Arsenide bromide

Short description: Class of chemical compounds

Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

## List

formula  | system  | space group  | unit cell Å  | volume  | density  | comment  | ref

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(Ca2−x□x)(As1−xBr1+x) Ca2AsBr  | cubic  |  | a=6.05  |  | 3.47  | yellow, or dark brown  | [1][2]
Ca3AsBr3 | cubic  | Pm3  | a=5.91  |  | 3.48  | colourless or yellow  | [1][2]
Cu6AsS5Br  | cubic  | F43m | a=9.8763  |  | 4.80  |  | [3][4]
(Ge38As8)+8⋅8 I− | cubic  | Pm3n | a=10.625  |  | 5.71  | semiconductor resistivity 1 Ω cm; band gap 0.9 eV; silvery grey  | [5]
I8As21Ge25 | cubic  | Pm3n | a=10.5963 Z=1  | 1189.77  | 6.143  | colourless  | [6]
Cd2As3Br  | monoclinic  | C2/c | a = 8.281, b = 9.411, c = 7.993, β = 101.49°, z = 4  |  | 5.76  | black  | [7][8]
Cd4As2Br3 | cubic  | Pa3 | a=12.61  |  | 5.51  | semiconductor band gap 1.8 eV  | [9]
Cd4PAsBr3 | cubic  | Pa3 | a=12.521  |  | 5.38  |  | [10][4]
Cd4As2I1.5Br1.5 | cubic  | Pa3 | a=12.83  |  |  |  | [11][4]
La3AsBr3 | cubic  | I4132  | a=12.09  |  | 5.50  |  | [12]
Pr3AsBr3 | cubic  | I4132  | a=12.02  |  | 5.64  |  | [12]
Hg2As3Br  | monoclinic  | C2/c | a = 8.0914, b = 9.300, c = 8.1084, β = 99.323°, z = 4  |  | 7.79  | black  | [7]
Hg4As2Br3 | cubic  | Pa3  | a=12.610 Z=8  | 2012.4  | 5.54 7.90  | red; dark grey  | [13][14]
Hg19As10Br18 | triclinic  | P1 | a = 11.262, b = 11.352, c = 12.309, α = 105.724, β = 105.788, γ = 109.078°  | 1314.3  |  | dark brown  | [15]
(HgBr2)3(As4S4)2 | monoclinic  | P21/c | a = 9.593, b = 11.395, c = 13.402, β = 107.27, Z = 2  | 1399  |  |  | [16]
Hg3AsS4Br  | hexagonal  | P63mc | a = 7.430, c = 9.364 Z=2  |  |  |  | [17]
(Hg6As4)[TiBr6]Br  | cubic  | Pa3  | a= 1230.9  |  |  |  | [18]
[Hg6As4](CrBr6)Br  | cubic  | Pa | a=12.275  |  |  | [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV  | [19]
[Hg6As4](FeBr6)Hg0.6 | cubic  | Pa | a=12.332  |  |  | [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV  | [19]
[Hg6As4](CuBr3)2 | monoclinic  | I2/a | a = 14.884, b = 9.358, c = 20.413, β=92.88°, Z = 6  |  |  | dark red  | [20]
[Hg11As4](GaBr4)4 | monoclinic  | C2/m |  |  |  |  | [21]
Hg3AsSe4Br  | hexagonal  | P63mc | a = 7.707, c = 9.47 Z=2  |  |  |  | [17]
(Hg2Cd2As2Br)Br  | orthorhombic  | Pmma | a = 8.791, b = 4.701, c = 9.779, Z=2  | 404.2  | 7.688  | dark red  | [22]
(Hg6As4)(CdBr6)  | cubic  | Pa3 | a=12.3738 Z=4  | 1894.6  | 7.345  | red; air stable; band gap 1.94  | [23]
[Hg6As4][InBr6]Br  | cubic  | Pa3 | a=12.3511 Z=4  | 1884.2  |  | dark red  | [24]
[Hg4As2](InBr3.5As0.5)  | Hexagonal  | P63/mmc | a = 7.7408, c = 12.535, Z=2  | 650.47  |  |  | [25]
[Hg6As4Br3](SnBr3)  | cubic  | P213  | a=12.383 Z=4  |  |  |  | [26]
[Hg6As4][YbBr6]Br  | cubic  | Pa3 | a=12.362 Z=4  | 1889.1  | 7.860  | dark red  | [27]
Hg9As4Bi2Br12 | tetragonal  | P43 | a=10.865 b=10.865 c=28.357 Z=4  | 3347.5  | 6.91  | orange  | [28]

## References

1. ↑ 1.0 1.1 Hadenfeldt, C.; Schulz, P. (November 1984). "Darstellung, Struktur und Temperaturabhängigkeit der Phasenbreite der Phase Ca2-xAs1-xBr1+x und thermisches Verhalten der Verbindung Ca3AsBr3" (in de). Zeitschrift für anorganische und allgemeine Chemie 518 (11): 77–86. doi:10.1002/zaac.19845181108. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19845181108.
2. ↑ 2.0 2.1 Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca2AsBr, Sr2AsCl, and Ca3AsBr3" (in en). Zeitschrift für Naturforschung B 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117.
3. ↑ Nilges, Tom; Pfitzner, Arno (2005-03-01). "A structural differentiation of quaternary copper argyrodites: Structure — property relations of high temperature ion conductors" (in en). Zeitschrift für Kristallographie - Crystalline Materials 220 (2–3): 281–294. doi:10.1524/zkri.220.2.281.59142. ISSN 2196-7105. Bibcode: 2005ZK....220..281N. https://www.degruyter.com/document/doi/10.1524/zkri.220.2.281.59142/html.
4. ↑ 4.0 4.1 4.2 Handbook of Inorganic Compounds 2015. 2015. pp. 826.
5. ↑ Chu, T. L.; Chu, Shirley S.; Ray, R. L. (October 1982). "Germanium arsenide iodide: A clathrate semiconductor" (in en). Journal of Applied Physics 53 (10): 7102–7103. doi:10.1063/1.330019. ISSN 0021-8979. Bibcode: 1982JAP....53.7102C. http://aip.scitation.org/doi/10.1063/1.330019.
6. ↑ Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (2009-03-15). "I8As21Ge25". Acta Crystallographica Section E 65 (3): i15. doi:10.1107/S1600536809004991. ISSN 1600-5368. PMID 21582033. PMC 2968696. Bibcode: 2009AcCrE..65I..15A. http://scripts.iucr.org/cgi-bin/paper?S1600536809004991.
7. ↑ 7.0 7.1 Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (November 1994). "A Novel Metallic Halide, Hg2As3Br: Synthesis and Crystal Structure, and Crystal Structure of Cd2As3Br" (in en). Journal of Solid State Chemistry 113 (1): 116–119. doi:10.1006/jssc.1994.1348. Bibcode: 1994JSSCh.113..116S. https://linkinghub.elsevier.com/retrieve/pii/S002245968471348X.
8. ↑ Breitinger, Dietrich; Herrmann, Wolfgang A.; Hiller, Wolfgang (2014-05-14) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 5, 1999: Volume 5: Copper, Silver, Gold, Zinc, Cadmium and Mercury. Georg Thieme Verlag. pp. 178. ISBN 978-3-13-179211-2. https://books.google.com/books?id=riaGAwAAQBAJ&pg=PA178.
9. ↑ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd4As2Br3 and Cd4Sb2I3, analogues of CdSe and CdTe" (in en). Solid State Communications 255-256: 5–10. doi:10.1016/j.ssc.2017.03.001. Bibcode: 2017SSCom.255....5R. https://linkinghub.elsevier.com/retrieve/pii/S0038109817300765.
10. ↑ REBBAH, A; A, DESCHANVRES (1981). "STRUCTURE CRISTALLINE DE Cd4PAsBr3". Ann. Chim. 6 (7): 585–590. https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=PASCAL82X0129781.
11. ↑ GAM, NS (1988). "PRODUCTION AND PROPERTIES OF CRYSTALS OF Cd4As2BrXI3-X SOLID-SOLUTIONS". Inorganic Materials 24 (9): 1348–1350.
12. ↑ 12.0 12.1 Handbook of Inorganic Substances 2015. 2015. pp. 245.
13. ↑ Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996). "Two New Cubic Structures of Mercury Arsenidehalides" (in en). Journal of Solid State Chemistry 126 (2): 324–327. doi:10.1006/jssc.1996.0344. Bibcode: 1996JSSCh.126..324S. https://linkinghub.elsevier.com/retrieve/pii/S0022459696903448.
14. ↑ Kars, Mohammed; Roisnel, Thierry; Dorcet, Vincent; Rebbah, Allaoua; Otero-Diáz, L. Carlos (2014-03-01). "Cd4As2Br3". Acta Crystallographica Section E 70 (3): i15. doi:10.1107/S160053681400395X. ISSN 1600-5368. PMID 24764933. PMC 3998459. Bibcode: 2014AcCrE..70I..15K. http://scripts.iucr.org/cgi-bin/paper?S160053681400395X.
15. ↑ "Synthesis, crystal and band structures, and optical properties of mercury pnictide halide Hg19As10Br18". Chinese Journal of Structural Chemistry 30 (12): 1827–1832. 15 December 2011. https://www.scopus.com/record/display.uri?eid=2-s2.0-84055212117&origin=inward&txGid=caef7e5599993793bc673f510fc8cca5&featureToggles=FEATURE_NEW_DOC_DETAILS_EXPORT:1.
16. ↑ Bräu, Michael F.; Pfitzner, Arno (June 2007). "(HgBr2)3(As4S4)2: An Adduct of HgBr2 Molecules and Undistorted As4S4 Cages" (in de). Zeitschrift für anorganische und allgemeine Chemie 633 (7): 935–937. doi:10.1002/zaac.200600363. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200600363.
17. ↑ 17.0 17.1 Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg3AsE4X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure" (in en). Inorganic Chemistry 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388. https://pubs.acs.org/doi/10.1021/ic0003527.
18. ↑ Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie 626 (7): 1620–1626. doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R.
19. ↑ 19.0 19.1 Olenev, Andrei V.; Oleneva, Olga S.; Lindsjö, Martin; Kloo, Lars A.; Shevelkov, Andrei V. (2003-07-21). "Coordinated and Clathrated Guests in the [Hg6As44+ Bicompartmental Framework: Synthesis, Crystal and Electronic Structure, and Properties of the Novel Supramolecular Complexes [Hg6As4](CrBr6)Br and [Hg6As4](FeBr6)Hg0.6"]. Chemistry - A European Journal 9 (14): 3201–3208. doi:10.1002/chem.200204687. PMID 12866063. https://onlinelibrary.wiley.com/doi/10.1002/chem.200204687.
20. ↑ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4(CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework"] (in en). Journal of Cluster Science 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-005-4548-y.
21. ↑ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2 and [Hgn] (n = 2, 3) Cluster Groups"] (in en). Journal of Structural Chemistry 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. https://link.springer.com/10.1134/S0022476620020109.
22. ↑ Zou, Jian-Ping; Guo; Chen, Wen-Tong; Liu, Xi; Fu, Ming-Lai; Zhang; Huang, Jin-Shun (2006-08-01). "Synthesis, Crystal and Band Structures, and Optical Properties of a New Quaternary Metal Pnictidehalide: (Hg2Cd2As2Br)Br" (in en). Inorganic Chemistry 45 (16): 6365–6369. doi:10.1021/ic060503r. ISSN 0020-1669. PMID 16878947. https://pubs.acs.org/doi/10.1021/ic060503r.
23. ↑ Zou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg6Z4(MX6)Hgy (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)"] (in en). European Journal of Inorganic Chemistry 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200600894.
24. ↑ Deiseroth, Hans-Jörg; Schlirf, Jens; Reiner, Christof (June 2009). "Crystal structure of tetraarsenidohexamercury hexabromoindate bromide, [Hg6As4][InBr6]Br and tetraantimonidohexamercury hexabromoindate bromide, [Hg6Sb4][InBr6]Br". Zeitschrift für Kristallographie - New Crystal Structures 224 (2): 167–168. doi:10.1524/ncrs.2009.0075.
25. ↑ Zou, Jian-Ping; Luo, Sheng-Lian; Tang, Xing-Hua; Li, Ming-Jun; Zhang, Ai-Qin; Peng, Qiang; Guo, Guo-Cong (January 2011). "Synthesis, crystal and band structures, and optical properties of a new framework mercury pnictides: [Hg4As2(InBr3.5As0.5) with tridymite topology"] (in en). Journal of Alloys and Compounds 509 (2): 221–225. doi:10.1016/j.jallcom.2010.09.035. https://linkinghub.elsevier.com/retrieve/pii/S0925838810022437.
26. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
27. ↑ Olenev, Andrei V.; Shestimerova, Tatiana A.; Schnelle, Walter; Shevelkov, Andrei V. (July 2005). "Synthesis, Structure, and Properties of [Hg6As4[YbBr6]Br, a Supramolecular Assembly Featuring a Discrete [YbBr6]3− Anion"] (in de). Zeitschrift für anorganische und allgemeine Chemie 631 (9): 1698–1701. doi:10.1002/zaac.200500059. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200500059.
28. ↑ Puff, H.; Grönke, M.; Kilger, B.; Möltgen, P. (November 1984). "Darstellung und Struktur des Mercuroarsoniumbromo-bismutats [Hg7(HgBr)2As4 [Bi2Br10]"] (in de). Zeitschrift für anorganische und allgemeine Chemie 518 (11): 120–128. doi:10.1002/zaac.19845181112. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19845181112.

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