Titanium(IV) acetate

Titanium(IV) acetate  Names

Other names

* Titanium tetraacetate

Identifiers

CAS Number

* 13057-42-6 Y

3D model (JSmol)

* Interactive image

ChemSpider |

* 8141204 Y

EC Number |

* 235-944-4

PubChem CID

* 59044991

InChI

* InChI=1S/4C2H4O2.Ti/c4*1-2(3)4;/h4*1H3,(H,3,4);

Key: INNSZZHSFSFSGS-UHFFFAOYSA-N

SMILES

* CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Ti]

Properties

Chemical formula

| Ti(C2H3O2)4
Molar mass | 288.07 g/mol
Appearance  | colorless
Melting point |  117 °C (243 °F; 390 K)
Related compounds

Other cations

| Zirconium(IV) acetate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Titanium(IV) acetate or titanium tetraacetate is a hypothetical coordination complex with the formula Ti(C2H3O2)4. It is discussed in archaic literature,[1] well before the advent of X-ray crystallography and an appreciation of the structural trends in metal carboxylate complexes.

## Contents

* 1 Preparation
* 2 Related titanium acetates
* 3 Uses
* 4 References

## Preparation

Titanium(IV) acetate can be prepared by reacting tetramethyltitanium with acetic acid.[2]

## Related titanium acetates

Evidence for the composition much less the structure as a tetraacetate has not been presented.[3] Instead a variety of titanium oxo acetates have been prepared by reactions of titanium alkoxides and acetic acid.[4]

## Uses

Species claimed to be titanium(IV) acetate have been used in the production of bismuth titanate ferroelectric thin films. Titanium(IV) acetate is used in the step of making the acetate-derived solutions. The acetate derived solutions were created by blending acetic acid and bismuth acetate together and adding titanium(IV) acetate.[5] "Titanium(IV) acetate" is a substitute for antimony potassium tartrate(emetic tartar) when making red and brown dyes.[6]

## References

1. ↑ Frederick Pearson Treadwell (1916) (in English). Qualitative analysis. J.Wiley & sons, Incorporated. pp. 538. https://books.google.com/books?id=svIZAAAAYAAJ. Retrieved 26 March 2021.
2. ↑ K.-H. Thiele; M. Panse (1978). "Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. XXVII. Darstellung von Titanacetaten aus Tetramethyl- und Tetrabenzyltitan". Z. anorg. allg. Chem. 441 (1): 23-28. doi:10.1002/zaac.19784410103.
3. ↑ Pande, K. C.; Mehrotra, R. C. (1957). "Attempted Preparation of Titanium Tetra-Acetate". Journal für praktische Chemie 5 (1–2): 101–104. doi:10.1002/prac.19570050112.
4. ↑ Gautier-Luneau, I.; Mosset, A.; Galy, J. (1987). "Structural Characterization of a Hexanuclear Titanium Acetate Complex, Ti6(μ3–O)2(μ2–O)2(μ2–OC2H5)2-μ-CH3COO)8(OC2H5)6, Built Up of Two Trinuclear, oxo-Centered, Units". Zeitschrift für Kristallographie 180 (1–4): 83–95. doi:10.1524/zkri.1987.180.1-4.83. Bibcode: 1987ZK....180...83G.
5. ↑ (in English) Scientific and Technical Aerospace Reports. NASA, Office of Scientific and Technical Information. 1995. pp. 1198. https://books.google.com/books?id=62GCbS7Mu3kC. Retrieved 26 March 2021.
6. ↑ The Year-book for Colorists and Dyers. the New York Public Library. 1905. pp. 413. https://books.google.com/books?id=VBFSAAAAYAAJ. Retrieved 26 March 2021.

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Titanium compounds

Titanium(II)|

* TiCl2
* TiH2
* TiO
* TiS
* TiSi2

| Organotitanium(II) compounds|

[(C5H5)2Ti(CO)2]

|

Titanium(III)|

* TiAl
* TiBr3
* TiCl3
* TiF3
* TiI3
* TiN
* TiP
* Ti2O3
* Ti2S3

| Organotitanium(III) compounds|

[(C5H5)2TiCl]2

|

Titanium(IV)|

* TiB2
* TiBr4
* TiC
* TiCl4
* Ti(ClO4)4
* TiF4
* H2TiF6
* TiH4
* TiI4
* Ti(NMe2)4
* Ti(NO3)4
* TiO2
* H4TiO4
* Ti4(OCH2CH3)16
* Ti(OCH(CH3)2)4
* Ti(OCH2CH2CH2CH3)4
* KTiOPO4
* NiO*Sb2O3*20TiO2
* TiS2
* TiSe2
* TiSi2

| Titanate compounds|

* BaTiO3
* Ba2TiO4
* Bi4Ti3O12
* CaTiO3
* CaCu3Ti4O12
* CaZrTi2O7
* Cs2TiO3
* Dy2Ti2O7
* EuBaTiO4
* FeTiO3
* Ho2Ti2O7
* Li2TiO3
* MnTiO3
* Na2Ti3O7
* Na0.5Bi0.5TiO3
* NiTiO3
* PbTiO3
* Pb(Zr,Ti)O3
* SrTiO3
* ZnTiO3

|

Organotitanium(IV) compounds|

* [(C5H5)2TiCl2]
* [(C5H5)2Ti(CH3)2]
* [(C5H5)2TiS5]
* [(C5H5)2Ti(μ-Cl)(μ-CH2)Al(CH3)2]
* [(η5-C5H4-CH2C6H4OCH3)2TiCl2]

|

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Acetyl halides and salts of the acetate ion

AcOH |  |  |  | He
LiOAc | Be(OAc)2
BeAcOH | B(OAc)3 | AcOAc
ROAc | NH4OAc | AcOOH | FAc | Ne
NaOAc | Mg(OAc)2 | Al(OAc)3
ALSOL
Al(OAc)2OH
Al2SO4(OAc)4 | Si  | P  | S  | ClAc | Ar
KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2
Cr(OAc)3 | Mn(OAc)2
Mn(OAc)3 | Fe(OAc)2
Fe(OAc)3 | Co(OAc)2,
Co(OAc)3 | Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge  | As(OAc)3 | Se  | BrAc | Kr
RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb  | Mo(OAc)2 | Tc  | Ru(OAc)2
Ru(OAc)3
Ru(OAc)4 | Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In  | Sn(OAc)2
Sn(OAc)4 | Sb(OAc)3 | Te  | IAc | Xe
CsOAc | Ba(OAc)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt(OAc)2 | Au  | Hg2(OAc)2,
Hg(OAc)2 | TlOAc
Tl(OAc)3 | Pb(OAc)2
Pb(OAc)4 | Bi(OAc)3 | Po  | At  | Rn
Fr  | Ra  |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(OAc)3 | Ce(OAc)x | Pr  | Nd  | Pm  | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb  | Dy(OAc)3 | Ho(OAc)3 | Er  | Tm  | Yb(OAc)3 | Lu(OAc)3
Ac  | Th  | Pa  | UO2(OAc)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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