Sulfuryl fluoride

Sulfuryl fluoride  | Structure and dimensions of sulfuryl fluoride | Ball-and-stick model of sulfuryl fluoride

|

Names
IUPAC name

Sulfuryl fluoride

Other names

Sulfonyl fluoride; Sulfur dioxide difluoride; Sulphuryl fluoride; Sulfuryl difluoride; Vikane; Zythor

Identifiers

CAS Number

* 2699-79-8 Y

3D model (JSmol)

* Interactive image

ChEBI |

* CHEBI:39287 Y

ChemSpider |

* 16647 Y

PubChem CID

* 17607

UNII |

* 64B59K7U6Q Y

InChI

* InChI=1S/F2O2S/c1-5(2,3)4 Y

Key: OBTWBSRJZRCYQV-UHFFFAOYSA-N Y

* InChI=1/F2O2S/c1-5(2,3)4

Key: OBTWBSRJZRCYQV-UHFFFAOYAJ

SMILES

* FS(F)(=O)=O

Properties

Chemical formula

| SO2F2
Molar mass | 102.06 g/mol
Appearance  | colourless gas
Odor | odorless[1]
Density | 4.172 g/L (gas), 1.632 g/mL (liquid under compressed gas at 0 °C)
Melting point |  −124.7 °C (−192.5 °F; 148.5 K)
Boiling point |  −55.4 °C (−67.7 °F; 217.8 K)

Solubility in water

| 0.2% (0°C)[1]
Solubility in other solvents  | SO2
Vapor pressure | 15.8 atm (21°C)[1]
Structure

Coordination geometry

| tetrahedral
Hazards
Main hazards | neurotoxin
NFPA 704 (fire diamond)  |

Lethal dose or concentration (LD, LC):

LC50 (median concentration)

| 991 ppm (rat, 4 hr)[2]

LCLo (lowest published)

| 1200 ppm (mouse, 1 hr)
5000 ppm (rabbit, 1 hr)[2]
NIOSH (US health exposure limits):

PEL (Permissible)

| TWA 5 ppm (20 mg/m3)[1]

REL (Recommended)

| TWA 5 ppm (20 mg/m3) ST 10 ppm (40 mg/m3)[1]

IDLH (Immediate danger)

| 200 ppm[1]
Related compounds

Other anions

| SO2Cl2,
SO2ClF

Other cations

| SeO2F2

Related compounds

| SF6,
SO3
SO2F3−
CrO

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Tracking categories (test):

* PairSizeSet

Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO2F2. It is an easily condensed gas and has properties more similar to sulfur hexafluoride than sulfuryl chloride, being resistant to hydrolysis even up to 150 °C.[3] It is neurotoxic and a potent greenhouse gas, but is widely used as a fumigant insecticide to control termites.

## Contents

* 1 Structure, preparation, reactions
* 2 Use as a fumigant
* 2.1 Fumigation methodology
* 2.2 U.S. perspective
* 3 Health hazards
* 3.1 Case studies
* 4 Greenhouse gas
* 5 References
* 6 External links

## Structure, preparation, reactions

The molecule is tetrahedral with C2v symmetry. The S-O distance is 140.5 pm, S-F is 153.0 pm. As predicted by VSEPR, the O-S-O angle is more open than the F-S-F angle, 124° and 97°, respectively.[3]

One synthesis begins with the preparation of potassium fluorosulfite:[4]

SO2 \+ KF → KSO2F

This salt is then chlorinated to give sulfuryl chloride fluoride:

KSO2F + Cl2 → SO2ClF + KCl

Heating the sulfuryl chloride fluoride with potassium fluorosulfite at 180 °C gives the desired product:[5]

SO2ClF + KSO2F → SO2F2 \+ KCl + SO2

Heating metal fluorosulfonate salts also gives this molecule:[3]

Ba(OSO2F)2 → BaSO4 \+ SO2F2

It can be prepared by direct reaction of fluorine with sulfur dioxide:

SO2 \+ F2 → SO2F2

On a laboratory scale, sulfuryl fluoride has been conveniently prepared from 1,1'-sulfonyldiimidazole, in the presence of potassium fluoride and acid.[6][7]

Sulfuryl fluoride is unreactive toward molten sodium metal.[3] Similarly it is slow to hydrolyze, but eventually converts to sulfur trioxide.[8][9]

Sulfuryl fluoride gas is a precursor to fluorosulfates and sulfamoyl fluorides:[10]

SO2F2 \+ ROH + base → ROSO2F + Hbase+F−

## Use as a fumigant

Originally developed by the Dow Chemical Company, sulfuryl fluoride is in widespread use as a structural fumigant insecticide to control drywood termites, particularly in warm-weather portions of the southwestern and southeastern United States and in Hawaii. It has a non-specific mode of action (IRAC group 8C). Less commonly, it can also be used to control rodents, powderpost beetles, deathwatch beetles, bark beetles, and bedbugs. Its use has increased as a replacement for methyl bromide, which was phased out because of harm to the ozone layer. It is an alternative to the use of phosphine, which is acutely toxic.[11]

### Fumigation methodology

During application, the building is enclosed and filled with the gas for a period of time, usually at least 16–18 hours, sometimes as long as 72 hours. The building must then be ventilated, generally for at least 6 hours, before occupants can return. California regulations are such that the tent will be on for three to five days, which includes ventilation. In the US, sulfuryl fluoride must be transported in a vehicle marked with "Inhalation Hazard 2" placards.[12][13] Most states require a license or certification for the individual applying the fumigant.

The concentration is continuously monitored and maintained at the specified level using electronic equipment. Possible leakages are also checked by low range electronic detectors. Reentry to the home is allowed when the concentration level is at or below 5 ppm.[14] Sulfuryl fluoride is colorless and odorless, however, during the fumigation process, a warning agent called chloropicrin is first released into the building to ensure that no occupants remain. Tent fumigation is the most effective treatment for the extermination of known and unknown infestations of wood-destroying insects. Heat is the only other approved method for whole structure treatment for termites in California.[15] Sulfuryl fluoride provides no protection from future infestations, although heavy re-infestation can take several years since drywood termites have slower growing colonies than ground termites.

### U.S. perspective

Sulfuryl fluoride is marketed in the U.S. by three manufacturers, under four different brand names. Vikane (Dow) (EPA Reg. No. 62719- 4-ZA) has been commercially available since the early 1960s, with Zythor (marketed by competitor Ensystex of North Carolina) (EPA Reg. No. 81824- 1-AA) being more recently introduced gradually as its use is approved by individual states (in Florida circa 2004, but not in California until October 2006, for example). Sulfuryl fluoride has been marketed as a post-harvest fumigant for dry fruits, nuts, and grains under the trade name ProFume (U.S. EPA Reg. No. 62719- 376-AA).[16] Most recently Drexel Chemical Company has registered Master Fume (EPA Reg. No. 19713-596-AA) for the structural market, competing against Vikane and Zythor.[17]

## Health hazards

Inhalation of sulfuryl fluoride is hazardous and may result in respiratory irritation, pulmonary edema, nausea, abdominal pain, central nervous system depression, numbness in the extremities, muscle twitching, seizures, and death.[18][19][20] These high exposures occurred when people entered into structures illegally during fumigation or after insufficient aeration. Epidemiological studies showed that fumigation workers who used sulfuryl fluoride showed neurological effects, which included reduced performance on cognitive tests and pattern memory tests, and reduced olfactory function.[21]

### Case studies

In 1987, an elderly couple was exposed to sulfuryl fluoride in their house already cleared for reentry.[21] While the fumigation company opened windows and doors, and aerated the house with fans, sulfuryl fluoride level was not measured. It was not detected when the air was sampled 12 days after aeration. The couple experienced weakness, nausea and shortness of breath that evening. The man suffered a seizure and died the following day. His wife's condition got worse with pulmonary edema, and she died after a cardiovascular arrest 6 days later.

In 2015, a 10-year-old boy suffered severe brain damage and lost function of his left arm and leg after his home was treated with sulfuryl fluoride and insufficiently aerated, prompting a criminal investigation by the Department of Justice and the Florida Department of Agricultural and Consumer Services.[22] Two pest control workers later pled guilty to charges of misuse of the pesticide resulting in the boy's poisoning, and were each sentenced to one year in prison.[23]

In 2016, a 24-year-old man who allegedly entered an apartment that was being fumigated in Fremont, California to commit a burglary was exposed to sulfuryl fluoride and chloropicrin and died shortly thereafter. According to a police officer, he experienced labored breathing and was sweating before he collapsed just a few steps from the first floor window of the apartment he allegedly burglarized.[24]

In April 2024, In Pompano Beach Florida, two company pesticide workers died. The owner was also hospitalized but survived.[25]

## Greenhouse gas

Sulfuryl fluoride (SO2F2) measured by the Advanced Global Atmospheric Gases Experiment (AGAGE) in the lower atmosphere (troposphere) at stations around the world. Abundances are given as pollution free monthly mean mole fractions in parts-per-trillion. Sulfuryl fluoride timeseries at various latitudes.

Based on the first high frequency, high precision, in situ atmospheric and archived air measurements, sulfuryl fluoride has an atmospheric lifetime of 30–40 years,[8] much longer than the 5 years earlier estimated.[26]

Sulfuryl fluoride has been reported to be a greenhouse gas which is about 4000–5000 times more efficient in trapping infrared radiation (per kg) than carbon dioxide (per kg).[8][27][28] The amount of sulfuryl fluoride released into the atmosphere is about 2000 metric tons per year.[8] The most important loss process of sulfuryl fluoride is dissolution of atmospheric sulfuryl fluoride in the ocean followed by hydrolysis.

## References

1. ↑ 1.0 1.1 1.2 1.3 1.4 1.5 NIOSH Pocket Guide to Chemical Hazards. "#0581". National Institute for Occupational Safety and Health (NIOSH). https://www.cdc.gov/niosh/npg/npgd0581.html.
2. ↑ 2.0 2.1 "Sulfuryl fluoride". Immediately Dangerous to Life and Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH). https://www.cdc.gov/niosh/idlh/2699798.html.
3. ↑ 3.0 3.1 3.2 3.3 Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
4. ↑ Seel, F. "Potassium Fluorosulfite" Inorganic Syntheses 1967, IX, pages 113-115. doi:10.1002/9780470132401.ch29.
5. ↑ Seel, F. "Sulfuryl Chloride Fluoride and Sulfuryl Fluoride" Inorganic Syntheses 1967, vol. IX, pages 111-113. doi:10.1002/9780470132401.ch28
6. ↑ Veryser, Cedrick; Demaerel, Joachim; Bieliunas, Vidmantas; Gilles, Philippe; De Borggraeve, Wim M. (2017-10-06). "Ex Situ Generation of Sulfuryl Fluoride for the Synthesis of Aryl Fluorosulfates" (in en). Organic Letters 19 (19): 5244–5247. doi:10.1021/acs.orglett.7b02522. ISSN 1523-7060. PMID 28901771. https://lirias.kuleuven.be/handle/123456789/599322.
7. ↑ Gurjar, Jitendra; Bater, Jorick; Fokin, Valery V. (2019-02-06). "Sulfuryl Fluoride Mediated Conversion of Aldehydes to Nitriles" (in en). Chemistry – A European Journal 25 (8): 1906–1909. doi:10.1002/chem.201805175. ISSN 0947-6539. PMID 30346050. Bibcode: 2019ChEuJ..25.1906G.
8. ↑ 8.0 8.1 8.2 8.3 Mühle, J., J. Huang, R.F. Weiss, R.G. Prinn, B.R. Miller, P.K. Salameh, C.M. Harth, P.J. Fraser, L.W. Porter, B.R. Greally, S. O'Doherty, and P.G. Simmonds, Sulfuryl Fluoride in the Global Atmosphere, Journal of Geophysical Research, 114, D05306, doi:10.1029/2008JD011162, 2009
9. ↑ Cady, G.H., and S. Misra, Hydrolysis of Sulfuryl Fluoride, Inorganic Chemistry, 13 (4), 837-841, 1974. doi:10.1021/ic50134a016
10. ↑ Dong, J.; Krasnova, L.; Finn, M. G.; Sharpless, K. B. (2014). "Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry". Angewandte Chemie International Edition 53 (36): 9430–9448. doi:10.1002/anie.201309399. PMID 25112519. Bibcode: 2014ACIE...53.9430D.
11. ↑ Bell, C. H. "Fumigation in the 21st century" "Crop Protection, 2000, 19, 563-569. ISSN 0261-2194. AN 2000:895590
12. ↑ "Code of Federal Regulations, Title 49, Part 172.101". 5 September 2015. http://www.gpo.gov/fdsys/pkg/CFR-1998-title49-vol2/xml/CFR-1998-title49-vol2-part172.xml.
13. ↑ "Electronic Code of Federal Regulations, 49 CFR part 172.540, POISON GAS placard". 5 September 2015. http://www.ecfr.gov/cgi-bin/text-idx?SID=e1d8b9021caef9e89cb8f89a491f08a2&mc=true&node=se49.2.172_1540&rgn=div8.
14. ↑ "SULFURYL FLUORIDE (Vikane®) RISK CHARACTERIZATION DOCUMENT". State of California. http://www.cdpr.ca.gov/docs/emon/pubs/tac/draft_rcd_pdfs/sf_rcd_execsum.pdf.
15. ↑ Termites Fact Sheet
16. ↑ "Welcome to Corteva Agriscience". http://www.dowagro.com/profume/index.htm.
17. ↑ "Output Reporting". http://www.cdpr.ca.gov/cgi-bin/label/labq.pl?p_chem=618&activeonly=on.
18. ↑ "Systemic fluoride poisoning and death from inhalational exposure to sulfuryl fluoride". Clin Toxicol 46 (9): 850–4. November 2008. doi:10.1080/15563650801938662. PMID 18608259.
19. ↑ Centers for Disease Control (CDC) (Sep 18, 1987). "Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia". MMWR Morb Mortal Wkly Rep 36 (36): 602–4, 609–11. PMID 3114607.
20. ↑ Scheuerman EH (1986). "Suicide by exposure to sulfuryl fluoride". J Forensic Sci 31 (3): 1154–8. doi:10.1520/JFS11128J. PMID 3734735.
21. ↑ 21.0 21.1 "SULFURYL FLUORIDE (Vikane®) RISK CHARACTERIZATION DOCUMENT". State of California. http://www.cdpr.ca.gov/docs/emon/pubs/tac/tacpdfs/sulfluor/final_rcd_vol1.pdf.
22. ↑ Ganim, Sara (5 September 2015). "10-year-old hospitalized after termite fumigation". http://www.cnn.com/2015/09/04/us/termite-fumigation-hospitalization/index.html. "Sulfuryl fluoride, a gas fumigant, was the pesticide used to fumigate, sources told CNN."
23. ↑ "Fumigators sentenced in child's poisoning". 11 May 2016. http://www.wptv.com/news/region-martin-county/palm-city/9-months-after-peyton-mccaughey-was-poisoned-florida-pest-control-industry-stronger-than-ever.
24. ↑ "Fremont Burglary Suspect Who Entered Fumigated Home Dies". 20 May 2016. http://sanfrancisco.cbslocal.com/2016/05/20/fremont-burglary-suspect-fumigated-home-dies/.
25. ↑ "Cause of death released for 1 of 2 pest control workers who died after Pompano Beach job". 24 June 2023. https://www.nbcmiami.com/news/local/cause-of-death-released-for-1-of-2-pest-control-workers-who-died-after-pompano-beach-job/3053949/.
26. ↑ KEMI, SULFURYL FLUORIDE (PT8), Competent Authority Report, Document III-A7, Ecotoxicological Profile Including Environmental Fate and Behaviour, Swedish Chemicals Agency, Sweden, 2005.
27. ↑ Papadimitriou, V.C., R.W. Portmann, D.W. Fahey, J. Mühle, R.F. Weiss, and J.B. Burkholder, Experimental and Theoretical Study of the Atmospheric Chemistry and Global Warming Potential of SO2F2, Journal of Physical Chemistry A, 112 (49), 12657-12666, doi:10.1021/jp806368u, 2008.
28. ↑ Sulbaek Andersen, M.P., D.R. Blake, F.S. Rowland, M.D. Hurley, and T.J. Wallington, Atmospheric Chemistry of Sulfuryl Fluoride: Reaction with OH Radicals, Cl Atoms and O3, Atmospheric Lifetime, IR Spectrum, and Global Warming Potential, Environmental Science & Technology, doi:10.1021/es802439f, 2009.

## External links

* Sulfuryl Fluoride Technical Fact Sheet - National Pesticide Information Center
* Sulfuryl Fluoride General Fact Sheet - National Pesticide Information Center
* Sulfuryl Fluoride Pesticide Information Profile - Extension Toxicology Network
* NIOSH Pocket Guide to Chemical Hazards - Centers for Disease Control and Prevention

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* t
* e

Neurotoxins

Animal|

* Batrachotoxin
* Bestoxin
* Birtoxin
* Bungarotoxin
* Charybdotoxin
* Conotoxin
* Fasciculin
* Huwentoxin
* Poneratoxin
* Saxitoxin
* Tetrodotoxin
* Vanillotoxin
* Spooky toxin (SsTx)
* Epibatidine
* Zetekitoxin AB
* Dendrotoxin

Bacterial|

* Botulinum toxin
* Tetanospasmin

Cyanotoxins|

* Anatoxin-a
* Anatoxin-a(S)
* BMAA
* Saxitoxin

Plant|

* Bicuculline
* Penitrem A
* Picrotoxin
* Strychnine
* Tutin
* Rotenone
* Ginkgotoxin
* Cicutoxin
* Oenanthotoxin
* Thujone
* Volkensin

Mycotoxins|

* Ibotenic acid
* Muscarine
* Muscimol

Pesticides|

* Fenpropathrin
* Tetramethylenedisulfotetramine
* Bromethalin
* Crimidine
* Methamidophos
* Endosulfan
* Fipronil
* Phenylsilatrane
* Chlorophenylsilatrane
* Sulfuryl fluoride
* Mipafox
* Schradan
* Dimefox

Nerve agents|

* Cyclosarin
* EA-3148
* Novichok agent
* Sarin
* Soman
* Tabun
* VE
* VG
* VM
* VP
* VR
* VX
* GV
* EA-3990
* EA-4056
* T-1123
* Octamethylene-bis(5-dimethylcarbamoxyisoquinolinium bromide)
* Fluorotabun
* Chinese VX
* EA-2192

Bicyclic phosphates|

* TBPS
* TBPO
* IPTBO

Other|

* Dimethylmercury
* Toxopyrimidine
* IDPN

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* t
* e

Sulfur compounds

* Al2S3
* As2S2
* As2S3
* As2S5
* As4S4
* Au2S
* Au2S3
* B2S3
* BaS
* BeS
* Bi2S3
* Br2S
* Br2S2
* CS2
* C3S2
* C6S6
* CaS
* CdS
* CeS
* SCl2
* S2Cl2
* CoS
* Cr2S3
* CuS
* D2S
* Dy2S3
* Er2S3
* EuS
* SF4
* S2F10
* SF6
* FeS2
* GaS
* H2S
* HfS2
* HgS
* InS
* I2S
* LaS
* LiS
* MgS
* MoS3
* NiS
* SO2
* SO3
* P4S7
* PbS
* PbS2
* PtS
* ReS2
* SrS
* TlS
* SV
* SeS2
* S2U
* WS2
* Sb2S3
* Sb2S5
* Sm2S3
* Y2S3
* Ag2SO4
* SOBr2
* CSTe
* C2H4S
* C2H6S3
* C4H4S
* CaSO4
* C32H66S2
* CuFeS2
* H2SO4
* H2SO3
* F2OS
* NaHS
* K2SO3
* O3S3Sb4
* Yb2(SO4)3
* AlKO8S2
* CHCl3S
* KSCN
* CdSO3
* PSCl3
* SOCl2
* Cs2O4S
* Re2S7
* Na2S
* K2S
* H2S2O7
* H2SO5
* NH5S
* HgSO4
* K2SO4
* RaSO4
* SnSO4
* SrSO4
* Zr(SO4)2
* Ti(SO4)2
* Tm2(SO4)3
* AlNa(SO4)2
* Er2(SO4)3
* Eu2(SO4)3
* CHNS
* Co(SCN)2
* C2H3SN
* PSI3
* ZrS2
* SiS
* CSSe

Chemical formulas

* v
* t
* e

Oxygen compounds

* AgO
* Al2O3
* AmO2
* Am2O3
* As2O3
* As2O5
* Au2O3
* B2O3
* BaO
* BeO
* Bi2O3
* BiO2
* Bi2O5
* BrO2
* Br2O3
* Br2O5
* CO
* CO2
* C2O3
* CaO
* CaO2
* CdO
* CeO2
* Ce3O4
* Ce2O3
* ClO2
* Cl2O
* Cl2O3
* Cl2O4
* Cl2O6
* Cl2O7
* CoO
* Co2O3
* Co3O4
* CrO3
* Cr2O3
* Cr2O5
* Cr5O12
* CsO2
* Cs2O3
* CuO
* D2O
* Dy2O3
* Er2O3
* Eu2O3
* FeO
* Fe2O3
* Fe3O4
* Ga2O
* Ga2O3
* GeO
* GeO2
* H2O
* H218O
* H2O2
* HfO2
* HgO
* Hg2O
* Ho2O3
* I2O4
* I2O5
* I2O6
* I4O9
* In2O3
* IrO2
* KO2
* K2O2
* La2O3
* Li2O
* Li2O2
* Lu2O3
* MgO
* Mg2O3
* MnO
* MnO2
* Mn2O3
* Mn2O7
* MoO2
* MoO3
* Mo2O3
* NO
* NO2
* N2O
* N2O3
* N2O4
* N2O5
* NaO2
* Na2O
* Na2O2
* NbO
* NbO2
* Nd2O3
* OF2
* O2F2
* O3F2
* O4F2
* O2PtF6

Chemical formulas

* v
* t
* e

Fluorine compounds

| HF |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|

LiF | BeF2 |  |  |  |  |  |  |  |  |  |  | BF3
B2F4 | CF4 | NF3 | OF2 | F− | Ne
NaF | MgF2 |  |  |  |  |  |  |  |  |  |  | AlF3 | SiF4 | PF3
PF5 | SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF2 | ScF3 | TiF3
TiF4 | VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5 | MnF2
MnF3 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF3 | GeF4 | AsF3
AsF5 | SeF4
SeF6 | BrF3
BrF5 | KrF2
RbF | SrF2 | YF3 | ZrF4 | NbF4
NbF5 | MoF5
MoF6 | TcF6 | RuF3
RuF4
RuF5
RuF6 | RhF6 | PdF2 | AgF
AgF2
Ag2F | CdF2 | InF3 | SnF2
SnF4 | SbF3
SbF5 | TeF4 | IF
IF3
IF5
IF7 | XeF2
XeF4
XeF6
CsF | BaF2 | *  | HfF4 | TaF5 | WF4
WF6 | ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF3
IrF5
IrF6 | PtF4
PtF6 | AuF3
Au2F10
AuF5·F2
| HgF2
Hg2F2 | TlF
TlF3 | PbF2
PbF4 | BiF3
BiF5 | Po | At | RnF2
Fr | Ra | **  | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | LaF3 | CeF3 | Pr | NdF3 | PmF3 | SmF3
| Eu | Gd | Tb | DyF3 | Ho | Er | Tm | YbF3
| Lu |
| ** | AcF3 | ThF4 | Pa | UF3
UF4
UF5
UF6 | NpF3
NpF4
NpF5
NpF6
| PuF3
PuF4
PuF5
PuF6 | AmF3
AmF4 | CmF3 | Bk | Cf | Es | Fm | Md | No | Lr |

Other|

* AgBF4
* AgPF6
* Cs2AlF5
* K3AlF6
* Na3AlF6
* KAsF6
* LiAsF6
* NaAsF6
* HBF4
* KBF4
* LiBF4
* NaBF4
* RbBF4
* Ba(BF4)2
* Ni(BF4)2
* Pb(BF4)2
* Sn(BF4)2
* BaClF
* BaSiF6
* BaGeF6
* BrOF3
* BrO2F
* CBrF3
* CBr2F2
* CBr3F
* CClF3
* CCl2F2
* CCl3F
* CFN
* CF2O
* CF3I
* CHF3
* CH2F2
* CH3F
* C2Cl3F3
* C2H3F
* C6H5F
* C7H5F3
* C15F33N
* ClFO2
* CrFO4
* CrF2O2
* CsBF4
* NH4F
* FNO
* FNO2
* FNO3
* KHF2
* NaHF2
* ThOF2
* NH5F2
* (NH4)2SiF6
* F2OS
* F3OP
* PSF3
* HPF6
* HSbF6
* NH4PF6
* KPF6
* KSbF6
* LiPF6
* NaPF6
* NaSbF6
* Na2SiF6
* Na2TiF6
* Na2ZrF6
* TlPF6
* IOF3
* K2NbF7
* K2TaF7
* IO3F
* UO2F2

Chemical formulas

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Original source: https://en.wikipedia.org/wiki/Sulfuryl fluoride. Read more

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