Platinum(IV) bromide

Names
IUPAC name

Platinum(IV) bromide

Other names

Platinic bromide

Identifiers

CAS Number

* 68938-92-1 N

3D model (JSmol)

* Interactive image

ChemSpider |

* 100307

EC Number |

* 273-151-5

PubChem CID

* 111865

InChI

* InChI=1S/4BrH.Pt/h4*1H;/q;;;;+4/p-4

Key: SNPHNDVOPWUNON-UHFFFAOYSA-J

SMILES

* Br[Pt](Br)(Br)Br

Properties

Chemical formula

| PtBr4
Molar mass | 514.694 g/mol
Appearance  | brownish-black crystals
Melting point | decomposes at 180°C

Solubility in water

| 0.41 g/100mL @ 20°C
Solubility | slightly soluble in ethanol, diethyl ether[1]
Hazards
Safety data sheet | [1]
GHS pictograms |
GHS Signal word | Danger

GHS hazard statements

| H314

GHS precautionary statements

| P260, P264, P280, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)  |

Flash point | non-flammable
Related compounds

Other anions

| Platinum(IV) fluoride
Platinum(IV) chloride
Platinum(IV) iodide

Other cations

| Nickel(II) bromide
Palladium(II) bromide

Related compounds

| Platinum(II) bromide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is YN ?)
Infobox references

Platinum(IV) bromide is the inorganic compound with the formula PtBr4. It is a brown solid. It is a little-used compound mainly of interest for academic research.[2] It is a component of a reagent used in qualitative inorganic analysis.[3]

In terms of structure, the compound is an inorganic polymer consisting of interconnected PtBr6 octahedra.

## References

1. ↑ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), CRC Press, pp. 481, ISBN 0-8493-0594-2, https://books.google.com/books?id=lFjg0L-uOxoC&q="Platinum(IV)+bromide"&pg=PT866, retrieved 2008-06-19
2. ↑ Lagrow, Alec P.; Knudsen, Kristian Rahbek; Alyami, Noktan M.; Anjum, Dalaver H.; Bakr, Osman M. (2015). "Effect of Precursor Ligands and Oxidation State in the Synthesis of Bimetallic Nano-Alloys". Chemistry of Materials 27 (11): 4134–4141. doi:10.1021/acs.chemmater.5b01247.
3. ↑ Wenger, P. E. (2007), Reagents for Qualitative Inorganic Analysis, Read Country Books, pp. 242, ISBN 978-1-4067-4847-5, https://books.google.com/books?id=SRAR3FOYxhEC&q="Platinum(IV)+bromide"&pg=PA360, retrieved 2008-06-18

* v
* t
* e

Platinum compounds

Pt(0)|

* Pt(P(C6H5)3)4

Pt(II)|

* Pt(NH3)2(CO2)2C4H6
* cis-Pt(NH3)2Cl2
* trans-Pt(NH3)2Cl2
* K2Pt(CN)4
* Pt(NH3)4PtCl4
* Pt(NH3)2CO2CH2O
* C6H10(NH2)2PtC2O4
* NH3PtCl2NC5H4CH3
* Pt(C2H3O2)2
* PtBr2
* PtCl2
* K2PtCl4
* (PtCl(NH3)2C6H12(NH2)2)Pt(NH3)2(NO3)4
* Pt(OH)2
* PtS

| Organoplatinum(II) compounds|

* PtCl2C8H12
* KPtCl3C2H4

|

Pt(IV)|

* PtO2
* (NH4)2PtCl6
* H2PtCl6
* PtBr4
* PtCl4
* PtF4
* K2PtCl6
* Pt(C2H3O2)2Cl2NH3NH2C6H11
* Na2PtCl6
* Pt(OH)4
* PtS2
* PtSe2
* XeFPtF5

Pt(V)|

* PtF5
* O2PtF6
* XePtF6

Pt(VI)|

* PtF6

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*[CID]: Compound ID
*[H314]: Causes severe skin burns and eye damage
*[P260]: Do not breathe dust/fume/gas/mist/vapours/spray
*[P264]: Wash … thoroughly after handling
*[P280]: Wear protective gloves/protective clothing/eye protection/face protection
*[P301+330+331]: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
*[P303+361+353]: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
*[P304+340]: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
*[P305+351+338]: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
*[P310]: Immediately call a POISON CENTER or doctor/physician
*[P321]: Specific treatment (see … on this label)
*[P363]: Wash contaminated clothing before reuse
*[P405]: Store locked up
*[P501]: Dispose of contents/container to …
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