Rhodium(III) nitrate

Rhodium(III) nitrate[1][2] Names

Other names

* Rhodium trinitrate

Identifiers

CAS Number

* 10139-58-9

3D model (JSmol)

* Interactive image

ChemSpider |

* 132398

EC Number |

* 233-397-6

PubChem CID

* 150190

InChI

* InChI=1S/3NO3.Rh/c3*2-1(3)4;/q3*-1;+3

Key: VXNYVYJABGOSBX-UHFFFAOYSA-N

SMILES

* [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Rh+3]

Properties

Chemical formula

| Rh(NO3)3
Molar mass | 288.92 g/mol
Appearance  | Yellow solid
Density | 1.41 g/cm3

Solubility in water

| Soluble
Structure

Crystal structure

| Hexagonal[3]
Hazards
GHS pictograms |
GHS Signal word | Danger

GHS hazard statements

| H271, H290, H302, H314, H317, H341, H410

GHS precautionary statements

| P201, P202, P210, P220, P221, P234, P260, P261, P264, P270, P272, P273, P280, P281, P283, P301+312, P301+330+331, P302+352, P303+361+353, P304+340, P305+351+338, P306+360, P308+313, P310, P321
Related compounds

Other anions

| Rhodium(III) sulfate

Other cations

| Cobalt(III) nitrate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Rhodium(III) nitrate is a inorganic compound, a salt of rhodium and nitric acid with the formula Rh(NO3)3. This anhydrous complex has been the subject of theoretical analysis but has not been isolated.[4] However, a dihydrate and an aqueous solution are known with similar stoichiometry; they contain various hexacoordinated rhodium(III) aqua and nitrate complexes.[3] A number of other rhodium nitrates have been characterized by X-ray crystallography: Rb4[trans-[Rh(H2O)2(NO3)4][Rh(NO3)6]Cite error: Closing `</ref>` missing for `<ref>` tag

## References

1. ↑ "Rhodium nitrate". https://pubchem.ncbi.nlm.nih.gov/compound/Rhodium-nitrate.
2. ↑ "Rhodium nitrate". https://www.americanelements.com/rhodium-nitrate-10139-58-9.
3. ↑ 3.0 3.1 G. Bongiovanni; R. Caminiti; D. Atzei; P. Cucca; A. Anedda (1986). "Structure of rhodium(III) nitrate aqueous solutions. An investigation by x-ray diffraction and Raman spectroscopy" (in English). The Journal of Physical Chemistry (ACS Publications) 90 (2): 238–243. doi:10.1021/j100274a007. https://pubs.acs.org/doi/10.1021/j100274a007. Retrieved 12 March 2021.
4. ↑ Cite error: Invalid `<ref>` tag; no text was provided for refs named `eur`

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Rhodium compounds

Rh(0)|

| Organorhodium(0) compounds|

* [Rh6(CO)16]
* [Rh4(CO)12]

|

Rh(I)|

* [RhCl(PPh3)3]

| Organorhodium(I) compounds|

* [(C8H12)RhCl]2
* [(C8H14)2)RhCl]2
* [(CO)2)RhCl]2
* [HRh(CO)(PPh3)3]

|

Rh(II)|

* Rh2(CH3CO2)4

| Organorhodium(II) compunds|

* [Rh(C5H5)2]

|

Rh(III)|

* RhCl3
* Rh2O3
* YbRh2Si2
* [Rh(NH3)5Cl]Cl2

| Organorhodium(III) compunds|

* [Cp*RhCl2]2

|

Rh(IV)|

* RhO2

Rh(V)|

* XeRhF6

Rh(VI)|

* RhF6

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Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

|
|
|
|

LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Rhodium(III)_nitrate&oldid=556061"
*[CID]: Compound ID
*[H271]: May cause fire or explosion: strong oxidizer
*[H290]: May be corrosive to metals
*[H302]: Harmful if swallowed
*[H314]: Causes severe skin burns and eye damage
*[H317]: May cause an allergic skin reaction
*[H341]: Suspected of causing genetic defects
*[H410]: Very toxic to aquatic life with long lasting effects
*[P201]: Obtain special instructions before use
*[P202]: Do not handle until all safety precautions have been read and understood
*[P210]: Keep away from heat/sparks/open flames/hot surfaces – No smoking
*[P220]: Keep/Store away from clothing/…/combustible materials
*[P221]: Take any precaution to avoid mixing with combustibles
*[P234]: Keep only in original container
*[P260]: Do not breathe dust/fume/gas/mist/vapours/spray
*[P261]: Avoid breathing dust/fume/gas/mist/vapours/spray
*[P264]: Wash … thoroughly after handling
*[P270]: Do not eat, drink or smoke when using this product
*[P272]: Contaminated work clothing should not be allowed out of the workplace
*[P273]: Avoid release to the environment
*[P280]: Wear protective gloves/protective clothing/eye protection/face protection
*[P281]: Use personal protective equipment as required
*[P283]: Wear fire/flame resistant/retardant clothing
*[P301+312]: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
*[P301+330+331]: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
*[P302+352]: IF ON SKIN: Wash with soap and water
*[P303+361+353]: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
*[P304+340]: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
*[P305+351+338]: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
*[P306+360]: IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
*[P308+313]: IF exposed or concerned: Get medical advice/attention
*[P310]: Immediately call a POISON CENTER or doctor/physician
*[P321]: Specific treatment (see … on this label)
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