Telluride bromide

Short description: Class of chemical compounds

The telluride bromides are chemical compounds that contain both telluride ions (Te2−) and bromide ions (Br−). They are in the class of mixed anion compounds or chalcogenide halides.[1]

In many tellurium bromide compounds, tellurium atoms link up in a helix, similar to pure tellurium structure. In Rhenium compounds tellurium atoms form a cluster with rhenium atoms. In some materials, tellurium forms a honeycomb like structure containing tubes filled with bromine and the other elements.

## List

name  | formula  | system  | space group  | unit cell Å  | volume  | density  | properties  | ref

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| Sb2Te2BrAlCl4 | monoclinic  | C2/c |  |  |  |  | [1]
copper telluride bromide  | CuBrTe  | tetragonal  | I41/amd | a = 16.417 c = 4.711 Z = 16  | 1269.7  | 5.67  | black  | [2]
| MoTe4Br  |  |  |  |  |  | silver  | [3]
| Mo4Te7Br8 |  |  |  |  |  | black semiconductor  | [3]
| MoTe6Br3 |  |  |  |  |  | silver  | [3]
| [Mo3Se7(TeBr3)Br2]2[Te2Br10]  | triclinic  | P1 | a=10.1638 b=11.0241 c=12.5200 α =85.461 β =85.529 γ =76.410°; Z =1  | 1358.94  | 4.631  |  | [1][4]
| NbOTe7Br5 |  |  |  |  |  |  | [3]
decasilver tetratelluride tribromide  | Ag10Te4Br3 | hexagonal *2

orthorhombic*2

| P6/mmm

P63/mmc

Cmc21

|  |  |  | Ag+ conductor  | [5]
| Ag10Te4Br3 | orthorhombic  | Cmcm | a=15.381 b=15.765 c=13.726  | 3328.2  |  | Ag ion conductor  | [6]
| Ag23Te12Br  | orthorhombic  | Pnnm |  |  |  | honeycomb Te; Ag ion conductor  | [1]
| Ag19Te6Br7 | trigonal

monoclinic

| R3m  |  |  |  |  | [1]
| Ag19Te6Br5.4I1.6 | orthorhombic  | Pnma |  |  |  | electric conductor  | [1]
| Ag19Te5SeBr7 | orthorhombic  | Pbam |  |  |  |  | [1]
| La3Te4Br  | orthorhombic  | Pnma | a = 16.343 b = 4.350 c = 14.266 Z = 4  | 1014.1  |  |  | [1][7]
| W2O2Te4Br5 |  |  |  |  |  |  |
| Re4Te8Br16 |  | I4 | a=11.202 c=13.935  | 1748.6  |  |  | [8]

[Re2Br4(Te2)(TeBr)2(TeBr2)2]

|  |  |  |  |  |  | [1]
| [Re6Te8(TeBr2)6]Br2 |  |  |  |  |  |  | [1]
| Pd4Br4Te3 | triclinic  | P1 | a =8.425 b =8.450 c =8.648; α =82.55 β =73.36 γ =88.80°; Z =2  |  |  | semiconductor  | [9]
| AuBrTe2 | orthorhombic  |  | a=4.033 b=12.375 c=8.942  |  | 7.89  | silvery white, metallic melt 457 C  | [2][10]
| Hg3Te2Br2 |  |  |  |  |  | yellow  | [1][11]
| Hg3Te2BrI  | monoclinic  | C2  | 18.376 b=9.587 c=10.575 β=100.11°  |  |  |  | [11][12]
| Tl5Te2Br  |  |  |  |  |  |  | [13]
| BiTeBr  | trigonal  | P3m1  | a = 4.2662 c = 6.487  |  |  | melt 526  | [14]
| Bi2Te2BrAlCl4 | monoclinic  | C2/c |  |  |  |  | [1]

## References

1. ↑ 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
2. ↑ 2.0 2.1 Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride" (in en). Journal of Solid State Chemistry 18 (2): 183–189. doi:10.1016/0022-4596(76)90094-3. Bibcode: 1976JSSCh..18..183C.
3. ↑ 3.0 3.1 3.2 3.3 Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides" (in en). Angewandte Chemie International Edition in English 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
4. ↑ Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo3Se7Te2Br10, Mo3Se7TeI6, and Mo6Te21I22 Containing TeX3 \- (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †" (in en). Inorganic Chemistry 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
5. ↑ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials 18 (10): 2538–2544. doi:10.1021/cm060226m.
6. ↑ Giller, Malte; Bawohl, Melanie; Gerstle, Alexandra P.; Nilges, Tom (November 2013). "Copper Substitution and Mixed Cation Effect in Ag10Te4Br3: Copper Substitution and Mixed Cation Effect in Ag10Te4Br3" (in en). Zeitschrift für anorganische und allgemeine Chemie 639 (14): 2379–2381. doi:10.1002/zaac.201300309.
7. ↑ Larres, Markus; Mudring, Anja-Verena; Meyer, Gerd (2011-03-21). "The First Lanthanide Telluride-Bromide: La3Te4Br, a Valence Compound" (in en). Crystals 1 (1): 15–21. doi:10.3390/cryst1010015. ISSN 2073-4352.
8. ↑ Mironov, Yu. V.; Fedorov, V. E. (2002). "Tetranuclear rhenium chalcogenide cluster complexes with a cubane core. Synthesis, structures, and properties". Russian Chemical Bulletin 51 (4): 569–580. doi:10.1023/A:1015843529164.
9. ↑ Janetzky, Manuel; Rödel, Eva; Pietzonka, Clemens; Müller, Ulrich; Ressler, Thorsten; Harbrecht, Bernd (2007-09-18). "The Valence Problem of Pd4Br4Te3" (in en). Chemistry - A European Journal 13 (35): 9882–9891. doi:10.1002/chem.200700658. PMID 17879245.
10. ↑ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold" (in en). Journal of the Less Common Metals 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3.
11. ↑ 11.0 11.1 Kozin, L. F.; Hansen, Steve C. (2013-10-11) (in en). Mercury Handbook: Chemistry, Applications and Environmental Impact. Royal Society of Chemistry. pp. 294. ISBN 978-1-84973-515-5. https://books.google.com/books?id=dXYoDwAAQBAJ&pg=PA294.
12. ↑ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2" (in en). Journal of Alloys and Compounds 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.
13. ↑ Babanly, D. M.; Babanly, M. B. (October 2010). "Phase equilibria in the Tl-TlBr-Te system and thermodynamic properties of the compound Tl5Te2Br" (in en). Russian Journal of Inorganic Chemistry 55 (10): 1620–1629. doi:10.1134/S0036023610100219. ISSN 0036-0236.
14. ↑ Petasch, U.; Oppermann, H. (1999-04-01). "Untersuchungen zum quasibinären System Bi2Te3/BiBr3 / Investigations on the Pseudobinary System Bi2Te3/BiBr3". Zeitschrift für Naturforschung B 54 (4): 487–490. doi:10.1515/znb-1999-0412. ISSN 1865-7117. https://www.degruyter.com/view/journals/znb/54/4/article-p487.xml.

Template:Bromides

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Tellurides

| H2Te |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

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Li2Te | BeTe |  |  |  |  |  |  |  |  |  |  | B  | CTe2
(CH3)2Te | (NH4)2Te | O  | F  | Ne
Na2Te | MgTe |  |  |  |  |  |  |  |  |  |  | Al2Te | Si  | P2Te5 | S  | Cl  | Ar
K2Te | CaTe | Sc2Te3 | Ti  | VTe2 | CrTe
Cr2Te3 | MnTe
MnTe2 | FeTe | CoTe | NiTe | CuTe | ZnTe | GaTe
Ga2Te3 | GeTe | As2Te3
As4Te3 | Se  | Br  | Kr
Rb2Te | SrTe | Y2Te3 | Zr  | NbTe2 | MoTe2 | Tc  | Ru  | Rh  | Pd  | Ag2Te | CdTe | In2Te3 | SnTe
SnTe2 | Sb2Te3 | Te2- | I  | Xe
Cs2Te | BaTe | *  | Hf  | TaTe2 | WTe2
WTe3 | ReTe2 | Os  | Ir  | Pt  | AuxTey | HgTe | Tl2Te | PbTe | Bi2Te3 | Po  | At  | Rn
Fr  | Ra  | **  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og  |  |  |  |  |  |  |  |
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | La2Te3 | Ce2Te3 | Pr2Te3 | Nd2Te3 | Pm  | Sm2Te3 | Eu2Te3 | Gd  | Tb  | Dy  | Ho  | Er2Te3 | Tm2Te3 | Yb  | Lu  |
| ** | Ac  | ThTe2 | Pa  | UTe2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr  |

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