Tellurite fluoride

Short description: Class of chemical compounds

A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.

Comparable compounds are sulfite fluorides or selenite fluorides.

## List

name  | formula  | ratio

TeO3:F

| mw | crystal
system  | space group | unit cell Å  | volume  | density  | optical  | comment  | references

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| Li7(TeO3)3F  |  |  |  | P63 | a =11.4178 c =4.8433  |  |  |  | band gap 4.75 eV  |
| KTe3O6F  | 3:1  |  | rhombohedral  | R3 | a=9.486, c=13.774, Z=6  |  |  |  |  | [1]
| ScTeO3F  |  | 239.56  | orthorhombic  | Pnma | a = 5.7740 b = 22.062 c = 5.500  | 700.6  |  | colourless  |  | [2]
titanium(IV) tellurium(IV) trioxide difluoride  | TiTeO3F2 | 1:1  | 361.50  | orthorhombic  | Pnma | a = 7.392 b = 16.369 c=6.4886 Z=8  | 785.1  |  | colourless  |  | [3]
divanadium(IV) ditellurium(IV) heptaoxide difluoride  | V2Te2O7F2 | 2:2  | 507.38  | triclinic  | P1 | a = 4.882 b = 5.112 c = 7.243 α = 108.17° β = 91.64° γ = 92.63°  | 171.4  |  | green-brown  |  | [3]
| CrIIITeO3F  | 1:1  |  |  |  |  |  |  |  |  | [4]
| FeTeO3F  | 1:1  | 250.45  | monoclinic  | P21/n | a = 5.0667 b = 5.0550 c = 12.397 β = 97.63° Z=4  | 314.72  |  | green  |  | [4]
| Co2TeO3F2 | 1:2  | 331.46  | orthorhombic  | Pnma | a=7.3810 b=10.1936 c=5.3013 Z=4  | 398.86  | 5.520  | purple  |  | [5]
| Co15F2(TeO3)14 | 14:2  | 3380.35  | trigonal  | R3 | a =11.6649 c =27.317 Z=3  | 3219.1  | 5.231  | blue  |  | [6]
| Cu7(TeO3)6F2 | 6:2  |  | triclinic  | P1 | a =4.9844 b =9.4724 c =9.958, α =82.318° β =76.275° γ =78.847°  |  |  |  |  | [7]
| GaTeO3F  | 1:1  |  | monoclinic  | P21/n | a = 5.0625 b = 4.9873 c = 12.166 β = 97.952 (13)° Z=4  | 304.22  |  | colourless  |  | [4]
| RbTe3O6F  | 3:1  |  |  |  |  |  |  |  |  |
| InTeO3F  | 1:1  | 309.42  |  |  | a = 7.939 b = 5.3867 c = 8.053 β = 91.06°  | 344.35  |  | colourless  |  | [8][2]
| InTe2O5F  | 2:1  |  | orthorhombic  | Cmmm | a = 7.850, b = 27.637, c = 4.098, Z = 4  | 889.1  |  |  |  | [8]
| In3TeO3F7 | 1:7  |  | orthorhombic  | Cmmm | a  = 7.850(2) A, b  = 27.637(6) A, c  = 4.098  |  |  |  |  | [8][9]
| In3(SO4)(TeO3)2F3(H2O)  |  |  |  | P212121 | a =8.3115 b =9.4341 c =14.807  |  |  |  | band gap 4.10 eV  | [10]
| BaF2TeF2(OH)2 |  |  |  | Pmn21 |  |  |  | SHG ~3 × KDP  | fluorotellurite  | [11]
| Ba2Ga3F3(Te6F2O16)  |  |  |  |  | a =8.8753 b =8.8753 c =11.655  |  |  |  | band gap 4.4 eV  | [12]
| Ba(MoOF2)(TeO4)  | 1:2  | 478.87  | monoclinic  | P21/c | a 5.4281 b 10.1306 c 12.3186 β 116.145° Z=4  | 608.09  | 5.231  | colourless  |  | [13]
| Ba(MoO2F)2(TeO3)2 | 2:2  | 782.42  | orthorhombic  | Aba2  | a=12.5605 b=11.0264 c=7.2858 Z=4  | 1009.1  | 5.150  | colourless  |  | [14]
| Ba(WOF2)(TeO4)  |  | 566.77  | monoclinic  | P21/c | a 5.4483 b 10.0179 c 12.3134 β 115.422(6)° Z=4  | 607.00  | 6.202  | green  |  | [13]
| Pb2Al3F3(Te6F2O16)  |  |  | orthorhombic  | P4/mbm | a =8.7627 b =8.7627 c =11.235  |  |  |  | band gap 4.1 eV  | [12]
| PbVTeO5F  |  | 484.73  | orthorhombic  | Pbca | a=9.8976 b=8.0685 c=13.070  | 1043.8  | 6.169  | orange;

birefringence 0.142 at 590 nm

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| Pb2Ga3F3(Te6F2O16)  |  |  | orthorhombic  | P4/mbm | a =8.8439 b =8.8439 c =11.580  |  |  |  | band gap 4.2 eV  | [12]
| Bi4TeO4F2(TeO3)2(SeO3)2 | 2:2  | 1670.64  | monoclinic  | P21/c | a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2  | 782.66  | 7.089  | colourless  |  | [15]

## References

1. ↑ Laval, J.P.; Guillet, L.; Frit, B. (April 2002). "KTe3O6F: a new layer TeO2 structure, stuffed with KF units" (in en). Solid State Sciences 4 (4): 549–556. doi:10.1016/S1293-2558(02)01290-6. Bibcode: 2002SSSci...4..549L. https://linkinghub.elsevier.com/retrieve/pii/S1293255802012906.
2. ↑ 2.0 2.1 Jennene Boukharrata, Nefla; Laval, Jean-Paul; Thomas, Philippe (2008-07-15). "Two new types of oxyfluorotellurates(IV): ScTeO 3 F and InTeO 3 F". Acta Crystallographica Section C Crystal Structure Communications 64 (7): i57–i61. doi:10.1107/S0108270108017150. ISSN 0108-2701. PMID 18599966. Bibcode: 2008AcCrC..64I..57J. http://scripts.iucr.org/cgi-bin/paper?S0108270108017150.
3. ↑ 3.0 3.1 Laval, Jean Paul; Jennene Boukharrata, Nefla (2009-01-15). "New vanadium(IV) and titanium(IV) oxyfluorotellurates(IV): V 2 Te 2 O 7 F 2 and TiTeO 3 F 2". Acta Crystallographica Section C Crystal Structure Communications 65 (1): i1–i6. doi:10.1107/S0108270108036755. ISSN 0108-2701. PMID 19129587. Bibcode: 2009AcCrC..65I...1L. http://scripts.iucr.org/cgi-bin/paper?S0108270108036755.
4. ↑ 4.0 4.1 4.2 Laval, Jean Paul; Jennene Boukharrata, Nefla; Thomas, Philippe (2008-02-15). "New oxyfluorotellurates(IV): M TeO 3 F ( M = Fe III , Ga III and Cr III )". Acta Crystallographica Section C Crystal Structure Communications 64 (2): i12–i14. doi:10.1107/S0108270107062683. ISSN 0108-2701. PMID 18252985. Bibcode: 2008AcCrC..64I..12L. http://scripts.iucr.org/cgi-bin/paper?S0108270107062683.
5. ↑ Hu, Shichao; Johnsson, Mats (2012). "Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F2" (in en). Dalton Transactions 41 (41): 12786–12789. doi:10.1039/c2dt31188g. ISSN 1477-9226. PMID 22968840. http://xlink.rsc.org/?DOI=c2dt31188g.
6. ↑ Lü, Minfeng; Jiang, Jianhua; Zhu, Bei; Zhao, Yuwei; Zhu, Tianyu; Yang, Haoming; Jin, Yong; Kabbour, Houria et al. (2020). "Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 14" (in en). Dalton Transactions 49 (7): 2234–2243. doi:10.1039/C9DT04176A. ISSN 1477-9226. PMID 32003383. http://xlink.rsc.org/?DOI=C9DT04176A.
7. ↑ Hu, Shichao; Mace, Amber; Johnsson, Mats; Gnezdilov, Vladimir; Lemmens, Peter; Tapp, Joshua; Möller, Angela (2014-07-21). "Crystal Structure and Magnetic Properties of the S = 1 / 2 Quantum Spin System Cu 7 (TeO 3 ) 6 F 2 with Mixed Dimensionality" (in en). Inorganic Chemistry 53 (14): 7661–7667. doi:10.1021/ic5009686. ISSN 0020-1669. PMID 24956023. https://pubs.acs.org/doi/10.1021/ic5009686.
8. ↑ 8.0 8.1 8.2 Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels" (in en). Journal of Alloys and Compounds 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139. https://linkinghub.elsevier.com/retrieve/pii/S0925838810026691.
9. ↑ Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels" (in en). Journal of Alloys and Compounds 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139. https://linkinghub.elsevier.com/retrieve/pii/S0925838810026691.
10. ↑ Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)" (in en). Inorganic Chemistry 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN 0020-1669. PMID 31365247. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01730.
11. ↑ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Jiang, Shutong; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng; Halasyamani, P. Shiv (2020-03-11). "BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering" (in en). Journal of the American Chemical Society 142 (10): 4616–4620. doi:10.1021/jacs.0c00702. ISSN 0002-7863. PMID 32096982. Bibcode: 2020JAChS.142.4616Z. https://pubs.acs.org/doi/10.1021/jacs.0c00702.
12. ↑ 12.0 12.1 12.2 Li, Peng-Fei; Kong, Fang; Mao, Jiang-Gao (June 2020). "MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings" (in en). Journal of Solid State Chemistry 286. doi:10.1016/j.jssc.2020.121288. Bibcode: 2020JSSCh.28621288L. https://linkinghub.elsevier.com/retrieve/pii/S0022459620301183.
13. ↑ 13.0 13.1 Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2018). "A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron" (in en). Dalton Transactions 47 (5): 1513–1519. doi:10.1039/C7DT04442A. ISSN 1477-9226. PMID 29313546. http://xlink.rsc.org/?DOI=C7DT04442A.
14. ↑ Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2020-11-24). "Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response" (in en). Chemistry of Materials 32 (22): 9688–9695. doi:10.1021/acs.chemmater.0c03353. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.0c03353.
15. ↑ Gong, Ya-Ping; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2019-03-07). "Exploration of New Birefringent Crystals in Bismuth d 0 Transition Metal Selenites" (in en). Chemistry – A European Journal 25 (14): 3685–3694. doi:10.1002/chem.201806328. ISSN 0947-6539. PMID 30637825. Bibcode: 2019ChEuJ..25.3685G.

Template:Tellurites

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Salts and covalent derivatives of the fluoride ion

HF |  |  |  | He

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LiF | BeF2 | BF
BF3
B2F4 | CF4
other compounds | NF3
FN3
N2F2
N2F4
NF5§  | F2O
F2O2
other compounds | F2 | Ne
NaF | MgF2 | AlF
AlF3 | SiF4 | P2F4
PF3
PF5 | S2F2
SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF
CaF2 | ScF3 | TiF2
TiF3
TiF4 | VF2
VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5
CrF6§  | MnF2 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF2
GaF3 | GeF2
GeF4 | AsF3
AsF5 | Se2F2
SeF4
SeF6 | BrF
BrF3
BrF5 | KrF2
RbF | SrF
SrF2 | YF3 | ZrF3
ZrF4 | NbF4
NbF5 | MoF2
MoF3
MoF4
MoF5
MoF6 | TcF4
TcF6 | RuF3
RuF5
RuF6 | RhF3
RhF5
RhF6 | PdF2 | AgF | CdF2 | InF
InF2
InF3 | SnF2
SnF4 | SbF3
SbF5 | Te3F2
TeF4
TeF6 | IF
IF3</br>IF5</br>IF7 | XeF2
XeF4
XeF6
CsF | BaF2 |  | HfF4 | TaF5 | WF2
WF3
WF4
WF5
WF6 | Re3F9
ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF2
IrF3
IrF4
IrF5
IrF6 | PtF2
PtF4
PtF5
PtF6 | AuF
AuF3
Au2F10
AuF5•F2 | Hg2F2
HgF2
HgF4 | TlF | PbF2
PbF4 | BiF3
BiF5 | PoF2
PoF4
PoF6 | AtF  | RnF2
FrF | RaF2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
LaF3 | CeF3
CeF4 | PrF3 | NdF2,
NdF3 | PmF3 | SmF2,
SmF3 | EuF2,
EuF3 | GdF3 | TbF3 | DyF2,
DyF3 | HoF3 | ErF3 | TmF2
TmF3 | YbF2
YbF3 | LuF3
AcF3 | ThF4 | PaF5 | UF3
UF4
UF5
UF6 | NpF4
NpF6 | PuF3
PuF6 | AmF2
AmF3 | CmF3 | BkF3 | CfF3 | EsF3 | Fm  | Md  | No  | LrF3

§ means the substance has not been made.

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