Manganese diselenide

Manganese(II) diselenide  Identifiers

CAS Number

* 12299-98-8 Y

3D model (JSmol)

* Interactive image

EC Number |

* 235-569-6

PubChem CID

* 83014

UNII |

* VJ084QU1P0 Y

InChI

* InChI=1S/Mn.2Se

Key: KDAKOPXAEMJUSU-UHFFFAOYSA-N

SMILES

* [Mn](=[Se])=[Se]

Properties

Chemical formula

| MnSe2
Molar mass | 212.880 g·mol−1
Appearance  | grey, odorless powder
Density | 5.55 g/cm3

Solubility in water

| insoluble
Hazards
GHS pictograms |
GHS Signal word | Danger

GHS hazard statements

| H301, H331, H373, H410

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is YN ?)
Infobox references

Manganese(II) diselenide is the inorganic compound with the formula MnSe2. This rarely encountered solid is structurally similar to that of iron pyrite (FeS2). Analogous to the description of iron pyrite, manganese diselenide is sometimes viewed as being composed of Mn2+ and Se22− ions, although being a semiconductor, MnSe2 is not appropriately described in formal oxidation states.[1][2]

## Spectroscopy

The high‐resolution Mn 2p spectra of the MnSe2 has two distinct peaks at 642.2 and 653.9 electronvolts correspond to the Mn 2p3/2 and Mn 2p1/2 spin–orbit components, respectively. The energy difference (Δ 2p) of 11.7 eV confirms the presence of Mn4+ ions in the sample. A good correlation was observed with the literature value for the Mn4+ state.[3] No peaks for Mn2+ ions were observed at 640–641 eV, which confirmed the formation of only the Mn4+ oxidation state with a d3 electronic configuration. The Se 3d spectra were deconvoluted into two well‐defined peaks (3d5/2 and 3d3/2) at a binding energy of 54.46 and 55.31 eV, respectively. These two peaks confirmed the presence of Se2− ions in MnSe2.[4]

## References

1. ↑ "The Mn–Se (Manganese–selenium) System" Journal of Phase Equilibria, Volume 19, Number 6, 12/1998, pp.588-590, M. E. Schlesinger doi:10.1361/105497198770341798
2. ↑ The Crystal Structure of Manganese Diselenide and Manganese Ditelluride, Norman Elliott, J. Am. Chem. Soc., 1937, 59 (10), pp 1958–1962 doi:10.1021/ja01289a049
3. ↑ Liu, Shuangyu; Zhu, Yunguang; Xie, Jian; Huo, Ying; Yang, Hui Ying; Zhu, Tiejun; Cao, Gaoshao; Zhao, Xinbing et al. (2014). "Direct Growth of Flower-Like δ-MnO2on Three-Dimensional Graphene for High-Performance Rechargeable Li-O2Batteries". Advanced Energy Materials 4 (9). doi:10.1002/aenm.201301960.
4. ↑ Balamuralitharan, B.; Karthick, S. N.; Balasingam, Suresh Kannan; Hemalatha, K. V.; Selvam, Samayanan; Raj, J. Anandha; Prabakar, Kandasamy; Jun, Yongseok et al. (2017). "Hybrid Reduced Graphene Oxide/Manganese Diselenide Cubes: A New Electrode Material for Supercapacitors". Energy Technology 5 (11): 1953–1962. doi:10.1002/ente.201700097.

* v
* t
* e

Manganese compounds

* MnO
* Mn3O4
* Mn5O8
* MnS
* MnS2
* MnSO4
* MnSe2
* MnSe
* MnTe
* Mn(NO3)2
* MnCO3
* MnCl2
* MnCl3
* MnCl4
* MnF2
* MnBr2
* MnI2
* MnTiO3
* MnMoO4
* Mn(CH3COO)2
* Mn2O3
* MnF3
* K6Mn2O6
* MnO2
* Mn(OH)2
* MnO3
* K3MnO4
* MnF4
* Na2MnO4
* K2MnO4
* Mn2O7
* NaMnO4
* KMnO4
* NH4MnO4
* AgMnO4
* Ca(MnO4)2
* Ba(MnO4)2
* MnH(CO)5
* Mn2(CO)10

* v
* t
* e

Selenides

| H2Se
H2Se2 |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|

Li2Se | Be |  |  |  |  |  |  |  |  |  |  | B | CSe2
OCSe | (NH4)2Se | O | F | Ne
Na2Se | MgSe |  |  |  |  |  |  |  |  |  |  | Al2Se3 | Si | PxSey | S | Cl | Ar
K2Se | CaSe | Sc2Se3 | TiSe2 | V | CrSe
Cr2Se3 | MnSe
MnSe2 | FeSe | CoSe | NiSe | CuSe | ZnSe | GaSe
Ga2Se3 | GeSe | As2Se3
As4Se3 | Se | Br | Kr
Rb2Se | SrSe | Y2Se3 | Zr | NbSe2
NbSe3 | MoSe2 | Tc | Ru | Rh | Pd | Ag2Se | CdSe | In2Se3 | SnSe
SnSe2 | Sb2Se3 | Te | I | Xe
Cs2Se | BaSe | *  | Hf | Ta | WSe2
WSe3 | ReSe2 | Os | Ir | Pt | Au | HgSe | Tl2Se | PbSe | Bi2Se3 | Po | At | Rn
Fr | Ra | **  | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | CnSe | Nh | Fl | Mc | Lv | Ts | Og |  |  |  |  |  |  |  |
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | La2Se3 | Ce2Se3 | Pr2Se3 | Nd2Se3 | Pm | Sm2Se3 | Eu2Se3 | Gd | Tb | Dy | Ho | Er2Se3 | Tm2Se3 | Yb | Lu |
| ** | Ac | ThSe2 | Pa | USe2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Manganese diselenide. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Manganese_diselenide&oldid=812359"
*[CID]: Compound ID
*[H301]: Toxic if swallowed
*[H331]: Toxic if inhaled
*[H373]: May cause damage to organs through prolonged or repeated exposure
*[H410]: Very toxic to aquatic life with long lasting effects
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template