Bent molecular geometry

Examples| H2O, SO2
Point group| C2v
Coordination number| 2
Bond angle(s)| 90°<θ<120°
μ (Polarity)| >0
Oxygen difluoride, an example of a molecule with the bent coordination geometry.

In chemistry, molecules with a non-collinear arrangement of two adjacent bonds have bent molecular geometry, also known as angular or V-shaped. Certain atoms, such as oxygen, will almost always set their two (or more) covalent bonds in non-collinear directions due to their electron configuration. Water (H2O) is an example of a bent molecule, as well as its analogues. The bond angle between the two hydrogen atoms is approximately 104.45°.[1] Nonlinear geometry is commonly observed for other triatomic molecules and ions containing only main group elements, prominent examples being nitrogen dioxide (NO2), sulfur dichloride (SCl2), and methylene (CH2).

This geometry is almost always consistent with VSEPR theory, which usually explains non-collinearity of atoms with a presence of lone pairs. There are several variants of bending, where the most common is AX2E2 where two covalent bonds and two lone pairs of the central atom (A) form a complete 8-electron shell. They have central angles from 104° to 109.5°, where the latter is consistent with a simplistic theory which predicts the tetrahedral symmetry of four sp3 hybridised orbitals. The most common actual angles are 105°, 107°, and 109°: they vary because of the different properties of the peripheral atoms (X).

Other cases also experience orbital hybridisation, but in different degrees. AX2E1 molecules, such as SnCl2, have only one lone pair and the central angle about 120° (the centre and two vertices of an equilateral triangle). They have three sp2 orbitals. There exist also sd-hybridised AX2 compounds of transition metals without lone pairs: they have the central angle about 90° and are also classified as bent.[citation needed] (See further discussion at VSEPR theory).

## See also

* AXE method

## References

1. ↑ Miessler, G. L.; Tarr, D. A. (2004). Inorganic Chemistry (3rd ed.). Pearson/Prentice Hall. ISBN 0-13-035471-6. https://archive.org/details/inorganicchemist03edmies.

## External links

* 3D Chem: Chemistry, Structures, and 3D Molecules
* Indiana University Molecular Structure Center
* Interactive molecular examples for point groups
* Molecular Modeling
* Animated Trigonal Planar Visual

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Molecular geometry (VSEPR)

Coordination number 2|

* Linear
* Bent

Coordination number 3|

* Trigonal planar
* Trigonal pyramidal
* T-shaped

Coordination number 4|

* Tetrahedral
* Square planar
* Seesaw

Coordination number 5|

* Trigonal bipyramidal
* Square pyramidal
* Pentagonal planar

Coordination number 6|

* Octahedral
* Trigonal prismatic
* Pentagonal pyramidal

Coordination number 7|

* Pentagonal bipyramidal
* Capped octahedral
* Capped trigonal prismatic

Coordination number 8|

* Square antiprismatic
* Dodecahedral
* Bicapped trigonal prismatic

Coordination number 9|

* Tricapped trigonal prismatic
* Capped square antiprismatic

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