Sulfate nitrates

Short description: Class of chemical compounds

The sulfate nitrates are a family of double salts that contain both sulfate and nitrate ions (NO3−, SO42−). They are in the class of mixed anion compounds. A few rare minerals are in this class. Two sulfate nitrates are in the class of anthropogenic compounds, accidentally made as a result of human activities in fertilizers that are a mix of ammonium nitrate and ammonium sulfate, and also in the atmosphere as polluting ammonia, nitrogen dioxide, and sulfur dioxide react with the oxygen and water there to form solid particles. The nitro group (NO3−) can act as a ligand, and complexes containing it can form salts with sulfate.[1]

## List

name  | formula  | ratio  | system  | space group  | unit cell  | volume Å3 | density  | optical  | references

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Darapskite  | Na3(SO4)(NO3) · H2O  | 1:1  | Monoclinic  | 2/m | a = 10.57 Å, b = 6.91 Å, c = 5.18 Å β = 102.77°  | 368.98  |  | Biaxial (-) nα = 1.388 nβ = 1.479 nγ = 1.486

2V: 28°

| [2]
Humberstonite  | Na7K3Mg2(SO4)6(NO3)2 · 6H2O  | 6:2  | Trigonal  | R3 | a = 10.905 Å, c = 24.394 Å Z=3  | 2,512.26  | 2.252  | Uniaxial (-) nω = 1.474 nε = 1.436  | [3]
Ungemachite  | K3Na8Fe(SO4)6(NO3)2 · 6H2O  | 6:2  | Trigonal  | R3 | a = 10.898 Å, c = 24.989 Å  | 2,570.24  | 2.287  | Uniaxial (-) nω = 1.502 nε = 1.449  | [4]
Mbobomkulite  | Ni0.75Cu0.25Al4(NO3)1.5(SO4)0.5(OH)12•3(H2O)  | ?  | Monoclinic  | P21 | a =10.171 b=8.865 c=17.145 β=95.37°  | 1,539.11  | 2.45  | blue  | [5]
hydrombobomkulite  |  |  |  |  |  |  |  |  |
Witzkeite  | Na4K4Ca(NO3)2(SO4)4·2H2O  | 4:2  | Monoclinic  | C2/c | a = 24.902, b = 5.3323, c = 17.246 Å, β = 94.281(7)°,  | 2283.6  | 2.40  | biaxial (−) α = 1.470, β = 1.495, γ = 1.510, 2V = 50–70°  | [6]
Artificial
Ammonium sulfate nitrate 2AN.AS  | (NH4)4SO4(NO3)2 | 1:2  | Monoclinic  | P21/c | a=10.3178 b=11.4014 c=10.2567 β=105.956 z=4
| 1160.09  |  |  | [7][8]
Ammonium sulfate nitrate 3AN.AS  | (NH4)5SO4(NO3)3 | 1:3  | Monoclinic  | P21 | a=9.9566 b=5.9332 c=12.4161 β=92.817 z=2  | 732.59  |  |  | [9][8]
?  | K(NH4)3(NO3)2SO4 |  |  |  |  |  |  |  | [10]
?  | K2(NH4)2(NO3)2SO4 |  |  |  |  |  |  |  | [10]
Neodymium sulfate nitrate trihydrate  | Nd[SO4][NO3]·3H2O  | 1:1  | Monoclinic  | P21/m | a = 6.3056, b = 6.9234, c = 8.9827, β = 93.305° Z=2  |  |  | Pale violet  | [11]
Complexes
| [Co(2,2'-bipy)2(NO3)]2SO4·(H2O)5 |  |  |  |  |  |  |  | [12]
thiourea complex  | [Cu4(SCN2H4)7(NO3)](NO3)(SO4) · 3.3H2O  |  | Monoclinic  | P21 | a = 12.6072 Å, b = 15.4265 Å, c=22.108 Å, β=120.133° Z=4  |  |  |  | [1]
guanidinium  | CN3H6Bi(NO3)2SO4 | 1:2  |  |  |  |  |  |  | [13]
ethylenediammonium  | C2N2H10BiNO3(SO4)2 | 2:1  |  |  |  |  |  |  | [13]
ethylenediammonium  | (C2N2H10)5Bi4(NO3)2(SO4)10·8H2O  | 10:2  |  |  |  |  |  |  | [13]

## References

1. ↑ 1.0 1.1 Solov'ev, L. A.; Vasil'ev, A. D.; Golovnev, N. N. (2002). "Mixed Complex Salt [Cu4(SCN2H4)7(NO3)](NO3)(SO4)•3.3H2O: Synthesis and X-Ray Diffraction Analysis". Russian Journal of Coordination Chemistry 28 (8): 587–592. doi:10.1023/A:1019765831404.
2. ↑ "Darapskite: Mineral information, data and localities.". https://www.mindat.org/min-1226.html.
3. ↑ "Humberstonite: Mineral information, data and localities.". https://www.mindat.org/min-1944.html.
4. ↑ "Ungemachite: Mineral information, data and localities.". https://www.mindat.org/min-4095.html.
5. ↑ "Mbobomkulite Mineral Data". http://webmineral.com/data/Mbobomkulite.shtml.
6. ↑ Nestola, F.; Camara, F.; Chukanov, N. V.; Atencio, D.; Coutinho, J. M. V.; Contreira Filho, R. R.; Farber, G. (2012-10-01). "Witzkeite: A new rare nitrate-sulphate mineral from a guano deposit at Punta de Lobos, Chile" (in en). American Mineralogist 97 (10): 1783–1787. doi:10.2138/am.2012.4109. ISSN 0003-004X. Bibcode: 2012AmMin..97.1783N. https://pubs.geoscienceworld.org/ammin/article/97/10/1783-1787/45561.
7. ↑ Jänecke, Ernst; Eissner, W.; Brill, Rudolf (1927-02-21). "Über das System NH 4 NO 3 (NH 4 ) 2 SO 4 H 2 O" (in en). Zeitschrift für anorganische und allgemeine Chemie 160 (1): 171–184. doi:10.1002/zaac.19271600117.
8. ↑ 8.0 8.1 Montejo-Bernardo, J. M.; García-Granda, S.; Fernández-González, A. (2010-06-01). "Structures of relevant ammonium salts in fertilizers". Acta Crystallographica Section B: Structural Science 66 (3): 358–365. doi:10.1107/S0108768110015430. ISSN 0108-7681. PMID 20484806. http://scripts.iucr.org/cgi-bin/paper?S0108768110015430.
9. ↑ Smith, J. P.; Lehr, J. R.; Frazier, A. W. (January 1962). "Characterization of Fertilizer Materials, Crystallographic Properties of the Ammonium Nitrate-Sulfates 3NH 4 NO 3 (NH 4 ) 2 SO 4 and 2NH 4 NO 3 (NH 4 ) 2 SO 4" (in en). Journal of Agricultural and Food Chemistry 10 (1): 77–78. doi:10.1021/jf60119a025. ISSN 0021-8561.
10. ↑ 10.0 10.1 Борисович, Дормешкин Олег; Иванович, Воробьев Николай; Хаимовна, Черчес Галина; Николаевич, Гаврилюк Андрей (2011). "Влияние азотсодержащих компонентов на фазовый состав и физико-механические свойства np- и NPK-удобрений". Труды БГТУ. №3. Химия и технология неорганических веществ (3). ISSN 1683-0377. https://cyberleninka.ru/article/n/vliyanie-azotsoderzhaschih-komponentov-na-fazovyy-sostav-i-fiziko-mehanicheskie-svoystva-np-i-npk-udobreniy.
11. ↑ Strobel, Sabine; Hartenbach, Ingo; Schleid, Thomas (September 2006). "Synthesis and Crystal Structure of the Neodymium Sulfate Nitrate Trihydrate Nd[SO4][NO3]·3H2O" (in de). Zeitschrift für anorganische und allgemeine Chemie 632 (12–13): 1927–1929. doi:10.1002/zaac.200600049. ISSN 0044-2313.
12. ↑ "Hydrothermal synthesis and crystal structure of cobalt(II) complex [Co(2,2'-bipy)2(NO3)2 SO4·(H2O)5"]. Chemical Reagents. September 2009. http://en.cnki.com.cn/Article_en/CJFDTotal-HXSJ200909004.htm. Retrieved 2020-05-21.
13. ↑ 13.0 13.1 13.2 Davidovich, R. L.; Medkov, M. A.; Zakomornyi, V. I. (March 1982). "Complex compounds of metals with mixed acidoligands. Communication 9. Nitrate-sulfate complex compounds of bismuth(III)" (in en). Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 31 (3): 437–440. doi:10.1007/BF00949753. ISSN 0568-5230. http://link.springer.com/10.1007/BF00949753.

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