Arsenide iodide

Short description: Class of chemical compounds

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

## List

formula  | system  | space group  | unit cell Å  | volume  | density  | comment  | ref

|
|
|
|
|
|
|

Ca2AsI  | trigonal  | R3m | a=4.397, c = 22.29, Z = 3  |  | 3.76  | brown  | [1][2]
Ca3AsI3 | cubic  | I4132  | a=12.42  |  | 3.99  | colourless  | [1]
Cu2P1.8As1.2I2 | monoclinic  | P21/c | a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16  |  |  | Cu exchangeable with Ag; band gap 1.2 eV  | [3]
Ge38As8I8 | cubic  | P43m | a=10.611  |  |  | metallic; water and air stable  | [4]
Ag2P1.8As1.2I2 | monoclinic  | P21/c | a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16  |  |  |  | [5]
Sn24As19.3I8 | cubic  |  | a=22.179 Z=8  |  |  | black  | [6]
Sn20.5□3.5As22I8 | cubic  |  | a=22.1837  |  |  | low thermal conductivity  | [7]
Sn24AsxP19.3−xI8 x=0-16 | cubic  | Pm3n | a = 10.9358—11.1495  |  |  |  | [8]
Sn19.3Cu4.7As22I8 | cubic  | Pm3n | a = 11.1736 Z = 1  | 1394.4  | 6.236  | clathrate; Zintl; diamagnetic  | [9]
Sn24–x–δInxAs22–yI8 | cubic  | Pm3n | a = 11.088 (x = 0) to a = 11.343 (x = 10.7)  |  |  | clathrate  | [10]
La2AsI2 | trigonal  | P3m1 | a=4.3795 c=10.910  |  | 5.56  |  | [11]
Hg4AsI5 | orthorhombic  | Cmca | a=11.927 b=12.128 c=19.776 Z=8  | 2859.0  | 7.025  | red  | [12]
Hg4As2I3 | cubic  | Pa3 | a=12.999 Z=8  | 2196  | 8.06  | black  | [13]
HgI2⋅As4S4 | monoclinic  | P21/c | a=9.433 b=14.986 c=11.624 β=127.72° Z=4  | 1299  | 4.509  | orange; dec 212 °C  | [14]
Hg5AsS2I3 | monoclinic  | C2/c | a=13.339 b=8.444 c=13.428 β=118.352 Z=4  | 1331.2  | 7.599  | black; dec 150 °C  | [15]
Hg3AsSe4I  | hexagonal  | P63mc | a = 7.6902, c = 9.968 Z=2  |  |  | red; air stable  | [16]
[Hg7As4](AgI3)2 | cubic  | Pa | a = 13.138 Z = 4  |  |  |  | [17][18]
(Hg2As)2(CdI4)  | monoclinic  | P21 | a=7.945, b=12.934, c=8.094, β=116.898°  | 741.7  |  |  | [19]
[Hg7As4I3](SnI3)  | cubic  | P213  | a = 13.110, Z = 4  | 2253.2  | 7.617  | black  | [20]

## References

1. ↑ 1.0 1.1 Hadenfeldt, C.; Fester, W. (July 1982). "Reindarstellung und thermische Stabilität von Calcium-phosphid- und -arsenidiodiden: Ca3PI3, Ca3AsI3, Ca2PI und Ca2AsI" (in de). Zeitschrift für anorganische und allgemeine Chemie 490 (1): 25–30. doi:10.1002/zaac.19824900105. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19824900105.
2. ↑ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr" (in de). Zeitschrift für anorganische und allgemeine Chemie 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313. Bibcode: 1987ZAACh.545..177H. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19875450220.
3. ↑ Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01). "Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu2P1.8As1.2I2" (in en). Inorganic Chemistry 42 (3): 658–660. doi:10.1021/ic0258936. ISSN 0020-1669. PMID 12562174. https://pubs.acs.org/doi/10.1021/ic0258936.
4. ↑ von Schnering, Hans-Georg; Menke, Heinz (January 1972). "Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure" (in en). Angewandte Chemie International Edition in English 11 (1): 43–44. doi:10.1002/anie.197200431. ISSN 0570-0833. https://onlinelibrary.wiley.com/doi/10.1002/anie.197200431.
5. ↑ Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu2P3I2 and Cu2P1.8As1.2I2" (in en). MRS Proceedings 755. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172. http://link.springer.com/10.1557/PROC-755-DD6.12.
6. ↑ Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01). "First Tin Pnictide Halides Sn24P19.3I8 and Sn24As19.3I8: Synthesis and the Clathrate-I Type of the Crystal Structure" (in en). Inorganic Chemistry 38 (15): 3455–3457. doi:10.1021/ic990153r. ISSN 0020-1669. PMID 11671088. https://pubs.acs.org/doi/10.1021/ic990153r.
7. ↑ Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V. et al. (2007-06-15). "Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity" (in en). Chemistry - A European Journal 13 (18): 5090–5099. doi:10.1002/chem.200601772. PMID 17385200. Bibcode: 2007ChEuJ..13.5090Z. https://onlinelibrary.wiley.com/doi/10.1002/chem.200601772.
8. ↑ Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24AsxP19.3-xI8 with the structure of clathrate-I" (in en). Russian Chemical Bulletin 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. http://link.springer.com/10.1007/s11172-009-0089-0.
9. ↑ Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01). "Sn19.3Cu4.7As22I8: a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (in en). Inorganic Chemistry 44 (24): 8786–8793. doi:10.1021/ic051160k. ISSN 0020-1669. PMID 16296833. http://ematweb.cmi.ua.ac.be/emat/pdf/1331.pdf.
10. ↑ Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011). "Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System" (in en). Zeitschrift für anorganische und allgemeine Chemie 637 (13): 2059–2067. doi:10.1002/zaac.201100287. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201100287.
11. ↑ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" (in en). Zeitschrift für Naturforschung B 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117.
12. ↑ Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006). "Synthesis and the crystal and electronic structure of Hg4AsI5" (in en). Russian Chemical Bulletin 55 (5): 762–765. doi:10.1007/s11172-006-0329-5. ISSN 1066-5285. http://link.springer.com/10.1007/s11172-006-0329-5.
13. ↑ Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01). "Crystal structure of Hg4As2I3" (in en). Zeitschrift für Kristallographie - Crystalline Materials 187 (1–4): 117–124. doi:10.1524/zkri.1989.187.14.117. ISSN 2196-7105. https://www.degruyter.com/document/doi/10.1524/zkri.1989.187.14.117/html.
14. ↑ Bräu, Michael F.; Pfitzner, Arno (2006-07-03). "HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages" (in en). Angewandte Chemie International Edition 45 (27): 4464–4467. doi:10.1002/anie.200600690. ISSN 1433-7851. PMID 16758498. https://onlinelibrary.wiley.com/doi/10.1002/anie.200600690.
15. ↑ Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015). "Hg5AsS2I3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions" (in en). European Journal of Inorganic Chemistry 2015 (14): 2402–2406. doi:10.1002/ejic.201500150. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.201500150.
16. ↑ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE4X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure" (in en). Inorganic Chemistry 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388. https://pubs.acs.org/doi/10.1021/ic0003527.
17. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003). "Synthesis, Crystal and Electronic Structure of [Hg7As4(AgI3)2, a Novel Supramolecular Complex with the Off-Plane AgI32− Guest Anion"] (in en). European Journal of Inorganic Chemistry 2003 (6): 1053–1057. doi:10.1002/ejic.200390137. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200390137.
18. ↑ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2 and [Hgn] (n = 2, 3) Cluster Groups"] (in en). Journal of Structural Chemistry 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. https://link.springer.com/10.1134/S0022476620020109.
19. ↑ Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007). "Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)" (in en). Journal of Solid State Chemistry 180 (3): 805–811. doi:10.1016/j.jssc.2006.11.018. Bibcode: 2007JSSCh.180..805Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459606006049.
20. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry 2000 (2): 265–270. doi:10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A.

Template:Arsenides

HI |  |  |  | He

|
|
|
|

LiI | BeI2 | BI3 | CI4 | NI3 | I2O4,
I2O5,
I4O9 | IF,
IF3,
IF5,
IF7 | Ne
NaI | MgI2 | AlI3 | SiI4 | PI3,
P2I4 | S  | ICl,
ICl3 | Ar
KI | CaI2 | Sc  | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2,
GeI4 | AsI3 | Se  | IBr | Kr
RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo  | Tc  | Ru  | Rh  | Pd  | AgI | CdI2 | InI3 | SnI4,
SnI2 | SbI3 | TeI4 | I  | Xe
CsI | BaI2 |  | HfI4 | TaI5 | W  | Re  | Os  | Ir  | Pt  | AuI | Hg2I2,
HgI2 | TlI | PbI2 | BiI3 | Po  | AtI | Rn
Fr  | RaI2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La  | Ce  | Pr  | Nd  | Pm  | SmI2 | Eu  | Gd  | TbI3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac  | ThI4 | Pa  | UI3,
UI4 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | EsI3 | Fm  | Md  | No  | Lr

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Arsenide iodide. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Arsenide_iodide&oldid=4244091"