Rhodium(III) sulfide

Names
IUPAC name

Rhodium(III) sulfide

Other names

Rhodium sesquisulfide

Identifiers

CAS Number

* 12067-06-0

3D model (JSmol)

* Interactive image

ChemSpider |

* 23349348

EC Number |

* 235-075-0

PubChem CID

* 54672740

InChI

* Key: ILLXJAWVPNCIFC-UHFFFAOYSA-N

* InChI=1S/2Rh.3S

SMILES

* S=[Rh]S[Rh]=S

Properties

Chemical formula

| Rh2S3
Molar mass | 301.99 g·mol−1
Appearance  | black solid
Density | 6.46 g/cm−3

Solubility in water

| insoluble

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Rhodium(III) sulfide is the inorganic compound with the formula Rh2S3. It is an insoluble black solid, prepared by the heating a mixture of elemental rhodium and sulfur. Crystals can be grown by chemical vapor transport using bromine as the transporting agent. The structure consists of octahedral and tetrahedral Rh and S centers, respectively. No close Rh-Rh contacts are observed.[1] Rh2Se3 and Ir2S3 adopt the same structure as Rh2S3.

## References

1. ↑ Parthé, Erwin; Hohnke, Dieter K.; Hulliger, Fritz (1967). "New Structure Type with Octahedron Pairs for Rhodium(III) Sulfide, Rhodium(III) Selenide, and Iridium(III) Sulfide". Acta Crystallographica 23: 832–40. doi:10.1107/S0365110X67003767.

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Rhodium compounds

Rh(0)|

| Organorhodium(0) compounds|

* [Rh6(CO)16]
* [Rh4(CO)12]

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Rh(I)|

* [RhCl(PPh3)3]

| Organorhodium(I) compounds|

* [(C8H12)RhCl]2
* [(C8H14)2)RhCl]2
* [(CO)2)RhCl]2
* [HRh(CO)(PPh3)3]

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Rh(II)|

* Rh2(CH3CO2)4

| Organorhodium(II) compunds|

* [Rh(C5H5)2]

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Rh(III)|

* RhCl3
* Rh2O3
* YbRh2Si2
* [Rh(NH3)5Cl]Cl2

| Organorhodium(III) compunds|

* [Cp*RhCl2]2

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Rh(IV)|

* RhO2

Rh(V)|

* XeRhF6

Rh(VI)|

* RhF6

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Sulfides

| H2S
H2S2 |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

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Li2S | BeS |  |  |  |  |  |  |  |  |  |  | B2S3 | CS2
COS | (NH4)SH | O | F | Ne
Na2S
Na2Sx | MgS |  |  |  |  |  |  |  |  |  |  | Al2S3 | SiS
SiS2 | PxSy | S | Cl | Ar
K2S | CaS | Sc2S3 | TiS2 | V | CrS
Cr2S3 | MnS
MnS2 | FeS
Fe3S4 | CoS | NiS | Cu2S
CuS | ZnS | GaS
Ga2S3 | GeS
GeS2 | As2S3
As4S3 | SeS2 | Br | Kr
Rb2S | SrS | Y2S3 | ZrS2 | NbS2 | MoS2 | Tc | Ru | Rh2S3 | PdS | Ag2S | CdS | In2S3 | SnS
SnS2 | Sb2S3
Sb2S5 | TeS2 | I | Xe
Cs2S | BaS | *  | HfS2 | TaS2 | WS2
WS3 | ReS2
Re2S7 | Os | Ir2S3
IrS2 | PtS
PtS2 | Au2S
Au2S3 | HgS | Tl2S | PbS
PbS2 | Bi2S3 | Po | At | Rn
Fr | Ra | **  | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og |  |  |  |  |  |  |  |
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | La2S3 | CeS
Ce2S3 | Pr2S3 | Nd2S3 | Pm2S3 | SmS
Sm2S3 | Eu2S3 | Gd2S3 | Tb2S3 | Dy2S3 | Ho2S3 | Er2S3 | Tm2S3 | Yb2S3 | Lu2S3 |
| ** | Ac | ThS2 | Pa | US2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |

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