Thallium barium calcium copper oxide

Short description: Family of high-temperature superconductors

Schematic layered structure of TBCCO-2223.

Thallium barium calcium copper oxide, or TBCCO (pronounced "tibco"), is a family of high-temperature superconductors having the generalized chemical formula TlmBa2Can−1CunO2n+m+2.

Tl2Ba2Ca2Cu3O10 (TBCCO-2223) was discovered in Prof. Allen M. Hermann's laboratory in the physics department of the University of Arkansas in October 1987 by the post-doctoral researcher Zhengzhi Sheng and Prof. Hermann.[1] The bulk superconductivity in this material was confirmed by observations of magnetic flux expulsion and flux trapping signals (under zero field cooled and field cooled conditions) with a SQUID magnetometer in the superconductor laboratory of Timir Datta in the University of South Carolina.[2] Allen Hermann announced his discovery and the critical temperature of 127 K, in Houston, Texas at the World Congress on Superconductivity organized by Paul Chu in February 1988.

The first series of the Tl-based superconductor containing one Tl–O layer has the general formula TlBa2Can-1CunO2n+3,[2] whereas the second series containing two Tl–O layers has a formula of Tl2Ba2Can-1CunO2n+4 with n =1, 2 and 3. In the structure of Tl2Ba2CuO6 (Tl-2201), there is one CuO2 layer with the stacking sequence (Tl–O) (Tl–O) (Ba–O) (Cu–O) (Ba–O) (Tl–O) (Tl–O). In Tl2Ba2CaCu2O8 (Tl-2212), there are two Cu–O layers with a Ca layer in between. Similar to the Tl2Ba2CuO6 structure, Tl–O layers are present outside the Ba–O layers. In Tl2Ba2Ca2Cu3O10 (Tl-2223), there are three CuO2 layers enclosing Ca layers between each of these. In Tl-based superconductors, Tc is found to increase with the increase in CuO2 layers. However, the value of Tc decreases after four CuO2 layers in TlBa2Can-1CunO2n+3, and in the Tl2Ba2Can-1CunO2n+4 compound, it decreases after three CuO2 layers.[3]

## See also

* Cuprate superconductors
* Bismuth strontium calcium copper oxide
* Yttrium barium copper oxide
* Lanthanum barium copper oxide

## References

1. ↑ Sheng, Z. Z.; Hermann A. M. (1988). "Bulk superconductivity at 120 K in the Tl–Ca/Ba–Cu–O system". Nature 332 (6160): 138-139. doi:10.1038/332138a0. Bibcode: 1988Natur.332..138S.
2. ↑ 2.0 2.1 Sheng, Z. Z.; Hermann, A.M.; El Ali, A.; Almasan, C.; Estrada, J.; Datta, T.; Matson, R.J. (1988). "Superconductivity at 90 K in the Tl-Ba-Cu-O system". Physical Review Letters 60 (10): 937-940. doi:10.1103/physrevlett.60.937. PMID 10037895. Bibcode: 1988PhRvL..60..937S.
3. ↑ Sheng, Z. Z.; Hermann, A. M. (1988). "Superconductivity in the rare-earth-free Tl-Ba-Cu-O system above liquid-nitrogen temperature". Nature 332 (6159): 55–58. doi:10.1038/332055a0. Bibcode: 1988Natur.332...55S.

* Copper Oxide Superconductors:, by Charles P. Poole, Timir Datta, Horacio A. Farach, John Wiley & Sons, 1988, ISBN:0-471-62342-3
* Superconductivity: Its historical Roots and Development from Mercury to the Ceramic Oxides, by Per Fridtjof Dahl, AIP, New York, 1st ed. 1992, ISBN:0-88318-848-1

## External links

* Thallium-based high-temperature superconductors

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Thallium compounds

Thallium(I)|

* TlN3
* TlOH
* TlI
* TlBr
* Tl2CO3
* TlCl
* TlF
* Tl2O
* Tl2SO4
* Tl2S
* Tl2Te
* TlI3
* TBCCO

| Organothallium(I)|

* Tl(C2H3O2)3
* Tl2C3H2O4
* TlC5H5

|

Thallium(III)|

* TlH3
* Tl(OH)3
* Tl2O3
* Tl(NO3)3

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