Carbon dioxide

"CO2" and "CO₂" redirect here. For other uses, see CO2 (disambiguation).

Carbon dioxide

| Ball-and-stick model of carbon dioxide | Space-filling model of carbon dioxide

|

Names
IUPAC name

Carbon dioxide

Other names

* Carbonic acid gas
* Carbonic anhydride
* Carbonic dioxide
* Carbonic oxide
* Carbon(IV) oxide
* Methanedione
* R-744 (refrigerant)
* R744 (refrigerant alternative spelling)
* Dry ice (solid phase)

Identifiers

CAS Number

* 124-38-9 Y

3D model (JSmol)

* Interactive image
* Interactive image

3DMet  |

* B01131

Beilstein Reference

| 1900390
ChEBI |

* CHEBI:16526 Y

ChEMBL |

* ChEMBL1231871 N

ChemSpider |

* 274 Y

EC Number |

* 204-696-9

Gmelin Reference

| 989
KEGG |

* D00004 Y

MeSH | Carbon+dioxide

PubChem CID

* 280

RTECS number |

* FF6400000

UNII |

* 142M471B3J Y

UN number | 1013 (gas), 1845 (solid)

InChI

* InChI=1S/CO2/c2-1-3 Y

Key: CURLTUGMZLYLDI-UHFFFAOYSA-N Y

* InChI=1/CO2/c2-1-3

Key: CURLTUGMZLYLDI-UHFFFAOYAO

SMILES

* O=C=O

* C(=O)=O

Properties

Chemical formula

| CO2
Molar mass | 44.009 g·mol−1
Appearance  | Colorless gas
Odor |

* Low concentrations: none
* High concentrations: sharp; acidic[1]

Density |

* 1562 kg/m3 (solid at 1 atm (100 kPa) and −78.5 °C (−109.3 °F))
* 1101 kg/m3 (liquid at saturation −37 °C (−35 °F))
* 1.977 kg/m3 (gas at 1 atm (100 kPa) and 0 °C (32 °F))

Critical point (T, P)  | 304.128(15) K[2] (30.978(15) °C), 7.3773(30) MPa[2] (72.808(30) atm)

Sublimation
conditions

| 194.6855(30) K (−78.4645(30) °C) at 1 atm (0.101325 MPa)

Solubility in water

| 1.45 g/L at 25 °C (77 °F), 100 kPa (0.99 atm)
Vapor pressure | 5.7292(30) MPa, 56.54(30) atm (20 °C (293.15 K))
Acidity (pKa)  | Carbonic acid:
pKa1 = 3.6
pKa1(apparent) = 6.35
pKa2 = 10.33

Magnetic susceptibility (χ)

| −20.5·10−6 cm3/mol
Thermal conductivity | 0.01662 W·m−1·K−1 (300 K (27 °C; 80 °F))[3]

Refractive index (nD)

| 1.00045
Viscosity |

* 14.90 μPa·s at 25 °C (298 K)[4]
* 70 μPa·s at −78.5 °C (194.7 K)

Dipole moment

| 0 D
Structure

Crystal structure

| Trigonal

Point group

| D∞h

Molecular shape

| Linear
Thermochemistry

Heat capacity (C)

| 37.135 J/(K·mol)

Std molar
entropy (S ~~o~~ 298)

| 214 J·mol−1·K−1

Std enthalpy of
formation (ΔfH⦵298)

| −393.5 kJ·mol−1
Pharmacology
1=ATC code }}  | V03AN02 (WHO)
Hazards
Safety data sheet | Sigma-Aldrich
GHS pictograms |
GHS Signal word | Warning

GHS hazard statements

| H280, H281

GHS precautionary statements

| P282, P336+317Script error: No such module "Preview warning".Category:GHS errors, P403, P410+403
NFPA 704 (fire diamond)  |

[7][8]

Lethal dose or concentration (LD, LC):

LCLo (lowest published)

| 90,000 ppm (162,000 mg/m3) (human, 5 min)[6]
NIOSH (US health exposure limits):

PEL (Permissible)

| TWA 5000 ppm (9000 mg/m3)[5]

REL (Recommended)

| TWA 5000 ppm (9000 mg/m3), ST 30,000 ppm (54,000 mg/m3)[5]

IDLH (Immediate danger)

| 40,000 ppm (72,000 mg/m3)[5]
Related compounds

Other anions

* Carbon disulfide
* Carbon diselenide
* Carbon ditelluride

Other cations

* Silicon dioxide
* Germanium dioxide
* Tin dioxide
* Lead dioxide
* Titanium dioxide
* Zirconium dioxide
* Hafnium dioxide
* Cerium dioxide
* Thorium dioxide

Related carbon oxides

| See Oxocarbon

Related compounds

* Carbonic acid
* Carbonyl sulfide
* Carbonyl selenide

Supplementary data page

Structure and
properties

| Refractive index (n),
Dielectric constant (εr), etc.

Thermodynamic
data

| Phase behaviour
solid-liquid-gas

Spectral data

| UV, IR, NMR, MS

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is YN ?)
Infobox references

Tracking categories (test):

* SizeSet

Carbon dioxide is a chemical compound with the chemical formula CO
2. It is made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric CO
2 is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater.

It is a trace gas in Earth's atmosphere at 428 parts per million (ppm),[lower-alpha 1] or about 0.043% (as of July 2025) having risen from pre-industrial levels of 280 ppm or about 0.028%.[10][11] Burning fossil fuels is the main cause of these increased CO
2 concentrations, which are the primary cause of climate change.[12]

Its concentration in Earth's pre-industrial atmosphere since late in the Precambrian was regulated by organisms and geological features. Plants, algae and cyanobacteria use energy from sunlight to synthesize carbohydrates from carbon dioxide and water in a process called photosynthesis, which produces oxygen as a waste product.[13] In turn, oxygen is consumed and CO
2 is released as waste by all aerobic organisms when they metabolize organic compounds to produce energy by respiration.[14] CO
2 is released from organic materials when they decay or combust, such as in forest fires. When carbon dioxide dissolves in water, it forms carbonate and mainly bicarbonate (HCO3–), which causes ocean acidification as atmospheric CO
2 levels increase.[15]

Carbon dioxide is 53% denser than dry air, but is long-lived and thoroughly mixes in the atmosphere. About half of excess CO
2 emissions to the atmosphere are absorbed by land and ocean carbon sinks.[16] These sinks can become saturated and are volatile, as decay and wildfires result in the CO
2 being released back into the atmosphere.[17] CO
2, or the carbon it holds, is eventually sequestered (stored for the long term) in rocks and organic deposits like coal, petroleum and natural gas.

Nearly all CO
2 produced by humans goes into the atmosphere. Less than 1% of CO
2 produced annually is put to commercial use, mostly in the fertilizer industry and in the oil and gas industry for enhanced oil recovery. Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses.[18]: 3

## Contents

* 1 Chemical and physical properties
* 1.1 Structure, bonding and molecular vibrations
* 1.2 In aqueous solution
* 1.3 Chemical reactions
* 1.4 Physical properties
* 2 Biological role
* 2.1 Photosynthesis and carbon fixation
* 2.2 Toxicity
* 2.2.1 Below 1%
* 2.2.2 Ventilation
* 2.2.3 Indoor air
* 2.2.4 Outdoor areas with elevated concentrations
* 3 Human physiology
* 3.1 Content
* 3.2 Transport in the blood
* 3.3 Regulation of respiration
* 4 Concentrations and role in the environment
* 4.1 Atmosphere
* 4.2 Oceans
* 4.2.1 Ocean acidification
* 4.2.2 Hydrothermal vents
* 5 Sources
* 5.1 Biological processes
* 5.1.1 Combustion
* 5.1.2 By-product from hydrogen production
* 5.1.3 Thermal decomposition of limestone
* 6 Commercial uses
* 6.1 Precursor to chemicals
* 6.2 Fossil fuel recovery
* 6.3 Agriculture
* 6.4 Foods
* 6.4.1 Beverages
* 6.4.2 Winemaking
* 6.4.3 Stunning animals
* 6.5 Inert gas
* 6.6 Fire extinguisher
* 6.7 Supercritical CO2 as solvent
* 6.8 Refrigerant
* 6.9 Minor uses
* 7 History of discovery
* 8 See also
* 9 Notes
* 10 References
* 11 External links

## Chemical and physical properties

### Structure, bonding and molecular vibrations

The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm, noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls.[19] Since it is centrosymmetric, the molecule has no electric dipole moment.

Stretching and bending oscillations of the CO
2 molecule. Upper left: symmetric stretching. Upper right: antisymmetric stretching. Lower line: degenerate pair of bending modes.

As a linear triatomic molecule, CO
2 has four vibrational modes as shown in the diagram. In the symmetric and the antisymmetric stretching modes, the atoms move along the axis of the molecule. There are two bending modes, which are degenerate, meaning that they have the same frequency and same energy, because of the symmetry of the molecule. When a molecule touches a surface or touches another molecule, the two bending modes can differ in frequency because the interaction is different for the two modes. Some of the vibrational modes are observed in the infrared (IR) spectrum: the antisymmetric stretching mode at wavenumber 2349 cm−1 (wavelength 4.25 μm) and the degenerate pair of bending modes at 667 cm−1 (wavelength 15.0 μm). The symmetric stretching mode does not create an electric dipole so is not observed in IR spectroscopy, but it is detected in Raman spectroscopy at 1388 cm−1 (wavelength 7.20 μm), with a Fermi resonance doublet at 1285 cm−1.[20]

In the gas phase, carbon dioxide molecules undergo significant vibrational motions and do not keep a fixed structure. However, in a Coulomb explosion imaging experiment, an instantaneous image of the molecular structure can be deduced. Such an experiment[21] has been performed for carbon dioxide. The result of this experiment, and the conclusion of theoretical calculations[22] based on an ab initio potential energy surface of the molecule, is that none of the molecules in the gas phase are ever exactly linear. This counter-intuitive result is trivially due to the fact that the nuclear motion volume element vanishes for linear geometries.[22] This is so for all molecules except diatomic molecules.

### In aqueous solution

See also: Chemistry:Carbonic acid

Carbon dioxide is soluble in water, in which it reversibly forms H
2CO
3 (carbonic acid), which is a weak acid, because its ionization in water is incomplete.

2 \+ H
2O ⇌ H
2CO

The hydration equilibrium constant of carbonic acid is, at 25 °C:

Kh=[HA2COA3][COA2A(aq)]=1.70×10−3

Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as CO
2 molecules, not affecting the pH.

The relative concentrations of CO
2, H
2CO
3, and the deprotonated forms HCO3– (bicarbonate) and CO32– (carbonate) depend on the pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) becoming the most prevalent (>95%) at the pH of seawater. In very alkaline water (pH > 10.4), the predominant (>50%) form is carbonate. The oceans, being mildly alkaline with typical pH = 8.2–8.5, contain about 120 mg of bicarbonate per liter.

Being diprotic, carbonic acid has two acid dissociation constants, the first one for the dissociation into the bicarbonate (also called hydrogencarbonate) ion (HCO3–):

2CO
3 ⇌ H+
\+ HCO3–
Ka1 = 2.5 × 10−4 mol/L; pKa1 = 3.6 at 25 °C.[19]

This is the true first acid dissociation constant, defined as

Ka1=[HCOA3A−][HA+][HA2COA3]

where the denominator includes only covalently bound H
2CO
3 and does not include hydrated CO
2(aq). The much smaller and often-quoted value near 4.16 × 10−7 (or pKa1 = 6.38) is an apparent value calculated on the (incorrect) assumption that all dissolved CO
2 is present as carbonic acid, so that

Ka1(apparent)=[HCOA3A−][HA+][HA2COA3]+[COA2A(aq)]

Since most of the dissolved CO
2 remains as CO
2 molecules, Ka1(apparent) has a much larger denominator and a much smaller value than the true Ka1.[23]

The bicarbonate ion is an amphoteric species that can act as an acid or as a base, depending on pH of the solution. At high pH, it dissociates significantly into the carbonate ion (CO32–):

HCO3– ⇌ CO32– \+ H+
Ka2 = 4.69 × 10−11 mol/L; pKa2 = 10.329

In organisms, carbonic acid production is catalysed by the enzyme known as carbonic anhydrase.

In addition to altering its acidity, the presence of carbon dioxide in water also affects its electrical properties.

Electrical conductivity of carbondioxide saturated desalinated water when heated from 20 to 98 °C. The shadowed regions indicate the error bars associated with the measurements. A comparison with the temperature dependence of vented desalinated water can be found here .

When carbon dioxide dissolves in desalinated water, the electrical conductivity increases significantly from below 1 μS/cm to nearly 30 μS/cm. When heated, the water begins to gradually lose the conductivity induced by the presence of

CO2

, especially noticeable as temperatures exceed 30 °C.

The temperature dependence of the electrical conductivity of fully deionized water without CO
2 saturation is comparably low in relation to these data.

### Chemical reactions

2 is a potent electrophile having an electrophilic reactivity that is comparable to benzaldehyde or strongly electrophilic α,β-unsaturated carbonyl compounds. However, unlike electrophiles of similar reactivity, the reactions of nucleophiles with CO
2 are thermodynamically less favored and are often found to be highly reversible.[24] The reversible reaction of carbon dioxide with amines to make carbamates is used in CO
2 scrubbers and has been suggested as a possible starting point for carbon capture and storage by amine gas treating. Only very strong nucleophiles, like the carbanions provided by Grignard reagents and organolithium compounds react with CO
2 to give carboxylates:

MR + CO
2 → RCO

where M = Li or MgBr and R = alkyl or aryl.

In metal carbon dioxide complexes, CO
2 serves as a ligand, which can facilitate the conversion of CO
2 to other chemicals.[25]

The reduction of CO
2 to CO is ordinarily a difficult and slow reaction:

2 \+ 2 e−
\+ 2 H+
→ CO + H

The redox potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode. The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process.[26]

Photoautotrophs (i.e. plants and cyanobacteria) use the energy contained in sunlight to photosynthesize simple sugars from CO
2 absorbed from the air and water:

n CO
2 \+ n H
2O → (CH
2O)
n \+ n O

### Physical properties

Pellets of "dry ice", a common form of solid carbon dioxide

Carbon dioxide is colorless. At low concentrations, the gas is odorless; however, at sufficiently high concentrations, it has a sharp, acidic odor.[1] At standard temperature and pressure, the density of carbon dioxide is around 1.98 kg/m3, about 1.53 times that of air.[27]

Carbon dioxide has no liquid state at pressures below 0.51795(10) MPa[2] (5.11177(99) atm). At a pressure of 1 atm (0.101325 MPa), the gas deposits directly to a solid at temperatures below 194.6855(30) K[2] (−78.4645(30) °C) and the solid sublimes directly to a gas above this temperature. In its solid state, carbon dioxide is commonly called dry ice.

Pressure–temperature phase diagram of carbon dioxide. Note that it is a log-lin chart.

Liquid carbon dioxide forms only at pressures above 0.51795(10) MPa[2] (5.11177(99) atm); the triple point of carbon dioxide is 216.592(3) K[2] (−56.558(3) °C) at 0.51795(10) MPa[2] (5.11177(99) atm) (see phase diagram). The critical point is 304.128(15) K[2] (30.978(15) °C) at 7.3773(30) MPa[2] (72.808(30) atm). Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid.[28] This form of glass, called carbonia, is produced by supercooling heated CO
2 at extreme pressures (40–48 GPa, or about 400,000 atmospheres) in a diamond anvil. This discovery confirmed the theory that carbon dioxide could exist in a glass state similar to other members of its elemental family, like silicon dioxide (silica glass) and germanium dioxide. Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released.

At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide.

Table of thermal and physical properties of saturated liquid carbon dioxide:[29][30]

Temperature
(°C)  | Density
(kg/m3)  | Specific heat
(kJ/(kg⋅K))  | Kinematic viscosity
(m2/s)  | Thermal conductivity
(W/(m⋅K))  | Thermal diffusivity
(m2/s)  | Prandtl Number

|
|
|
|
|
|

−50  | 1156.34  | 1.84  | 1.19 × 10−7 | 0.0855  | 4.02 × 10−8 | 2.96
−40  | 1117.77  | 1.88  | 1.18 × 10−7 | 0.1011  | 4.81 × 10−8 | 2.46
−30  | 1076.76  | 1.97  | 1.17 × 10−7 | 0.1116  | 5.27 × 10−8 | 2.22
−20  | 1032.39  | 2.05  | 1.15 × 10−7 | 0.1151  | 5.45 × 10−8 | 2.12
−10  | 983.38  | 2.18  | 1.13 × 10−7 | 0.1099  | 5.13 × 10−8 | 2.2
0  | 926.99  | 2.47  | 1.08 × 10−7 | 0.1045  | 4.58 × 10−8 | 2.38
10  | 860.03  | 3.14  | 1.01 × 10−7 | 0.0971  | 3.61 × 10−8 | 2.8
20  | 772.57  | 5  | 9.10 × 10−8 | 0.0872  | 2.22 × 10−8 | 4.1
30  | 597.81  | 36.4  | 8.00 × 10−8 | 0.0703  | 0.279 × 10−8 | 28.7

Table of thermal and physical properties of carbon dioxide (CO
2) at atmospheric pressure:[29][30]

Temperature
(K)  | Density
(kg/m3)  | Specific heat
(kJ/(kg⋅°C))  | Dynamic viscosity
(kg/(m⋅s))  | Kinematic viscosity
(m2/s)  | Thermal conductivity
(W/(m⋅°C))  | Thermal diffusivity
(m2/s)  | Prandtl Number

|
|
|
|
|
|
|

220  | 2.4733  | 0.783  | 1.11 × 10−5 | 4.49 × 10−6 | 0.010805  | 5.92 × 10−6 | 0.818
250  | 2.1657  | 0.804  | 1.26 × 10−5 | 5.81 × 10−6 | 0.012884  | 7.40 × 10−6 | 0.793
300  | 1.7973  | 0.871  | 1.50 × 10−5 | 8.32 × 10−6 | 0.016572  | 1.06 × 10−5 | 0.77
350  | 1.5362  | 0.9  | 1.72 × 10−5 | 1.12 × 10−5 | 0.02047  | 1.48 × 10−5 | 0.755
400  | 1.3424  | 0.942  | 1.93 × 10−5 | 1.44 × 10−5 | 0.02461  | 1.95 × 10−5 | 0.738
450  | 1.1918  | 0.98  | 2.13 × 10−5 | 1.79 × 10−5 | 0.02897  | 2.48 × 10−5 | 0.721
500  | 1.0732  | 1.013  | 2.33 × 10−5 | 2.17 × 10−5 | 0.03352  | 3.08 × 10−5 | 0.702
550  | 0.9739  | 1.047  | 2.51 × 10−5 | 2.57 × 10−5 | 0.03821  | 3.75 × 10−5 | 0.685
600  | 0.8938  | 1.076  | 2.68 × 10−5 | 3.00 × 10−5 | 0.04311  | 4.48 × 10−5 | 0.668
650  | 0.8143  | 1.1  | 2.88 × 10−5 | 3.54 × 10−5 | 0.0445  | 4.97 × 10−5 | 0.712
700  | 0.7564  | 1.13  | 3.05 × 10−5 | 4.03 × 10−5 | 0.0481  | 5.63 × 10−5 | 0.717
750  | 0.7057  | 1.15  | 3.21 × 10−5 | 4.55 × 10−5 | 0.0517  | 6.37 × 10−5 | 0.714
800  | 0.6614  | 1.17  | 3.37 × 10−5 | 5.10 × 10−5 | 0.0551  | 7.12 × 10−5 | 0.716

## Biological role

Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration.

### Photosynthesis and carbon fixation

Overview of the Calvin cycle and carbon fixation

Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and cyanobacteria into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen is produced as a by-product.

Ribulose-1,5-bisphosphate carboxylase oxygenase, commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO
2 and ribulose bisphosphate, as shown in the diagram at left.

RuBisCO is thought to be the single most abundant protein on Earth.[31]

Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids, and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales.[32] A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.

Overview of photosynthesis and respiration. Carbon dioxide (at right), together with water, form oxygen and organic compounds (at left) by photosynthesis (green), which can be respired (red) to water and CO

Plants can grow as much as 50% faster in concentrations of 1,000 ppm CO
2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients.[33] Elevated CO
2 levels cause increased growth reflected in the harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO
2 in FACE experiments.[34][35]

Increased atmospheric CO
2 concentrations result in fewer stomata developing on plants[36] which leads to reduced water usage and increased water-use efficiency.[37] Studies using FACE have shown that CO
2 enrichment leads to decreased concentrations of micronutrients in crop plants.[38] This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain the same amount of protein.[39]

The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO
2.[40][41]

Plants also emit CO
2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis, are only net absorbers during the day. Though a growing forest will absorb many tons of CO
2 each year, a mature forest will produce as much CO
2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants.[42] Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon[43] and remain valuable carbon sinks, helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO
2 in the upper ocean and thereby promotes the absorption of CO
2 from the atmosphere.[44]

### Toxicity

Symptoms of carbon dioxide toxicity, by increasing volume percent in air[45]

Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (412 ppm), depending on the location.[46]

In humans, exposure to CO
2 at concentrations greater than 5% causes the development of hypercapnia and respiratory acidosis.[47] Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour.[48] Concentrations of more than 10% may cause convulsions, coma, and death. CO
2 levels of more than 30% act rapidly leading to loss of consciousness in seconds.[47]

Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without the dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO
2 emissions from the nearby volcano Mount Nyiragongo.[49] The Swahili term for this phenomenon is mazuku.

Rising levels of CO
2 threatened the Apollo 13 astronauts, who had to adapt cartridges from the command module to supply the carbon dioxide scrubber in the Apollo Lunar Module, which they used as a lifeboat.

Adaptation to increased concentrations of CO
2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance the effects of blood acidification (acidosis). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days.[50][51] Yet, other studies show a decrease in cognitive function even at much lower levels.[52][53] Also, with ongoing respiratory acidosis, adaptation or compensatory mechanisms will be unable to reverse the condition.

#### Below 1%

There are few studies of the health effects of long-term continuous CO
2 exposure on humans and animals at levels below 1%. Occupational CO
2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period.[54] At this CO
2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption.[55] Studies in animals at 0.5% CO
2 have demonstrated kidney calcification and bone loss after eight weeks of exposure.[56] A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000 ppm) CO
2 likely due to CO
2 induced increases in cerebral blood flow.[52] Another study observed a decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm.[53]

However a review of the literature found that a reliable subset of studies on the phenomenon of carbon dioxide induced cognitive impairment to only show a small effect on high-level decision making (for concentrations below 5000 ppm). Most of the studies were confounded by inadequate study designs, environmental comfort, uncertainties in exposure doses and differing cognitive assessments used.[57] Similarly a study on the effects of the concentration of CO
2 in motorcycle helmets has been criticized for having dubious methodology in not noting the self-reports of motorcycle riders and taking measurements using mannequins. Further when normal motorcycle conditions were achieved (such as highway or city speeds) or the visor was raised the concentration of CO
2 declined to safe levels (0.2%).[58][59]

Typical CO
2 concentration effects  Concentration | Note

|

280 ppm | Pre-industrial levels
421 ppm | Current (May 2022) levels
~1121 ppm | ASHRAE recommendation for indoor air[60]
5,000 ppm | USA 8h exposure limit[54]
10,000 ppm | Cognitive impairment, Canada's long term exposure limit[45]
10,000-20,000 ppm | Drowsiness[48]
20,000-50,000 ppm | Headaches, sleepiness; poor concentration, loss of attention, slight nausea also possible[54]

#### Ventilation

A carbon dioxide sensor that measures CO
2 concentration using a nondispersive infrared sensor

Poor ventilation is one of the main causes of excessive CO
2 concentrations in closed spaces, leading to poor indoor air quality. Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO
2 concentration has stabilized) are sometimes used to estimate ventilation rates per person.[61] Higher CO
2 concentrations are associated with occupant health, comfort and performance degradation.[62][63] ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if the outdoor concentration is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000 ppm).

Miners, who are particularly vulnerable to gas exposure due to insufficient ventilation, referred to mixtures of carbon dioxide and nitrogen as "blackdamp", "choke damp" or "stythe". Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked. The canary is more sensitive to asphyxiant gases than humans, and as it became unconscious would stop singing and fall off its perch. The Davy lamp could also detect high levels of blackdamp (which sinks, and collects near the floor) by burning less brightly, while methane, another suffocating gas and explosion risk, would make the lamp burn more brightly.

In February 2020, three people died from suffocation at a party in Moscow when dry ice (frozen CO
2) was added to a swimming pool to cool it down.[64] A similar accident occurred in 2018 when a woman died from CO
2 fumes emanating from the large amount of dry ice she was transporting in her car.[65]

#### Indoor air

Humans spend more and more time in a confined atmosphere (around 80-90% of the time in a building or vehicle). According to the French Agency for Food, Environmental and Occupational Health & Safety (ANSES) and various actors in France, the CO
2 rate in the indoor air of buildings (linked to human or animal occupancy and the presence of combustion installations), weighted by air renewal, is "usually between about 350 and 2,500 ppm".[66]

In homes, schools, nurseries and offices, there are no systematic relationships between the levels of CO
2 and other pollutants, and indoor CO
2 is statistically not a good predictor of pollutants linked to outdoor road (or air, etc.) traffic.[67] CO
2 is the parameter that changes the fastest (with hygrometry and oxygen levels when humans or animals are gathered in a closed or poorly ventilated room). In poor countries, many open hearths are sources of CO
2 and CO emitted directly into the living environment.[68]

#### Outdoor areas with elevated concentrations

Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of CO
2 rise to above 75% overnight, sufficient to kill insects and small animals. After sunrise the gas is dispersed by convection.[69] High concentrations of CO
2 produced by disturbance of deep lake water saturated with CO
2 are thought to have caused 37 fatalities at Lake Monoun, Cameroon in 1984 and 1700 casualties at Lake Nyos, Cameroon in 1986.[70]

## Human physiology

### Content

Reference ranges or averages for partial pressures of carbon dioxide (abbreviated pCO
2)  Blood compartment  | (kPa)  | (mm Hg)

|
|

Venous blood carbon dioxide  | 5.5–6.8  | 41–51[71]
Alveolar pulmonary
gas pressures | 4.8  | 36
Arterial blood carbon dioxide  | 4.7–6.0  | 35–45[71]

The body produces approximately 2.3 pounds (1.0 kg) of carbon dioxide per day per person,[72] containing 0.63 pounds (290 g) of carbon.  In humans, this carbon dioxide is carried through the venous system and is breathed out through the lungs, resulting in lower concentrations in the arteries. The carbon dioxide content of the blood is often given as the partial pressure, which is the pressure which carbon dioxide would have had if it alone occupied the volume.[73] In humans, the blood carbon dioxide contents are shown in the adjacent table.

### Transport in the blood

2 is carried in blood in three different ways. Exact percentages vary between arterial and venous blood.

* Majority (about 70% to 80%) is converted to bicarbonate ions (HCO3–) by the enzyme carbonic anhydrase in the red blood cells,[74] by the reaction:

2 \+ H
2O → H
2CO
3 → H+
+ HCO3–

* 5–10% is dissolved in blood plasma[74]
* 5–10% is bound to hemoglobin as carbamino compounds[74]

Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the CO
2 bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of CO
2 decreases the amount of oxygen that is bound for a given partial pressure of oxygen. This is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of CO
2 or a lower pH will cause offloading of oxygen from hemoglobin, which is known as the Bohr effect.

### Regulation of respiration

Carbon dioxide is one of the mediators of local autoregulation of blood supply. If its concentration is high, the capillaries expand to allow a greater blood flow to that tissue.[75]

Bicarbonate ions are crucial for regulating blood pH. A person's breathing rate influences the level of CO
2 in their blood. Breathing that is too slow or shallow causes respiratory acidosis, while breathing that is too rapid leads to hyperventilation, which can cause respiratory alkalosis.[76]

Although the body requires oxygen for metabolism, low oxygen levels normally do not stimulate breathing. Rather, breathing is stimulated by higher carbon dioxide levels. As a result, breathing low-pressure air or a gas mixture with no oxygen at all (such as pure nitrogen) can lead to loss of consciousness without ever experiencing air hunger. This is especially perilous for high-altitude fighter pilots. It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.[74]

The respiratory centers try to maintain an arterial CO
2 pressure of 40 mmHg. With intentional hyperventilation, the CO
2 content of arterial blood may be lowered to 10–20 mmHg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving.[77]

## Concentrations and role in the environment

### Atmosphere

This section is an excerpt from Carbon dioxide in Earth's atmosphere[ edit ]

Annual CO
2 flows from anthropogenic sources (left) into Earth's atmosphere, land, and ocean sinks (right) since the 1960s. Units in equivalent gigatonnes carbon per year.[78]

### Oceans

Main articles: Earth:Carbon cycle and Ocean acidification

#### Ocean acidification

Carbon dioxide dissolves in the ocean to form carbonic acid (H
2CO
3), bicarbonate (HCO3–), and carbonate (CO32–). There is about fifty times as much carbon dioxide dissolved in the oceans as exists in the atmosphere. The oceans act as an enormous carbon sink, and have taken up about a third of CO
2 emitted by human activity.[79]

This section is an excerpt from ocean acidification[ edit ]

Pterapod shell dissolved in seawater adjusted to an ocean chemistry projected for the year 2100

This section is an excerpt from Ocean acidification#Decreased calcification in marine organisms[ edit ]

#### Hydrothermal vents

Carbon dioxide is also introduced into the oceans through hydrothermal vents. The Champagne hydrothermal vent, found at the Northwest Eifuku volcano in the Mariana Trench, produces almost pure liquid carbon dioxide, one of only two known sites in the world as of 2004, the other being in the Okinawa Trough.[80] The finding of a submarine lake of liquid carbon dioxide in the Okinawa Trough was reported in 2006.[81]

## Sources

The burning of fossil fuels for energy produces 36.8 billion tonnes of CO
2 per year as of 2023.[82] Nearly all of this goes into the atmosphere, where approximately half is subsequently absorbed into natural carbon sinks.[83] Less than 1% of CO
2 produced annually is put to commercial use.[18]: 3

### Biological processes

Carbon dioxide is a by-product of the fermentation of sugar in the brewing of beer, whisky and other alcoholic beverages and in the production of bioethanol. Yeast metabolizes sugar to produce CO
2 and ethanol, also known as alcohol, as follows:

12O
6 → 2 CO
2 \+ 2 CH
3CH
2OH

All aerobic organisms produce CO
2 when they oxidize carbohydrates, fatty acids, and proteins. The large number of reactions involved are exceedingly complex and not described easily. Refer to cellular respiration, anaerobic respiration and photosynthesis. The equation for the respiration of glucose and other monosaccharides is:

12O
6 \+ 6 O
2 → 6 CO
2 \+ 6 H

Anaerobic organisms decompose organic material producing methane and carbon dioxide together with traces of other compounds.[84] Regardless of the type of organic material, the production of gases follows well defined kinetic pattern. Carbon dioxide comprises about 40–45% of the gas that emanates from decomposition in landfills (termed "landfill gas"). Most of the remaining 50–55% is methane.[85]

#### Combustion

The combustion of all carbon-based fuels, such as methane (natural gas), petroleum distillates (gasoline, diesel, kerosene, propane), coal, wood and generic organic matter produces carbon dioxide and, except in the case of pure carbon, water. As an example, the chemical reaction between methane and oxygen:

4 \+ 2 O
2 → CO
2 \+ 2 H

Iron is reduced from its oxides with coke in a blast furnace, producing pig iron and carbon dioxide:[86]

3 \+ 3 CO → 3 CO
2 \+ 2 Fe

#### By-product from hydrogen production

Carbon dioxide is a byproduct of the industrial production of hydrogen by steam reforming and the water gas shift reaction in ammonia production. These processes begin with the reaction of water and natural gas (mainly methane).[87]

#### Thermal decomposition of limestone

It is produced by thermal decomposition of limestone, CaCO
3 by heating (calcining) at about 850 °C (1,560 °F), in the manufacture of quicklime (calcium oxide, CaO), a compound that has many industrial uses:

CaCO
3 → CaO + CO

Acids liberate CO
2 from most metal carbonates. Consequently, it may be obtained directly from natural carbon dioxide springs, where it is produced by the action of acidified water on limestone or dolomite. The reaction between hydrochloric acid and calcium carbonate (limestone or chalk) is shown below:

CaCO
3 \+ 2 HCl → CaCl
2 \+ H
2CO

The carbonic acid (H
2CO
3) then decomposes to water and CO

2CO
3 → CO
2 \+ H

Such reactions are accompanied by foaming or bubbling, or both, as the gas is released. They have widespread uses in industry because they can be used to neutralize waste acid streams.

## Commercial uses

The biggest commercial uses of CO2 are in producing urea for fertilizer and in extracting oil from the ground. Beverages, food, metal fabrication, and other uses account for 3%, 3%, 2%, and 4% of commercial CO2 use, respectively.[88]

Around 230 Mt of CO
2 are used each year,[89] mostly in the fertiliser industry for urea production (130 million tonnes) and in the oil and gas industry for enhanced oil recovery (70 to 80 million tonnes).[18]: 3 Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses.[18]: 3

Technology exists to capture CO
2 from industrial flue gas or from the air. Research is ongoing on ways to use captured CO
2 in products and some of these processes have been deployed commercially.[90] However, the potential to use products is very small compared to the total volume of CO
2 that could foreseeably be captured.[91] The vast majority of captured CO
2 is considered a waste product and sequestered in underground geologic formations.[92]

### Precursor to chemicals

See also: Chemistry:Sabatier reaction

In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of urea, with a smaller fraction being used to produce methanol and a range of other products.[93] Some carboxylic acid derivatives such as sodium salicylate are prepared using CO
2 by the Kolbe–Schmitt reaction.[94]

Captured CO
2 could be to produce methanol or electrofuels. To be carbon-neutral, the CO
2 would need to come from bioenergy production or direct air capture.[95]: 21–24

### Fossil fuel recovery

Carbon dioxide is used in enhanced oil recovery where it is injected into or adjacent to producing oil wells, usually under supercritical conditions, when it becomes miscible with the oil. This approach can increase original oil recovery by reducing residual oil saturation by 7–23% additional to primary extraction.[96] It acts as both a pressurizing agent and, when dissolved into the underground crude oil, significantly reduces its viscosity, and changing surface chemistry enabling the oil to flow more rapidly through the reservoir to the removal well.[97]

Most CO
2 injected in CO
2-EOR projects comes from naturally occurring underground CO
2 deposits.[98] Some CO
2 used in EOR is captured from industrial facilities such as natural gas processing plants, using carbon capture technology and transported to the oilfield in pipelines.[98]

### Agriculture

Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of large size, must) be enriched with additional CO
2 to sustain and increase the rate of plant growth.[99][100] At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as whiteflies and spider mites in a greenhouse.[101] Some plants respond more favorably to rising carbon dioxide concentrations than others, which can lead to vegetation regime shifts like woody plant encroachment.[102]

### Foods

Carbon dioxide bubbles in a soft drink

Carbon dioxide is a food additive used as a propellant and acidity regulator in the food industry. It is approved for usage in the EU[103] (listed as E number E290), US,[104] Australia and New Zealand[105] (listed by its INS number 290).

A candy called Pop Rocks is pressurized with carbon dioxide gas[106] at about 4,000 kPa (40 bar; 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles with an audible pop.

Leavening agents cause dough to rise by producing carbon dioxide.[107] Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids.

#### Beverages

Carbon dioxide is used to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British real ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen.

The taste of soda water (and related taste sensations in other carbonated beverages) is an effect of the dissolved carbon dioxide rather than the bursting bubbles of the gas. Carbonic anhydrase 4 converts carbon dioxide to carbonic acid leading to a sour taste, and also the dissolved carbon dioxide induces a somatosensory response.[108]

#### Winemaking

Dry ice used to preserve grapes after harvest

Carbon dioxide in the form of dry ice is often used during the cold soak phase in winemaking to cool clusters of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over water ice is that it cools the grapes without adding any additional water that might decrease the sugar concentration in the grape must, and thus the alcohol concentration in the finished wine. Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine.

Carbon dioxide is sometimes used to top up wine bottles or other storage vessels such as barrels to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers.

#### Stunning animals

Carbon dioxide is often used to "stun" animals before slaughter.[109] "Stunning" may be a misnomer, as the animals are not knocked out immediately and may suffer distress.[110][111]

### Inert gas

Carbon dioxide is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are more brittle than those made in more inert atmospheres.[112] When used for MIG welding, CO
2 use is sometimes referred to as MAG welding, for Metal Active Gas, as CO
2 can react at these high temperatures. It tends to produce a hotter puddle than truly inert atmospheres, improving the flow characteristics. Although, this may be due to atmospheric reactions occurring at the puddle site. This is usually the opposite of the desired effect when welding, as it tends to embrittle the site, but may not be a problem for general mild steel welding, where ultimate ductility is not a major concern.

Carbon dioxide is used in many consumer products that require pressurized gas because it is inexpensive and nonflammable, and because it undergoes a phase transition from gas to liquid at room temperature at an attainable pressure of approximately 60 bar (870 psi; 59 atm), allowing far more carbon dioxide to fit in a given container than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. Aluminium capsules of CO
2 are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water. High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy[113] and in the decaffeination of coffee beans.

### Fire extinguisher

Use of a CO
2 fire extinguisher

Carbon dioxide can be used to extinguish flames by flooding the environment around the flame with the gas. It does not itself react to extinguish the flame, but starves the flame of oxygen by displacing it. Some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because they do not cool the burning substances significantly, and when the carbon dioxide disperses, they can catch fire upon exposure to atmospheric oxygen. They are mainly used in server rooms.[114]

Carbon dioxide has also been widely used as an extinguishing agent in fixed fire-protection systems for local application of specific hazards and total flooding of a protected space.[115] International Maritime Organization standards recognize carbon dioxide systems for fire protection of ship holds and engine rooms. Carbon dioxide-based fire-protection systems have been linked to several deaths, because it can cause suffocation in sufficiently high concentrations. A review of CO
2 systems identified 51 incidents between 1975 and the date of the report (2000), causing 72 deaths and 145 injuries.[116]

### Supercritical CO
2 as solvent

See also: Physics:Supercritical carbon dioxide and Green chemistry

Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to decaffeinate coffee.[117] Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional solvents such as organochlorides. It is also used by some dry cleaners for this reason. It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide.

### Refrigerant

See also: Chemistry:Refrigerant and Sustainable automotive air conditioning

Comparison of the pressure–temperature phase diagrams of carbon dioxide (red) and water (blue) as a log-lin chart with phase transitions points at 1 atmosphere

Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C (−109.3 °F) at regular atmospheric pressure, regardless of the air temperature.

Liquid carbon dioxide (industry nomenclature R744 or R-744) was used as a refrigerant prior to the use of dichlorodifluoromethane (R12, a chlorofluorocarbon (CFC) compound).[118] CO
2 might enjoy a renaissance because one of the main substitutes to CFCs, 1,1,1,2-tetrafluoroethane (R134a, a hydrofluorocarbon (HFC) compound) contributes to climate change more than CO
2 does. CO
2 physical properties are highly favorable for cooling, refrigeration, and heating purposes, having a high volumetric cooling capacity. Due to the need to operate at pressures of up to 130 bars (1,900 psi; 13,000 kPa), CO
2 systems require highly mechanically resistant reservoirs and components that have already been developed for mass production in many sectors. In automobile air conditioning, in more than 90% of all driving conditions for latitudes higher than 50°, CO
2 (R744) operates more efficiently than systems using HFCs (e.g., R134a). Its environmental advantages (GWP of 1, non-ozone depleting, non-toxic, non-flammable) could make it the future working fluid to replace current HFCs in cars, supermarkets, and heat pump water heaters, among others. Coca-Cola has fielded CO
2-based beverage coolers and the U.S. Army is interested in CO
2 refrigeration and heating technology.[119][120]

### Minor uses

A carbon-dioxide laser

Carbon dioxide is the lasing medium in a carbon-dioxide laser, which is one of the earliest type of lasers.

Carbon dioxide can be used as a means of controlling the pH of swimming pools,[121] by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this is the avoidance of handling (more hazardous) acids. Similarly, it is also used in the maintaining reef aquaria, where it is commonly used in calcium reactors to temporarily lower the pH of water being passed over calcium carbonate in order to allow the calcium carbonate to dissolve into the water more freely, where it is used by some corals to build their skeleton.

Used as the primary coolant in the British advanced gas-cooled reactor for nuclear power generation.

Carbon dioxide induction is commonly used for the euthanasia of laboratory research animals. Methods to administer CO
2 include placing animals directly into a closed, prefilled chamber containing CO
2, or exposure to a gradually increasing concentration of CO
2. The American Veterinary Medical Association's 2020 guidelines for carbon dioxide induction claim that a displacement rate of 30–70% of the chamber or cage volume per minute is optimal for the euthanasia of small rodents.[122]: 5, 31 Percentages of CO
2 vary for different species, based on identified optimal percentages claimed to minimize distress.[122]: 22

Carbon dioxide is also used in several related cleaning and surface-preparation techniques.

## History of discovery

Crystal structure of dry ice

Carbon dioxide was the first gas to be described as a discrete substance. In about 1640,[123] the Flemish chemist Jan Baptist van Helmont observed that when he burned charcoal in a closed vessel, the mass of the resulting ash was much less than that of the original charcoal. His interpretation was that the rest of the charcoal had been transmuted into an invisible substance he termed a "gas" (from Greek "chaos") or "wild spirit" (spiritus sylvestris).[124]

The properties of carbon dioxide were further studied in the 1750s by the Scottish physician Joseph Black. He found that limestone (calcium carbonate) could be heated or treated with acids to yield a gas he called "fixed air". He observed that the fixed air was denser than air and supported neither flame nor animal life. Black also found that when bubbled through limewater (a saturated aqueous solution of calcium hydroxide), it would precipitate calcium carbonate. He used this phenomenon to illustrate that carbon dioxide is produced by animal respiration and microbial fermentation. In 1772, English chemist Joseph Priestley published a paper entitled Impregnating Water with Fixed Air in which he described a process of dripping sulfuric acid (or oil of vitriol as Priestley knew it) on chalk in order to produce carbon dioxide, and forcing the gas to dissolve by agitating a bowl of water in contact with the gas.[125]

Carbon dioxide was first liquefied (at elevated pressures) in 1823 by Humphry Davy and Michael Faraday.[126] The earliest description of solid carbon dioxide (dry ice) was given by the French inventor Adrien-Jean-Pierre Thilorier, who in 1835 opened a pressurized container of liquid carbon dioxide, only to find that the cooling produced by the rapid evaporation of the liquid yielded a "snow" of solid CO
2.[127][128]

Carbon dioxide in combination with nitrogen was known from earlier times as Blackdamp, stythe or choke damp.[lower-alpha 2] Along with the other types of damp it was encountered in mining operations and well sinking. Slow oxidation of coal and biological processes replaced the oxygen to create a suffocating mixture of nitrogen and carbon dioxide.[129]

## See also

* Medicine:Arterial blood gas test - Blood test that measures amounts of dissolved gas
* Chemistry:Bosch reaction - Process that is used to industrially create hydrogen
* Earth:Carbon dioxide removal - Removal of atmospheric carbon dioxide through human activity (from the atmosphere)
* Chemistry:Greenhouse Gases Observing Satellite
* List of countries by carbon dioxide emissions
* List of least carbon efficient power stations
* NASA's Chemistry:Orbiting Carbon Observatory 2
* Earth:Soil gas - Gases in the air space between soil components

## Notes

1. ↑ where "part" here means per molecule[9]
2. ↑ Sometimes spelt "choak-damp" in 19th Century texts.

## References

1. ↑ 1.0 1.1 "Carbon Dioxide". http://www.airproducts.com/~/media/Files/PDF/company/product-summary-carbon-dioxide.pdf?la=en.
2. ↑ 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 "A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800 MPa". Journal of Physical and Chemical Reference Data 25 (6): 1519. 1996-11-01. doi:10.1063/1.555991. Bibcode: 1996JPCRD..25.1509S.
3. ↑ "Thermophysical properties of matter - the TPRC data series". Thermal Conductivity - Nonmetallic Liquids and Gases (Data book) 3. 1970.
4. ↑ "Measurements of the viscosity of carbon dioxide at temperatures from (253.15 to 473.15) K with pressures up to 1.2 MPa". The Journal of Chemical Thermodynamics 89: 7–15. 2015. doi:10.1016/j.jct.2015.04.015. ISSN 0021-9614. Bibcode: 2015JChTh..89....7S.
5. ↑ 5.0 5.1 5.2 NIOSH Pocket Guide to Chemical Hazards. "#0103". National Institute for Occupational Safety and Health (NIOSH). https://www.cdc.gov/niosh/npg/npgd0103.html.
6. ↑ "Carbon dioxide". Immediately Dangerous to Life and Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH). https://www.cdc.gov/niosh/idlh/124389.html.
7. ↑ "Safety Data Sheet – Carbon Dioxide Gas – version 0.03 11/11". AirGas.com. 12 February 2018. https://www.airgas.com/msds/001013.pdf.
8. ↑ "Carbon dioxide, refrigerated liquid". Praxair. p. 9. http://www.praxair.com/-/media/documents/sds/carbon-dioxide/liquiflow-liquid-carbon-dioxide-medipure-gas-co2-safety-data-sheet-sds-p4573.pdf?la=en#page=9.
9. ↑ "CO2 Gas Concentration Defined" (in en). 2022-11-18. https://www.co2meter.com/blogs/news/15164297-co2-gas-concentration-defined.
10. ↑ A Short Introduction to Climate Change. Cambridge University Press. 2013. p. 52. ISBN 978-1-107-61876-3. https://books.google.com/books?id=jeSwRly2M_cC&q=280&pg=PA52. Retrieved 9 November 2020.
11. ↑ "Carbon dioxide now more than 50% higher than pre-industrial levels | National Oceanic and Atmospheric Administration". 3 June 2022. https://www.noaa.gov/news-release/carbon-dioxide-now-more-than-50-higher-than-pre-industrial-levels.
12. ↑ IPCC (2022) Summary for policy makers in Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press, Cambridge, United Kingdom and New York, NY, US
13. ↑ Biosphere 2000: protecting our global environment. Kendall/Hunt Pub. Co.. 1996. ISBN 978-0-7872-0460-0. https://archive.org/details/biosphere2000pro0000kauf.
14. ↑ "Food Factories". http://www.legacyproject.org/activities/foodfactories.html.
15. ↑ Ocean Acidification: A National Strategy to Meet the Challenges of a Changing Ocean. Washington, DC: National Academies Press. 22 April 2010. pp. 23–24. doi:10.17226/12904. ISBN 978-0-309-15359-1. Bibcode: 2010nap..book12904N. http://www.nap.edu/catalog/12904/ocean-acidification-a-national-strategy-to-meet-the-challenges-of. Retrieved 29 February 2016.
16. ↑ IPCC (2021). "Summary for Policymakers". Climate Change 2021: The Physical Science Basis. pp. 20. https://www.ipcc.ch/report/ar6/wg1/downloads/report/IPCC_AR6_WGI_SPM_final.pdf.
17. ↑ Myles, Allen (September 2020). "The Oxford Principles for Net Zero Aligned Carbon Offsetting". https://www.smithschool.ox.ac.uk/publications/reports/Oxford-Offsetting-Principles-2020.pdf.
18. ↑ 18.0 18.1 18.2 18.3 "Putting CO2 to Use – Analysis" (in en-GB). 2019-09-25. https://www.iea.org/reports/putting-co2-to-use.
19. ↑ 19.0 19.1 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 305–314. ISBN 978-0-08-037941-8.
20. ↑ Physical Chemistry (8th ed.). W.H. Freeman. 2006. pp. 461, 464. ISBN 978-0-7167-8759-4.
21. ↑ "Complete Coulomb fragmentation of CO
2 in collisions with 5.9 MeV u−1 Xe18+ and Xe43+". J Phys B 35 (17): 3755. 2002. doi:10.1088/0953-4075/35/17/311. Bibcode: 2002JPhB...35.3755S.CO2+in+collisions+with+5.9+MeV+u−1+Xe18++and+Xe43+&rft.jtitle=J+Phys+B&rft.date=2002&rft.volume=35&rft.issue=17&rft.pages=3755&rft_id=info:doi/10.1088/0953-4075/35/17/311&rft_id=info:bibcode/2002JPhB...35.3755S&rfr_id=info:sid/en.wikibooks.org:Chemistry:Carbon_dioxide">
22. ↑ 22.0 22.1 "The CO
2 molecule is never linear−". J Mol Struct 1212. 2020. doi:10.1016/j.molstruc.2020.128087. Bibcode: 2020JMoSt121228087J.CO2+molecule+is+never+linear−&rft.jtitle=J+Mol+Struct&rft.date=2020&rft.volume=1212&rft_id=info:doi/10.1016/j.molstruc.2020.128087&rft_id=info:bibcode/2020JMoSt121228087J&rfr_id=info:sid/en.wikibooks.org:Chemistry:Carbon_dioxide">
23. ↑ Modern Inorganic Chemistry. McGraw-Hill. 1984. pp. 196. ISBN 978-0-07-032760-3.
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97. ↑ "CO
2 for Enhanced Oil Recovery Needs – Enhanced Fiscal Incentives". Exploration & Production: The Oil & Gas Review. 2005. http://www.touchoilandgas.com/enhanced-recovery-needs-enhanced-a423-1.html. Retrieved 28 September 2007.CO2+for+Enhanced+Oil+Recovery+Needs+–+Enhanced+Fiscal+Incentives&rft.jtitle=Exploration+&+Production:+The+Oil+&+Gas+Review&rft.date=2005&rft_id=http://www.touchoilandgas.com/enhanced-recovery-needs-enhanced-a423-1.html&rfr_id=info:sid/en.wikibooks.org:Chemistry:Carbon_dioxide">
98. ↑ 98.0 98.1 "Can CO2-EOR really provide carbon-negative oil? – Analysis" (in en-GB). 2019-04-11. https://www.iea.org/commentaries/can-co2-eor-really-provide-carbon-negative-oil. Text was copied from this source, which is available under a Creative Commons Attribution 4.0 International License
99. ↑ "Plant Growth Factors: Photosynthesis, Respiration, and Transpiration". Colorado Master Gardener Program. August 2010. http://www.ext.colostate.edu/mg/gardennotes/141.html.
100. ↑ "Carbon dioxide". How Much Land Can Ten Billion People Spare for Nature?. February 1994. http://www-formal.stanford.edu/jmc/nature/node21.html. Retrieved 10 October 2011.
101. ↑ "Future crops: the other greenhouse effect". Nature 448 (7153): 526–528. August 2007. doi:10.1038/448526a. PMID 17671477. Bibcode: 2007Natur.448..526S.
102. ↑ Archer, Steven R.; Andersen, Erik M.; Predick, Katharine I.; Schwinning, Susanne; Steidl, Robert J.; Woods, Steven R. (2017), Briske, David D., ed., "Woody Plant Encroachment: Causes and Consequences" (in en), Rangeland Systems (Cham: Springer International Publishing): pp. 25–84, doi:10.1007/978-3-319-46709-2_2, ISBN 978-3-319-46707-8
103. ↑ UK Food Standards Agency: "Current EU approved additives and their E Numbers". http://www.food.gov.uk/safereating/chemsafe/additivesbranch/enumberlist.
104. ↑ US Food and Drug Administration: "Food Additive Status List". https://www.fda.gov/food/ingredientspackaginglabeling/foodadditivesingredients/ucm091048.htm.
105. ↑ Australia New Zealand Food Standards Code"Standard 1.2.4 – Labelling of ingredients". 8 September 2011. http://www.comlaw.gov.au/Details/F2011C00827.
106. ↑ Futurific Leading Indicators Magazine. 1. CRAES LLC. ISBN 978-0-9847670-1-4. https://books.google.com/books?id=0XeSJLflq90C&q=Pop+Rocks+is+pressurized+with+carbon+dioxide+gas&pg=PA7-IA3. Retrieved 9 November 2020.
107. ↑ Indian Breads: A Comprehensive Guide to Traditional and Innovative Indian Breads. Westland. 25 September 2015. ISBN 978-93-85724-46-6. https://books.google.com/books?id=2bmaCgAAQBAJ&q=Leavening+agents+cause+dough+to+rise+by+producing+carbon+dioxide&pg=PT29.
108. ↑ "Scientists Discover Protein Receptor For Carbonation Taste". 16 October 2009. https://www.sciencedaily.com/releases/2009/10/091015141510.htm.
109. ↑ "A more humane way of slaughtering chickens might get EU approval". New Scientist. 3 February 2018. https://www.newscientist.com/article/2159895-a-more-humane-way-of-slaughtering-chickens-might-get-eu-approval. Retrieved 24 June 2018.
110. ↑ "What is CO
2 stunning?". RSPCA. http://kb.rspca.org.au/What-is-CO2-stunning_118.html.CO2+stunning?&rft.atitle=&rft.pub=RSPCA&rft_id=http://kb.rspca.org.au/What-is-CO2-stunning_118.html&rfr_id=info:sid/en.wikibooks.org:Chemistry:Carbon_dioxide">
111. ↑ "Humane execution and the fear of the tumbril". New Scientist. 10 March 2018. https://www.newscientist.com/letter/mg23731680-900-humane-execution-and-the-fear-of-the-tumbril-3. Retrieved 24 June 2018.
112. ↑ International, Petrogav (in en). Production Course for Hiring on Offshore Oil and Gas Rigs. Petrogav International. pp. 214. https://books.google.com/books?id=ZS7JDwAAQBAJ.
113. ↑ "Critical-point drying versus freeze drying for scanning electron microscopy: a quantitative and qualitative study on isolated hepatocytes". Journal of Microscopy 137 (Pt 2): 189–207. February 1985. doi:10.1111/j.1365-2818.1985.tb02577.x. PMID 3989858.
114. ↑ "Types of Fire Extinguishers". https://www.firesafe.org.uk/types-use-and-colours-of-portable-fire-extinguishers/.
115. ↑ National Fire Protection Association Code 12.
116. ↑ Carbon Dioxide as a Fire Suppressant: Examining the Risks, US EPA. 2000.
117. ↑ Modern drying technology. Vol. 3: Product quality and formulation. John Wiley & Sons. 2011. ISBN 978-3-527-31558-1. https://books.google.com/books?id=5210HQIwxzsC&pg=PA185. Retrieved 3 December 2019.
118. ↑ Pearson, S. Forbes. "Refrigerants Past, Present and Future". http://www.r744.com/files/pdf_597.pdf.
119. ↑ "The Coca-Cola Company Announces Adoption of HFC-Free Insulation in Refrigeration Units to Combat Global Warming". The Coca-Cola Company. 5 June 2006. http://www.coca-colacompany.com/cooling-equipment-pushing-forward-with-hfc-free.
120. ↑ "Modine reinforces its CO
2 research efforts". R744.com. 28 June 2007. http://www.r744.com/news/news_ida145.php.CO2+research+efforts&rft.atitle=&rft.date=28+June+2007&rft.pub=R744.com&rft_id=http://www.r744.com/news/news_ida145.php&rfr_id=info:sid/en.wikibooks.org:Chemistry:Carbon_dioxide">
121. ↑ TCE, the Chemical Engineer. Institution of Chemical Engineers. 1990. https://books.google.com/books?id=IWpWAAAAMAAJ&q= Carbon+dioxide+can+be+used+as+a+means+of+controlling+the+pH+of+swimming+pool. Retrieved 2 June 2020.
122. ↑ 122.0 122.1 "AVMA guidelines for the euthanasia of animals: 2020 Edition". American Veterinary Medical Association. 2020. https://www.avma.org/kb/policies/documents/euthanasia.pdf.
123. ↑ "The Pioneer in the Hygiene of Ventilation". The Lancet 176 (4542): 906–908. September 1910. doi:10.1016/S0140-6736(00)52420-9. https://zenodo.org/record/2088803. Retrieved 6 December 2019.
124. ↑ History of industrial gases. Springer. 2003. p. 93. ISBN 978-0-306-47277-0.
125. ↑ "Observations on Different Kinds of Air". Philosophical Transactions 62: 147–264. 1772. doi:10.1098/rstl.1772.0021. Bibcode: 1772RSPT...62..147.. http://web.lemoyne.edu/~GIUNTA/priestley.html. Retrieved 11 October 2007.
126. ↑ "On the Application of Liquids Formed by the Condensation of Gases as Mechanical Agents". Philosophical Transactions 113: 199–205. 1823. doi:10.1098/rstl.1823.0020. https://archive.org/details/jstor-107649.
127. ↑ "Solidification de l'Acide carbonique". Comptes Rendus 1: 194–196. 1835. http://gallica.bnf.fr/ark:/12148/bpt6k29606/f194.item. Retrieved 1 September 2017.
128. ↑ "Solidification of carbonic acid". The London and Edinburgh Philosophical Magazine 8 (48): 446–447. 1836. doi:10.1080/14786443608648911. https://books.google.com/books?id=4GwqAAAAYAAJ&pg=PA446. Retrieved 15 November 2015.
129. ↑ Haldane, John (1894). "Notes of an Enquiry into the Nature and Physiological Action of Black-Damp, as Met with in Podmore Colliery, Staffordshire, and Lilleshall Colliery, Shropshire". Proceedings of the Royal Society of London 57: 249–257. Bibcode: 1894RSPS...57..249H. https://www.jstor.org/stable/115391.

## External links

Library resources about
Carbon dioxide

* * *

* Resources in your library
* Resources in other libraries

* Current global map of carbon dioxide concentration
* CDC – NIOSH Pocket Guide to Chemical Hazards – Carbon Dioxide
* Trends in Atmospheric Carbon Dioxide (NOAA)
* The rediscovery of CO
2: History, What is Shecco? \- as refrigerant

* v
* t
* e

Oxides

Mixed oxidation states|

* Antimony tetroxide (Sb2O4)
* Cobalt(II,III) oxide (Co3O4)
* Europium(II,III) oxide (Eu3O4)
* Iron(II,III) oxide (Fe<sub>3O4)
* Lead(II,IV) oxide (Pb3O4)
* Manganese(II,III) oxide (Mn3O4)
* Silver(I,III) oxide (Ag2O2)
* Triuranium octoxide (U3O8)
* Carbon suboxide (C3O2)
* Mellitic anhydride (C12O9)
* [[Chemistry:Praseodymium(III,IV) Praseodymium(III,IV) oxide]] (Pr6O11)
* Terbium(III,IV) oxide (Tb4O7)

+1 oxidation state|

* Copper(I) oxide (Cu<sub>2O)
* Caesium oxide (Cs2O)
* Dicarbon monoxide (C2O)
* Dichlorine monoxide (Cl2O)
* Gallium(I) oxide (Ga2O)
* Lithium oxide (Li2O)
* Potassium oxide (K2O)
* Rubidium oxide (Rb2O)
* Silver oxide (Ag2O)
* Thallium(I) oxide (Tl2O)
* Sodium oxide (Na2O)
* Water (hydrogen oxide) (H2O)

+2 oxidation state|

* Aluminium(II) oxide (AlO)
* Barium oxide (BaO)
* Beryllium oxide (BeO)
* Cadmium oxide (CdO)
* Calcium oxide (CaO)
* Carbon monoxide (CO)
* Chromium(II) oxide (CrO)
* Cobalt(II) oxide (CoO)
* Copper(II) oxide (CuO)
* Europium(II) oxide (EuO)
* Germanium monoxide (GeO))
* Iron(II) oxide (FeO)
* Lead(II) oxide (PbO)
* Magnesium oxide (MgO)
* Manganese(II) oxide (MnO)
* Mercury(II) oxide (HgO)
* Nickel(II) oxide (NiO)
* Nitric oxide (NO)
* Palladium(II) oxide (PdO)
* Silicon monoxide (SiO)
* Strontium oxide (SrO)
* Sulfur monoxide (SO)
* Disulfur dioxide (S2O2)
* Thorium monoxide (ThO)
* Tin(II) oxide (SnO)
* Titanium(II) oxide (TiO)
* Vanadium(II) oxide (VO)
* Zinc oxide (ZnO)

+3 oxidation state|

* Aluminium oxide (Al<sub>2O3)
* Antimony trioxide (Sb2O3)
* Arsenic trioxide (As2O3)
* Bismuth(III) oxide (Bi2O3)
* Boron trioxide (B2O3)
* Cerium(III) oxide (Ce2O3)
* Dibromine trioxide (Br2O3)
* Chromium(III) oxide (Cr2O3)
* Dinitrogen trioxide (N2O3)
* Dysprosium(III) oxide (Dy2O3)
* Erbium(III) oxide (Er2O3)
* Europium(III) oxide (Eu2O3)
* Gadolinium(III) oxide (Gd2O3)
* Gallium(III) oxide (Ga2O3)
* Holmium(III) oxide (Ho2O3)
* Indium(III) oxide (In<sub>2O3)
* Iron(III) oxide (Fe2O3)
* Lanthanum oxide (La2O3)
* Lutetium(III) oxide (Lu2O3)
* Manganese(III) oxide (Mn2O3)
* Neodymium(III) oxide (Nd2O3)
* Nickel(III) oxide (Ni2O3)
* Phosphorus trioxide (P4O6)
* Praseodymium(III) oxide (Pr2O3)
* Promethium(III) oxide (Pm2O3)
* Rhodium(III) oxide (Rh2O3)
* [[Chemistry:Samarium(III) Samarium(III) oxide]] (Sm2O3)
* Scandium oxide (Sc2O3)
* Terbium(III) oxide (Tb2O3)
* Thallium(III) oxide (Tl2O3)
* Thulium(III) oxide (Tm2O3)
* Titanium(III) oxide (Ti2O3)
* Tungsten(III) oxide (W2O3)
* Vanadium(III) oxide (V2O3)
* Ytterbium(III) oxide (Yb2O3)
* Yttrium(III) oxide (Y2O3)

+4 oxidation state|

* Americium dioxide (AmO2)
* Carbon dioxide (CO2)
* Carbon trioxide (CO3)
* Cerium(IV) oxide (CeO2)
* Chlorine dioxide (ClO2)
* Chromium(IV) oxide (CrO<sub>2)
* Dinitrogen tetroxide (N2O4)
* Germanium dioxide (GeO<sub>2)
* [[Chemistry:Hafnium(IV) Hafnium(IV) oxide]] (HfO2)
* Lead dioxide (PbO2)
* Manganese dioxide (MnO2)
* Neptunium(IV) oxide (NpO2)
* Nitrogen dioxide (NO2)
* Osmium dioxide (OsO2)
* Plutonium(IV) oxide (PuO2)
* Praseodymium(IV) oxide (PrO2)
* Protactinium(IV) oxide (PaO2)
* Rhodium(IV) oxide (RhO2)
* Ruthenium(IV) oxide (RuO<sub>2)
* Selenium dioxide (SeO2)
* Silicon dioxide (SiO2)
* Sulfur dioxide (SO2)
* Tellurium dioxide (TeO<sub>2)
* [[Chemistry:Terbium(IV) Terbium(IV) oxide]] (TbO2)
* Thorium dioxide (ThO2)
* Tin dioxide (SnO2)
* Titanium dioxide (TiO<sub>2)
* Tungsten(IV) oxide (WO2)
* Uranium dioxide (UO2)
* Vanadium(IV) oxide (VO2)
* Zirconium dioxide (ZrO2)

+5 oxidation state|

* Antimony pentoxide (Sb2O5)
* Arsenic pentoxide (As2O5)
* Dinitrogen pentoxide (N2O5)
* Niobium pentoxide (Nb2O5)
* Phosphorus pentoxide (P2O5)
* Protactinium(V) oxide (Pa2O5)
* Tantalum pentoxide (Ta2O5)
* Vanadium(V) oxide (V2O5)

+6 oxidation state|

* Chromium trioxide (CrO3)
* Molybdenum trioxide (MoO3)
* Rhenium trioxide (ReO3)
* Selenium trioxide (SeO3)
* Sulfur trioxide (SO3)
* Tellurium trioxide (TeO3)
* Tungsten trioxide (WO3)
* Uranium trioxide (UO3)
* Xenon trioxide (XeO3)
* Iridium trioxide (IrO3)

+7 oxidation state|

* Dichlorine heptoxide (Cl2O7)
* Manganese heptoxide (Mn2O7)
* [[Chemistry:Rhenium(VII) Rhenium(VII) oxide]] (Re2O7)
* Technetium(VII) oxide (Tc2O7)

+8 oxidation state|

* Osmium tetroxide (OsO4)
* Ruthenium tetroxide (RuO4)
* Xenon tetroxide (XeO4)
* Iridium tetroxide (IrO4)
* Hassium tetroxide (HsO4)

Related|

* Oxocarbon
* Suboxide
* Oxyanion
* Ozonide
* Peroxide
* Superoxide

Oxides are sorted by oxidation state. Category:Oxides

* v
* t
* e

Oxocarbons

Common oxides|

* CO
* CO2

Exotic oxides|

* CO3
* CO4
* CO5
* CO6
* C2O
* C2O2
* C2O3
* C2O4 (1,2-Dioxetanedione and 1,3-Dioxetanedione)
* C3O
* C3O2
* C3O3
* C3O6
* C4O2
* C4O4
* C4O6
* C5O2
* C5O5
* C6O6 (Cyclohexanehexone and Ethylenetetracarboxylic dianhydride)
* C8O8
* C9O9
* C10O8
* C10O10
* C12O6
* C12O9
* C12O12

Polymers|

* Graphite oxide
* C3O2
* CO
* CO2

Compounds derived from oxides|

* Metal carbonyls
* Carbonic acid
* Bicarbonates
* Carbonates
* Dicarbonates
* Tricarbonates

* v
* t
* e

Inorganic compounds of carbon and related ions

Compounds|

* CBr4
* CCl4
* CF
* CF4
* CI4
* CO
* CO2
* CO3
* COS
* CS
* CS2
* CSe2
* C3O2
* C3S2
* SiC

Carbon ions|

* Carbides [:C≡C:]2-, [::C::]4-, [:C=C=C:]4-
* Cyanides [:C≡N:]-
* Cyanates [:O-C≡N:]-
* Thiocyanates [:S-C≡N:]-
* Fulminates [:C≡N-O:]-
* Thiofulminates [:C≡N-S:]-

Oxides and related|

* Oxides
* Metal carbonyls
* Carbonic acid
* Bicarbonates
* Carbonates

* v
* t
* e

Global warming

Temperatures

* Geologic record
* Hiatus
* Historical climatology
* Instrumental record
* Proxy data
* Record of the past 1,000 years

Causes

| Human

* Attribution of recent climate change
* Aviation
* Black carbon
* Carbon dioxide
* Deforestation
* Fossil fuel
* Global dimming
* Greenhouse effect
* Infrared window
* Greenhouse gases
* Land use, land-use change, and forestry
* Tropospheric ozone

|

Natural|

* Bond events
* Climate variability
* AMO
* ENSO
* IOD
* PDO
* Global cooling
* Milankovitch cycles
* Orbital forcing
* Solar variation
* Volcanism

History

* History of climate change science
* Atmospheric thermodynamics
* Svante Arrhenius
* James Hansen
* Charles David Keeling

Effects and issues

| Physical|

* Abrupt climate change
* Anoxic event
* Arctic methane emissions
* Drought
* Ocean acidification
* Ozone depletion
* Physical impacts
* Retreat of glaciers since 1850
* Runaway climate change
* Sea level rise
* Season creep
* Shutdown of thermohaline circulation

|

Flora and fauna|

* Climate change and ecosystems
* Effects on plant biodiversity
* Effects on marine mammals
* Extinction risk from global warming
* Forest dieback

Society|

* Climate change and agriculture
* Climate change and ecosystems
* Climate change and gender
* Climate change and poverty
* Economics of global warming
* Effects on health
* Effects on humans
* Environmental migrant
* Fisheries and climate change
* Industry and society

By country|

* Australia
* South Asia
* India
* Nepal

Society and climate change

| General|

* Environmental ethics
* Climate movement
* Media coverage of global warming
* Public opinion on global warming
* Popular culture
* Scientific consensus on climate change
* Scientists who disagree with the mainstream assessment
* Climate change denial

|

By country & region|

* Africa
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Politics

| General|

* Climate change denial
* Intergovernmental Panel on Climate Change (IPCC)
* United Nations Framework Convention on Climate Change (UNFCCC / FCCC)
* Global climate regime

|

International|

* Kyoto Protocol
* Clean Development Mechanism
* Joint Implementation
* Bali Road Map
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Regional policy|

* Clean Power Plan
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* European Climate Change Programme
* G8 Climate Change Roundtable
* United Kingdom Climate Change Programme
* Regional climate change initiatives in the United States
* List of climate change initiatives

Protest|

* Extinction Rebellion
* Global Climate March
* List of environmental protests
* School strike for climate

Mitigation

| Emissions reduction|

* Carbon credit
* Carbon-neutral fuel
* Carbon offset
* Carbon tax
* Emissions trading
* Fossil fuel phase-out

|

Carbon-free energy|

* Efficient energy use
* Renewable energy
* Low-carbon economy
* Nuclear power
* Carbon capture and storage
* Energy transition

Personal|

* Individual action on climate change
* Simple living

Other|

* Carbon dioxide removal
* Climate change mitigation scenarios
* Climate engineering
* Reducing emissions from deforestation and forest degradation
* Reforestation
* Urban reforestation

Climate change adaptation

| Strategies|

* Desalination
* Drought tolerance
* Sustainable development
* Weather modification

|

Programmes|

* Land allocation decision support system

Background and theory

| Measurements|

* Satellite measurements

|

Theory|

* Albedo
* Carbon sink
* Climate change (general concept)
* Climate sensitivity
* Cloud forcing
* Feedbacks
* Effective temperature
* Earth's energy budget
* Global warming potential
* Radiative forcing

Research|

* Paleoclimatology
* Paleotempestology
* Climate model

* Glossary
* Index
* Climate change
* Global warming
* Portal

* v
* t
* e

Molecules detected in outer space

Molecules|

| Diatomic|

* Aluminium monochloride
* Aluminium monofluoride
* Aluminium monoxide
* Argonium
* Carbon monophosphide
* Carbon monosulfide
* Carbon monoxide
* Carborundum
* Cyanogen radical
* Diatomic carbon
* Fluoromethylidynium
* Helium hydride ion
* Hydrogen chloride
* Hydrogen fluoride
* Hydrogen (molecular)
* Hydroxyl radical
* Iron(II) oxide
* Magnesium monohydride cation
* Methylidyne radical
* Nitric oxide
* Nitrogen (molecular)
* Nitrogen monohydride
* Nitrogen sulfide
* Oxygen (molecular)
* Phosphorus monoxide
* Phosphorus mononitride
* Potassium chloride
* Silicon carbide
* Silicon mononitride
* Silicon monoxide
* Silicon monosulfide
* Sodium chloride
* Sodium iodide
* Sulfur monohydride
* Sulfur monoxide
* Titanium oxide

|
|

Triatomic|

* Aluminium hydroxide
* Aluminium isocyanide
* Amino radical
* Carbon dioxide
* Carbonyl sulfide
* CCP radical
* Chloronium
* Diazenylium
* Dicarbon monoxide
* Disilicon carbide
* Ethynyl radical
* Formyl radical
* Hydrogen cyanide (HCN)
* Hydrogen isocyanide (HNC)
* Hydrogen sulfide
* Hydroperoxyl
* Iron cyanide
* Isoformyl
* Magnesium cyanide
* Magnesium isocyanide
* Methylene radical
* N2H+
* Nitrous oxide
* Nitroxyl
* Ozone
* Phosphaethyne
* Potassium cyanide
* Protonated molecular hydrogen
* Sodium cyanide
* Sodium hydroxide
* Silicon carbonitride
* c-Silicon dicarbide
* SiNC
* Sulfur dioxide
* Thioformyl
* Thioxoethenylidene
* Titanium dioxide
* Tricarbon
* Water

Four
atoms|

* Acetylene
* Ammonia
* Cyanic acid
* Cyanoethynyl
* Cyclopropynylidyne
* Formaldehyde
* Fulminic acid
* HCCN
* Hydrogen peroxide
* Hydromagnesium isocyanide
* Isocyanic acid
* Isothiocyanic acid
* Ketenyl
* Methylene amidogen
* Methyl radical
* Propynylidyne
* Protonated carbon dioxide
* Protonated hydrogen cyanide
* Silicon tricarbide
* Thioformaldehyde
* Tricarbon monoxide
* Tricarbon sulfide
* Thiocyanic acid

Five
atoms|

* Ammonium ion
* Butadiynyl
* Carbodiimide
* Cyanamide
* Cyanoacetylene
* Cyanoformaldehyde
* Cyanomethyl
* Cyclopropenylidene
* Formic acid
* Isocyanoacetylene
* Ketene
* Methane
* Methoxy radical
* Methylenimine
* Propadienylidene
* Protonated formaldehyde
* Protonated formaldehyde
* Silane
* Silicon-carbide cluster

Six
atoms|

* Acetonitrile
* Cyanobutadiynyl radical
* E-Cyanomethanimine
* Cyclopropenone
* Diacetylene
* Ethylene
* Formamide
* HC4N
* Ketenimine
* Methanethiol
* Methanol
* Methyl isocyanide
* Pentynylidyne
* Propynal
* Protonated cyanoacetylene

Seven
atoms|

* Acetaldehyde
* Acrylonitrile
* Vinyl cyanide
* Cyanodiacetylene
* Ethylene oxide
* Glycolonitrile
* Hexatriynyl radical
* Methylacetylene
* Methylamine
* Methyl isocyanate
* Vinyl alcohol

Eight
atoms|

* Acetic acid
* Aminoacetonitrile
* Cyanoallene
* Ethanimine
* Glycolaldehyde
* Heptatrienyl radical
* Hexapentaenylidene
* Methylcyanoacetylene
* Methyl formate
* Propenal

Nine
atoms|

* Acetamide
* Cyanohexatriyne
* Cyanotriacetylene
* Dimethyl ether
* Ethanol
* Methyldiacetylene
* Octatetraynyl radical
* Propene
* Propionitrile

Ten
atoms
or more|

* Acetone
* Benzene
* Benzonitrile
* Buckminsterfullerene (C60, C60+, fullerene, buckyball)
* C70 fullerene
* Cyanodecapentayne
* Cyanopentaacetylene
* Cyanotetra-acetylene
* Ethylene glycol
* Ethyl formate
* Methyl acetate
* Methyl-cyano-diacetylene
* Methyltriacetylene
* Propanal
* n-Propyl cyanide
* Pyrimidine

Deuterated
molecules|

* Ammonia
* Ammonium ion
* Formaldehyde
* Formyl radical
* Heavy water
* Hydrogen cyanide
* Hydrogen deuteride
* Hydrogen isocyanide
* Methylacetylene
* N2D+
* Trihydrogen cation

Unconfirmed|

* Anthracene
* Dihydroxyacetone
* Ethyl methyl ether
* Glycine
* Graphene
* H2NCO+
* Linear C5
* Naphthalene cation
* Phosphine
* Pyrene
* Silylidine

Related|

* Abiogenesis
* Astrobiology
* Astrochemistry
* Atomic and molecular astrophysics
* Chemical formula
* Circumstellar envelope
* Cosmic dust
* Cosmic ray
* Cosmochemistry
* Diffuse interstellar band
* Earliest known life forms
* Extraterrestrial life
* Extraterrestrial liquid water
* Forbidden mechanism
* Homochirality
* Intergalactic dust
* Interplanetary medium
* Interstellar medium
* Photodissociation region
* Iron–sulfur world theory
* Kerogen
* Molecules in stars
* Nexus for Exoplanet System Science
* Organic compound
* Outer space
* PAH world hypothesis
* Panspermia
* Polycyclic aromatic hydrocarbon (PAH)
* RNA world hypothesis
* Spectroscopy
* Tholin

* Category:Astrochemistry
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Oxygen compounds

* AgO
* Al2O3
* AmO2
* Am2O3
* As2O3
* As2O5
* Au2O3
* B2O3
* BaO
* BeO
* Bi2O3
* BiO2
* Bi2O5
* BrO2
* Br2O3
* Br2O5
* CO
* CO2
* C2O3
* CaO
* CaO2
* CdO
* CeO2
* Ce3O4
* Ce2O3
* ClO2
* Cl2O
* Cl2O3
* Cl2O4
* Cl2O6
* Cl2O7
* CoO
* Co2O3
* Co3O4
* CrO3
* Cr2O3
* Cr2O5
* Cr5O12
* CsO2
* Cs2O3
* CuO
* D2O
* Dy2O3
* Er2O3
* Eu2O3
* FeO
* Fe2O3
* Fe3O4
* Ga2O
* Ga2O3
* GeO
* GeO2
* H2O
* H218O
* H2O2
* HfO2
* HgO
* Hg2O
* Ho2O3
* I2O4
* I2O5
* I2O6
* I4O9
* In2O3
* IrO2
* KO2
* K2O2
* La2O3
* Li2O
* Li2O2
* Lu2O3
* MgO
* Mg2O3
* MnO
* MnO2
* Mn2O3
* Mn2O7
* MoO2
* MoO3
* Mo2O3
* NO
* NO2
* N2O
* N2O3
* N2O4
* N2O5
* NaO2
* Na2O
* Na2O2
* NbO
* NbO2
* Nd2O3
* OF2
* O2F2
* O3F2
* O4F2
* O2PtF6

Chemical formulas

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Original source: https://en.wikipedia.org/wiki/Carbon dioxide. Read more

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*[CID]: Compound ID
*[H280]: Contains gas under pressure: may explode if heated
*[H281]: Contains refrigerated gas: may cause cryogenic burns or injury
*[P282]: Wear cold insulating gloves/face shield/eye protection
*[P403]: Store in a well ventilated place
*[P410+403]: Protect from sunlight. Store in a well ventilated place
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