Borate nitrate

Borate nitrates are mixed anion compounds containing separate borate and nitrate anions. They are distinct from the boronitrates where the borate is linked to a nitrate via a common oxygen atom.

## List

| chem  | mw  | crystal system  | space group  | unit cell Å  | volume  | density  | comment  | references

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| Na3(NO3)[B6O10]  |  |  |  |  |  |  |  | [1]
| K3B6O10NO3 |  |  |  |  |  |  |  | [2]
| K3Na[B6O9(OH)3]NO3 |  |  | Pnnm | a=13.208, b=9.107, c=12.325 Z=4  |  |  |  | [3]
| Co3B7O13NO3 |  |  |  |  |  |  |  | [4]
| [Co(H2O)6](NO3)2·[Co{B3O3(OH)4}2(H2O)4]·2H2O  |  |  |  |  |  |  |  | [5]
| [Ni(H2O)6](NO3)2·[Ni{B3O3(OH)4}2(H2O)4]·2H2O  |  |  |  |  |  |  |  | [5]
| Ni3B7O13NO3 |  |  |  |  |  |  |  | [4]
| K7Ni[B18O24(OH)9](NO3)6· (H3BO3)  | 1497.96  | trigonal  | R3 | a=12.2229 c=54.784 Z=6  | 7088  | 2.11  | green  | [6]
| Cu3B7O13NO3 |  |  |  |  |  |  |  | [4]
| Zn3B7O13NO3 |  |  |  |  |  |  |  | [4]
| [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O  |  | monoclinic  | P21/c | a = 11.282, b = 6.5374, c = 17.668, β = 100.981°  |  |  |  | [5]
| Rb3(NO3)[B6O10]  |  |  |  |  |  |  |  | [2]
| Cd3B7O13NO3 |  |  |  |  |  |  |  | [4]
| La[B5O8(OH)]NO3 |  |  |  |  |  |  |  |
| La[B5O8(OH)]NO3·2H2O  |  | monoclinic  | P21/n | a=6.540, b=15.550, c=10.672, β=90.44° and Z=4  |  |  |  | [7]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate  | Ce[B5O8(OH)(H2O)]NO3·2H2O  | 455.24  | monoclinic  | P21/n | a=6.444 b=15.572 c=10.745 β=90.395 Z=4  | 1078.2  | 2.904  | colourless  | [8]
| Pr[B5O8(OH)(H2O)x]NO3·2H2O  |  | monoclinic  | P21/n | a=6.419, b=15.518, c=10.684, with β=90.54° Z=4  | 1064.3  |  |  | [9]
| Pr7(BO3)3(NO3)N3O  |  | hexagonal  | P63 | a=10.6834 c=6.6752 Z=2  |  | 6.457  | green; contains N(OBO3)3 clusters, oxide and nitride  | [10]
| Nd7(BO3)3(NO3)N3O  |  | hexagonal  | P63 | a=10.6446 c=6.6339 Z=2  |  | 6.664  | purplish-blue;contains N(OBO3)3 clusters oxide, and nitride;SHG  | [10]
| Nd[B5O8(OH)(H2O)x]NO3·2H2O  |  |  | P21/n | a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39°  | 1068.44  |  |  | [11]
| Sm[B5O8(OH)(H2O)x]NO3·2H2O  |  |  | P21/n | a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33°  | 1043.79  |  |  | [11]
| Lu2B2O5(NO3)2·2H2O  |  | triclinic  | P1  | a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4  |  |  |  | [6][12]
| Pb2(BO3)(NO3)  | 535.20  | hexagonal  | P63mc | a=5.0731 c=13.040 Z=2  | 290.64  | 6.116  | colourless SHG 9×KDP  | [13]
| [Pb3(B3O7)](NO3)  | 828.01  |  | Pnma | a=10.3481 b=7.8908 c=11.2123 Z=4  | 914.54  | 6.007  | colourless  | [14]

## References

1. ↑ Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10NO3 (x=0.5, 0.6, 0.7)"]. Zeitschrift für Naturforschung B 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-3/znb-2016-0242/znb-2016-0242.xml.
2. ↑ 2.0 2.1 Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate‐nitrates with noncentrosymmetric structures" (in en). European Journal of Inorganic Chemistry 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.202001167.
3. ↑ Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3" (in en). Journal of Solid State Chemistry 221: 66–72. doi:10.1016/j.jssc.2014.09.016. Bibcode: 2015JSSCh.221...66O.
4. ↑ 4.0 4.1 4.2 4.3 4.4 Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F" (in en). Journal of Solid State Chemistry 10 (4): 302–311. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596. Bibcode: 1974JSSCh..10..302B. https://dx.doi.org/10.1016/0022-4596(74)90039-5.
5. ↑ 5.0 5.1 5.2 Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6(NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant"] (in en). Journal of Cluster Science 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-020-01806-7.
6. ↑ 6.0 6.1 Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. CC-BY can use images
7. ↑ Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks" (in en). Journal of Solid State Chemistry 206: 91–98. doi:10.1016/j.jssc.2013.07.032. Bibcode: 2013JSSCh.206...91Z.
8. ↑ Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)NO 3 ·2H 2 O"]. Acta Crystallographica Section E 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMID 22590053. PMC 3344287. http://scripts.iucr.org/cgi-bin/paper?S1600536812016169.
9. ↑ Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87NO3·2H2O"]. Zeitschrift für Naturforschung B 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-9/znb-2017-0121/znb-2017-0121.xml.
10. ↑ 10.0 10.1 Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation" (in en). Inorganic Chemistry 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02909.
11. ↑ 11.0 11.1 Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]"] (in en). European Journal of Inorganic Chemistry 2016 (22): 3659–3665. doi:10.1002/ejic.201600480. http://doi.wiley.com/10.1002/ejic.201600480.
12. ↑ Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O" (in en). Journal of Solid State Chemistry 233: 329–334. doi:10.1016/j.jssc.2015.11.005. Bibcode: 2016JSSCh.233..329O.
13. ↑ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units" (in en). Angewandte Chemie 127 (12): 3750–3753. doi:10.1002/ange.201412344. Bibcode: 2015AngCh.127.3750S. http://doi.wiley.com/10.1002/ange.201412344.
14. ↑ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )(NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems"] (in en). Inorganic Chemistry 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222. https://pubs.acs.org/doi/10.1021/ic401175r.

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Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

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LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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