Caesium cadmium chloride

Caesium cadmium chloride  Names

IUPAC name

Caesium cadmium chloride

Other names

* Caesium trichlorocadmate
* Caesium chlorocadmate
* Caesium trichlorocadmate(II)

Identifiers

CAS Number

* 13845-08-4

3D model (JSmol)

* Interactive image

PubChem CID

* 159356594

InChI

* InChI=1S/Cd.3ClH.Cs/h;3*1H;/q+2;;;;+1/p-3

Key: LHZPOBUPLFKLBV-UHFFFAOYSA-K

SMILES

* [Cd+2]([Cl-])([Cl-])[Cl-].[Cs+]

* [Cs+].[Cl-] [Cd+2]([Cl-])[Cl-]

Properties

Chemical formula

| Cs Cd Cl3
Molar mass | 351.675 g/mol
Appearance  | White or colourless solid
Structure

Crystal structure

| hexagonal

Space group

| P63/mmc

Lattice constant

a = 7.403, c = 18.406

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Y verify (what is YN ?)
Infobox references

Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group (where A=alkali metal, M=bivalent metal, X=halogen ions). It crystallizes in a hexagonal space group P63/mmc with unit cell lengths a = 7.403 Å and c = 18.406 Å, with one cadmium ion having D3d symmetry and the other having C3v symmetry.[1]

It is formed when an aqueous solution of hydrochloric acid containing an equimolar solution of caesium chloride and cadmium chloride.[2]

## References

1. ↑ Chang, Jin Rong.; McPherson, Gary L.; Atwood, Jerry L. (December 1975). "Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride". Inorganic Chemistry 14 (12): 3079–3085. doi:10.1021/ic50154a044.
2. ↑ Electron paramagnetic spectrum of manganese(II)-manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5-) dimer Gary L. McPherson, and Jin Rong Chang, Inorg. Chem., 1976, 15 (5), 1018-1022. doi:10.1021/ic50159a006

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Cadmium compounds

Cadmium(I)|

* Cd2(AlCl4)2

Cadmium(II)|

* Cd(BF4)2
* CdF2
* CdCl2
* CdBr2
* CdI2
* Cd(CN)2
* CdH2
* CdO
* CdS
* CdSe
* CdTe
* Cd(OH)2
* Cd(NO3)2
* CdSO4
* CdWO4
* Cd3As2
* CsCdCl3
* CsCdBr3

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