Antimonide iodide

Short description: Class of chemical compounds

Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

## List

formula  | system  | space group  | unit cell Å  | volume  | density  | comment  | ref

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Ge38Sb8I8 | cubic  | Pm3n | a=10.8892  |  |  | clathrate; band gap 1.16 eV; thermal conductivity 7 mWcm−1K−1 | [1]
Cd4Sb2I3 | cubic  | Pa3 | a=13.48  |  |  |  | [2]
Sn38Sb8I8 | cubic  | Pm3n | a=12.0447  |  |  | clathrate; band gap 0.80 eV; thermal conductivity 12mWcm−1K−1 | [1]
La2SbI2 | rhombohedral  |  | a=4.530 c=32.80  |  |  |  | [3]
Hg5Sb2I6 | orthorhombic  | Pc21n  | a=8.108, b=10.702, c=21.295  | 1847.7  | 7.217  | Dark red  | [4]
(Hg6Sb4)(CdI6)  | rhombohedral  | R3c | a = 13.3818, α = 90.93°,  | 2395.3  | 7.111  | black  | [5]
(Hg6Sb4)(CdI6)Hg0.6 | cubic  | Pa3 | a=13.234  | 2317.7  | 7.604  | black; band gap 1.23; air stable  | [6]
[Hg6Sb4I3](SnI3)Hg0.16 | cubic  | P213  | a=13.285 Z=4  |  |  |  | [7]

## References

1. ↑ 1.0 1.1 Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8" (in en). Applied Physics Letters 88 (22): 222115. doi:10.1063/1.2209207. ISSN 0003-6951. Bibcode: 2006ApPhL..88v2115K. http://aip.scitation.org/doi/10.1063/1.2209207.
2. ↑ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe" (in en). Solid State Communications 255-256: 5–10. doi:10.1016/j.ssc.2017.03.001. Bibcode: 2017SSCom.255....5R. https://linkinghub.elsevier.com/retrieve/pii/S0038109817300765.
3. ↑ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" (in en). Zeitschrift für Naturforschung B 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2007-1105/html.
4. ↑ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6" (in de). Zeitschrift für anorganische und allgemeine Chemie 620 (2): 389–392. doi:10.1002/zaac.19946200232. ISSN 0044-2313.
5. ↑ Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing et al. (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )" (in en). Inorganic Chemistry 46 (18): 7321–7325. doi:10.1021/ic0624165. ISSN 0020-1669. PMID 17665902. https://pubs.acs.org/doi/10.1021/ic0624165.
6. ↑ Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 (MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)"] (in en). European Journal of Inorganic Chemistry 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200600894.
7. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

HI |  |  |  | He

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LiI | BeI2 | BI3 | CI4 | NI3 | I2O4,
I2O5,
I4O9 | IF,
IF3,
IF5,
IF7 | Ne
NaI | MgI2 | AlI3 | SiI4 | PI3,
P2I4 | S  | ICl,
ICl3 | Ar
KI | CaI2 | Sc  | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2,
GeI4 | AsI3 | Se  | IBr | Kr
RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo  | Tc  | Ru  | Rh  | Pd  | AgI | CdI2 | InI3 | SnI4,
SnI2 | SbI3 | TeI4 | I  | Xe
CsI | BaI2 |  | HfI4 | TaI5 | W  | Re  | Os  | Ir  | Pt  | AuI | Hg2I2,
HgI2 | TlI | PbI2 | BiI3 | Po  | AtI | Rn
Fr  | RaI2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La  | Ce  | Pr  | Nd  | Pm  | SmI2 | Eu  | Gd  | TbI3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac  | ThI4 | Pa  | UI3,
UI4 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | EsI3 | Fm  | Md  | No  | Lr

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