Chlorosyl fluoride

Identifiers

CAS Number

* 22363-68-4 N

3D model (JSmol)

* Interactive image

ChEBI |

* CHEBI:30127

ChemSpider |

* 21864975

PubChem CID

* 24906310

InChI

* InChI=1S/ClFO/c2-1-3

Key: AXCBHWGTRNNXKG-UHFFFAOYSA-N

SMILES

* O=ClF

Properties

Chemical formula

| ClFO
Molar mass | 70.45 g·mol−1

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Chlorosyl fluoride is an inorganic compound of chlorine, fluorine, and oxygen with the chemical formula OClF.[1][2][3]

## Synthesis

* Partial hydrolysis of chlorine trifluoride in diluted gas phase at low temperatures.[4]

* Reaction of chlorine trifluoride with nitric acid.[4]

## Chemical properties

Chlorosyl fluoride is thermolabile and disproportionates to ClF and ClO2F.[4]:

2FClO → ClF + FClO

2FClO → 2ClF +O

## References

1. ↑ Müller, Holger S. P (10 December 1999). "Infrared spectroscopy and molecular properties of chlorosyl fluoride, FClO" (in en). Chemical Physics Letters 314 (5): 396–402. doi:10.1016/S0009-2614(99)01197-5. ISSN 0009-2614. Bibcode: 1999CPL...314..396M. https://www.sciencedirect.com/science/article/abs/pii/S0009261499011975. Retrieved 27 March 2023.
2. ↑ Müller, Holger S. P.; Cohen, Edward A. (8 February 2002). "The molecular properties of chlorosyl fluoride, FClO, as determined from the ground-state rotational spectrum". The Journal of Chemical Physics 116 (6): 2407–2416. doi:10.1063/1.1433002. ISSN 0021-9606. Bibcode: 2002JChPh.116.2407M. https://aip.scitation.org/doi/abs/10.1063/1.1433002?journalCode=jcp. Retrieved 27 March 2023.
3. ↑ Vogt, J. (2011). "755 ClFO Chlorosyl fluoride". Asymmetric Top Molecules. Part 3. Landolt-Börnstein - Group II Molecules and Radicals (Springer Berlin Heidelberg) 29D3: 296–298. doi:10.1007/978-3-642-14145-4_177. ISBN 978-3-642-14144-7. Bibcode: 2011LanB.29D3..296V. https://www.researchgate.net/publication/258535120.
4. ↑ 4.0 4.1 4.2 Haupt, Axel (22 March 2021) (in en). Organic and Inorganic Fluorine Chemistry: Methods and Applications. Walter de Gruyter GmbH & Co KG. p. 139. ISBN 978-3-11-065933-7. https://books.google.com/books?id=5fwkEAAAQBAJ&dq=Chlorosyl+fluoride&pg=PA618. Retrieved 27 March 2023.

* v
* t
* e

Chlorine compounds

* ClF
* ClF3
* ClF5
* ClNO3
* ClO
* ClOF3
* Cl2O2
* ClO2
* ClO2F
* ClO3F
* Cl2O
* Cl2O4
* Cl2O6
* Cl2O7
* HCl
* SiCl4

* v
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* e

Fluorine compounds

| HF |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | He

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LiF | BeF2 |  |  |  |  |  |  |  |  |  |  | BF3
B2F4 | CF4 | NF3 | OF2 | F− | Ne
NaF | MgF2 |  |  |  |  |  |  |  |  |  |  | AlF3 | SiF4 | PF3
PF5 | SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF2 | ScF3 | TiF3
TiF4 | VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5 | MnF2
MnF3 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF3 | GeF4 | AsF3
AsF5 | SeF4
SeF6 | BrF3
BrF5 | KrF2
RbF | SrF2 | YF3 | ZrF4 | NbF4
NbF5 | MoF5
MoF6 | TcF6 | RuF3
RuF4
RuF5
RuF6 | RhF6 | PdF2 | AgF
AgF2
Ag2F | CdF2 | InF3 | SnF2
SnF4 | SbF3
SbF5 | TeF4 | IF
IF3
IF5
IF7 | XeF2
XeF4
XeF6
CsF | BaF2 | *  | HfF4 | TaF5 | WF4
WF6 | ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF3
IrF5
IrF6 | PtF4
PtF6 | AuF3
Au2F10
AuF5·F2
| HgF2
Hg2F2 | TlF
TlF3 | PbF2
PbF4 | BiF3
BiF5 | Po | At | RnF2
Fr | Ra | **  | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og
|  | ↓ |  |  |  |  |  |  |  |  |  |  |  |  |  |  |
| * | LaF3 | CeF3 | Pr | NdF3 | PmF3 | SmF3
| Eu | Gd | Tb | DyF3 | Ho | Er | Tm | YbF3
| Lu |
| ** | AcF3 | ThF4 | Pa | UF3
UF4
UF5
UF6 | NpF3
NpF4
NpF5
NpF6
| PuF3
PuF4
PuF5
PuF6 | AmF3
AmF4 | CmF3 | Bk | Cf | Es | Fm | Md | No | Lr |

Other|

* AgBF4
* AgPF6
* Cs2AlF5
* K3AlF6
* Na3AlF6
* KAsF6
* LiAsF6
* NaAsF6
* HBF4
* KBF4
* LiBF4
* NaBF4
* RbBF4
* Ba(BF4)2
* Ni(BF4)2
* Pb(BF4)2
* Sn(BF4)2
* BaClF
* BaSiF6
* BaGeF6
* BrOF3
* BrO2F
* CBrF3
* CBr2F2
* CBr3F
* CClF3
* CCl2F2
* CCl3F
* CFN
* CF2O
* CF3I
* CHF3
* CH2F2
* CH3F
* C2Cl3F3
* C2H3F
* C6H5F
* C7H5F3
* C15F33N
* ClFO2
* CrFO4
* CrF2O2
* CsBF4
* NH4F
* FNO
* FNO2
* FNO3
* KHF2
* NaHF2
* ThOF2
* NH5F2
* (NH4)2SiF6
* F2OS
* F3OP
* PSF3
* HPF6
* HSbF6
* NH4PF6
* KPF6
* KSbF6
* LiPF6
* NaPF6
* NaSbF6
* Na2SiF6
* Na2TiF6
* Na2ZrF6
* TlPF6
* IOF3
* K2NbF7
* K2TaF7
* IO3F
* UO2F2

Chemical formulas

* v
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* e

Oxygen compounds

* AgO
* Al2O3
* AmO2
* Am2O3
* As2O3
* As2O5
* Au2O3
* B2O3
* BaO
* BeO
* Bi2O3
* BiO2
* Bi2O5
* BrO2
* Br2O3
* Br2O5
* CO
* CO2
* C2O3
* CaO
* CaO2
* CdO
* CeO2
* Ce3O4
* Ce2O3
* ClO2
* Cl2O
* Cl2O3
* Cl2O4
* Cl2O6
* Cl2O7
* CoO
* Co2O3
* Co3O4
* CrO3
* Cr2O3
* Cr2O5
* Cr5O12
* CsO2
* Cs2O3
* CuO
* D2O
* Dy2O3
* Er2O3
* Eu2O3
* FeO
* Fe2O3
* Fe3O4
* Ga2O
* Ga2O3
* GeO
* GeO2
* H2O
* H218O
* H2O2
* HfO2
* HgO
* Hg2O
* Ho2O3
* I2O4
* I2O5
* I2O6
* I4O9
* In2O3
* IrO2
* KO2
* K2O2
* La2O3
* Li2O
* Li2O2
* Lu2O3
* MgO
* Mg2O3
* MnO
* MnO2
* Mn2O3
* Mn2O7
* MoO2
* MoO3
* Mo2O3
* NO
* NO2
* N2O
* N2O3
* N2O4
* N2O5
* NaO2
* Na2O
* Na2O2
* NbO
* NbO2
* Nd2O3
* OF2
* O2F2
* O3F2
* O4F2
* O2PtF6

Chemical formulas

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