Fluoride nitrate

Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.

## List

name  | formula  | mw  | crystal system  | space group  | unit cell Å  | volume  | density  | comment  | reference

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L-Argininium  | L-Arg2+•F−•NO3− |  | triclinic  | P1  | a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2  |  |  |  | [1]
| 2L-Arg2+•F−•3NO3−•HF  |  | orthorhombic  | P212121 | a=7.3960 b=12.8672 c=26.990 Z=4  |  |  |  | [1]
L-histidine  | L-His2+•F−•NO3− |  |  |  |  |  |  |  | [1]
| [Cr(NH3)5F](NO3)2 |  |  |  |  |  |  |  | [2]
hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate  | [Co(Im)6][F·NO3•(H2O)4]  |  | hexagonal  | P63/m | a 8.972 c 21.077 Z=2  | 1469.3  | 1.402  | pink  | [3]
| [Co(NH3)4(OH)F]NO3 |  |  |  |  |  |  |  | [4]
| [Co(NH3)5F](NO3)2 |  |  |  |  |  |  |  | [5]
| [Co(NH3)6]F(NO3)2 |  |  |  |  |  |  |  | [4]
| [Co(en)2F2]NO3 |  |  |  |  |  |  |  | [4]
| [As(ONO2)4]+[AsF6]− |  |  |  |  |  |  | pale yellow; hydroscopic  | [6]
| [Zr2F3OH(NO3)2(H2O)5]2+ |  |  |  |  |  |  | in solution  | [7]
| SnF2(ONO2)2 |  |  |  |  |  |  |  | [6]
| SnF3(ONO2)  |  |  |  |  |  |  | stable < 40 °C; hydroscopic  | [6]
| SbF(ONO2)4 |  |  |  |  |  |  |  | [6]
| SbF3(ONO2)2 |  |  |  |  |  |  |  | [6]
Xenon fluoride nitrate | FXeONO2 |  | monoclinic  |  | a = 4.6663 b = 8.799 c = 9.415 β = 90.325°  | 386.6  | 3.648  |  |
| CsFHONO2 |  |  |  |  |  |  |  | [8]
| [HfF4NO3]− |  |  |  |  |  |  | in solution  | [7]
| [HfF3(NO3)2]− |  |  |  |  |  |  | in solution  | [7]
| Hg3O2(NO3)F  |  | orthorhombic  | Pnma | a=7.547 b=10.990 c=6.9906  |  |  | birefringence Δn = 0.23 @ 1064 nm  | [9]
| Pb3F5NO3 |  | triclinic  | P1 | a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517°  |  |  | layered; stable to 450 °C  | [10][11]
| Pb(OF)Cu3(SeO3)2(NO3)  |  | trigonal  | R3m | a 6.6973 c 18.5548 Z=3  | 720.75  | 5.175  | yellow; stable to 400 °C  | [12]
| PbCdF(SeO3)(NO3)  |  | orthorhombic  | Pca21 | a=11.121 b=10.366 c=5.3950  |  |  | NLO 2.6×KDP; band gap 4.42 eV  | [13]
| BaPb2F5NO3 |  |  |  |  |  |  |  | [14]
| Bi2OF3(NO3)  |  | hexagonal  | P63/m |  |  |  | band gap 3.5 eV  | [15]
| Bi6O6F5(NO3)  |  | trigonal  | R3  |  |  |  | band gap 4.0 eV  | [15]
| [(UO2)4F13][Sr3(H2O)8](NO3)·H2O  | 1814.13  | triclinic  | P1 | a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2.  | 1468.1  | 4.105  | yellow  | [16]

## References

1. ↑ 1.0 1.1 1.2 Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 503–507. ISBN 978-3-319-06298-3.
2. ↑ Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines" (in en). Physical Review B 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829. https://link.aps.org/doi/10.1103/PhysRevB.38.11589.
3. ↑ Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n  in metal complex crystals"] (in en). CrystEngComm 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033. http://xlink.rsc.org/?DOI=C8CE00532J.
4. ↑ 4.0 4.1 4.2 Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations" (in en). Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944. http://xlink.rsc.org/?DOI=j19660000146.
5. ↑ Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia" (in en). Journal of Solution Chemistry 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. http://link.springer.com/10.1007/BF00650393.
6. ↑ 6.0 6.1 6.2 6.3 6.4 Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn" (in en). Chemische Berichte 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940. https://onlinelibrary.wiley.com/doi/10.1002/cber.19650980939.
7. ↑ 7.0 7.1 7.2 Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations" (in en). European Journal of Inorganic Chemistry 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001140.
8. ↑ Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2−"] (in en). Journal of Inorganic and Nuclear Chemistry 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9. https://linkinghub.elsevier.com/retrieve/pii/0022190280804209.
9. ↑ Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) +  ∞ cationic framework and excellent optical anisotropy"] (in en). Inorganic Chemistry Frontiers 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553. http://xlink.rsc.org/?DOI=D3QI01146A.
10. ↑ Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride" (in en). Crystal Growth & Design 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/cg9011923.
11. ↑ Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange" (in en). Journal of the American Chemical Society 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835. https://pubs.acs.org/doi/10.1021/ja017333w.
12. ↑ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice" (in en). Chemical Communications 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. http://xlink.rsc.org/?DOI=D0CC03684F.
13. ↑ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units" (in en). Inorganic Chemistry 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02044.
14. ↑ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3". https://www.elibrary.ru/item.asp?id=42697541.
15. ↑ 15.0 15.1 Cho, Eun Jeong; Oh, Seung-Jin; Jo, Hongil; Lee, Junsu; You, Tae-Soo; Ok, Kang Min (2019-02-04). "Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties" (in en). Inorganic Chemistry 58 (3): 2183–2190. doi:10.1021/acs.inorgchem.8b03343. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b03343.
16. ↑ Jouffret, Laurent J.; Hiltbrunner, Jean-Michel; Rivenet, Murielle; Sergent, Nicolas; Obbade, Saïd; Avignant, Daniel; Dubois, Marc (2016-12-05). "Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO 2 ) 4 F 13 [Sr 3 (H 2 O) 8 ](NO 3 )·H 2 O"] (in en). Inorganic Chemistry 55 (23): 12185–12192. doi:10.1021/acs.inorgchem.6b01765. ISSN 0020-1669. PMID 27934437. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01765.

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Salts and covalent derivatives of the fluoride ion

HF |  |  |  | He

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LiF | BeF2 | BF
BF3
B2F4 | CF4
other compounds | NF3
FN3
N2F2
N2F4
NF5§  | F2O
F2O2
other compounds | F2 | Ne
NaF | MgF2 | AlF
AlF3 | SiF4 | P2F4
PF3
PF5 | S2F2
SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF
CaF2 | ScF3 | TiF2
TiF3
TiF4 | VF2
VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5
CrF6§  | MnF2 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF2
GaF3 | GeF2
GeF4 | AsF3
AsF5 | Se2F2
SeF4
SeF6 | BrF
BrF3
BrF5 | KrF2
RbF | SrF
SrF2 | YF3 | ZrF3
ZrF4 | NbF4
NbF5 | MoF2
MoF3
MoF4
MoF5
MoF6 | TcF4
TcF6 | RuF3
RuF5
RuF6 | RhF3
RhF5
RhF6 | PdF2 | AgF | CdF2 | InF
InF2
InF3 | SnF2
SnF4 | SbF3
SbF5 | Te3F2
TeF4
TeF6 | IF
IF3</br>IF5</br>IF7 | XeF2
XeF4
XeF6
CsF | BaF2 |  | HfF4 | TaF5 | WF2
WF3
WF4
WF5
WF6 | Re3F9
ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF2
IrF3
IrF4
IrF5
IrF6 | PtF2
PtF4
PtF5
PtF6 | AuF
AuF3
Au2F10
AuF5•F2 | Hg2F2
HgF2
HgF4 | TlF | PbF2
PbF4 | BiF3
BiF5 | PoF2
PoF4
PoF6 | AtF  | RnF2
FrF | RaF2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
LaF3 | CeF3
CeF4 | PrF3 | NdF2,
NdF3 | PmF3 | SmF2,
SmF3 | EuF2,
EuF3 | GdF3 | TbF3 | DyF2,
DyF3 | HoF3 | ErF3 | TmF2
TmF3 | YbF2
YbF3 | LuF3
AcF3 | ThF4 | PaF5 | UF3
UF4
UF5
UF6 | NpF4
NpF6 | PuF3
PuF6 | AmF2
AmF3 | CmF3 | BkF3 | CfF3 | EsF3 | Fm  | Md  | No  | LrF3

§ means the substance has not been made.

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Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

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LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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