Air pollution measurement

Air pollution measurement is the process of collecting and measuring the components of air pollution, notably gases and particulates. The earliest devices used to measure pollution include rain gauges (in studies of acid rain), Ringelmann charts for measuring smoke, and simple soot and dust collectors known as deposit gauges.[1] Modern air pollution measurement is largely automated and carried out using many different devices and techniques. These range from simple absorbent test tubes known as diffusion tubes through to highly sophisticated chemical and physical sensors that give almost real-time pollution measurements, which are used to generate air quality indexes.

## Contents

* 1 Importance of measurement
* 2 Passive and active measurement
* 2.1 Passive measurement
* 2.2 Active measurement
* 3 Air quality sensors
* 3.1 Personal air quality sensors
* 3.2 Small-scale static pollution monitoring
* 3.3 Large-scale pollution monitoring
* 3.4 Remote monitoring
* 4 Methods of measurement for different pollutants
* 4.1 Particulates
* 4.2 Nitrogen dioxide
* 4.3 Sulphur dioxide and hydrogen sulphide
* 4.4 Carbon monoxide and carbon dioxide
* 4.5 Ozone
* 4.6 Volatile organic compounds (VOCs)
* 4.7 Hydrocarbons
* 4.8 Ammonia
* 5 Natural measurements
* 6 Measurement units
* 7 History
* 8 See also
* 9 References

## Importance of measurement[edit | edit source]

Air pollution is caused by many things. In urban environments, it can contain many components, notably solid and liquid particulates (such as soot from engines and fly ash escaping from incinerators), and numerous different gases (most commonly sulphur dioxide, nitrogen oxides, and carbon monoxide, all related to fuel combustion). These different forms of pollution have different effects on people's health, on the natural world (water, soil, crops, trees, and other vegetation), and on the built environment.[2] Measuring air pollution is the first step in identifying its causes and then reducing or regulating them to keep the quality of the air inside legal limits (mandated by regulators such as the Environmental Protection Agency in the United States) or advisory guidelines suggested by bodies such as the World Health Organization (WHO).[3] According to the WHO, over 6000 cities in 117 countries now routinely monitor the quality of their air.[4]

## Passive and active measurement[edit | edit source]

Air pollution is (broadly) measured in two different ways, passively or actively.[5]

### Passive measurement[edit | edit source]

A diffusion tube is an example of a passive air pollution monitor.

Passive devices are relatively simple and low-cost.[6] They work by soaking up or otherwise passively collecting a sample of the ambient air, which then has to be analyzed in a laboratory. One of the most common forms of passive measurement is the diffusion tube, which looks similar to a laboratory test tube and is fastened to something like a lamp post to absorb one or more specific pollutant gases of interest. After a period of time, the tube is taken down and sent to a laboratory for analysis. Deposit gauges, one of the oldest forms of pollution measurement, are another type of passive device.[7] They are large funnels that collect soot or other particulates and drain them into sampling bottles, which, again have to be analyzed in a laboratory.

### Active measurement[edit | edit source]

Active measurement devices are more automated, complex, and sophisticated, though not always more sensitive or reliable.[6] They use fans to suck in the air, filter it, and either analyze it automatically there and then or collect and store it for later analysis in a laboratory. Active sensors use either physical or chemical methods. Physical methods measure an air sample without changing it, for example, by seeing how much of a certain wavelength of light it absorbs. Chemical methods change the sample in some way, through a chemical reaction, and measure that. Most automated air-quality sensors are examples of active measurement.

## Air quality sensors[edit | edit source]

Air quality sensors range from small handheld devices to large-scale static monitoring stations in urban areas, and remote monitoring devices used on aeroplanes and space satellites.

### Personal air quality sensors[edit | edit source]

The Air Quality Egg: An example of a low-cost, personal air pollution sensor.

At one end of the scale, there are small, inexpensive portable (and sometimes wearable), Internet-connected air pollution sensors, such as the Air Quality Egg, PurpleAir, and Plume Flow.[8] These constantly sample particulates and gases and produce moderately accurate, almost real-time measurements that can be analyzed by smartphone apps.[9] They can be used for both indoor and outdoor environments and the majority focus on measuring five forms of air pollution: ozone, particulate matter, carbon monoxide, sulfur dioxide, and nitrogen dioxide.

Sensors like this were once expensive, but the 2010s saw a trend towards cheaper portable devices that can be worn by individuals to monitor their local air quality levels, which are now sometimes informally referred to as low-cost sensors (LCS).[8][10] A recent review by the European Commission's Joint Research Center identified 112 examples, made by 77 different manufacturers.[11]

Personal sensors can empower individuals and communities to better understand their exposure environments and risks from air pollution.[12] For example, a research group led by William Griswold at UCSD handed out portable air pollution sensors to 16 commuters, and found "urban valleys" where buildings trapped pollution. The group also found that passengers in buses have higher exposures than those in cars.[13]

### Small-scale static pollution monitoring[edit | edit source]

An EkoSłupek air pollution sensor in Poland. The green light indicates good nearby air quality.

Unlike low-cost monitors, which are carried from place to place, static monitors continuously sample and measure the air quality in a particular, urban location. Public places such as busy railroad stations sometimes have active air quality monitors permanently fixed alongside platforms to measure levels of nitrogen dioxide and other pollutants.[14] Some static monitors are designed to give immediate feedback on local air quality. In Poland, EkoSłupek air monitors measure a range of pollutant gases and particulates and have small lamps on top that change colour from red to green to signal how healthy the air is nearby.[15]

### Large-scale pollution monitoring[edit | edit source]

An air pollution monitoring station in Shaftesbury Avenue, London.

At the opposite end of the spectrum from low-cost sensors are the large, very expensive, static street-side monitoring stations that constantly sample the various different pollutants commonly found in urban air for local authorities and that make up metropolitan monitoring systems such as the London Air Quality Network[16] and a wider British network called the Automatic Urban and Rural Network (AURN).[17] In the United States, the EPA maintains a repository of air quality data through the Air Quality System (AQS), where it stores data from over 10,000 monitors.[18] The European Environment Agency collects its air quality data from 3,500 monitoring stations across the continent.[19]

The measurements made by sensors like these, which are much more accurate, are also near real-time and are used to generate air quality indexes (AQIs). Between the two extremes of large-scale static and small-scale wearable sensors are medium-sized, portable monitors (sometimes mounted in large wheelable cases) and even built into "smog-mobile" sampling trucks.[20]

### Remote monitoring[edit | edit source]

Air quality can also be measured remotely, from the air, by lidar,[21] drones,[22] and satellites, through methods such as gas filter correlation.[23] Among the earliest satellite pollution monitoring efforts were GOME (Global Ozone Monitoring Experiment), which measured global (tropospheric) ozone levels from the ESA European Remote Sensing Satellite (ERS-2) in 1995,[24] and NASA's MAPS (Mapping Pollution with Satellites), which measured the distribution of carbon monoxide in Earth's lower atmosphere, also in the 1990s.[25]

## Methods of measurement for different pollutants[edit | edit source]

Each different component of air pollution has to be measured by a different process, piece of equipment, or chemical reaction. Analytical chemistry techniques used for measuring pollution include gas chromatography; various forms of spectrometry, spectroscopy, and spectrophotometry; and flame photometry.

### Particulates[edit | edit source]

Ringelmann charts were developed for measuring smoke from chimneys and smokestacks at the end of the 19th century.

Until the late 20th century, the amount of soot produced by something like a smokestack was often measured visually, and relatively crudely, by holding up cards with lines ruled onto them to indicate different shades of grey. These were known as Ringelmann charts, after their inventor, Max Ringelmann, and measured smoke on a six-point scale.[26] In modern pollution monitoring stations, coarse (PM10) and fine (PM2.5) particulates are measured using a device called a tapered element oscillating microbalance (TEOM), based on a glass tube that vibrates more or less as collected particles accumulate on it. Particulates can also be measured using other kinds of particulate matter sampler, including optical photodetectors, which measure the light reflected from samples of light (bigger particles reflect more light) and gravimetric analysis (collected on filters and weighed).[27]

### Nitrogen dioxide[edit | edit source]

Nitrogen dioxide (NO
2) can be measured passively with diffusion tubes, though it takes time to collect samples, analyze them, and produce results.[28][29] It can also be measured actively, much more quickly, by a chemiluminescence analyzer, which measures nitrogen oxide levels from the light they give off. In the UK, for example, there are over 200 sites where NO
2 is continuously monitored by chemiluminescence.[30]

Air monitoring stations sample and measure multiple pollutants. This station in Reno, Nevada monitors carbon monoxide, ozone, fine and coarse particulates (PM2.5 and PM10), and nitrogen dioxide.

### Sulphur dioxide and hydrogen sulphide[edit | edit source]

Sulphur dioxide (SO
2) is measured by fluorescence spectroscopy. This involves firing ultraviolet light at a sample of the air and measuring the fluorescence produced.[31] Absorption spectrophotometers are also used for measuring SO
2. Flame photometric analyzers are used for measuring other sulphur compounds in the air.[32]

### Carbon monoxide and carbon dioxide[edit | edit source]

Carbon monoxide (CO) and carbon dioxide (CO
2) are measured by non-dispersive infrared (NDIR) light absorption based on the Beer-Lambert law.[33] CO can also be measured using electrochemical gel sensors and metal-oxide semiconductor (MOS) detectors.[34]

### Ozone[edit | edit source]

Ozone (O3) is measured by seeing how much light a sample of ambient air absorbs.[35] Higher concentrations of ozone absorb more light according to the Beer-Lambert law.

### Volatile organic compounds (VOCs)[edit | edit source]

These are measured using gas chromatography and flame ionization (GC-FID).[36]

### Hydrocarbons[edit | edit source]

Hydrocarbons can be measured by gas chromatography and flame ionization detectors.[37][38] They are sometimes expressed as separate measurements of methane (CH
4), NMHC (non-methane hydrocarbons), and THC (total hydrocarbon) emissions (where THC is the sum of CH
4 and NMHC emissions).[37]

### Ammonia[edit | edit source]

Ammonia (NH
3) can be measured by various methods including chemiluminescence.[39]

## Natural measurements[edit | edit source]

Lichens such as Lobaria pulmonaria are sensitive to air pollution.

Air pollution can also be assessed more qualitatively by observing the effect of polluted air on growing plants such as lichens and mosses (an example of biomonitoring).[40][41][42] Some scientific projects have used specially grown plants such as strawberries.[43]

## Measurement units[edit | edit source]

Main article: Air pollutant concentrations

The amount of pollutant present in air is usually expressed as a concentration, measured in either parts-per notation (usually parts per billion, ppb, or parts per million, ppm) or micrograms per cubic meter (μg/m³). It's relatively simple to convert one of these units into the other, taking account the different molecular weights of different gases and their temperatures and pressures. Urban air quality index (AQI) values are computed by combining the concentrations of a "basket" of common air pollutants (typically ozone, carbon monoxide, sulphur dioxide, nitrogen oxides, and both fine and coarse particulates) to produce a single number on an easy-to-understand (and often colour-coded) scale.

## History[edit | edit source]

An early deposit gauge used for measuring air pollution. Photograph from The Smoke Problem of Great Cities by Shaw and Owens, 1925.

Air pollution was first systematically measured, in Britain, in the 19th century. In 1852, Scottish chemist Robert Angus Smith discovered (and named) acid rain after collecting rain samples that turned out to contain significant quantities of sulphur from coal burning. According to a chronology of air pollution by David Fowler and colleagues, Smith was "the first scientist to attempt multisite, multipollutant investigations of the chemical climatology of the polluted atmosphere".[44]

In the early 20th century, Irish physician and environmental engineer John Switzer Owens and the Committee for the Investigation of Atmospheric Pollution, of which he was secretary, greatly advanced the measurement and monitoring of air pollution using a network of deposit gauges. Owens also developed a number of new methods of measuring pollution.[45]

In December 1952, the Great Smog of London led to the deaths of 12,000 people.[46] This event, and similar ones such as the 1948 Donora smog tragedy in the United States,[47] became one of the great turning points in environmental history because they brought about a radical rethink in pollution control. In the UK, the Great Smog of London lead directly to the Clean Air Act, which may have had consequences even more far reaching than it originally intended.[48] Catastrophic events like this lead to pollution being measured and controlled much more rigorously.[44]

## See also[edit | edit source]

* Air quality index
* Environmental monitoring

## References[edit | edit source]

1. ↑ Brimblecombe, Peter (1987). The Big Smoke: A History of Air Pollution in London Since Medieval Times. Routledge. pp. 136–160. ISBN 9781136703294.
2. ↑ Jacobsen, Mark Z. (2012). Air Pollution and Global Warming: History, Science, and Solutions. Cambridge University Press. ISBN 9781107691155. Archived from the original on 19 June 2022. Retrieved 29 March 2022.
3. ↑ Bower, Jon (1999). Monitoring Ambient Air Quality for Health Impact Assessment. World Health Organization, Regional Office for Europe. p. 1\. ISBN 9789289013512. Archived from the original on 19 June 2022. Retrieved 29 March 2022.
4. ↑ Coules, Chloe (4 April 2022). "Over 6,000 cities now monitor air quality, WHO reveals". Air Quality News. Archived from the original on 5 April 2022. Retrieved 6 April 2022.
5. ↑ "Monitoring Methodologies". Air Quality Wales. Welsh Government. Archived from the original on 15 December 2021. Retrieved 29 March 2022.
6. ↑ 6.0 6.1 Fan, Zih-Hua Tina (January 2011). "Passive Air Sampling: Advantages, Limitations, and Challenges". Epidemiology. 22 (1): S132. doi:10.1097/01.ede.0000392075.06031.d9. S2CID 75942106. Archived from the original on 27 March 2022. Retrieved 27 March 2022.
7. ↑ Brimblecombe, Peter (1987). The Big Smoke: A History of Air Pollution in London Since Medieval Times. Routledge. pp. 147–160. ISBN 9781136703294.
8. ↑ 8.0 8.1 Lewis, A; Lee, James; Edwards, Peter; Shaw, Marvin; Evans, Mat; Moller, Sarah; Smith, Katie; Buckley, Jack; Ellis, Matthew; Gilot, Stefan; White, Andrew (2016). "Evaluating the performance of low cost chemical sensors for air pollution research". Faraday Discussions. 189: 85–103. Bibcode:2016FaDi..189...85L. doi:10.1039/C5FD00201J. PMID 27104223. Archived from the original on 6 April 2022. Retrieved 28 March 2022.
9. ↑ "Experimenting at Home With Air Quality Monitors". The New York Times. April 15, 2015. Archived from the original on April 20, 2015. Retrieved May 29, 2015.
10. ↑ Austen, Kat (7 January 2015). "Environmental science: Pollution patrol". Nature. 517 (7533): 136–138. Bibcode:2015Natur.517..136A. doi:10.1038/517136a. PMID 25567265. S2CID 4446361. Archived from the original on 27 March 2022. Retrieved 29 March 2022.
11. ↑ Karagulian, F; Gerboles, M; Barbiere, M; Kotsev, A; Lagler, F; Borowiak, A (2019). Review of sensors for air quality monitoring: EUR 29826 EN (PDF). Luxembourg: Publications Office of the European Union. ISBN 978-92-76-09255-1. Archived (PDF) from the original on 1 February 2022. Retrieved 28 March 2022.
12. ↑ "Air Pollution Monitoring for Communities". Epa.gov. Archived from the original on April 16, 2015. Retrieved May 29, 2015.
13. ↑ "Microsampling Air Pollution". The New York Times. June 3, 2013. Archived from the original on December 27, 2021. Retrieved May 29, 2015.
14. ↑ Hickman, A; Baker, C; Cai, X; Delgado-Saborit, J; Thornes, J (16 January 2018). "Evaluation of air quality at the Birmingham New Street Railway Station". Proc Inst Mech Eng F J Rail Rapid Transit. 232 (6): 1864–1878. doi:10.1177/0954409717752180. PMC 6319510. PMID 30662169.
15. ↑ "EcoClou AirSensor". Archived from the original on 9 January 2022. Retrieved 28 March 2022.
16. ↑ "How is pollution measured?". London Air. Imperial College, London. Archived from the original on 27 November 2021. Retrieved 27 November 2021.
17. ↑ "Automatic Urban and Rural Network (AURN)". UK Air. Defra. Archived from the original on 29 March 2022. Retrieved 29 March 2022.
18. ↑ "TTN AIRS AQS". Epa.gov. Archived from the original on March 30, 2015. Retrieved May 29, 2015.
19. ↑ "The European Air Quality Index". European Environment Agency. European Union. Archived from the original on 29 March 2022. Retrieved 29 March 2022.
20. ↑ Walsh, Fergus (15 February 2016). "Smog-mobile' measures pollution levels". BBC News. Archived from the original on 27 March 2022. Retrieved 27 March 2022.
21. ↑ Richter, P (August 1994). "Air pollution monitoring with LIDAR". TrAC Trends in Analytical Chemistry. 13 (7): 263–266. doi:10.1016/0165-9936(94)87062-4. ISSN 0165-9936. Archived from the original on 28 March 2022. Retrieved 28 March 2022.
22. ↑ Abarca, Mónica. "qAIRa: Using drones to monitor air quality from illegal mining areas in Peru". UNICEF Office of Innovation. UNICEF. Archived from the original on 8 April 2022. Retrieved 27 March 2022.
23. ↑ Tony R. Kuphaldt. "23. Introduction to Continuous Analytical Measurement". Lessons In Industrial Instrumentation. Control Automation. Archived from the original on 15 April 2021. Retrieved 28 March 2022.
24. ↑ "Ozone GOME". UK Air. Defra. Archived from the original on 19 April 2021. Retrieved 28 March 2022.
25. ↑ "Measurement of Air Pollution from Satellites (MAPS) - understanding the chemistry of the atmosphere". NASA. 19 September 1996. Archived from the original on 21 October 2020. Retrieved 19 May 2022.
26. ↑ "Maximilien Ringelmann: Smoke Charts". Science History Institute. 2 August 2016. Archived from the original on 26 March 2019. Retrieved 27 March 2022.
27. ↑ "Particulate Matter in the United Kingdom Summary" (PDF). Air Quality Expert Group. Defra. 2005. Archived (PDF) from the original on 19 January 2022. Retrieved 27 March 2022.
28. ↑ "Using Diffusion Tubes". Care4Air. Sheffield City Council. Archived from the original on 9 May 2021. Retrieved 28 February 2022.
29. ↑ "Diffusion Tubes". LoveCleanAir South London. 26 June 2014. Archived from the original on 28 February 2022. Retrieved 28 February 2022.
30. ↑ "Nitrogen Dioxide in the United Kingdom: Summary" (PDF). Air Quality Expert Group. Defra. p. 4\. Archived (PDF) from the original on 14 July 2021. Retrieved 29 March 2022.
31. ↑ "Sulfur dioxide" (PDF). Queensland Government. Archived (PDF) from the original on 23 October 2021. Retrieved 29 March 2022.
32. ↑ Li, Kwong-Chi; Shooter, David (25 January 2007). "Analysis of sulfur-containing compounds in ambient air using solid-phase microextraction and gas chromatography with pulsed flame photometric detection". International Journal of Environmental Analytical Chemistry. 84 (10): 749–760. doi:10.1080/03067310410001729619. S2CID 93587574. Archived from the original on 29 March 2022. Retrieved 19 May 2022.
33. ↑ Jha, Ravindra Kumar (23 November 2021). "Non-Dispersive Infrared Gas Sensing Technology: A Review". IEEE Sensors Journal. 22 (1): 6–15. doi:10.1109/JSEN.2021.3130034. S2CID 244564847. Archived from the original on 29 March 2022. Retrieved 29 March 2022.
34. ↑ Fine, George; Cavanagh, Leon; Afonja, Ayo; Binions, Russell (2010). "Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring". Sensors. 10 (6): 5469–5502. Bibcode:2010Senso..10.5469F. doi:10.3390/s100605469. PMC 3247717. PMID 22219672.
35. ↑ "How We Measure Ozone". National Park Service. US Department of the Interior. Archived from the original on 30 March 2022. Retrieved 30 March 2022.
36. ↑ Srivastava, Anjali; Majumdar, Dipanjali (2011). "7: Monitoring and reporting VOCs in ambient air". In Mazzeo, Nicolás (ed.). Air Quality Monitoring, Assessment and Management. Rijeka, Croatia: InTech Open. pp. 137–148. ISBN 978-9533073170. Archived from the original on 19 June 2022. Retrieved 30 March 2022.
37. ↑ 37.0 37.1 Hydrocarbons (THC, CH4 and NMHC) (PDF). Alberta, Canada: Alberta Government. 16 December 2015. ISBN 9781460118047. Archived (PDF) from the original on 10 December 2019. Retrieved 7 April 2022.
38. ↑ Morris, Robert; Chapman, Robert (1961). "Flame lonization Hydrocarbon Analyzer". Journal of the Air Pollution Control Association. 11 (10): 467–489. doi:10.1080/00022470.1961.10468025. Archived from the original on 30 March 2022. Retrieved 30 March 2022.
39. ↑ Baumgardner, Ralph (February 1979). Optimized Chemiluminescence System for Measuring Atmospheric Ammonia: EPA-600 2-79-028. Research Triangle Park, NC: US Environmental Protection Agency. Archived from the original on 19 June 2022. Retrieved 30 March 2022.
40. ↑ Conti, M; Cecchetti, G (2001). "Biological monitoring: lichens as bioindicators of air pollution assessment - a review". Environ Pollut. 114 (3): 471–92. doi:10.1016/s0269-7491(00)00224-4. PMID 11584645. Archived from the original on 30 March 2022. Retrieved 30 March 2022.
41. ↑ "Impacts of air pollution on Lichens and Bryophytes (mosses and liverworts)". Air Pollution Information System. Centre for Ecology and Hydrology. Archived from the original on 27 March 2022. Retrieved 30 March 2022.
42. ↑ Ndlovu, Ntombizikhona Beaulah (10 July 2015). "Mosses and lichens come to the rescue in battle against air pollution". The Conversation. Archived from the original on 27 March 2022. Retrieved 27 March 2022.
43. ↑ "StrawbAIRies". University of Antwerp. Archived from the original on 10 April 2022. Retrieved 27 March 2022.
44. ↑ 44.0 44.1 Fowler, David; Brimblecombe, Peter; Burrows, John; Heal, Mathew; Grennfelt, Peringe; Stevenson, David; Jowett, Alan; Nemitz, Eiko; Coyle, Mhairi; Liu, Xuejun; Chang, Yunhua; Fuller, Gary; Sutton, Mark; Klimont, Zbigniew; Unsworth, Mike; Vieno, Massimo (30 October 2020). "A chronology of global air quality". Phil. Trans. R. Soc. A. 378 (2183). Bibcode:2020RSPTA.37890314F. doi:10.1098/rsta.2019.0314. PMC 7536029. PMID 32981430. Archived from the original on 27 March 2022. Retrieved 27 March 2022.
45. ↑ Fuller, Gary (13 August 2020). "Pollutionwatch: how lessons from 1920s were forgotten for 50 years". The Guardian. Archived from the original on 17 January 2022. Retrieved 17 January 2022.
46. ↑ Bell, M.L.; Davis, D.L.; Fletcher, T. (2004). "A Retrospective Assessment of Mortality from the London Smog Episode of 1952: The Role of Influenza and Pollution". Environ Health Perspect. 112 (1, January): 6–8. doi:10.1289/ehp.6539. PMC 1241789. PMID 14698923.
47. ↑ Gorney, Cynthia (27 October 2020). "Decades ago, this pollution disaster exposed the perils of dirty air". National Geographic. Archived from the original on 28 March 2022. Retrieved 28 March 2022.
48. ↑ Brimblecombe, Peter (2006-11-01). "The Clean Air Act after 50 years". Weather. 61 (11): 311–314. Bibcode:2006Wthr...61..311B. doi:10.1256/wea.127.06. ISSN 1477-8696. S2CID 123552841.