Fluoride phosphate

Short description: Class of chemical compounds

The fluoride phosphates or phosphate fluorides are inorganic double salts that contain both fluoride and phosphate anions. In mineralogy, Hey's Chemical Index of Minerals groups these as 22.1. The Nickel-Strunz grouping is 8.BN.

Related mixed anion compounds are the chloride phosphates, the fluoride arsenates and fluoride vanadates.

They are distinct from the fluorophosphates: monofluorophosphate, difluorophosphate and hexafluorophosphate which have fluorine bonds to the phosphorus.

## Minerals

name  | formula  | ratio

PO4:F

| formula weight  | crystal system  | space group  | unit cell  | volume  | density  | refractive index  | comment  | reference

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Althausite | Mg4(PO4)2(OH,O)(F,☐)  | 2:~1  |  | Orthorhombic  | Pnma | a = 8.258 b = 6.054, c = 14.383  | 719.06  | 2.97  | Biaxial (+) nα = 1.588 nβ = 1.592 nγ = 1.598

2V: measured: 70° , calculated: 80°

Max birefringence: δ = 0.010

|  | [1]
Amblygonite | LiAl(PO4)F  | 1:1  |  | Triclinic  | P1 | a = 6.644 b = 7.744 c = 6.91

α = 90.35°, β = 117.33°, γ = 91.01° Z=4

| 315.75  | 3.04-3.11  | Biaxial (-) nα = 1.577 - 1.591 nβ = 1.592 - 1.605 nγ = 1.596 - 1.613

2V: Measured: 107° to 129.5°

Birefringence: 0.020

|  | [2]
aravaite  | Ba2Ca18(SiO4)6(PO4)3(CO3)F3O  | 3:3  |  | trigonal  | R3m | a = 7.1255, c = 66.290 Z=3  | 2914.8  |  |  |  | [3]
Arctite | Na2Ca4(PO4)3F  | 3:1  |  | Trigonal  | R3m | a = 7.078 c = 41.203 Z=6  | 1,787.64  | 3.13  | Uniaxial (-) nω = 1.578 nε = 1.577 Birefringence: 0.001  |  | [4]
Ariegilatite  | BaCa12(SiO4)4(PO4)2F2O  |  |  | Trigonal  | R3m | a = 7.1551 c = 41.303  | 1381.2  |  | Uniaxial (-) nω = 1.650 nε = 1.647

Max Birefringence: δ = 0.003

|  | [5]
Babefphite | BaBePO4(F,OH)  | 1:~1  |  | Tetragonal  |  |  |  |  | Uniaxial (+) nω = 1.629 nε = 1.632

Max birefringence: δ = 0.003

|  | [6]
Belovite-(Ce) | NaCeSr3(PO4)3F  | 3:1  |  | Trigonal  | P3 | a = 9.692 c = 7.201  | 585.80  | 4.19  | Uniaxial (-) nω = 1.653 - 1.660 nε = 1.634 - 1.640

Birefringence: 0.015

|  | [7]
Belovite-(La) | NaLaSr3(PO4)3F  | 3:1  |  | Trigonal  | P3 | a = 9.647 c = 7.17  | 577.88  | 4.19  | Uniaxial (-) nω = 1.653 nε = 1.635 - 1.636

Max birefringence: δ = 0.018

|  | [8]
Bøggildite  | Na2Sr2Al2PO4F9 | 1:9  |  | Monoclinic  |  |  |  |  | Biaxial (+) nα = 1.462 nβ = 1.466 nγ = 1.469

2V: 80° Max birefringence:δ = 0.007

|  | [9]
Carlgieseckeite-(Nd)  | NaNdCa3(PO4)3F  |  |  | Trigonal  | P3 | a = 9.4553 c = 6.9825  | 540.62  | 3.91  |  |  | [10]
Cloncurryite  | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O  | 2:2  |  | Monoclinic  | P21/b | a = 4.9573 b = 12.1824 c = 18.9749 β = 90.933° Z=4  | 1145.78  | 2.525  | Biaxial (-) nα = 1.548(2) nγ = 1.550(2)

2V: calculated: 56°

Max brefringence: δ = 0.002

|  | [11]
Deloneite  | (Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5 |  |  | Trigonal  | P3  | a = 9.51 c = 7.01 Z=2  | 549.05  | 3.92  | Uniaxial (-) nω = 1.682 nε = 1.660

Max birefringence: δ = 0.022

|  | [12]
Fluellite | Al2(PO4)F2(OH) · 7H2O  |  |  | Orthorhombic  | Fddd | a = 11.22 b = 21.15 c = 8.54  | 2,027  | 2.139 - 2.17  | Biaxial (+) nα = 1.473 - 1.490 nβ = 1.490 - 1.496 nγ = 1.506 - 1.511

Max birefringence: δ = 0.033

|  | [13]
Fluorapatite | Ca5(PO4)3F  | 3:1  |  | Hexagonal  | P63/m | a = 9.3973 c = 6.8782  | 526.03  | 3.1-3.25  | Uniaxial (-) nω = 1.631 - 1.650 nε = 1.627 - 1.646

Birefringence: 0.004

|  | [14]
Fluorcaphite | SrCaCa3(PO4)3F  | 3:1  |  | Hexagonal  | P63/m | a = 9.485 c = 7.000 Z=2  | 545.39  |  | Uniaxial (-) nω = 1.649 nε = 1.637

Max birefringence: δ = 0.012

|  | [15]
Fluorphosphohedyphane  | Ca2Pb3(PO4)3F  | 3:1  |  | Hexagonal  | P63/m | a = 9.640, c = 7.012 Z=2  | 564.4  | 5.445  | Uniaxial (-) nω = 1.836 nε = 1.824

Max birefringence: δ = 0.012

|  | [16]
Fluorstrophite  | SrCaSr3(PO4)3F  | 3:1  |  | Hexagonal  | P63/m | a = 9.565 c = 7.115 Z=2  | 563.74  |  | Uniaxial (-) nω = 1.651 nε = 1.637

Max birefringence: δ = 0.014

|  | [17]
Francolite |  |  |  |  |  |  |  |  |  |  |
Herderite | CaBe(PO4)F  |  |  | Monoclinic  |  | a = 4.81, b = 7.7 c = 9.82 β = 90.1°  | 363.7  | 3.02  | Biaxial (-) nα = 1.556 - 1.592 nβ = 1.578 - 1.610 nγ = 1.589 - 1.620

2V: calculated: 70°

Max birefringence: δ = 0.033

|  | [18]
Iangreyite  | Ca2Al7(PO4)2(PO3OH)2(OH,F)15 · 8H2O  | 4:~15  |  | Trigonal  | P3 2 1  | a = 6.988 c = 16.707  | 706.5  |  |  |  | [19]
Isokite  | CaMg(PO4)F  |  |  | Monoclinic  | B2/b | a = 6.52 b = 8.75 c = 7.51 β = 121.47°  | 365.4  | 3.15-3.27  | Biaxial (+) nα = 1.590 nβ = 1.595 nγ = 1.615

2V: ,easured: 51°

Max birefringence: δ = 0.025

|  | [20]
Kingite  | Al3(PO4)2F2(OH) · 7H2O  | 2:2  |  | Triclinic  |  | a = 9.15 b = 10 c = 7.24

α = 98.6°, β = 93.6°, γ = 93.2°

|  |  | Biaxial  |  | [21]
Kuannersuite-(Ce)  | NaCeBa3(PO4)3F0.5Cl0.5 | 6:1  |  | Trigonal  | P3 | a = 9.909 c = 7.402  | 629.42  | 4.51  |  |  | [22]
Lacroixite  | NaAl(PO4)F  | 1:1  |  | Monoclinic  | B2/b | a = 6.414 b = 8.207 c = 6.885 β = 115.47°  | 327.20  | 3.126 - 3.29  | Biaxial (-) nα = 1.546 nβ = 1.563 nγ = 1.580

2V: measured: 89°

Birefringence: 0.034

|  | [23]
Mcauslanite  | Fe3Al2(PO4)3(PO3OH)F · 18H2O  | 4:1  |  | Triclinic  |  | a = 10.05 b = 11.56 c = 6.88

α = 105.84°, β = 93.66°, γ = 106.47°

| 728.7  |  | Biaxial (-) nα = 1.522 nβ = 1.531 nγ = 1.534

2V: measured: 55° to 59.7°, calculated: 58°

Max birefringence:δ = 0.012

|  | [24]
Minyulite | KAl2(PO4)2(OH,F) · 4H2O  | 2:~1  |  | Orthorhombic  | Pba2 | a = 9.34 b = 9.74 c = 5.52  | 502  | 2.47  | Biaxial (+) nα = 1.531 nβ = 1.534 nγ = 1.538

2V: measured: 70° , calculated: 82°

Max birefringence: δ = 0.007

|  | [25]
Miyahisaite  | (Sr,Ca)2Ba3(PO4)3F  | 3:1  |  | Hexagonal  | P63/m | a = 9.921, c = 7.469 Z=2  | 636.7  | 4.511  |  |  | [26]
Morinite  | NaCa2Al2(PO4)2(OH)F4 · 2H2O  | 2:4  |  | Monoclinic  |  |  |  | 2.94  | Biaxial (-) nα = 1.551 nβ = 1.563 nγ = 1.565

2V: measured: 43° , calculated: 44°

Max birefringence: δ = 0.014

|  | [27]
Nacaphite  | Na2Ca(PO4)F  |  |  | Monoclinic  | P21/b | a = 13.318 b = 7.0964 c = 10.6490 β = 113.526° Z=8  | 922.81  |  | Biaxial (-) nα = 1.508 nβ = 1.515 nγ = 1.520

2V: 80° Max birefringence: δ = 0.012

|  | [28]
natrophosphate  | Na7(PO4)2F.19H2O  | 2:1  |  | Isometric  | Fd3c | a = 27.79 Z=56  | 21,461.78  | 1,71-1.72  | Isotropic  |  | [29][30]
Nefedovite  | Na5Ca4(PO4)4F  | 4:1  |  | Triclinic  |  | a = 5.4 Å, b = 11.64 Å, c = 16.48 Å

α = 134.99°, β = 90.04°, γ = 89.96°

| 732.60  |  | Biaxial (+) nα = 1.571 nγ = 1.590

Max birefringence: δ = 0.019

|  | [31]
Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O  | 8:8  |  | Orthorhombic  | P21mn  | a = 12.123 b = 18.999 c = 4.961  |  | 2.54  | Biaxial (-) nα = 1.540 nβ = 1.548 nγ = 1.553

2V: measured: 76°, calculated: 76°

Max birefringence: δ = 0.013

|  | [32]
Panasqueiraite  | CaMg(PO4)(OH,F)  | 1:~1  |  | monoclinic  |  | a = 6.53 b = 8.75 c = 6.91 β = 112.33°  | 365.2  | 3.27  | Biaxial (+) nα = 1.590 nβ = 1.596 nγ = 1.616

2V: measured: 51° , calculated: 58°

Max birefringence: δ = 0.026

|  | [33]
Richellite  | CaFe3+2(PO4)2(OH,F)2 | 2:~2  |  |  |  | a = 5.18 c = 12.61  |  |  |  |  | [34]
Stronadelphite  | Sr5(PO4)3F  | 3:1  |  | Hexagonal  | P63/m | a = 9.845 c = 7.383  | 619.72  |  | Uniaxial (-) nω = 1.630(1) nε = 1.623(1)

Max birefringence: δ = 0.007

|  | [35]
Triplite | Mn2+2(PO4)F  | 1:1  |  | Monoclinic  | P21/b | a = 11.9 b = 6.52 c = 10.09 β = 105.62°  | 758.4  | 3.9  | Biaxial (+) nα = 1.650 nβ = 1.660 nγ = 1.680

2V: measured: 70° to 90°, calculated: 72°

Max birefringence: δ = 0.030

|  | [36]
Väyrynenite | Mn2+Be(PO4)(OH,F)  | 1:~1  |  | Monoclinic  | P21/b | a = 5.411 b = 14.49 c = 4.73 β = 102.75°  | 361.71  | 3.22  | Biaxial (-) nα = 1.638 - 1.640 nβ = 1.658 - 1.662 nγ = 1.664 - 1.667

2V: measured: 46° to 55°, Calculated: 51° to 57°

Max birefringence: δ = 0.026 - 0.027

|  | [37]
Viitaniemiite  | Na(Ca,Mn2+)Al(PO4)(F,OH)3 | 1:~3  |  | Monoclinic  |  | a = 6.83 b = 7.14 c = 5.44 β = 109.37°  | 250.27  |  | Biaxial (-) nα = 1.557 nβ = 1.565 nγ = 1.571

2V: measured: 81° , calculated: 80°

Max birefringence: δ = 0.014

|  | [38]
Wagnerite | (Mg,Fe2+)2(PO4)F  | 1:1  |  | Monoclinic  | P21/b | a = 9.645 b = 31.659 c = 11.914 β = 108.26(3)°  | 3454.8  | 3.15  | Biaxial (+) nα = 1.568 nβ = 1.572 nγ = 1.582

2V: Measured: 25° to 35°

? Birefringence:0.046

Max birefringence: δ = 0.015

|  | [39]
Wavellite | Al3(PO4)2(OH,F)3 · 5H2O  | 2:~3  |  | Orthorhombic  |  | a = 9.621 b = 17.363 c = 6.994  | 1168.3  | 2.36  | Biaxial (+) nα = 1.518 - 1.535 nβ = 1.524 - 1.543 nγ = 1.544 - 1.561

2V: measured: 60° to 72°, calculated: 60° to 70°

Max birefringence: δ = 0.026

|  | [40]
Zwieselite  | Fe2+2(PO4)F  | 1:1  |  | Monoclinic  | P21/b |  | 753.82  |  | Biaxial (+) nα = 1.686 - 1.696 nβ = 1.690 - 1.704 nγ = 1.703 - 1.713

2V: measured: 58° , calculated: 60°

Max birefringence: δ = 0.017

|  | [41]
| Na5-4.5PO4(CO3,F,Cl)  | 1:~1  |  |  |  |  |  |  |  |  | [29]

## Artificial

name  | formula  | formula weight  | crystal system  | space group  | unit cell Å  | volume  | density  | refractive index  | comment  | reference

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EMM-9; 4-(dimethylamino)pyridine fluoroaluminophosphate  | (DMAP)2Al4P4O17F2•H2O  |  | monoclinic  | P21/a | a=14.335 b=13.561 c=14.497 β =101.094°  |  |  |  | layered  | [42]
| KBPO4F  |  | monoclinic  | Cc |  |  |  |  |  | [43]
Iron-Doped Sodium–Vanadium Fluorophosphate  | Na3V2–yO2–yFey(PO4)2F1+y (y < 0.3)  |  | tetrahedral  | P42/mnm  | a=9.0277 c=10.6259  | 866.0  |  |  |  | [44]
| Na3V2O1.6(PO4)2F1.4 |  |  |  |  |  |  |  |  | [44]
| Na3V2(PO4)2F3 |  |  |  |  |  |  |  |  | [45]
| Na2MnPO4F  |  |  |  |  |  |  |  |  | [46]
α  | Na2FePO4F  |  | monoclinic  | P21/c | a = 13.675, b = 5.2503, c = 13.7202, β = 120.230°  |  |  |  |  | [46]
β  | Na2FePO4F  |  | orthorhombic  |  |  |  |  |  |  | [46]
| RbBPO4F  | 210.25  | cubic  | P213  | a=7.5901 Z=4  | 437.26  | 3.194  |  | colourless  | [43]
MIL-145  | RbGa3(PO4)2(HPO4)F4·C5N2H16·2H2O  | 3187.11  | monoclinic  | P2  | a=14.4314 b=9.1152 c=16.7889 β = 112.708 Z=1  | 2037.30  | 2.598  |  | colourless  | [47]
| K2SnPO4F3 | 348.86  | monoclinic  | P21/c | a=10.039 b=9.415 c=21.602 beta=95.464 Z=12  | 2032.6  | 3.420  |  | colourless  | [48]
| K6Sn(P2O7)2F2 | 739.17  | monoclinic  | P21/c | a=8.515 b=12.400 c=8.403 beta=99.58 Z=29  | 874.8  | 2.806  |  | colourless  | [48]
| K2Sb(P2O7)F  |  | tetragonal  | P4bm  | a=8.5239 c=5.572 Z=2  | 404.8  | 3.223  |  | colourless SHG 4.0×KDP  | [49]
| CsBPO4F  |  | cubic  | P213  | a=7.7090 Z=4  | 458.14  | 3.736  |  | colourless  | [43]
| Na2PrF2(PO4)  |  | cubic  |  |  |  |  |  |  | [50]
| Na2NdF2(PO4)  |  | cubic  |  |  |  |  |  |  | [50]
| Na2SmF2(PO4)  |  | cubic  |  |  |  |  |  |  | [50]
| Na2EuF2(PO4)  |  | cubic  |  |  |  |  |  |  | [50]
| Na2TbF2(PO4)  |  | cubic  |  |  |  |  |  |  | [50]
| Na2PrF2(PO4)  |  | cubic  |  |  |  |  |  |  | [50]
| Sr4Gd3Na3(PO4)6F2 |  |  |  |  |  |  |  |  | [51]
| PbZn(PO4)F  | 386.53  | orthorhombic  | Pna21 | a=8.985 b=9.381 c=4.8212 Z=4  | 406.4  | 6.318  |  | colourless  | [52]

## References

1. ↑ "Althausite: Mineral information, data and localities.". https://www.mindat.org/min-148.html.
2. ↑ "Amblygonite: Mineral information, data and localities.". https://www.mindat.org/min-189.html.
3. ↑ Krüger, Biljana; Krüger, Hannes; Galuskin, Evgeny V.; Galuskina, Irina O.; Vapnik, Yevgeny; Olieric, Vincent; Pauluhn, Anuschka (2018-12-01). "Aravaite, Ba 2 Ca 18 (SiO 4 ) 6 (PO 4 ) 3 (CO 3 )F 3 O: modular structure and disorder of a new mineral with single and triple antiperovskite layers". Acta Crystallographica Section B 74 (6): 492–501. doi:10.1107/S2052520618012271. ISSN 2052-5206. Bibcode: 2018AcCrB..74..492K. http://scripts.iucr.org/cgi-bin/paper?S2052520618012271.
4. ↑ "Arctite: Mineral information, data and localities.". https://www.mindat.org/min-316.html.
5. ↑ "Ariegilatite: Mineral information, data and localities.". https://www.mindat.org/min-51569.html.
6. ↑ "Babefphite: Mineral information, data and localities.". https://www.mindat.org/min-476.html.
7. ↑ "Belovite-(Ce): Mineral information, data and localities.". https://www.mindat.org/min-618.html.
8. ↑ "Belovite-(La): Mineral information, data and localities.". https://www.mindat.org/min-6822.html.
9. ↑ "Bøggildite: Mineral information, data and localities.". https://www.mindat.org/min-703.html.
10. ↑ "Carlgieseckeite-(Nd): Mineral information, data and localities.". https://www.mindat.org/min-40295.html.
11. ↑ "Cloncurryite: Mineral information, data and localities.". https://www.mindat.org/min-29262.html.
12. ↑ "Deloneite: Mineral information, data and localities.". https://www.mindat.org/min-6900.html.
13. ↑ "Fluellite: Mineral information, data and localities.". https://www.mindat.org/min-1565.html.
14. ↑ "Fluorapatite: Mineral information, data and localities.". https://www.mindat.org/min-1572.html.
15. ↑ "Fluorcaphite: Mineral information, data and localities.". https://www.mindat.org/min-6948.html.
16. ↑ "Fluorphosphohedyphane: Mineral information, data and localities.". https://www.mindat.org/min-39334.html.
17. ↑ "Fluorstrophite: Mineral information, data and localities.". https://www.mindat.org/min-3757.html.
18. ↑ "Herderite: Mineral information, data and localities.". https://www.mindat.org/min-1876.html.
19. ↑ "Iangreyite: Mineral information, data and localities.". https://www.mindat.org/min-39883.html.
20. ↑ "Isokite: Mineral information, data and localities.". https://www.mindat.org/min-2054.html.
21. ↑ "Kingite: Mineral information, data and localities.". https://www.mindat.org/min-2210.html.
22. ↑ "Kuannersuite-(Ce): Mineral information, data and localities.". https://www.mindat.org/min-25711.html.
23. ↑ "Lacroixite: Mineral information, data and localities.". https://www.mindat.org/min-2310.html.
24. ↑ "Mcauslanite: Mineral information, data and localities.". https://www.mindat.org/min-2610.html.
25. ↑ "Minyulite: Mineral information, data and localities.". https://www.mindat.org/min-2724.html.
26. ↑ "Miyahisaite: Mineral information, data and localities.". https://www.mindat.org/min-42835.html.
27. ↑ "Morinite: Mineral information, data and localities.". https://www.mindat.org/min-2785.html.
28. ↑ "Nacaphite: Mineral information, data and localities.". https://www.mindat.org/min-2824.html.
29. ↑ 29.0 29.1 Mitchell, R. H. (5 July 2018). "An ephemeral pentasodium phosphate carbonate from natrocarbonatite lapilli, Oldoinyo Lengai, Tanzania". Mineralogical Magazine 70 (2): 211–218. doi:10.1180/0026461067020326.
30. ↑ "Natrophosphate: Mineral information, data and localities.". https://www.mindat.org/min-2862.html.
31. ↑ "Nefedovite: Mineral information, data and localities.". https://www.mindat.org/min-2870.html.
32. ↑ "Nevadaite: Mineral information, data and localities.". https://www.mindat.org/min-25696.html.
33. ↑ "Panasqueiraite: Mineral information, data and localities.". https://www.mindat.org/min-3073.html.
34. ↑ "Richellite: Mineral information, data and localities.". https://www.mindat.org/min-3413.html.
35. ↑ "Stronadelphite: Mineral information, data and localities.". https://www.mindat.org/min-35973.html.
36. ↑ "Triplite: Mineral information, data and localities.". https://www.mindat.org/min-4021.html.
37. ↑ "Väyrynenite: Mineral information, data and localities.". https://www.mindat.org/min-4220.html.
38. ↑ "Viitaniemiite: Mineral information, data and localities.". https://www.mindat.org/min-4178.html.
39. ↑ "Wagnerite: Mineral information, data and localities.". https://www.mindat.org/min-4229.html.
40. ↑ "Wavellite: Mineral information, data and localities.". https://www.mindat.org/min-4250.html.
41. ↑ "Zwieselite: Mineral information, data and localities.". https://www.mindat.org/min-4436.html.
42. ↑ Guo, Peng; Afeworki, Mobae; Cao, Guang; Yun, Yifeng; Sun, Junliang; Su, Jie; Wan, Wei; Zou, Xiaodong (2018-09-17). "Synthesis and Structure of a Layered Fluoroaluminophosphate and Its Transformation to a Three-Dimensional Zeotype Framework" (in en). Inorganic Chemistry 57 (18): 11753–11760. doi:10.1021/acs.inorgchem.8b01890. ISSN 0020-1669. PMID 30156401. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01890.
43. ↑ 43.0 43.1 43.2 Ding, Qingran; Zhao, Sangen; Li, Lina; Shen, Yaoguo; Shan, Pai; Wu, Zhenyue; Li, Xianfeng; Li, Yanqiang et al. (2019-02-04). "Abrupt Structural Transformation in Asymmetric ABPO 4 F (A = K, Rb, Cs)" (in en). Inorganic Chemistry 58 (3): 1733–1737. doi:10.1021/acs.inorgchem.8b02754. ISSN 0020-1669. PMID 30652880. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02754.
44. ↑ 44.0 44.1 Palomares, Verónica; Iturrondobeitia, Amaia; Sanchez-Fontecoba, Paula; Goonetilleke, Damian; Sharma, Neeraj; Lezama, Luis; Rojo, Teófilo (16 December 2019). "Iron-Doped Sodium–Vanadium Fluorophosphates: Na3V2–yO2–yFey(PO4)2F1+y (y < 0.3)". Inorganic Chemistry 59 (1): 854–862. doi:10.1021/acs.inorgchem.9b03111. PMID 31840984.
45. ↑ Semykina, Daria O.; Sharafutdinov, Marat R.; Kosova, Nina V. (2022-06-24). "Understanding of the Mechanism and Kinetics of the Fast Solid-State Reaction between NaF and VPO 4 to Form Na 3 V 2 (PO 4 ) 2 F 3" (in en). Inorganic Chemistry 61 (26): 10023–10035. doi:10.1021/acs.inorgchem.2c00951. ISSN 0020-1669. PMID 35748412. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00951.
46. ↑ 46.0 46.1 46.2 Kirsanova, Maria A.; Akmaev, Alexey S.; Aksyonov, Dmitry A.; Ryazantsev, Sergey V.; Nikitina, Victoria A.; Filimonov, Dmitry S.; Avdeev, Maxim; Abakumov, Artem M. (2020-11-16). "Monoclinic α-Na 2 FePO 4 F with Strong Antisite Disorder and Enhanced Na + Diffusion" (in en). Inorganic Chemistry 59 (22): 16225–16237. doi:10.1021/acs.inorgchem.0c01961. ISSN 0020-1669. PMID 33137251. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01961.
47. ↑ Martineau, Charlotte; Loiseau, Thierry; Beitone, Lionel; Férey, Gérard; Bouchevreau, Boris; Taulelle, Francis (2013). "Single-crystal XRD and solid-state NMR structural resolution of a layered fluorinated gallium phosphate: RbGa 3 (PO 4 ) 2 (HPO 4 )F 4 ·C 5 N 2 H 16 ·2H 2 O (MIL-145)" (in en). Dalton Trans. 42 (2): 422–431. doi:10.1039/C2DT31464A. ISSN 1477-9226. PMID 23069866. http://xlink.rsc.org/?DOI=C2DT31464A.
48. ↑ 48.0 48.1 Hu, Shuaishuai; Su, Zhi (2019). "Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges" (in en). New Journal of Chemistry 43 (41): 16127–16130. doi:10.1039/C9NJ04424H. ISSN 1144-0546. http://xlink.rsc.org/?DOI=C9NJ04424H.
49. ↑ Deng, Yalan; Huang, Ling; Dong, Xuehua; Wang, Lei; Ok, Kang Min; Zeng, Hongmei; Lin, Zhien; Zou, Guohong (2020-11-16). "K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance" (in en). Angewandte Chemie International Edition 59 (47): 21151–21156. doi:10.1002/anie.202009441. ISSN 1433-7851. PMID 32745331. Bibcode: 2020ACIE...5921151D. https://onlinelibrary.wiley.com/doi/10.1002/anie.202009441.
50. ↑ 50.0 50.1 50.2 50.3 50.4 50.5 Zimina, G. V.; Smirnova, I. N.; Gorkovenko, M. Yu.; Spiridonov, F. M.; Komissarova, L. N.; Kaloev, N. I. (1995-02-21). "ChemInform Abstract: Synthesis and Studies of Fluorophosphates of Rare Earth Elements Na2LnF2PO4." (in en). ChemInform 26 (8). doi:10.1002/chin.199508015. ISSN 0931-7597. https://onlinelibrary.wiley.com/doi/10.1002/chin.199508015.
51. ↑ Tikale, Rahul V.; Kadam, Abhijeet R.; Dhoble, S. J. (2025-08-09). "Comprehensive photoluminescence analysis and Judd-Ofelt analysis of eu³⁺-Activated Sr₄Gd₃Na₃(PO₄)₆F₂ phosphor: theoretical elucidation from PL emission spectra for optimized red emission" (in en). Optical and Quantum Electronics 57 (8). doi:10.1007/s11082-025-08407-6. ISSN 1572-817X. https://link.springer.com/10.1007/s11082-025-08407-6.
52. ↑ li, xiaobao; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2023). "Structure and Optical Property Evolutions in PbM(PO4)X (M = Zn, Sn; X = halogen): SHG Effect and Birefringence" (in en). Inorganic Chemistry Frontiers 10 (8): 2268–2275. doi:10.1039/D3QI00230F. ISSN 2052-1553.

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