Deuterated DMF

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Names
IUPAC name

1-Deuterio-N,N-bis(trideuteriomethyl)formamide[citation needed]

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is YN ?)
Infobox references

Tracking categories (test):

* SizeSet

|Section1=! colspan=2 style="background: #f8eaba; text-align: center;" |Identifiers

CAS Number

* 4472-41-7 Y

3D model (JSmol)

* Interactive image

| Abbreviations | DMF-d7[citation needed] |-

Beilstein Reference

| 1908468 |-

| ChemSpider

* 70601 N

| EC Number

* 224-745-8

PubChem CID

* 78225

| UN number | 2265 |-

| colspan="2" |

InChI

* InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D N

Key: ZMXDDKWLCZADIW-YYWVXINBSA-N N

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SMILES

* [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]

|- |Section2=! colspan=2 style="background: #f8eaba; text-align: center;" |Properties

Chemical formula

| C32H7NO

|- | Molar mass

| 80.1369 g mol−1

|- | Appearance | Colourless liquid |-

| Density | 1.03 g mL−1 |-

| Boiling point |  153 °C (307 °F; 426 K)

Refractive index (nD)

| 1.428 |- |Section3=! colspan=2 style="background: #f8eaba; text-align: center;" |Hazards

| GHS pictograms |  |- | GHS Signal word |DANGER

GHS hazard statements

| H312, H319, H332, H360 |-

GHS precautionary statements

| P280, P305+351+338, P308+313 |-

| Flash point |  58 °C (136 °F; 331 K)

| Explosive limits | 2.2–15.2% |-

| colspan=2 style="text-align:left; background-color:#f1f1f1;" | Lethal dose or concentration (LD, LC): |-

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LD50 (median dose)

* 2.8 g kg−1 (oral, rat)
* 1.5–4.72 g kg−1 (dermal, rabbit)

|- |Section4=! colspan=2 style="background: #f8eaba; text-align: center;" |Related compounds

Related alkanamides

* N-Methylformamide
* Dimethylformamide

Related compounds

* N-Nitroso-N-methylurea
* ENU

|- }} Deuterated dimethylformamide ((CD3)2NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH3)2NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.[1][2]

## References

1. ↑ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation" (in en). Macromolecules 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297. https://pubs.acs.org/doi/10.1021/ma951127p.
2. ↑ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution" (in en). New Journal of Chemistry 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. https://pubs.rsc.org/en/content/articlelanding/2019/nj/c9nj00899c.

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* t
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Deuterated NMR Solvents

Deuterated|

* Deuterated acetone \- (CD3)2C=O
* Deuterated benzene \- C6D6
* Deuterated chloroform \- CDCl3
* Deuterated dichloromethane \- CD2Cl2
* Deuterated DMF \- (CD3)2NCOD
* Deuterated DMSO \- (CD3)2S=O
* Deuterated ethanol \- C2D5OD
* Deuterated methanol \- CD3OD
* Deuterated THF \- (C4D8)O
* Deuterated water \- D2O

Reference

1H and 13C chemical shifts

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*[CID]: Compound ID
*[H312]: Harmful in contact with skin
*[H319]: Causes serious eye irritation
*[H332]: Harmful if inhaled
*[H360]: May damage fertility or the unborn child
*[P280]: Wear protective gloves/protective clothing/eye protection/face protection
*[P305+351+338]: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
*[P308+313]: IF exposed or concerned: Get medical advice/attention
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