15]⁠ Approaches for an improvement of processability include the incorporation of flexible spacers into the backbone, the attachment of stable pendent groups or the incorporation of non-symmetrical structures.⁠ Flexible spacers include, for example, ether or hexafluoroisopropylidene, carbonyl or aliphatic groups like isopropylidene; these groups allow bond rotation between aromatic rings. Less symmetrical structures, for example, based on meta\- or ortho-linked monomers, introduce structural disorder, decreasing the crystallinity.[4]

The generally poor processability of aromatic polymers (for example, a high melting point and a low solubility) also limits the available options for synthesis and may require strong electron-donating co-solvents like HFIP or TFA for analysis (e. g. 1H NMR spectroscopy) which themselves can introduce further practical limitations.

## Uses and applications

Fabrics woven or knitted from polyester thread or yarn are used extensively in apparel and home furnishings, from shirts and pants to jackets and hats, bed sheets, blankets, upholstered furniture and computer mouse mats. Industrial polyester fibers, yarns and ropes are used in car tire reinforcements, fabrics for conveyor belts, safety belts, coated fabrics and plastic reinforcements with high-energy absorption. Polyester fiber is used as cushioning and insulating material in pillows, comforters, stuffed animals and characters, and upholstery padding. Polyester fabrics are highly stain-resistant since polyester is a hydrophobic material, and therefore has difficulty absorbing liquids. The only class of dyes which can be used to alter the color of polyester fabric are what are known as disperse dyes.[16]

Polyesters are also used to make bottles, films, tarpaulin, sails[17] (Dacron), canoes, liquid crystal displays, holograms, filters, dielectric film for capacitors, film insulation for wire and insulating tapes. Polyesters are widely used as a finish on high-quality wood products such as guitars, pianos, and vehicle/yacht interiors. Thixotropic properties of spray-applicable polyesters make them ideal for use on open-grain timbers, as they can quickly fill wood grain, with a high-build film thickness per coat. It can be used for fashionable dresses, but it is most admired for its ability to resist wrinkling and shrinking while washing the product. Its toughness makes it a frequent choice for children's wear. Polyester is often blended with other fibres like cotton to get the desirable properties of both materials. Cured polyesters can be sanded and polished to a high-gloss, durable finish.

## Production

Polyester is typically produced through a process known as polymerization. For polyethylene terephthalate (PET), the production process involves the chemical reaction between two primary raw materials: purified terephthalic acid (PTA) or dimethyl terephthalate (DMT) and monoethylene glycol (MEG).

The production process includes the following steps:

1. Polycondensation Reaction: The reaction between PTA or DMT and MEG creates polyester polymer chains through a process called polycondensation. This reaction takes place at high temperatures and involves the removal of water or methanol byproducts.
2. Extrusion: Once the polymerization is complete, the molten polyester is extruded into long strands. These strands are then cooled and cut into small pellets or chips.
3. Spinning: To form fibers, these polyester chips are melted and extruded through spinnerets, forming fine strands of polyester filament. These filaments can be processed further to create continuous fibers, which are then woven into textiles.
4. Recycling: The production of polyester has evolved to include the recycling of PET, especially from post-consumer plastic bottles. Recycled PET (rPET) is increasingly being used in textile production, reducing the environmental impact of polyester manufacturing.

Polyethylene terephthalate, the polyester with the greatest market share, is a synthetic polymer made of purified terephthalic acid (PTA) or its dimethyl ester dimethyl terephthalate (DMT) and monoethylene glycol (MEG). With 18% market share of all plastic materials produced, it ranges third after polyethylene (33.5%) and polypropylene (19.5%) and is counted as commodity plastic.

There are several reasons for the importance of polyethylene terephthalate:

* The relatively easy accessible raw materials PTA or DMT and MEG
* The very well understood and described simple chemical process of its synthesis
* The low toxicity level of all raw materials and side products during production and processing
* The possibility to produce PET in a closed loop at low emissions to the environment
* The outstanding mechanical and chemical properties
* The recyclability
* The wide variety of intermediate and final products.

In the following table, the estimated world polyester production is shown. Main applications are textile polyester, bottle polyester resin, film polyester mainly for packaging and specialty polyesters for engineering plastics.

World polyester production (million tonnes/year)  Product type  | 2002  | 2008

|
|

Textile-PET  | 20  | 39
Resin, bottle/A-PET  | 9  | 16
Film-PET  | 1.2  | 1.5
Special polyester  | 1  | 2.5
Total  | 31.2  | 59

### Polyester processing

After the first stage of polymer production in the melt phase, the product stream divides into two different application areas which are mainly textile applications and packaging applications. In the following table, the main applications of textile and packaging of polyester are listed.

Textile and packaging polyester application list (melt or pellet)  Textile  | Packaging

|

Staple fiber (PSF)  | Bottles for CSD, water, beer, juice, detergents, etc.
Filaments POY, DTY, FDY  | A-PET film
Technical yarn and tire cord  | Thermoforming
Non-woven and spunbond  | biaxial-oriented film (BO-PET)
Mono-filament  | Strapping

Abbreviations:

PSF
Polyester-staple fiber
POY
Partially oriented yarn
DTY
Drawn textured yarn
FDY
Fully drawn yarn
CSD
Carbonated soft drink
A-PET
Amorphous polyethylene terephthalate film
BO-PET
Biaxial-oriented polyethylene terephthalate film

A comparable small market segment (much less than 1 million tonnes/year) of polyester is used to produce engineering plastics and masterbatch.

In order to produce the polyester melt with a high efficiency, high-output processing steps like staple fiber (50–300 tonnes/day per spinning line) or POY /FDY (up to 600 tonnes/day split into about 10 spinning machines) are meanwhile more and more vertically integrated direct processes. This means the polymer melt is directly converted into the textile fibers or filaments without the common step of pelletizing. We are talking about full vertical integration when polyester is produced at one site starting from crude oil or distillation products in the chain oil → benzene → PX → PTA → PET melt → fiber/filament or bottle-grade resin. Such integrated processes are meanwhile established in more or less interrupted processes at one production site. Eastman Chemicals were the first to introduce the idea of closing the chain from PX to PET resin with their so-called INTEGREX process. The capacity of such vertically integrated production sites is >1000 tonnes/day and can easily reach 2500 tonnes/day.

Besides the above-mentioned large processing units to produce staple fiber or yarns, there are ten thousands of small and very small processing plants, so that one can estimate that polyester is processed and recycled in more than 10 000 plants around the globe. This is without counting all the companies involved in the supply industry, beginning with engineering and processing machines and ending with special additives, stabilizers and colors. This is a gigantic industry complex and it is still growing by 4–8% per year, depending on the world region.

## Synthesis

Synthesis of polyesters is generally achieved by a polycondensation reaction. The general equation for the reaction of a diol with a diacid is:

(n+1) R(OH)2 \+ n R'(COOH)2 → HO[ROOCR'COO]nROH + 2n H2O.

Polyesters can be obtained by a wide range of reactions of which the most important are the reaction of acids and alcohols, alcoholysis and or acidolysis of low-molecular weight esters or the alcoholysis of acyl chlorides. The following figure gives an overview over such typical polycondensation reactions for polyester production. Furthermore, polyesters are accessible via ring-opening polymerization.

Azeotrope esterification is a classical method for condensation. The water formed by the reaction of alcohol and a carboxylic acid is continually removed by azeotropic distillation. When melting points of the monomers are sufficiently low, a polyester can be formed via direct esterification while removing the reaction water via vacuum.

Direct bulk polyesterification at high temperatures (150 – 290 °C) is well-suited and used on the industrial scale for the production of aliphatic, unsaturated, and aromatic–aliphatic polyesters. Monomers containing phenolic or tertiary hydroxyl groups exhibit a low reactivity with carboxylic acids and cannot be polymerized via direct acid alcohol-based polyesterification.[4]⁠ In the case of PET production, however, the direct process has several advantages, in particular a higher reaction rate, a higher attainable molecular weight, the release of water instead of methanol and lower storage costs of the acid when compared to the ester due to the lower weight.[1]

### Alcoholic transesterification

Main article: Chemistry:Transesterification

Transesterification: An alcohol-terminated oligomer and an ester-terminated oligomer condense to form an ester linkage, with loss of an alcohol. R and R' are the two oligomer chains, R'' is a sacrificial unit such as a methyl group (methanol is the byproduct of the esterification reaction).

The term "transesterification" is typically used to describe hydroxy–ester, carboxy–ester, and ester–ester exchange reactions. The hydroxy–ester exchange reaction possesses the highest rate of reaction and is used for the production of numerous aromatic–aliphatic and wholly aromatic polyesters.[4] The transesterification based synthesis is particularly useful for when high melting and poorly soluble dicarboxylic acids are used. In addition, alcohols as condensation product are more volatile and thereby easier to remove than water.[18]

The high-temperature melt synthesis between bisphenol diacetates and aromatic dicarboxylic acids or in reverse between bisphenols and aromatic dicarboxylic acid diphenyl esters (carried out at 220 to 320 °C upon the release of acetic acid) is, besides the acyl chloride based synthesis, the preferred route to wholly aromatic polyesters.[4]

### Acylation

In acylation, the acid begins as an acyl chloride, and thus the polycondensation proceeds with emission of hydrochloric acid (HCl) instead of water.

The reaction between diacyl chlorides and alcohols or phenolic compounds has been widely applied to polyester synthesis and has been subject of numerous reviews and book chapters.[4]⁠[19][20][21] The reaction is carried out at lower temperatures than the equilibrium methods; possible types are the high-temperature solution condensation, amine catalysed and interfacial reactions. In addition, the use of activating agents is counted as non-equilibrium method. The equilibrium constants for the acyl chloride-based condensation yielding arylates and polyarylates are very high indeed and are reported to be 4.3 × 103 and 4.7 × 103, respectively. This reaction is thus often referred to as a 'non-equilibrium' polyesterification. Even though the acyl chloride based synthesis is also subject of reports in the patent literature, it is unlikely that the reaction is utilized on the production scale.[22] The method is limited by the acid dichlorides' high cost, its sensitivity to hydrolysis and the occurrence of side reactions.[23]

The high temperature reaction (100 to > 300 °C) of an diacyl chloride with an dialcohol yields the polyester and hydrogen chloride. Under these relatively high temperatures the reaction proceeds rapidly without a catalyst:[21]

The conversion of the reaction can be followed by titration of the evolved hydrogen chloride. A wide variety of solvents has been described including chlorinated benzenes (e.g. dichlorobenzene), chlorinated naphthalenes or diphenyls, as well as non-chlorinated aromatics like terphenyls, benzophenones or dibenzylbenzenes. The reaction was also applied successfully to the preparation of highly crystalline and poorly soluble polymers which require high temperatures to be kept in solution (at least until a sufficiently high molecular weight was achieved).[23]

In an interfacial acyl chloride-based reaction, the alcohol (generally in fact a phenol) is dissolved in the form of an alkoxide in an aqueous sodium hydroxide solution, the acyl chloride in an organic solvent immiscible with water such as dichloromethane, chlorobenzene or hexane, the reaction occurs at the interface under high-speed agitation near room temperature.[21]

The procedure is used for the production of polyarylates (polyesters based on bisphenols), polyamides, polycarbonates, poly(thiocarbonate)s, and others. Since the molecular weight of the product obtained by a high-temperature synthesis can be seriously limited by side reactions, this problem is circumvented by the mild temperatures of interfacial polycondensation. The procedure is applied to the commercial production of bisphenol-A-based polyarylates like Unitika's U-Polymer.[4] Water could be in some cases replaced by an immiscible organic solvent (e. g. in the adiponitrile/carbon tetrachloride system).[21] The procedure is of little use in the production of polyesters based on aliphatic diols which have higher pKa values than phenols and therefore do not form alcoholate ions in aqueous solutions.[4] The base catalysed reaction of an acyl chloride with an alcohol may also be carried out in one phase using tertiary amines (e. g. triethylamine, Et3N) or pyridine as acid acceptors:

While acyl chloride-based polyesterifications proceed only very slowly at room temperature without a catalyst, the amine accelerates the reaction in several possible ways, although the mechanism is not fully understood.[21] However, it is known that tertiary amines can cause side-reactions such as the formation of ketenes and ketene dimers.⁠[24]

### Silyl method

In this variant of the HCl method, the carboxylic acid chloride is converted with the trimethyl silyl ether of the alcohol component and production of trimethyl silyl chloride is obtained

### Acetate method (esterification)

### Ring-opening polymerization

Aliphatic polyesters can be assembled from lactones under very mild conditions, catalyzed anionically, cationically, metallorganically or enzyme-based.[25][26] A number of catalytic methods for the copolymerization of epoxides with cyclic anhydrides have also recently been shown to provide a wide array of functionalized polyesters, both saturated and unsaturated. Ring-opening polymerization of lactones and lactides is also applied on the industrial scale.[27][28]

### Other methods

Numerous other reactions have been reported for the synthesis of selected polyesters, but are limited to laboratory-scale syntheses using specific conditions, for example using dicarboxylic acid salts and dialkyl halides or reactions between bisketenes and diols.[4]

Instead of acyl chlorides, so-called activating agents can be used, such as 1,1'-carbonyldiimidazole, dicyclohexylcarbodiimide, or trifluoroacetic anhydride. The polycondensation proceeds via the in situ conversion of the carboxylic acid into a more reactive intermediate while the activating agents are consumed. The reaction proceeds, for example, via an intermediate N-acylimidazole which reacts with catalytically acting sodium alkoxide:[4]

The use of activating agents for the production of high-melting aromatic polyesters and polyamides under mild conditions has been subject of intensive academic research since the 1980s, but the reactions have not gained commercial acceptance as similar results can be achieved with cheaper reactants.[4]

### Thermodynamics of polycondensation reactions

Polyesterifications are grouped by some authors[4][19] into two main categories: a) equilibrium polyesterifications (mainly alcohol-acid reaction, alcohol–ester and acid–ester interchange reactions, carried out in bulk at high temperatures), and b) non-equilibrium polyesterifications, using highly reactive monomers (for example acid chlorides or activated carboxylic acids, mostly carried out at lower temperatures in solution).

The acid-alcohol based polyesterification is one example of an equilibrium reaction. The ratio between the polymer-forming ester group (-C(O)O-) and the condensation product water (H2O) against the acid-based (-C(O)OH) and alcohol-based (-OH) monomers is described by the equilibrium constant KC.

KC=[...−C(O)O−...][HA2O][−C(O)OH][−OH]

The equilibrium constant of the acid-alcohol based polyesterification is typically KC ≤ 10, what is not high enough to obtain high-molecular weight polymers (DPn ≥ 100), as the number average degree of polymerization (DPn) can be calculated from the equilibrium constant KC.[20]

DPn=KC2+1

In equilibrium reactions, it is therefore necessary to remove the condensation product continuously and efficiently from the reaction medium in order to drive the equilibrium towards polymer.[20] The condensation product is therefore removed at reduced pressure and high temperatures (150–320 °C, depending on the monomers) to prevent the back reaction.[8] With the progress of the reaction, the concentration of active chain ends is decreasing and the viscosity of the melt or solution increasing. For an increase of the reaction rate, the reaction is carried out at high end group concentration (preferably in the bulk), promoted by the elevated temperatures.

Equilibrium constants of magnitude KC ≥ 104 are achieved when using reactive reactants (acid chlorides or acid anhydrides) or activating agents like 1,1′-carbonyldiimidazole. Using these reactants, molecular weights required for technical applications can be achieved even without active removal of the condensation product.

## History

In 1926, United States–based DuPont began research on large molecules and synthetic fibers. This early research, headed by Wallace Carothers, centered on what became nylon, which was one of the first synthetic fibers.[29] Carothers was working for DuPont at the time. Carothers' research was incomplete and had not advanced to investigating the polyester formed from mixing ethylene glycol and terephthalic acid. In 1928 polyester was patented in Britain by the British General Electric Company.[30] Carothers' project was revived by British scientists Whinfield and Dickson, who patented polyethylene terephthalate (PET) or PETE in 1941. Polyethylene terephthalate forms the basis for synthetic fibers like Dacron, Terylene and polyester. In 1946, DuPont bought all legal rights from Imperial Chemical Industries (ICI).[1]

## Environmental impact

### Biodegradation

The Futuro houses were made of fibreglass-reinforced polyester plastic; polyester-polyurethane, and poly(methyl methacrylate). One house was found to be degrading by cyanobacteria and Archaea.[31][32]

### Cross-linking

Unsaturated polyesters are thermosetting polymers. They are generally copolymers prepared by polymerizing one or more diols with saturated and unsaturated dicarboxylic acids (maleic acid, fumaric acid, etc.) or their anhydrides. The double bond of unsaturated polyesters reacts with a vinyl monomer, usually styrene, resulting in a 3-D cross-linked structure. This structure acts as a thermoset. The exothermic cross-linking reaction is initiated through a catalyst, usually an organic peroxide such as methyl ethyl ketone peroxide or benzoyl peroxide.

### Pollution of freshwater and seawater habitats

A team at Plymouth University in the UK spent 12 months analysing what happened when a number of synthetic materials were washed at different temperatures in domestic washing machines, using different combinations of detergents, to quantify the microfibres shed. They found that an average washing load of 6 kg could release an estimated 137,951 fibres from polyester-cotton blend fabric, 496,030 fibres from polyester and 728,789 from acrylic. Those fibers add to the general microplastics pollution.[33][34][35]

### Carbon footprint

The lifetime carbon emissions of a polyester t-shirt are estimated to be over 20kg CO2e, partly due to the intermediate polyethylene terephthalate in its production. Certification of low-carbon polyester has been suggested.[36] The carbon footprint can be reduced by using low-carbon energy in production.[37]

## Safety

### Fertility

Ahmed Shafik was a sexologist who won a Ig Nobel Prize on his research regarding how polyester can affect the fertility of rats,[38] dogs,[39] and men.[40]

Bisphenol A which is a endocrine disrupting chemical may be used in the synthesis of polyester.[41]

## Recycling

Recycling of polymers has become very important as the production and use of plastic is continuously rising. Global plastic waste may almost triple by 2060 if this continues.[42] Plastics can be recycled by various means like mechanical recycling, chemical recycling, etc. Among the recyclable polymers, polyester PET is one of the most recycled plastics.[43][44] The ester bond present in polyesters is susceptible to hydrolysis (acidic or basic conditions), methanolysis and glycolysis which makes this class of polymers suitable for chemical recycling.[45] Enzymatic/biological recycling of PET can be carried out using different enzymes like PETase, cutinase, esterase, lipase, etc.[46] PETase has been also reported for enzymatic degradation of other synthetic polyesters (PBT, PHT, Akestra™, etc.) which contains similar aromatic ester bond as that of PET.[47]

## See also

* Epoxy
* Glycerine phthalate
* Microfiber
* Oligoester
* Polyamide
* Rayon
* Viscose

## References

1. ↑ 1.0 1.1 1.2 1.3 1.4 "Polyesters". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. June 2000.
2. ↑ Mendelson, Cheryl (17 May 2005). Home Comforts: The Art and Science of Keeping House. Simon and Schuster. ISBN 9780743272865. https://books.google.com/books?id=xfB99Kf38MwC.
3. ↑ "Thermal Spray Abradable Coatings". https://www.gordonengland.co.uk/abradable.htm.
4. ↑ 4.00 4.01 4.02 4.03 4.04 4.05 4.06 4.07 4.08 4.09 4.10 4.11 Synthetic Methods in Step-Growth Polymers. Hoboken, New Jersey, US: John Wiley & Sons, Inc.. 2003.
5. ↑ Hefetz, Abraham; Fales, Henry M.; Batra, Suzanne W. T. (1979). "Natural Polyesters: Dufour's Gland Macrocyclic Lactones Form Blood Cell Laminesters in Colletes Bees". Science 204 (4391): 415–417. doi:10.1126/science.204.4391.415. PMID 17758016. Bibcode: 1979Sci...204..415H. https://www.science.org/doi/abs/10.1126/science.204.4391.415.
6. ↑ Eveleth, R.; Chachra, D. (19 December 2011). "Can Bees Make Tupperware?". Scientific American. http://www.scientificamerican.com/article.cfm?id=from-pollen-to-polyester.
7. ↑ "Synthesis and characterization of high-molecular weight aliphatic polyesters from monomers derived from renewable resources.". Journal of Applied Polymer Science 131 (15): 40579–40586. August 2014. doi:10.1002/app.40579. Bibcode: 2014JAPS..13140579K.
8. ↑ 8.0 8.1 "Synthesis of elastic biodegradable polyesters of ethylene glycol and butylene glycol from sebacic acid". Acta Biomaterialia 8 (8): 2911–8. August 2012. doi:10.1016/j.actbio.2012.04.026. PMID 22522011.
9. ↑ "Hyperbranched polymers for coating applications: a review.". Polymer-Plastics Technology and Engineering. 55 (1): 92–117. January 2016. doi:10.1080/03602559.2015.1021482.
10. ↑ "Hyperbranched polyesters by polycondensation of fatty acid-based AB n-type monomers.". Green Chemistry 19 (1): 259–69. 2017. doi:10.1039/C6GC02294D.
11. ↑ Plastic product material and process selection handbook. Elsevier. 2004. p. 85. ISBN 978-1-85617-431-2. https://books.google.com/books?id=Lqk5QgGoWFkC.
12. ↑ Parker, David; Bussink, Jan; van de Grampel, Hendrik T.; Wheatley, Gary W.; Dorf, Ernst-Ulrich; Ostlinning, Edgar; Reinking, Klaus; Schubert, Frank et al. (2012-04-15), Wiley-VCH Verlag GmbH & Co. KGaA, ed. (in en), Polymers, High-Temperature, Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, pp. a21_449.pub3, doi:10.1002/14356007.a21_449.pub4, ISBN 978-3-527-30673-2, http://doi.wiley.com/10.1002/14356007.a21_449.pub3, retrieved 2020-12-13
13. ↑ H.-G. Elias and R. Mülhaupt, in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2015, pp. 1–70.
14. ↑ P. E. Cassidy, T. M. Aminabhavi and V. S. Reddy, in Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc., Hoboken, New Jersey, US, 2000.
15. ↑ T. Whelan, Polymer Technology Dictionary, Springer Netherlands, Dordrecht, 1994.
16. ↑ Schuler, Mattias J. (1981). "Part 8: Dyeing with disperse dyes". Dyeing Primer. AATCC. p. 21. GGKEY:SK3T00EYAFR. https://books.google.com/books?id=FPz0QRwKHsMC&pg=PA21.
17. ↑ "Dacron sails | Elvstrøm Sails since 1954" (in en-US). https://elvstromsails.com/sail-technology/sail-materials/woven-sail-material-dacron/.
18. ↑ Principles of Polymer Chemistry. New York, New York, NY: Springer. 2012.
19. ↑ 19.0 19.1 "The basic principles of non-equilibrium polycondensation.". Polymer Science USSR 19 (4): 769–808. January 1977. doi:10.1016/0032-3950(77)90232-5.
20. ↑ 20.0 20.1 20.2 "Mechanisms of Aliphatic Polyester Formation". Biopolymers Online. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. 2005. pp. 371–383. doi:10.1002/3527600035.bpol3b12.
21. ↑ 21.0 21.1 21.2 21.3 21.4 "Polyesters". Comprehensive Polymer Science and Supplements. 5. Elsevier. 1989. pp. 275–315.
22. ↑ "Poly (ester-imide)s for industrial use". Progress in Polyimide Chemistry II. Advances in Polymer Science. 141. Berlin, Heidelberg: Springer. 1999. pp. 45–82. doi:10.1007/3-540-49814-1_2. ISBN 978-3-540-64963-2.
23. ↑ 23.0 23.1 "Synthesis of aliphatic polyesters by polycondensation using inorganic acid as catalyst". Polymers for Advanced Technologies 22 (5): 502–511. April 2011. doi:10.1002/pat.1541. PMID 25473252.
24. ↑ Handbook of Polyermer Synthesis (2nd ed.). CRC Press. 2004. ISBN 0-367-57822-0. OCLC 1156408945.
25. ↑ "Enzyme catalyzed synthesis of polyesters.". Progress in Polymer Science 30 (10): 949–81. October 2005. doi:10.1016/j.progpolymsci.2005.06.010.
26. ↑ "Ring-Opening Polymerization—An Introductory Review" (in en). Polymers 5 (2): 361–403. April 2013. doi:10.3390/polym5020361. ISSN 2073-4360. Bibcode: 2013Polys...5..361N.
27. ↑ "Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization". Advanced Drug Delivery Reviews 60 (9): 1056–76. June 2008. doi:10.1016/j.addr.2008.02.008. PMID 18403043. Bibcode: 2008ADDR...60.1056J. http://orbi.ulg.ac.be/handle/2268/3723.
28. ↑ "Controlled ring-opening polymerization of lactide and glycolide". Chemical Reviews 104 (12): 6147–76. December 2004. doi:10.1021/cr040002s. PMID 15584698.
29. ↑ "How polyester is made - material, manufacture, making, history, used, structure, steps, product, History". www.madehow.com. http://www.madehow.com/Volume-2/Polyester.html.
30. ↑ "The Development of the Synthetic Fibres". Journal of the Textile Institute Proceedings 42 (8): P411–P441. 1951. doi:10.1080/19447015108663852.
31. ↑ "Biodeterioration of modern materials in contemporary collections: can biotechnology help?". Trends in Biotechnology 24 (8): 350–4. August 2006. doi:10.1016/j.tibtech.2006.06.001. PMID 16782219.
32. ↑ "Saving a fragile legacy. Biotechnology and microbiology are increasingly used to preserve and restore the world's cultural heritage". EMBO Reports 7 (11): 1075–9. November 2006. doi:10.1038/sj.embor.7400844. PMID 17077862.
33. ↑ "Inside the lonely fight against the biggest environmental problem you've never heard of". The Guardian. 27 October 2014. https://www.theguardian.com/sustainable-business/2014/oct/27/toxic-plastic-synthetic-microscopic-oceans-microbeads-microfibers-food-chain.
34. ↑ Williams, Alan (27 September 2016). "Washing clothes releases thousands of microplastic particles into environment, study shows". Plymouth University. https://www.plymouth.ac.uk/news/washing-clothes-releases-thousands-of-microplastic-particles-into-environment-study-shows.
35. ↑ "Release of synthetic microplastic plastic fibres from domestic washing machines: Effects of fabric type and washing conditions". Marine Pollution Bulletin 112 (1–2): 39–45. November 2016. doi:10.1016/j.marpolbul.2016.09.025. PMID 27686821. Bibcode: 2016MarPB.112...39N.
36. ↑ Slanger, Dan (2024-11-15). "How Fashion and Furniture Can Lead Toward a Market for Lower-Emissions Polyester" (in en-US). https://rmi.org/how-fashion-and-furniture-can-lead-toward-a-market-for-lower-emissions-polyester/.
37. ↑ "Polyester Drives Surge in Apparel Sector Emissions | SupplyChainBrain" (in en). https://www.supplychainbrain.com/articles/42340-polyester-drives-surge-in-apparel-sector-emissions.
38. ↑ Shafik, Ahmed (1993). "Effect of Different Types of Textiles on Sexual Activity". European Urology (Elsevier BV) 24 (3): 375–380. doi:10.1159/000474332. ISSN 0302-2838. PMID 8262106.
39. ↑ Shafik, Ahmed (1993). "Effect of different types of textile fabric on spermatogenesis: an experimental study". Urological Research (Springer Science and Business Media LLC) 21 (5): 367–370. doi:10.1007/bf00296839. ISSN 0300-5623. PMID 8279095.
40. ↑ Shafik, Ahmed (1992). "Contraceptive efficacy of polyester-induced azoospermia in normal men". Contraception (Elsevier BV) 45 (5): 439–451. doi:10.1016/0010-7824(92)90157-o. ISSN 0010-7824. PMID 1623716.
41. ↑ D'Angelo, Stefania; Meccariello, Rosaria (2021-03-01). "Microplastics: A Threat for Male Fertility". International Journal of Environmental Research and Public Health (MDPI AG) 18 (5): 2392. doi:10.3390/ijerph18052392. ISSN 1660-4601. PMID 33804513.
42. ↑ "Global plastic waste set to almost triple by 2060, says OECD". 3 June 2022. https://www.oecd.org/environment/global-plastic-waste-set-to-almost-triple-by-2060.htm.
43. ↑ "How to keep a sustainable PET recycling industry in Europe - EPBP - European PET Bottle Platform". https://www.epbp.org/.
44. ↑ "Which Plastic Can Be Recycled?" (in en-US). 20 May 2021. https://www.plasticsforchange.org/blog/which-plastic-can-be-recycled.
45. ↑ Ghosal, Krishanu; Nayak, Chinmaya (2022-02-21). "Recent advances in chemical recycling of polyethylene terephthalate waste into value added products for sustainable coating solutions – hope vs. hype" (in en). Materials Advances 3 (4): 1974–1992. doi:10.1039/D1MA01112J. ISSN 2633-5409.
46. ↑ Ghosal, Krishanu; Nayak, Chinmaya (2022). "Recent advances in chemical recycling of polyethylene terephthalate waste into value added products for sustainable coating solutions – hope vs . hype" (in en). Materials Advances 3 (4): 1974–1992. doi:10.1039/D1MA01112J. ISSN 2633-5409.
47. ↑ Wagner-Egea, Paula; Tosi, Virginia; Wang, Ping; Grey, Carl; Zhang, Baozhong; Linares-Pastén, Javier A. (January 2021). "Assessment of IsPETase-Assisted Depolymerization of Terephthalate Aromatic Polyesters and the Effect of the Thioredoxin Fusion Domain" (in en). Applied Sciences 11 (18): 8315. doi:10.3390/app11188315. ISSN 2076-3417.

## Further reading

* Textiles, by Sara Kadolph and Anna Langford. 8th Edition, 1998.
* Spinning Machines https://en.wikipedia.org/wiki/Spinning_(textiles)

## External links

* Lipase catalyzed polyesterification: Enzyme-Catalyzed Polymerization of End-Functionalized Polymers in a Microreactor

* v
* t
* e

Plastics

Chemical types|

* Acrylonitrile butadiene styrene (ABS)
* Cross-linked polyethylene (PEX, XLPE)
* Ethylene vinyl acetate (EVA)
* Poly(methyl methacrylate) (PMMA)
* Poly(ethyl methacrylate) (PEMA)
* Polyacrylic acid (PAA)
* Polyamide (PA)
* Polybutylene (PB)
* Polybutylene terephthalate (PBT)
* Polycarbonate (PC)
* Polyetheretherketone (PEEK)
* Polyester (PEs)
* Polyethylene (PE)
* Polyethylene terephthalate (PET, PETE)
* Polyimide (PI)
* Polylactic acid (PLA)
* Polyoxymethylene (POM)
* Polyphenyl ether (PPE)
* Polypropylene (PP)
* Polystyrene (PS)
* Polysulfone (PES)
* Polytetrafluoroethylene (PTFE)
* Polyurethane (PU)
* Polyvinyl chloride (PVC)
* Polyvinylidene chloride (PVDC)
* Styrene maleic anhydride (SMA)
* Styrene-acrylonitrile (SAN)

Mechanical types|

* Thermoplastic
* Thermosetting polymer
* Duroplast
* Corrugated plastic
* Polymeric foam
* High performance plastics

Additives|

* Polymer additive
* Colorants
* Plasticizer
* Stabilizer for polymers
* Biodegradable additives
* Filler (materials)

Plastics processing|

* injection moulding
* plastics extrusion
* stretch-blow molding
* thermoforming
* compression molding
* calendering
* transfer molding
* laminating
* fiberglass molding
* pultrusion
* filament winding
* vacuum forming
* rotational molding

Products|

* Plastics industry
* Commodity plastics
* Engineering plastics
* High-performance plastics
* Plastic film
* Plastic bottle
* Plastic bag
* Plastic shopping bag
* Plastic cutlery
* Blister pack
* Foam food container
* Construction
* Geosynthetics
* Category:Plastics applications

Environment and health|

* v
* t
* e

Health issues of plastics and polyhalogenated compounds (PHCs)

Plasticizers: Phthalates|

* DIBP
* DBP
* BBP (BBzP)
* DIHP
* DEHP (DOP)
* DIDP
* DINP

Miscellaneous plasticizers|

* Organophosphates
* Adipates (DEHA
* DOA)

Monomers|

* Bisphenol A (BPA, in Polycarbonates)
* Vinyl chloride (in PVC)

Miscellaneous additives incl. PHCs|

* PBDEs
* PCBs
* Organotins
* PFCs
* Perfluorooctanoic acid

Health issues|

* Teratogen
* Carcinogen
* Endocrine disruptor
* Diabetes
* Obesity
* Obesogen
* Polymer fume fever

Pollution|

* Plastic pollution
* Rubber pollution
* Great Pacific garbage patch
* Persistent organic pollutant
* Dioxins
* List of environmental health hazards

Regulations|

* California Proposition 65
* European REACH regulation
* Japan Toxic Substances Law
* Toxic Substances Control Act

Waste|

* Plastic pollution
* Great Pacific garbage patch
* Persistent organic pollutant
* Dioxins
* List of environmental health hazards
* Plastic recycling
* Biodegradable plastic

Identification codes

* v
* t
* e

Fibers

Natural|

| Plant|

* Abacá
* Bagasse
* Bamboo
* Coir
* Cotton
* Fique
* Flax
* Linen
* Hemp
* Jute
* Kapok
* Kenaf
* Piña
* Pine
* Raffia
* Ramie
* Rattan
* Sisal
* Wood

|

Animal|

* Alpaca
* Angora
* Byssus
* Camel hair
* Cashmere
* Catgut
* Chiengora
* Guanaco
* Hair
* Llama
* Mohair
* Pashmina
* Qiviut
* Rabbit
* Silk
* Tendon
* Spider silk
* Wool
* Vicuña
* Yak

Mineral|

* Asbestos

Synthetic|

| Regenerated|

* Art silk

|

Semi-synthetic|

* Acetate
* Diacetate
* Lyocell
* Modal
* Rayon
* Triacetate

Mineral|

* Glass
* Carbon
* Tenax
* Basalt
* Metallic

Polymer|

* Acrylic
* Aramid
* Twaron
* Kevlar
* Technora
* Nomex
* Microfiber
* Modacrylic
* Nylon
* Olefin
* Polyester
* Polyethylene
* Dyneema
* Spectra
* Spandex
* Vectran
* Vinylon
* Vinyon
* Zylon

* Category
* Commons

* v
* t
* e

Fabric

Woven|

* Aertex
* Airdura
* Barathea
* Barkcloth
* Batiste
* Bedford cord
* Bengaline
* Beta cloth
* Bombazine
* Brilliantine
* Broadcloth
* Buckram
* Bunting
* Burlap
* Byrd Cloth
* C change
* Calico
* Cambric
* Canvas
* Chambray
* Capilene
* Cedar bark
* Challis
* Char cloth
* Charmeuse
* Charvet
* Cheesecloth
* Chiffon
* Chino
* Chintz
* Cloqué
* Cloth of gold
* Cordura
* Corduroy
* Duck
* Coutil
* Crape
* Crêpe
* Cretonne
* Dazzle
* Denim
* Dimity
* Donegal tweed
* Dornix
* Dowlas
* Drill
* Drugget
* Eolienne
* Flannel
* Foulard
* Fustian
* Gabardine
* Gauze
* Gazar
* Georgette
* Ghalamkar
* Gingham
* Grenadine
* Grenfell Cloth
* Grosgrain
* Habutai
* Haircloth
* Harris Tweed
* Herringbone
* Himroo
* Hodden
* Irish linen
* Jamdani
* Kerseymere
* Khādī
* Khaki drill
* Kente cloth
* Lamé
* Lawn
* Linsey-woolsey
* Loden
* Longcloth
* Mackinaw
* Madapollam
* Madras
* Moleskin
* Muslin
* Nainsook
* Nankeen
* Ninon
* Oilskin
* Organdy
* Organza
* Osnaburg
* Ottoman
* Oxford
* Paduasoy
* Percale
* Pongee
* Poplin
* Rakematiz
* Rayadillo
* Rep
* Rinzu
* Ripstop
* Russell cord
* Saga Nishiki
* Samite
* Sateen
* Satin
* Saye
* Scarlet
* Seersucker
* Sendal
* Serge
* Scrim
* Shot silk
* Stuff
* Taffeta
* Tais
* Ticking
* Toile
* Tucuyo
* Tweed
* Twill
* Ultrasuede
* Vegetable flannel
* Ventile
* Vinyl coated polyester
* Viyella
* Voile
* Wadmal
* Waffle
* Wigan
* Whipcord
* Zephyr
* Zorbeez

Figured woven|

* Brocade
* Camlet
* Damask
* Lampas
* Songket

Pile woven|

* Baize
* Chenille
* Corduroy
* Crimplene
* Fustian
* Mockado
* Moquette
* Plush
* Polar fleece
* Terrycloth
* Velours du Kasaï
* Velvet
* Velveteen
* Zibeline

Nonwoven|

* Felt
* Cedar bark

Knitted|

* Boiled wool
* Coolmax
* Machine knitting
* Milliskin
* Jersey
* Velour

Netted|

* Bobbinet
* Carbon fibers
* Lace
* Mesh
* Needlerun net
* Ninon
* Tulle

Technical|

* Ballistic nylon
* Ban-Lon
* Conductive
* Darlexx
* E-textiles
* Gannex
* Gore-Tex
* Lenticular
* Silnylon
* Spandex
* Stub-tex
* SympaTex
* Windstopper

Patterns|

* Argyle
* Bizarre silk
* Chiné
* Herringbone
* Houndstooth
* Kelsch
* Paisley
* Pin stripes
* Polka dot
* Shweshwe
* Tartan (plaid)
* Tattersall

Textile fibers|

* Acrylic
* Alpaca
* Angora
* Cashmere
* Coir
* Cotton
* Eisengarn
* Hemp
* Jute
* Kevlar
* Linen
* Mohair
* Nylon
* Microfiber
* Olefin
* Pashmina
* Polyester
* Piña
* Ramie
* Rayon
* Sea silk
* Silk
* Sisal
* Spandex
* Spider silk
* Wool

Finishing and
printing

* Androsia
* Batik
* Beetling
* Bingata
* Bògòlanfini
* Burnout
* Calendering
* Decatising
* Devoré
* Finishing
* Fulling
* Heatsetting
* Mercerization
* Moire
* Nap
* Parchmentising
* Rogan printing
* Rōketsuzome
* Roller printing
* Sanforization
* Tenterhook
* Textile printing
* Warp printing
* Waxed cotton
* Woodblock printing
* Indienne

Fabric mills|

* Carlo Barbera
* Cerruti
* Dormeuil
* Drago
* Ermenegildo Zegna
* E. Thomas
* Holland & Sherry
* Larusmiani
* Loro Piana
* Reda
* Scabal
* Vitale Barberis Canonico

Related|

* Dyeing
* Fiber
* History of textiles
* History of silk
* Knitting
* Pandy
* Shrinkage
* Swatches and strike-offs
* Synthetic fabric
* Terminology
* Manufacturing
* Preservation
* Weaving
* Yarn

* v
* t
* e

Clothing materials and parts

Garment structures|

* Armscye
* Collar
* Clerical collar
* Collar stays
* Detachable collar
* Cuff
* Dart
* Facing
* Fly
* Lapel
* Gore
* Hem
* Lining
* Placket
* Pleat
* Pocket
* Revers
* Ruffle
* Shoulder pad
* Strap
* Sleeve
* Train
* Waistband
* Yoke

Textiles|

| Natural|

* Cotton
* Fur
* Linen
* Silk
* Wool

|

Synthetic|

* Artificial leather
* Elastic
* Nylon
* Polyester
* Rayon
* Spandex

Animal hides / Leather|

* Calf
* Deer
* Goat
* Kangaroo
* Ostrich
* Seal
* Sheep
* Snake
* Stingray

Fasteners|

* Back closure
* Belt hook
* Buckle
* Button
* Buttonhole
* Frog
* Shank
* Hook-and-eye
* Hook-and-loop
* Velcro
* Snap
* Zipper

Seams|

* Neckline
* Bustline
* Waistline
* Hemline

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