Carbonate oxalate

Short description: Class of chemical compounds

The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates.[1]

## Contents

* 1 Formation
* 2 Reactions
* 3 List
* 4 References

## Formation

One method to form carbonate oxalates is to heat a metal salt with ascorbic acid, which decomposes to oxalate and carbonate and combines with the metal.[2]

## Reactions

When heated, oxalate carbonates decompose to carbon monoxide and carbonates, which form oxides at higher temperatures.[2]

## List

formula  | name  | formula weight  | crystal form  | space group  | unit cell Å  | volume Å3 | density  | properties  | references

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Sc  |  |  |  |  |  |  |  |  | [3]
K4Ti2O2(C2O4)3·CO3 |  |  |  |  |  |  |  |  | [4]
[Co*(C2O4)(CO3)]2− |  |  |  |  |  |  |  | anionic complex  | [5]
[CoIII(CO3)(C2O4)(NH3)2]-  |  |  |  |  |  |  |  | anionic complex  | [6]
Sr[TiO(C2O4)CO3]  |  |  |  |  |  |  |  |  | [7]
[Y(H2O)]2(C2O4)(CO3)2 | yttrium oxalate carbonate  | 421.876  | orthorhombic  | C2221 | a = 7.8177, b = 14.943, c = 9.4845, Z = 4  | 1108.0  | 2.526  |  | [8]
Ba[ZrO(C2O4)(CO3)]  |  |  |  |  |  |  |  |  | [9]
[Ce(H2O)]2[(C2O4)2(CO3)]·2.5H2O  |  |  | triclinic  | P1_  | a 6.329 b 8.743 c 13.000, α 105.61° β 90.55° γ 105.10°  |  |  |  | [10]
Pr4(C2O4)4(CO3)2]·3H2O  | catena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-praseodymium hydrate)  |  | triclinic  | P1_  | a 6.298 b 8.673 c 12.970, α 105.42° β 90.55° γ 105.01°  |  |  |  | [11]
Pr2(C2O4)(CO3)2 |  |  |  |  |  |  |  |  | [12]
Nd4(C2O4)4(CO3)2]·3H2O  | catena-[bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-neodymium hydrate]  |  | triclinic  | P1_  | a 6.273(6)Å b 8.616(7)Å c 12.928(9)Å, α 105.50(6)° β 90.52(7)° γ 105.00(6)°  |  |  |  | [11]
(NH4)2[Nd2(CO3)(C2O4)3(H2O)]·H2O  | diammonium aqua—carbonato-tri—oxalato-dineodymium(III) hydrate  |  | triclinic  | P1_  | a=8.706 b=9.530 c=10.327 α = 73.35° β = 86.90° γ = 80.50° Z=2  | 809.69  | 2.808  |  | [13]
Eu4(C2O4)4(CO3)2·3H2O  | catena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-europium hydrate)  |  | triclinic  | P1_  | a 6.179 b 8.464 c 12.856, α 105.13° β 90.46° γ 104.86°  |  |  |  | [11]
[Eu(H2O)]2(C2O4)(CO3)2 |  |  |  |  |  |  |  |  | [14]
[Gd(H2O)]2(C2O4)(CO3)2 |  |  |  |  |  |  |  |  | [14]
[Tb(H2O)]2(C2O4)(CO3)2 |  |  |  |  |  |  |  |  | [14]
[Dy(H2O)]2(C2O4)(CO3)2 |  |  |  |  |  |  |  |  | [14]
[Ho(H2O)]2(C2O4)(CO3)2 |  |  |  |  |  |  |  |  | [14]
Er2(CO3)2(C2O4)(H2O)2 |  |  | monoclinic  | Cm | a = 7.773, b = 14.920, c = 4.7309, β = 90.12° Z = 2  |  |  |  | [15]
Pb[ZrО(C2O4)CO3]  |  |  |  |  |  |  |  |  |
Pb4(CO3)2(C2O4)(OH)2 |  | 535.41  | monoclinic  | P21/c | a=11.8593 b=5.2486 c=9.0997 β =96.669 Z=4  | 562.58  | 6.321  | colourless  | [16]
(NH4)4[Th(CO3)2(C2O4)2]•0.5Н2O  |  |  |  |  |  |  |  |  | [17]
(NH4)4[Th(CO3)2(C2O4)2]•10Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)3(NH4)[Th(CO3)2(C2O4)2]•3Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•1.5Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•3Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)6[Th2(CO3)5(C2O4)]  | hexaguandinium pentacarbonatooxalato dithorium  |  |  |  |  |  |  |  | [18]
(CN3H6)6[Th2(CO3)5(C2O4)2]•4Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)6[Th2(CO3)5(C2O4)2]•8Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)6[Th2(CO3)4(C2O4)3]•14Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)8[Th2(CO3)7(C2O4)]  |  |  |  |  |  |  |  |  | [17]
(CN3H6)8[Th2(CO3)7(C2O4)]•5Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)8[Th2(CO3)7(C2O4)]•6Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)8[Th2(CO3)5(C2O4)3]•Н2O  |  |  |  |  |  |  |  |  | [17]
(CN3H6)10[Th2(CO3)8(C2O4)]•8Н2O  |  |  |  |  |  |  |  |  | [17]
Na4[Th2(OH)2(CO3)4(C2O4)]•4Н2O  |  |  |  |  |  |  |  |  | [17]
Na4[Th2(OH)6(CO3)2(C2O4)]•2Н2O  |  |  |  |  |  |  |  |  | [17]
Na8Th(C2O4)2(CO3)4 •11Н2O  |  |  |  |  |  |  |  |  | [19]
Na8[Th(CO3)5(C2O4)]•11Н2O  |  |  |  |  |  |  |  |  | [17]
Na10[Th(CO3)5(C2O4)2]•11Н2O  |  |  |  |  |  |  |  |  | [17]
Na10[Th(CO3)5(C2O4)2]•16Н2O  |  |  |  |  |  |  |  |  | [17]
Na10[Th(OH)2(CO3)3(C2O4)3]•8Н2O  |  |  |  |  |  |  |  |  | [17]
Na10[Th(OH)2(CO3)3(C2O4)3]  |  |  |  |  |  |  |  |  | [17]
Na12[Th(CO3)6(C2O4)2]•11Н2O  |  |  |  |  |  |  |  |  | [17]
K2[Th2(OH)2(CO3)3(C2O4)]•2Н2O  |  |  |  |  |  |  |  |  | [17]
K2[Th2(OH)2(CO3)3(C2O4)]  |  |  |  |  |  |  |  |  | [17]
K4[Th(CO3)3(C2O4)]•6Н2O  |  |  |  |  |  |  |  |  | [17]
K5[Th2(OH)(CO3)4(C2O4)2]•2Н2O  |  |  |  |  |  |  |  |  | [17]
K6[Th(CO3)4(C2O4)]•8Н2O  |  |  |  |  |  |  |  |  | [17]
K6[Th(CO3)3(C2O4)2]•4Н2O  |  |  |  |  |  |  |  |  | [17]
K6[Th2(CO3)5(C2O4)2]•2Н2O  |  |  |  |  |  |  |  |  | [17]
K6[Th2(CO3)4(C2O4)3]•6Н2O  |  |  |  |  |  |  |  |  | [17]
K8[Th2(CO3)5(C2O4)3]•13Н2O  |  |  |  |  |  |  |  |  | [17]
K8[Th2(CO3)5(C2O4)3]•16Н2O  |  |  |  |  |  |  |  |  | [17]
K10[Th2(CO3)7(C2O4)2]•8Н2O  |  |  |  |  |  |  |  |  | [17]
K10[Th2(CO3)7(C2O4)2]•12Н2O  |  |  |  |  |  |  |  |  | [17]
K10[Th2(CO3)7(C2O4)2]•14Н2O  |  |  |  |  |  |  |  |  | [17]
K10[Th2(CO3)5(C2O4)4]•5Н2O  |  |  |  |  |  |  |  |  | [17]
K10[Th2(CO3)5(C2O4)4]•7Н2O  |  |  |  |  |  |  |  |  | [17]
(NH4)(CN3H6)3[(UO2)2(CO3)(C2O4)2(C3H4N2O2)] · H2O  |  |  |  |  |  |  |  |  | [20]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C5H8N2O2)] · 1.5H2O  | guanidonium μ-carbonate μ-ethylmethylgyoximatedioxylatediuranylate sesquihydrate  |  | monoclinic  | P21 | a=6.909 b=15.794 c=30.064 β=96.720° Z=4  | 3258  | 2.383  | red plates  | [20][21]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H8N2O2)] · 3H2O  |  |  |  |  |  |  |  |  | [20]
(NH4)(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H4N2O2)] · H2O  |  |  |  |  |  |  |  |  | [20]
(CN3H6)4[(UO2)2(C6H8N2O2)(CO3)(C2O4)2] · (C6H10N2O2) · 2H2O  | guanidinium (3-methyl-1,2-cyclopenadionedioxime)dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrate  |  | triclinic  | P1_  | a=9.2474 b=14.8562 c=16.8917 α = 68.504° β = 77.721° γ = 89.792° Z=2  | 2102.7  | 2.108  | red  | [22]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C7H10N2O2)] · H2O  |  |  |  |  |  |  |  |  | [20]
NH4(CN3H6)3[(UO2)2(C7H10N2O2)(CO3)(C2O4)2] · 2H2O  | ammonium guanidinium dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrate  |  | orthorhombic  | P212121 | a=9.904 b=17.400 c=18.757 Z=4  | 3232.2  | 2.393  | red  | [22]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · H2O  | guanidinium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate  | 1176.59  | monoclinic  | P21/n  | a=7.6140 b=15.4388 c=28.010 β=95.99° Z=4  | 3274.6  | 2.387  | orange  | [23]
(CN3H6)2(C2H2N2)[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · 3H2O  | guanidinium ethylenediammonium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate  |  |  |  |  |  |  | orange  | [23]
[C(NH2)3]10[(UO2)6(μ3-O)2(μ2-OH)2(C2O4)4(CO3)4]· 2H2O  |  | 2913.21  | triclinic  | P1_  | a=11.5919 b=11.7868 c=13.3545 α = 102.637° β = 93.278° γ = 95.273° Z=1  | 1759.7  | 2.749  | yellow  | [24]

2(C

2CO
3 | Plutonium(III) dioxalate monocarbonate  |  |  |  |  |  |  |  | [25]

4(CO

2 | Plutonium(III) monooxalate dicarbonate  |  |  |  |  |  |  |  | [25]

## References

1. ↑ Cindrić, Marina; Strukan, Neven; Vrdoljak, Višnja; Devčić, Maja; Kamenar, Boris (2002-01-01). "Synthesis of Molybdovanadates Coordinated by Oxalato Ligands. The Crystal Structure of K 6 [Mo 6 V 2 O 24 (C 2 O 4 ) 2 ·6H 2 O"] (in en). Journal of Coordination Chemistry 55 (6): 705–710. doi:10.1080/00958970290027570. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958970290027570.
2. ↑ 2.0 2.1 Ma, Lin; Zhou, Xiaoliang; Yan, Zhengguang; Han, Xiaodong (May 2015). "Hydrothermal synthesis of [Y(H2O) ]2(C2O4)(CO3)2 powder using ascorbic acid". Advanced Powder Technology 26 (3): 853–856. doi:10.1016/j.apt.2015.02.015.
3. ↑ Fedorov, I. A.; Balakaeva, T. A. (1965-05-01). "SCANDIUM OXALATE-CARBONATE COMPOUNDS" (in Russian). Zh. Neorgan. Khim. 10. https://www.osti.gov/biblio/4589394.
4. ↑ Muraleedharan, K.; Labeeb, P.; Mujeeb, V. M. Abdul; Aneesh, M. H.; Devi, T. Ganga; Kannan, M. P. (2011-02-01). "Effect of Particle Size on Non-Isothermal Decomposition of Potassium Titanium Oxalate" (in en). Zeitschrift für Physikalische Chemie 225 (2): 169–181. doi:10.1524/zpch.2011.0051. ISSN 2196-7156. https://www.degruyter.com/document/doi/10.1524/zpch.2011.0051/html.
5. ↑ Matsuura, Tatsuo; Hashimoto, Tetsuo (December 1966). "Szilard-Chalmers Reaction of Anionic Cobalt Complex Ions on Ion-Exchange Resins" (in en). Bulletin of the Chemical Society of Japan 39 (12): 2647–2652. doi:10.1246/bcsj.39.2647. ISSN 0009-2673.
6. ↑ Enomoto, Yoshihiro; Ito, Teiichi; Shibata, Muraji (1974-05-05). "The Preparation Ofcis,Cis-Dicyanocarbonatodiamminecobalte(III) Andcis,Cis-Oxalatodiaquodiamminecobalt(III) Complexes" (in en). Chemistry Letters 3 (5): 423–426. doi:10.1246/cl.1974.423. ISSN 0366-7022.
7. ↑ Gopalakrishnamurthy, H.S.; Subba Rao, M.; Narayanan Kutty, T.R. (October 1975). "Thermal decomposition of titanyl oxalates IV. Strontium and calcium titanyl oxalates" (in en). Thermochimica Acta 13 (2): 183–191. doi:10.1016/0040-6031(75)80080-3. Bibcode: 1975TcAc...13..183G. https://linkinghub.elsevier.com/retrieve/pii/0040603175800803.
8. ↑ Bataille, Thierry; Louër, Daniel (2000-12-01). "Powder and single-crystal X-ray diffraction study of the structure of [Y(H 2 O)] 2 (C 2 O 4 )(CO 3 ) 2". Acta Crystallographica Section B: Structural Science 56 (6): 998–1002. doi:10.1107/S0108768100010004. PMID 11099966. Bibcode: 2000AcCrB..56..998B.
9. ↑ ВМ Погибко, ВВ Приседский, ИЛ Сидак (2010). "МЕХАНИЗМ ТЕРМИЧЕСКОГО РАЗЛОЖЕНИЯ ОКСАЛАТНОГО ПРЕКУРСОРА BaZrO3". http://udhtu.edu.ua/public/userfiles/file/VHHT/2010/5/Pogibko.pdf.
10. ↑ Runde, Wolfgang (2009). "Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions". Inorganic Chemistry 48 (13): 5967–5972. doi:10.1021/ic900344u. PMID 19485387. https://permalink.lanl.gov/object/tr?what=info:lanl-repo/lareport/LA-UR-09-00848.
11. ↑ 11.0 11.1 11.2 Romero, S.; Mosset, A.; Trombe, J.C. (December 1996). "Two New Families of Lanthanide Mixed-Ligand Complexes, Oxalate–Carbonate and Oxalate–Formate: Synthesis and Structure of [Ce(H2O)2(C2O4)2(CO3)·2.5 H2O and Ce(C2O4)(HCO2)"] (in en). Journal of Solid State Chemistry 127 (2): 256–266. doi:10.1006/jssc.1996.0382. Bibcode: 1996JSSCh.127..256R. https://linkinghub.elsevier.com/retrieve/pii/S0022459696903825.
12. ↑ Glasner, A.; Steinberg, M. (December 1961). "Thermal decomposition of the light rare earth oxalates" (in en). Journal of Inorganic and Nuclear Chemistry 22 (1–2): 39–48. doi:10.1016/0022-1902(61)80227-3. https://linkinghub.elsevier.com/retrieve/pii/0022190261802273.
13. ↑ Trombe, Jean-Christian; Galy, Jean; Enjalbert, Renée (2002-10-15). "A neodymium(III)–ammonium complex involving oxalate and carbonate ligands: (NH 4 ) 2 [Nd 2 (C 2 O 4 ) 3 (CO 3 )(H 2 O)·H 2 O"]. Acta Crystallographica Section C: Crystal Structure Communications 58 (10): m517–m520. doi:10.1107/S0108270102014737. ISSN 0108-2701. PMID 12359932. Bibcode: 2002AcCrC..58M.517T. http://scripts.iucr.org/cgi-bin/paper?S0108270102014737.
14. ↑ 14.0 14.1 14.2 14.3 14.4 Romero, S (1997). "A new family of lanthanide oxalate carbonate, [Ln(H2O)]2(C2O4)(CO3)2 with Ln = Eu...Ho, presenting a relatively open framework". European Journal of Solid State and Inorganic Chemistry 34: 209–219.
15. ↑ Müller-Buschbaum, Klaus (2002). "Er2(CO3)2(C2O4)(H2O)2 — Synthese, Kristallstruktur und thermischer Abbau eines Carbonat-Oxalat-Hydrates des Erbiums" (in de). Zeitschrift für anorganische und allgemeine Chemie 628 (8): 1761–1764. doi:10.1002/1521-3749(200208)628:8<1761::AID-ZAAC1761>3.0.CO;2-1. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749(200208)628:8<1761::AID-ZAAC1761>3.0.CO;2-1.
16. ↑ Yang, Hui; Mao, Feifei; Xu, Cuixia (2018-05-24). "Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 2" (in en). ChemistrySelect 3 (19): 5431–5438. doi:10.1002/slct.201801072. ISSN 2365-6549. https://onlinelibrary.wiley.com/doi/10.1002/slct.201801072.
17. ↑ 17.00 17.01 17.02 17.03 17.04 17.05 17.06 17.07 17.08 17.09 17.10 17.11 17.12 17.13 17.14 17.15 17.16 17.17 17.18 17.19 17.20 17.21 17.22 17.23 17.24 17.25 17.26 17.27 17.28 17.29 17.30 17.31 17.32 17.33 17.34 17.35 Bagnall, Kenneth W. (2013-12-12) (in en). Th Thorium: Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates. Springer Science & Business Media. pp. 98–102. ISBN 978-3-662-06315-6. https://books.google.com/books?id=ZUTtCAAAQBAJ&pg=PA99.
18. ↑ Bagnall, Kenneth W. (2013-12-12) (in en). Th Thorium: Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates. Springer Science & Business Media. pp. 10. ISBN 978-3-662-06315-6. https://books.google.com/books?id=ZUTtCAAAQBAJ&pg=PA10.
19. ↑ L. N. Essen, D. P. Alekseeva. "The production of mixed oxalate-carbonate complex compounds of thorium", Dokl. Akad. Nauk SSSR, 146:2 (1962), 380–382". http://www.mathnet.ru/php/archive.phtml?wshow=paper&jrnid=dan&paperid=26995&option_lang=eng.
20. ↑ 20.0 20.1 20.2 20.3 20.4 Beirakhov, A. G.; Orlova, I. M.; Mikhailov, Yu. N. (December 2014). "Coordination modes of α-dioximes in uranyl complexes" (in en). Russian Journal of Inorganic Chemistry 59 (14): 1679–1690. doi:10.1134/S0036023614140022. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023614140022.
21. ↑ Beirakhov, A. G.; Orlova, I. M.; Il’in, E. G.; Aleksandrov, G. G.; Kanishcheva, A. S.; Mikhailov, Yu. N. (September 2010). "Uranyl complexes with ethylmethylglyoxime" (in en). Russian Journal of Inorganic Chemistry 55 (9): 1373–1380. doi:10.1134/S003602361009007X. ISSN 0036-0236. http://link.springer.com/10.1134/S003602361009007X.
22. ↑ 22.0 22.1 Beirakhov, A. G.; Orlova, I. M.; Il’in, E. G.; Kanishcheva, A. S.; Churakov, A. V.; Mikhailov, Yu. N. (July 2012). "Uranyl complexes with methyl derivatives of alicyclic dioximes" (in en). Russian Journal of Inorganic Chemistry 57 (7): 945–952. doi:10.1134/S0036023612070054. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023612070054.
23. ↑ 23.0 23.1 Beirakhov, A. G.; Orlova, I. M.; Rotov, A. V.; Il’in, E. G.; Goeva, L. V.; Surazhskaya, M. D.; Churakov, A. V.; Mikhailov, Yu. N. (December 2016). "Conformation of diethylglyoxime in uranyl complexes" (in en). Russian Journal of Inorganic Chemistry 61 (12): 1522–1529. doi:10.1134/S0036023616120032. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023616120032.
24. ↑ Fedoseev, A. M.; Grigor’ev, M. S.; Yusov, A. B. (September 2012). "Interaction of tetravalent actinides and Np(V) with some hydroxy carboxylic acids" (in en). Radiochemistry 54 (5): 443–451. doi:10.1134/S1066362212050049. ISSN 1066-3622. Bibcode: 2012Radch..54..443F. http://link.springer.com/10.1134/S1066362212050049.
25. ↑ 25.0 25.1 South, Christopher J.; Roy, Lindsay E. (2021). "Insights into the thermal decomposition of plutonium(IV) oxalate – a DFT study of the intermediate structures". Journal of Nuclear Materials 549. doi:10.1016/j.jnucmat.2021.152864. Bibcode: 2021JNuM..54952864S. https://doi.org/10.1016/j.jnucmat.2021.152864.

Carbonates  H2CO3 |  |  |  | He

|
|
|
|

Li2CO3,
LiHCO3 | BeCO3 | B  | C  | (NH4)2CO3,
NH4HCO3 | O  | F  | Ne
Na2CO3,
NaHCO3,
Na3H(CO3)2 | MgCO3,
Mg(HCO3)2 | Al2(CO3)3 | Si  | P  | S  | Cl  | Ar
K2CO3,
KHCO3 | CaCO3,
Ca(HCO3)2 | Sc  | Ti  | V  | Cr  | MnCO3 | FeCO3 | CoCO3 | NiCO3 | CuCO3 | ZnCO3 | Ga  | Ge  | As  | Se  | Br  | Kr
Rb2CO3 | SrCO3 | Y  | Zr  | Nb  | Mo  | Tc  | Ru  | Rh  | Pd  | Ag2CO3 | CdCO3 | In  | Sn  | Sb  | Te  | I  | Xe
Cs2CO3,
CsHCO3 | BaCO3 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg  | Tl2CO3 | PbCO3 | (BiO)2CO3 | Po  | At  | Rn
Fr  | Ra  |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La2(CO3)3 | Ce2(CO3)3 | Pr  | Nd  | Pm  | Sm  | Eu  | Gd  | Tb  | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac  | Th  | Pa  | UO2CO3 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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Oxalates

* (NH4)2C2O4
* BaC2O4
* CaC2O4
* Ce2(C2O4)3
* CrC2O4
* CoC2O4
* CuC2O4
* FeC2O4
* Fe2(C2O4)3
* PbC2O4
* MgC2O4
* Ag2C2O4
* Na2C2O4
* SrC2O4
* Th(C2O4)2

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Original source: https://en.wikipedia.org/wiki/Carbonate oxalate. Read more

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