List of gases

Short description: none

Boiling liquid oxygen

This is a list of gases at standard conditions, which means substances that boil or sublime at or below 25 °C (77 °F) and 1 atm pressure and are reasonably stable.

## Contents

* 1 List
* 2 Known as gas
* 3 Possible
* 4 Near misses
* 5 Unstable substances
* 6 References

## List

This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately. Blue type items have an article available by clicking on the name.

Name  | Formula  | Boiling pt (°C)  | Melting pt (°C)  | Molecular weight  | CAS No

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Helium-3 | 3He  | −269.96  | N/A  | 3  | 14762-55-1
Helium-4 | 4He  | −268.928  | N/A  | 4  | 7440-59-7
Hydrogen | H2 | −252.879  | −259.16  | 2  | 1333-74-0
Deuterium[1] | D2 | −249.49  | −254.43  | 4  | 7782-39-0
Tritium[2] | T2 | −248.12  | −254.54  | 6  | 10028-17-8
Neon | Ne  | −246.046  | −248.59  | 20  | 7440-01-9
Nitrogen | N2 | −195.795  | −210.0  | 28  | 7727-37-9
Carbon monoxide | CO  | −191.5  | −205.02  | 28  | 630-08-0
Fluorine | F2 | −188.11  | −219.67  | 38  | 7782-41-4
Argon | Ar  | −185.848  | −189.34  | 40  | 7440-37-1
Oxygen | O2 | −182.962  | −218.79  | 32  | 7782-44-7
Methane | CH4 | −161.5  | −182.50  | 16  | 74-82-8
Krypton | Kr  | −153.415  | −157.37  | 84  | 7439-90-9
Nitric oxide | NO  | −151.74  | −163.6  | 30  | 10102-43-9
Oxygen difluoride | F2O  | −144.3  | −223.8  | 54  | 7783-41-7
Tetrafluoromethane | CF4 | −127.8  | −183.6  | 88  | 75-73-0
Nitrogen trifluoride | NF3 | −128.74  | −206.79  | 71  | 7783-54-2
Silane | SiH4 | −111.9  | −185  | 32  | 7803-62-5
trans-Dinitrogen difluoride | N2F2 | −111.45  | −172  | 66  | 13776-62-0
Ozone | O3 | −111.35  | −193  | 48  | 10028-15-6
Xenon | Xe  | −108.099  | −111.75  | 131  | 7440-63-3
cis-Dinitrogen difluoride | N2F2 | −105.75  | −195  | 66  | 13812-43-6
Ethylene | CH2=CH2 | −103.7  | −169.2  | 28  | 74-85-1
Phosphorus trifluoride | PF3 | −101.8  | −151.5  | 88  | 7783-55-3
Chlorine monofluoride | ClF  | −101.1  | −155.6  | 54.5  | 7790-89-8
Boron trifluoride | BF3 | −99.9  | −126.8  | 68  | 7637-07-2
Fluorosilane  | SiH3F  | −98.6  |  | 50  | 13537-33-2
Trifluorosilane | SiHF3 | −95  | −131  | 86  | 13465-71-9
Trifluoromethyl hypofluorite[3] | CF3OF  | −95  | −215  | 104  | 373-91-1
Diborane | B2H6 | −92.49  | −164.85  | 28  | 19287-45-7
3,3-Difluorodiazirine[4] | c-CF2N2 | −91.3  |  | 78  | 693-85-6
Ethane | CH3CH3 | −88.5  | −182.8  | 30  | 74-84-0
Nitrous oxide | N2O  | −88.48  | −90.8  | 44  | 10024-97-2
Germane | GeH4 | −88.1  | −165  | 77  | 7782-65-2
Phosphine | PH3 | −87.75  | −133.8  | 34  | 7803-51-2
Trifluoramine oxide | NOF3 | −87.5  | −161  | 87  | 13847-65-9
Tetrafluorosilane  | SiF4 | −86  | −90.2  | 104  | 7783-61-1
1,1-Difluoroethene | CF2=CH2 | −85.5  | −144  | 64  | 75-38-7
Trifluoronitrosomethane | CF3NO  | −85  | −196.6  | 99  | 334-99-6
Azidotrifluoromethane  | CF3N3 | −85  | −152  | 111  | 3802-95-7
Hydrogen chloride | HCl  | −85  | −114.17  | 36.5  | 7647-01-0
Difluorodioxirane[5] | F2COO  | ≈−85  | ≤−160  | 82  | 96740-99-7
Acetylene | CH≡CH  | −84.7  | −81.5  | 26  | 74-86-2
Phosphorus pentafluoride | PF5 | −84.6  | −93.8  | 126  | 7647-19-0
Carbonyl fluoride | COF2 | −84.5  | −111.2  | 66  | 353-50-4
Difluorodiazomethane  | CF2N2 | −83  |  | 78.02  | 693-85-6
Fluoroform | CHF3 | −82.1  | −155.2  | 70  | 75-46-7
Chlorotrifluoromethane | CClF3 | −81.5  | −181  | 104.5  | 75-72-9
Bis(difluoroboryl)methane[3] | BF2CF2BF2 | −81.4 ?  |  | 148  | 55124-14-6
Trifluoroisocyanomethane  | CF3NC  | −80  |  | 95  | 105879-13-8
Difluoromethylborane  | CH3BF2 | −78.5  |  | 64  | 373-64-8
Carbon dioxide | CO2 | −78.464 sub  | −56.561 triple  | 44  | 124-38-9
Fluoromethane | CH3F  | −78.4  | −137.8  | 34  | 593-53-3
Hexafluoroethane | CF3CF3 | −78.1  | −100.015  | 138  | 76-16-4
Pentafluoromethanamine  | CF3NF2 | −78  | −130  | 121  | 335-01-3
Difluorosilane | SiH2F2 | −77.8  | −122  | 68  | 13824-36-7
Tetrafluoroethene  | CF2=CF2 | −76  | −131.14  | 100  | 116-14-3
Fluoroacetylene  | FCCH  | −74  | −196  | 44  | 2713-09-9
Tetrafluorohydrazine | N2F4 | −74  | −164.5  | 104  | 10036-47-2
Nitryl fluoride | NO2F  | −72.4  | −166  | 65  | 10022-50-1
Fluoroethene  | CH2CHF  | −72  | −160.5  | 46  | 75-02-5
Chlorotrifluorosilane | SiClF3 | −70  | −138  | 120.5  | 14049-36-6
Trifluoroacetonitrile | CF3CN  | −68.8  |  | 95  | 353-85-5
Chlorodifluoroamine | NClF2 | −67  | −195  | 87.5  | 13637-87-1
Hydrogen bromide | HBr  | −66.38  | −86.80  | 81  | 10035-10-6
Difluorophosphine[6] | PHF2 | −65  | −124  | 70  | 14984-74-8
Borane carbonyl | BH3CO  | −64  | −137  | 42  | 13205-44-2
Fluoroperoxytrifluoromethane[7] | CF3OOF  | −64  |  | 120  |
Bis(fluoroxy)difluoromethane[8] | CF2(OF)2 | −64  |  | 120  | 16282-67-0
Sulfur hexafluoride | SF6 | −63.8  | −49.596 triple  | 146  | 2551-62-4
Tetrafluorooxirane[9] | C2F4O  | −63.5  |  | 116  | 694-17-7
Arsine | AsH3 | −62.5  | −166  | 78  | 7784-42-1
Thiocarbonyl fluoride[10] | CSF2 | −62.1  | −163.5  | 82  | 420-32-6
Radon | Rn  | −61.7  | −71  | 222  | 10043-92-2
Difluorocyanamide[3][11] | NF2CN  | −61  | −196  | 78  | 7127-18-6
Nitrosyl fluoride | ONF  | −59.9  | −132.5  | 49  | 7789-25-5
Hydrogen sulfide | H2S  | −59.55  | −85.5  | 34  | 7783-06-4
Trifluoroacetyl fluoride[12] | CF3COF  | −59  | −159.5  | 116  | 354-34-7
Hexafluorodimethyl ether[13] | CF3OCF3 | −59  |  | 154  | 333-36-8
Bromotrifluoromethane | CBrF3 | −57.75  | −167.78  | 149  | 75-63-8
Difluoroaminooxyperfluoromethane[3][14] | CF3ONF2 | −57.63  |  | 137  | 4217-93-0
Methylsilane | CH3SiH3 | −57.5  | −156.5  | 46  | 992-94-9
Dioxygen difluoride  | F2O2 | −57 dec  | −163.5  | 70  | 7783-44-0
Ethenone | CH2=C=O  | −56.1  | −151  | 42  | 463-51-4
Sulfuryl fluoride | SO2F2 | −55.4  | −135.8  | 102  | 2699-79-8
Dichlorofluorosilane  | SiHCl2F  | −54.3  |  | 119  | 19382-74-2
trans-1,2-Difluoroethene | CHF=CHF  | −53.1  |  | 64  | 1630-78-0
Trifluoroethene  | CF2=CHF  | −53  |  | 82  | 359-11-5
Arsenic pentafluoride | AsF5 | −52.8  | −79.8  | 170  | 7784-36-3
Phosphorothioic trifluoride  | PSF3 | −52.25  | −148.8  | 120  | 2404-52-6
Difluoromethane | CH2F2 | −52  | −136  | 52  | 75-10-5
Difluorocarbamyl fluoride[15][16] | F2NCOF  | −52  | −152.2  | 99  | 2368-32-3
Stannane | SnH4 | −51.8  | −146  | 123  | 2406-52-2
Tetrafluoropropyne[17] | CF3C≡CF  | −50.39  |  | 112  | 20174-11-2
Carbonyl sulfide | OCS  | −50.2  | −138.8  | 60  | 463-58-1
Pentafluoroethyl hypofluorite[18] | C2F5OF  | −50  |  | 154  |
Chlorodifluorosilane[19] | SiHClF2 | ~−50  |  | 102.5  | 80003-43-6
Digallane | Ga2H6 | 0 dec  | −50 sub  | 145.494  | 12140-58-8
Thionyl tetrafluoride | SOF4 | −48.5  | −99.6  | 124  | 13709-54-1
3,3,3-Trifluoro-1-propyne  | CF3CCH  | −48.3  |  | 94  | 661-54-1
Pentafluoroethane | CF3CHF2 | −48.1  | −100.6  | 120  | 354-33-6
Propene | C3H6 | −47.6  | −185.2  | 42  | 115-07-1
Chlorodifluorophosphine  | PClF2 | −47.3  | −164.8  | 104.5  | 14335-40-1
Carbonyl chloride fluoride  | COClF  | −47.2  | −148  | 82.5  | 353-49-1
1,1,1-Trifluoroethane | CF3CH3 | −47  | −111.8  | 84  | 420-46-2
Trifluoromethyl hypochlorite[3] | CF3OCl  | −47  | −164  | 120.5  | 22082-78-6
Perchloryl fluoride | ClO3F  | −46.75  | −147  | 102.5  | 7616-94-6
Selenium hexafluoride | SeF6 | −46.6 sub  | −34.6 triple  | 193  | 7783-79-1
Cyanogen fluoride | FCN  | −46  | −82  | 45  | 1495-50-7
Fluorine nitrate | FNO3 | −46  | −175  | 81  | 7789-26-6
Pentafluoronitrosoethane[20] | C2F5NO  | −45.7  |  | 137  | 354-72-3
Difluoromethylene dihypofluorite[21] | CF2(OF)2 | −45.8  | −142  | 120  | 16282-67-0
cis-1,2-Difluoroethene  | CHF=CHF  | −45  |  | 64  | 1630-77-9
1,1-Difluoro-1-propene[3] | CH3CH=CF2 | −44  |  | 78  | 430-63-7
(CH3)2BF  | −44  |  | 60  | 353-46-8
Fluoro(trifluoromethyl)silane[22] | CF3SiH2F  | −44  |  | 118  |
Thionyl fluoride | SOF2 | −43.8  | −110.5  | 86  | 7783-42-8
Phosphorus chloride tetrafluoride  | PClF4 | −43.4  | −132  | 142.5  | 13498-11-8
Methyldiborane | CH3B2H5 | −43  |  | 42  | 23777-55-1
Difluoro(trifluoromethyl)phosphine[23] | CF3PF2 | −43  |  | 138  | 1112-04-5
N,N,1,1-Tetrafluoromethylamine[24] | CHF2NF2 | −43  |  | 103  | 24708-53-0
Propane | C3H8 | −42.25  | −187.7  | 44  | 74-98-6
Trifluoro(trifluoromethyl)silane[25] | CF3SiF3 | −42  |  | 154  | 335-06-8
Bromotrifluorosilane  | BrSiF3 | −41.7  | −70.5  | 169  | 14049-39-9
Hydrogen selenide | H2Se  | −41.25  | −65.73  | 81  | 7783-07-5
Chlorodifluoromethane | CHClF2 | −40.7  | −175.42  | 86.5  | 75-45-6
Sulfur tetrafluoride | SF4 | −40.45  | −125  | 108  | 7783-60-0
Hexafluorodiazomethane cis[26] | CF3NNCF3 | −40  | −127  | 166  | 73513-59-4
Phosphoryl fluoride | POF3 | −39.7 sub  | −39.1 triple  | 104  | 13478-20-1
Chloropentafluoroethane | CF3CClF2 | −39.1  | −99  | 135.5  | 76-15-3
Trifluoromethyl difluoroarsine  | CF3AsF2 | −39  |  | 181.93  | 420-53-1
Tetrafluoro(trifluoromethyl)phosphorane[27] | CF3PF4 | −39  | −113  | 176  | 1184-81-2
tetrafluorophosphorane[28] | PHF4 | −39.0  | −100  | 108  | 13659-66-0
Tellurium hexafluoride | TeF6 | −38.9  | −37.6 triple  | 242  | 7783-80-4
Vinyldifluoroborane[29] | CH2=CHBF2 | −38.8  | −133.4  | 76  | 358-95-2
(Trifluoromethyl)silane  | CF3SiH3 | −38.3  | −124  | 100  | 10112-11-5
Heptafluoroethanamine[3] | C2F5NF2 | −38.1  | −183  | 171  | 354-80-3
Tetrafluoroallene[30] | CF2=C=CF2 | −38  |  | 112  | 461-68-7
Hexafluorooxetane[31] | C3F6O  | −38  |  | 166  | 425-82-1
Trifluoromethanethiol[32] | CF3SH  | −37.99  | −157.11  | 102  | 1493-15-8
Fluoroethane | CH3CH2F  | −37.7  | −143.2  | 48  | 353-36-6
Bis(trifluoromethyl)peroxide | CF3OOCF3 | −37  |  | 170  | 927-84-4
Pentafluoropropanenitrile[33] | C2F5CN  | −37  |  | 145  | 422-04-8
Perfluorodimethylamine[34] | (CF3)2NF  | −37  |  | 171  | 359-62-6
Perfluoropropane  | C3F8 | −36.8  | −147.7  | 188  | 76-19-7
Germanium tetrafluoride | GeF4 | −36.5  | −15 triple  | 149  | 7783-58-6
Cyclopropene | C3H4 | −36  |  | 40  | 2781-85-3
Trifluoromethyl fluoroformate[35] | CF3OC(O)F  | −36  | ≈−120  | 132  | 3299-24-9
Trifluoromethyl isocyanate[36] | CF3NCO  | −36  |  | 111  | 460-49-1
Tetrafluoro-1,2-diazetidine  | C2F4N2H2 | −36  |  | 130  |
Hydrogen iodide | HI  | −35.5  | −50.76  | 128  | 10034-85-2
Pentafluorosulfur hypofluorite | SOF6 | −35.1  | −86  | 162  | 15179-32-5
Difluoromethoxy(trifluoro)methane  | CF3OCHF2 | −35.0  | −157  | 136  | 3822-68-2
Propadiene  | CH2=C=CH2 | −34.8  | −136  | 40  | 463-49-0
Chlorine | Cl2 | −34.04  | −101.5  | 71  | 7782-50-5
Trifluoromethyl fluoroformate[3][37] | CF3OC(O)F  | −34  |  | 132  | 3299-24-9
Diboron tetrafluoride | B2F4 | −34  | −56  | 98  | 13965-73-6
Ammonia | NH3 | −33.33  | −77.73  | 17  | 7664-41-7
Perfluorocyclopropane[38] | -CF2CF2CF2\-  | −33  | −80  | 150  | 931-91-9
Trifluoronitromethane[39] | CF3NO2 | −32  |  | 115  | 335-02-4
Dichlorodifluorosilane  | SiCl2F2 | −32  | −44  | 137  | 18356-71-3
(Difluoroamino)difluoroacetonitrile[40] | NF2CF2CN  | −32  |  | 128  | 5131-88-4
Hexafluoromethanediamine[3][41] | (NF2)2CF2 | −31.9  | −161.9  | 154  | 4394-93-8
Fluorine fluorosulfate[42] | FSO3F  | −31.3  | −158.5  | 118  | 13536-85-1
Bis(trifluoromethyl)diazene trans[3] | CF3NNCF3 | −31.1  |  | 166  | 372-63-4
Cyclopropane | C3H6 | −31  | −127.6  | 42  | 75-19-4
Chlorosilane | SiH3Cl  | −30.4  | −118  | 66.5  | 13465-78-6
Hexafluoropropylene | CF2=CFCF3 | −30.2  | −156.6  | 150  | 116-15-4
Chloroacetylene  | HCCCl  | −30  | −126  | 60.5  | 593-63-5
Methyltrifluorosilane  | CH3SiF3 | −30  | −73  | 100  | 373-74-0
Fluorine azide[43] | FN3 | −30  | −139  | 61.019  | 14986-60-8
Dichlorodifluoromethane | CCl2F2 | −29.8  | −157.7  | 121  | 75-71-8
2,3,3,3-Tetrafluoropropene[44] | CF3CF=CH2 | −29.5  | −152.2  | 114  | 754-12-1
Tetrafluorodiaziridine[3] | CF4N2 | −29  |  | 116  | 17224-09-8
fluoroxypentafluoroselenium[45][46][47] | F5SeOF  | −29  | −54  | 209  | 27218-12-8
Perfluorooxetane  | C3OF6 | −28.6  | −117  | 166  | 425-82-1
Chlorotrifluoroethene  | CClF=CF2 | −28.3  | −158.14  | 116.5  | 79-38-9
Methyldifluorophosphine  | CH3PF2 | −28  | −110  | 84  | 753-59-3
Perfluoroacetone  | CF3COCF3 | −27.4  | −125.45  | 166  | 684-16-2
Trifluoro(trifluoromethyl)oxirane  | C2OF3CF3 | −27.4  | −144  | 166  | 428-59-1
Thiazyl trifluoride | N≡SF3 | −27.1  | −72.6  | 103  | 15930-75-3
Trifluoroacetyl chloride | CF3COCl  | −27  | −146  | 132.5  | 354-32-5
3,3,3-Trifluoropropene  | CF3CH=CH2 | −27  |  | 96  | 677-21-4
Phosphonium chloride  | PH4Cl  | −27 sub  |  | 70.5  | 24567-53-1
Formyl fluoride  | HCOF  | −26.5  | −142.2  | 48  | 1493-02-3
1,1,1,2-Tetrafluoroethane | CF3CH2F  | −26.1  | −103.296  | 102  | 811-97-2
Trifluoromethyl trifluorovinyl ether[3] | CF3OCF=CF2 | −26  |  | 166  | 1187-93-5
Methyl trifluoromethyl ether  | CF3OCH3 | −25.2  | −149.1  | 100  | 421-14-7
Bis(trifluoromethyl)nitroxide[48] | (CF3)2NO  | −25  | −70  | 168  | 2154-71-4
Sulfur cyanide pentafluoride[49] | SF5CN  | −25  | −107  | 153  | 1512-13-6[50]
Dimethyl ether | CH3OCH3 | −24.8  | −141.49  | 46  | 115-10-6
1,1,1,4,4,4-Hexafluoro-2-butyne  | CF3C≡CCF3 | −24.6  | −117.4  | 162  | 692-50-2
1-Chloro-1-fluoroethene[3] | CClF=CH2 | −24.1  |  | 80.5  | 2317-91-1
1,1-Difluoroethane | CHF2CH3 | −24.05  | −118.6  | 66  | 75-37-6
2-Fluoropropene[51] | CH3CF=CH2 | −24  |  | 60  | 1184-60-7
Borirane | C2H4BH  | −24  | −129  | 40  | 39517-80-1
Chloromethane | CH3Cl  | −23.8  | −97.4  | 50.5  | 74-87-3
Trifluoronitrosoethylene[52] | CF2=CFNO  | −23.7  |  | 111  | 2713-04-4
Pentafluoro(trifluoromethoxy)ethane[53] | C2F5OCF3 | −23.6  |  | 204  | 665-16-7
Difluoramine | NHF2 | −23.6  | −116  | 53  | 10405-27-3
1,1-Difluorocyclopropane[54] | CF2CH2CH2 | −23.5  |  | 78  | 558-29-2
Propyne or methylacetylene  | CH3CCH  | −23.2  | −103.0  | 40  | 74-99-7
Diazomethane | CH2N2 | −23  | −145  | 42  | 334-88-3
Methylgermane  | CH3GeH3 | −23  | −158  | 91  | 1449-65-6
Prop-1-en-1-one or methylketene  | CH3CH=CO  | −23  | −80  | 56  | 6004-44-0
Vinylsilane | CH2=CHSiH3 | −22.8  |  | 58  | 7291-09-0
Trifluoroiodomethane | CF3I  | −22.5  | −110  | 196  | 2314-97-8
Ethynylsilane  | HC≡CSiH3 | −22.5  |  | 56  | 1066-27-9
Bis(trifluoromethyl) sulfide[55] | (CF3)2S  | −22.2  |  | 170.08  | 371-78-8
Hexafluoro-1,3-dioxolane[56] | c-CF2OCF2OCF2\-  | −22.1  |  | 182.02  | 21297-65-4
Chloromethane sulfonyl chloride[3] | CH2ClS(O)(O)Cl  | −22  |  | 149  | 3518-65-8
Trifluoromethyl peroxychloride[3] | CF3OOCl  | −21.9  | −132  | 136.5  | 32755-26-3
Carbonyl selenide | COSe  | −21.7  | −124.4  | 107  | 1603-84-5
Trifluoromethanesulfonyl fluoride  | CF3SOF  | −21.7  |  | 136  | 335-05-7
Chlorine trifluoride dioxide | ClO2F3 | −21.6  | −81.2  | 124.5  | 38680-84-1
Carbonyl bromide fluoride  | COBrF  | −21  |  | 127  | 753-56-0
Bromopentafluoroethane  | C2BrF5 | −21  |  | 199  | 354-55-2
Cyanogen | NCCN  | −21  | −27.83  | 52  | 460-19-5
Methoxysilane  | CH3OSiH3 | −21  | −98.5  | 62  | 2171-96-2
1,1,3,3,3-Pentafluoropropene  | CF2=CHCF3 | −21  | -153  | 132  | 690-27-7
Carbonyl bromide fluoride[3] | CBrFO  | −20.6  |  | 127  | 753-56-0
Trifluoromethylsulfur pentafluoride[3] | CF3SF5 | −20.4  | −87  | 196  | 373-80-8
Chlorotrifluorogermane  | GeClF3 | −20.3  | −66.2  | 165.5  | 14188-40-0
Trimethylborane | (CH3)3B  | −20.2  | −159.93  | 56  | 593-90-8
Dimethylsilane | (CH3)2SiH2 | −20  | −150  | 60  | 1111-74-6
Perfluorovinylacetylene  | F2C=CF−C≡CF  | −20  |  | 126.03  | 667-28-7
1,1,2,2-Tetrafluoroethane | CHF2CHF2 | −19.9  | −89  | 102  | 359-35-3
Formaldehyde | H2CO  | −19.1  | −92  | 30  | 50-00-0
Hexafluorodisilane  | SiF3SiF3 | −19.1  | −18.7 triple  | 170  | 13830-68-7
Sulfur chloride pentafluoride | SClF5 | −19.05  | −64  | 158.5  | 13780-57-9
1-Chloro-2,2-difluoroethene  | CHCl=CF2 | −18.8  | −138.5  | 98.5  | 359-10-4
E-1,2,3,3,3-Pentafluoropropene | CFH=CFCF3 | −18.7  |  | 132  | 5595-10-8
1,1,1,2,2-Pentafluoropropane  | CF3CF2CH3 | −18  |  | 133  | 1814-88-6
Fluoral[57] | CF3CHO  | −18  |  | 98  | 75-90-1
2-Chloro-1,1-difluoroethylene[58] | CF2=CHCl  | −17.7  | −138.5  | 98  | 359-10-4
Difluoroamino sulfur pentafluoride[59] | NF2SF5 | −17.5  |  | 179  | 13693-10-2
Stibine | SbH3 | −17  | −88  | 125  | 7803-52-3
1,1,2,2,3,3,3-Heptafluoropropane[60] | CF2HCF2CF3 | −17  | −148.5  | 170  | 2252-84-8
1,1,1,2,3,3,3-Heptafluoropropane | CF3CHFCF3 | −16.34  | −126.8  | 170  | 431-89-0
Phosphorus(III) bromide difluoride  | PBrF2 | −16.1  | −133.8  | 149  | 15597-40-7
Methylphosphine | CH3PH2 | −16  |  | 48  | 593-54-4
Fluorine perchlorate | FOClO3 | −16  | −167.3  | 118.5  | 10049-03-3
Bis(trifluoromethyl) trioxide[61] | CF3OOOCF3 | −16  | −138  | 186  |
1,3,3,3-Tetrafluoropropene[3] | CF3CH=CHF  | −16  | −104.53  | 114  | 1645-83-6
N,N-Difluoromethanamine[3][62] | CH3NF2 | −15.9  | −114.8  | 67  | 753-58-2
1-Trifluoromethyl-1,2,2-trifluorocyclopropane[54] | CF3C3H2F3 | −15.8  |  | 152  |
Disiloxane | (SiH3)2O  | −15.2  | −144  | 78  | 13597-73-4
cis-1-Fluoropropene  | CH3CH=CHF  | −15  |  | 60  | 19184-10-2
trans-1-Fluoropropene  | CH3CH=CHF  | −15?  |  | 60  | 20327-65-5
Nitryl chloride | NO2Cl  | −15  | −145  | 81.5  | 13444-90-1
Chlorazide  | ClN3 | −15  | −100  | 77.47  | 13973-88-1
Disilane | Si2H6 | −14.8  | −129.4  | 62  | 1590-87-0
Z-1,2,3,3,3-Pentafluoropropene | CHF=CFCF3 | −14.7  |  | 132  | 5528-43-8
Bromodifluoromethane | CHBrF2 | −14.6  | −145  | 131  | 1511-62-2
Chloroethene  | CH2=CHCl  | −13.8  | −153.84  | 62.5  | 75-01-4
Monoethylsilane[63] | CH3CH2SiH3 | −13.7  | −180  | 60  | 2814-79-1
Chlorine pentafluoride | ClF5 | −13.1  | −103  | 130.5  | 13637-63-3
Perfluorocyclopropene[64] | -CF=CFCF2\-  | −13  | −60  | 112  | 19721-29-0
1,1,1-Trifluoropropane  | CF3CH2CH3 | −13  |  | 98  | 421-07-8
1-Chloro-1,1,2,2-tetrafluoroethane  | CClF2CHF2 | −13  | −117  | 135.5  | 354-25-6
Carboimidic difluoride  | CF2NH  | −13 dec  | −90  | 65  | 2712-98-3
Plumbane | PbH4 | −13  |  | 211  | 15875-18-0
Methyl nitrite | CH3NO2 | −12  | −16  | 61  | 624-91-9
Trifluoromethylarsine[65] | CF3AsH2 | −12  |  | 146  | 420-42-8
1-Chloro-1,2,2,2-tetrafluoroethane | CHClFCF3 | −11.96  | −199.15  | 136.5  | 2837-89-0
Isobutane | (CH3)2CHCH2 | −11.7  | −159.42  | 58  | 75-28-5
Trifluoromethoxy sulfur pentafluoride[66] | CF3OSF5 | −11  | −143  | 212  | 1873-23-0
Trifluoromethylarsenic tetrafluoride  | CF3AsF4 | −11  |  | 219.93  | 1519-13-7
Thiothionyl fluoride | SSF2 | −10.6  | −164.6  | 102  | 101947-30-2
Sulfur dioxide | SO2 | −10.05  | −75.5  | 64  | 7446-09-5
Pentafluorocyclopropane[64] | -CHFCF2CF2\-  | −10  | −10  | 132  | 872-58-2
2-Fluoropropane  | CH3CHFCH3 | −10  |  | 62  | 420-26-8
Pentafluoroethyl hypochlorite[67] | C2F5OCl  | −10±  |  | 170.5  | 22675-67-8
Fluoroformyl sulfurpentafluoride[68] | SF5C(O)F  | −10  |  | 174  |
Trifluoromethyl fluoroformyl peroxide[69] | CF3OOC(O)F  | ~−10  |  | 148  | 16118-40-4
Perfluorodimethoxymethane  | CF3OCF2OCF3 | −10  | −161  | 220  | 53772-78-4
1-Chloro-1,1-difluoroethane | CClF2CH3 | −9.6  | −130.8  | 100.5  | 75-68-3
Chlorofluoromethane | CH2ClF  | −9.1  | −133.0  | 68.5  | 593-70-4
Pentafluoroethyl isocyanate[70] | C2F5NCO  | −9  |  | 157  | 356-74-1
Bis(trifluoromethyl)chloramine[71] | (CF3)2NCl  | −9  |  | 187.5  |
Selenium dioxydifluoride  | SeO2F2 | −8.4  | −99.5  | 149  | 14984-81-7
Fluoro(trifluoro-methyl)diazine[3] | CF4N2O  | −7.63  |  | 132  | 815-10-1
Isobutene  | (CH3)2C=CH2 | −7.0  | −140.7  | 56  | 115-11-7
3-Fluoropropene  | CH2=CHCH2F  | −7  |  | 60  | 818-92-8
Bis(trifluoromethyl)amine[3] | (CF3)2NH  | −7  |  | 153  | 371-77-7
Ethoxytrifluorosilane[72] | CH3H2OSiF3 | −7  | −122  | 118  | 460-55-9
Trifluoromethylsulfur trifluoride[73] | CF3SF3 | −7  | −110  | 158  | 374-10-7
Perfluoro-2-methyl-1,2-oxazetidine[74] | (CF3-N)CF2CF2O  | −6.8  |  | 199  |
Tris(trifluoromethyl)-amine[34] | (CF3)3N  | −6.5  |  | 221  | 432-03-1
Methylamine | CH3NH2 | −6.4  | −93.42  | 31  | 74-89-5
1-Butene | CH2=CHCH2CH3 | −6.3  | −185.33  | 56  | 106-98-9
Diphosphorus tetrafluoride | P2F4 | −6.2  | −86.5  | 138  | 13824-74-3
Chloryl fluoride | ClO2F  | −6  | −115  | 86.5  | 13637-83-7
Trifluoromethyl iminosulfur difluoride[75] | CF3N=SF2 | −6  |  | 153  | 1512-14-7
Perfluorocyclobutane  | -CF2CF2CF2CF2\-  | −5.91  | −40.16  | 200  | 115-25-3
Perfluoro-2-butene  | CF3CCF=CF3 | −5.9  |  | 200  | 360-89-4 trans
Nitrosyl chloride | ONCl  | −5.55  | −59.4  | 65.5  | 2696-92-6
Difluorocarbamoyl chloride  | CClF2NO  | −5.5  |  | 115.5  | 16847-30-6
Hexafluoro 1,2-dioxolane[76] | -CF2CF2CF2OO-  | −5  | −115.5  | 182.02  |
2,3,3,3-tetrafluoro-2-(trifluoromethyl)-propanenitrile[77] | N≡CCF(CF3)2 | −4.7  | −118  | 195.038  | 42532-60-5
1,3-Butadiene | CH2=CHCH=CH2 | −4.6  | −108.9  | 54  | 106-99-0
Ethyltrifluorosilane[78] | CH3CH2SiF3 | −4.4  | −105  | 114  | 353-89-9
Difluoro-N-fluoromethanimine  | F2C=NF  | −4  |  | 83  | 338-66-9
Perfluoro-1,2-butadiene  | CF3CF=C=CF2 | −4  |  | 162.03  | 550-44-7
1,1-Dimethyldiborane | (CH3)2B(μ-H)2BH2 | −4  | −150.2  | 56  | 16924-32-6
trans-1-Chloro-2-fluoroethene[79] | CHCl=CHF  | −4  |  | 80.5  | 2268-32-8
Bromochlorodifluoromethane | CF2ClBr  | −3.7  | −159.5  | 165.5  | 353-59-3
N-Nitroso-bis(trifluoromethyl)amine[80] | ONN(CF3)2 | −3.5  |  | 182  |
Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether[56] | CF3OCF2CF2H  | −3.3  | −141  | 186  | 2356-61-8
1-Fluoropropane[3] | CH2FCH2CH3 | −3.2  | −159  | 62  | 460-13-9
3-Fluoropropene[51] | CH2CHCH2F  | −3  |  | 60  | 818-92-8
Dimethylperoxide  | CH3OOCH3 | −3  | −100  | 62  | 690-02-8
Trifluoromethyl thionitrite[81] | CF3SNO  | −3  |  | 131  |
Hydrogen astatide | HAt[82] (theoretical)  | −3  |  | 211  | 13464-71-6
Dichlorodifluorogermane  | GeCl2F2 | −2.8  | −51.8  | 182  | 24422-21-7
Bromotrifluoroethene  | CBrF=CF2 | −2.5  |  | 161  | 598-73-2
Trifluoromethane sulfinyl fluoride[3] | CF3SOF  | −2.5  |  | 136  | 812-12-4
Perfluorobutane | C4F10 | −2.1  | −129  | 238  | 355-25-9
Hydrogen telluride | H2Te  | −2  | −49  | 130  | 7783-09-7
1-Chloroheptafluoropropane[83] | CF3CF2CF2Cl  | −2  |  | 204.5  | 422-86-6
2-Chloroheptafluoropropane[83] | CF3CFClCF3 | −2  |  | 204.5  | 76-18-6
Bis(trifluoromethyl)selenium[84] | (CF3)2Se  | −2  |  | 217  | 371-79-9
Trifluoromethyl sulfinyl fluoride[73] | CF3S(O)F  | −1.6  |  | 136  | 812-12-4
1,1,1,2,2,3-Hexafluoropropane  | CF3CF2CFH2 | −1.44  | −98.38  | 152  | 677-56-5
1,1,1,3,3,3-Hexafluoropropane | CF3CH2CF3 | −1.4  | −93.6  | 152  | 690-39-1
Pentafluoroguanidine[85] | CF5N3 | −1  |  | 149  | 10051-06-6
Trifluoromethyl sulfenyl chloride  | CF3SCl  | −1  | −137  | 136.52  | 421-17-0
1,1,2,2-Tetrafluoropropane[86] | CHF2CF2CH3 | −0.8  | −121.1  | 116  | 40723-63-5
Heptafluoronitrosopropane[20] | C3F7NO  | −0.7  |  | 199  | 354-72-3
1,1,1,2-Tetrafluoropropane  | CF3CHFCH3 | −1-0  |  | 116  | 421-48-7
1,1,2,2,3,3-Hexafluoropropane[3] | CHF2CF2CHF2 | −0.3  | −98.38  | 152  | 680-00-2
Butane | C4H10 | 0  | −140  | 58  | 106-97-8
2,2-Difluoropropane  | CH3CF2CH3 | 0  | −104.8  | 80  | 420-45-1
Perfluoroisobutane  | C4F10 | 0  |  | 238  | 354-92-7
Nitrosyl bromide | NOBr  | 0  | −56  | 110  | 13444-87-6
Xenon tetroxide | XeO4 | 0 dec  | −35.9  | 195  | 12340-14-6
Trifluoromethylsulfonyl hypofluorite[87] | CF3SO2OF  | 0  | −87  | 168  |
Trifluoromethyl chloroformate[88] | CF3OC(O)Cl  | 0  |  | 148.5  | 23213-83-4
Decafluorodiethyl ether[89] | CF3CF2OCF2CF3 | 0  |  | 254  | 358-21-4
Perfluorocyclobutanone[90] | -CF2CF2CF2C(O)-  | 0  |  | 178  | 699-35-4
Trifluoromethyl peroxonitrate[3] | CF3OONO2 | 0.4  |  | 147  | 50311-48-3
Thiazyl fluoride[91] | NSF  | 0.4  | −89  | 65.07  | 18820-63-8
Perfluorotetrahydrofuran  | -OCF2CF2CF2CF2\-  | 0.6  | −85  | 216  | 773-14-8
pentafluorotellurium hypofluorite[92] | F5TeOF  | 0.6  |  |  |
Tetrafluoro(trifluoromethylimino)-λ6-sulfane[93] | F4S=NCF3 | 0.75±0.25  |  | 191  |
trans-2-Butene  | CH3CH=CHCH3 | 0.9  | −43.3  | 56  | 624-64-6
Methylcyclopropane | CH3CHCH2CH2 | 1  | −177.2  | 56  | 594-11-6
Bis(trifluoromethyl)phosphine[94] | (CF3)2PH  | 1  |  | 170  | 460-96-8
Oxalyl fluoride[15] | CFOCFO  | 1±1  | −12.42  | 94  | 359-40-0
Methylstannane  | CH3SnH3 | 1.4  |  | 137  | 1631-78-3
Azomethane | CH3N=NCH3 | 1.5  | −78  | 58  | 503-28-6
1,1,2,3,3-Pentafluoropropene  | CF2=CFCHF2 | 1.5  | −101.2  | 132  | 433-66-9
Bromosilane  | SiH3Br  | 1.9  | −94  | 111  | 13465-73-1
Methylarsine  | CH3AsH2 | 2  | −143  | 92  | 593-52-2
Perfluorocyclobutene | (CF2)2(CF)2 | 2  | −60  | 162  | 697-11-0
Dichlorine monoxide | Cl2O  | 2.2  | −120.6  | 87  | 7791-21-1
Cyclobutene | C4H6 | 2.5  |  | 54  | 822-35-5
Difluorodimethylsilane  | (CH3)2SiF2 | 2.5  | −87.5  | 96  | 353-66-2
1,1,1-Trifluoroazomethane[3] | CF3NNCH3 | 2.5  |  | 112  | 690-21-1
dichorotrifluorophosphorane[28] | PCl2F3 | 2.5  | −124  | 159  | 13659-65-9
Trimethylamine | (CH3)3N  | 2.8  | −117.1  | 59  | 75-50-3
1,1-Dichloro-1,2,2,2-tetrafluoroethane  | CCl2FCF3 | 3  | −56.6  | 152  | 374-07-2
Sulfur bromide pentafluoride  | SBrF5 | 3.1  | −79  | 207  | 15607-89-3
1,1,2-Trifluoroethane | CHF2CH2F  | 3.5  | −84  | 84  | 430-66-0
1,2-Dichloro-1,1,2,2-tetrafluoroethane | CClF2CClF2 | 3.6  | −92.52  | 171  | 76-14-2
cis-2-Butene  | CH3CH=CHCH3 | 3.72  | −138.9  | 56  | 590-18-1
Phosphorus dihydride trifluoride[28] | PH2F3 | 3.9  | −52  | 90  |
Bromomethane | CH3Br  | 4  | −93.66  | 95  | 74-83-9
1,2-Dimethyldiborane | [(CH3)BH2]2 | 4  | −124.9  | 56  | 17156-88-6
Selenium chloride pentafluoride  | SeClF5 | 4.5  | −19  | 209.5  | 34979-62-9
1,1,4,4-Tetrafluoro-1,3-butadiene[95] | CF2=CFCF=CF2 | 4.5±  |  | 162  | 407-70-5
Trifluoromethyl phosphorodifluoridate[87] | CF3OP(O)F2 | 4.6  | −96.2  | 170  | 39125-43-4
Bromoacetylene  | C2HBr  | 4.7  |  | 105  | 593-61-3
Iodine heptafluoride | IF7 | 4.8  | 6.5 triple  | 250  | 16921-96-3
Dimethylchloroborane[3] | (CH3)2BCl  | 4.9  | −39.9  | 76.5  | 1803-36-7
Perfluoro-1-butene[3] | CF3CF2CF=CF2 | 5  |  | 200  | 357-26-6
Pentafluorosulfanyl cyanate[93][96] | F5SOCN  | 5-5.5  | −60  | 169  |
1,1,2,3,4,4-Hexafluoro-1,3-butadiene  | CF2CFCFCF2 | 5.4  | −132  | 162  | 685-63-2
Bis(difluoromethyl) ether  | CHF2OCHF2 | 5.5  |  | 118  | 1691-17-4
Methyl pentafluoroethyl ether  | CH3OC2F5 | 5.6  |  | 140  | 22410-44-2
Tris(difluoroamine)fluoromethane[3] | (NF2)3CF  | 5.6  | −136.9  | 187  | 14362-68-6
Perfluoro ethyl methyl ether  | C2F5OCF3 | 5.61  |  | 204  |
1-Bromo-2,2-difluoro-ethylene[97] | CHBr=CF2 | 5.7  |  | 143  |
Perfluoro-1,3-butadiene[98] | CF2=CFCF=CF2 | 5.8  | −132  | 162  | 685-63-2
Methanethiol[3] | CH3SH  | 5.95  | −123  | 48  | 74-93-1
Vinylacetylene | H2C=CH−C≡CH  | 6  |  | 54  | 689-97-4
Methoxyethane | CH3OC2H5 | 6  | −113  | 60  | 540-67-0
Methyl vinyl ether | CH3OCH=CH2 | 6  | −122  | 58  | 107-25-5
1,1,1-Trifluoro-2-chloroethane | CF3CH2Cl  | 6.1  | −105.5  | 118.5  | 75-88-7
1,1,1,2,3,3-Hexafluoropropane  | CF3CH2CF3 | 6.2  |  | 152  | 431-63-0
Phosphorothioic chloride difluoride | PSClF2 | 6.3  | −155.2  | 136.5  | 2524-02-9
Perfluoro-2-methoxypropionylfluoride[90] | CF3OCF(CF3)C(O)F  | 5-8  |  | 232  |
Trimethylsilane | (CH3)3SiH  | 6.7  | −153.9  | 74  | 993-07-7
Carbon suboxide | OCCCO  | 6.8  | −111.3  | 68  | 504-64-3
2-Chloropentafluoropropene[60] | CF3CCl=CF2 | 6.8  |  | 166.5  | 2804-50-4
dimethylgermane[99] | CH3GeH2CH3 | 7.0  |  | 104.72  | 1449-64-5
Perfluoroisobutene | (CF3)2C=CF2 | 7  | −130  | 200  | 382-21-8
Pentafluoroethyl trifluorovinyl ether  | CF3CF2OCFCF2 | 7  |  | 216  | 10493-43-3
1,1-Difluoropropane  | CHF2CH2CH3 | 7-8  |  | 80  | 430-61-5
1,1,1,2,4,4,4-Heptafluoro-2-butene[74] | CF3CF=CHCF3 | 7-8  |  | 182  |
Chloromethylsilane  | CH3ClSi  | 7  | −135  | 78.5  | 993-00-0
Fluoromethyldifluoroborane[100][101] | CH2FBF2 | 7  | −47  | 82  |
Nitryl cyanide[102] | NCNO2 | 7  | −85  | 72  | 105879-05-8
Silylgermane[103] | GeH3SiH3 | 7.0  | −119.7  | 107  | 13768-63-3
Phosphorus(V) dichloride trifluoride  | PCl2F3 | 7.1  | −125  | 159  | 13454-99-4
Sulfuryl chloride fluoride | SO2ClF  | 7.1  | −124.7  | 118.5  | 13637-84-8
Dimethylamine | (CH3)2NH  | 7.3  | −93  | 45  | 124-40-3
3-Chloropentafluoropropene[60] | CF2ClCF=CF2 | 7.4  |  | 166.5  | 79-47-0
Phosgene | COCl2 | 7.5  | −127.77  | 99  | 75-44-5
Chloropentafluoroacetone  | CClF2COCF3 | 7.8  | −133  | 182.5  | 79-53-8
1-Butyne | CH3CH2C≡CH  | 8.08  | −125.7  | 54  | 107-00-6
Dichlorosilane | SiH2Cl2 | 8.3  | −122  | 101  | 4109-96-0
trans-1,1,1,4,4,4-hexafluoro-2-butene[104] | CF3CH=CHCF3 | 8.5  |  | 164  | 407-60-3
2-Bromo-1,1,1,2-tetrafluoroethane[74] | CF3CHFBr  | 8.65  |  | 181  | 124-72-1
Methyl chlorosilane[3] | CH3SiH2Cl  | 8.7  | −134.1  | 80.5  | 993-00-0
SF5OCl  | 8.9  |  | 178.5  |
Dichlorofluoromethane | CHCl2F  | 8.92  | −135  | 103  | 75-43-4
ethylgermane[105] | CH3CH2GeH3 | 9.2  |  | 104.66  | 1747-99-5
Neopentane | (CH3)4C  | 9.5  | −16.5  | 72  | 463-82-1
Trifluoromethylperchlorate  | CF3OClO3 | 9.5  |  | 168.5  | 52003-45-9
1,3-Butadiyne  | HC≡CC≡CH  | 10  | −35  | 50  | 460-12-8
N-Nitroso-O,N-bis(trifluoromethyl)-hydroxylamine or
O-Nitroso-bis(trifluoromethy1)hydroxylamine[106][107] | CF3(CF3O)NNO or
(CF3)2NONO  | 10  |  | 198  | 367-54-4
Ethylene oxide | CH2OCH2 | 10.4  | −112.46  | 44  | 75-21-8
1,2-Difluoroethane[3] | CH2FCH2F  | 10.5  | −118.6  | 66  | 624-72-6
1,2-Butadiene | CH3CH=C=CH2 | 11  | −136.20  | 54  | 590-19-2
Dichloromethylborane  | CH3BCl2 | 11  |  | 97  | 7318-78-7
Chlorine dioxide | ClO2 | 11  | −59  | 67.5  | 10049-04-4
2-Chloro-2,3,3,3-tetrafluoropropanoyl fluoride[108] | CF3CFClC(O)F  | 11  |  | 182.5  | 28627-00-1
Methyl trifluorovinyl ether[109] | CH3OCF=CF2 | 11  |  | 112  | 3823-94-7
Trifluoromethyl hydroperoxide[3][110] | CF3OOH  | 11.3  |  | 102  | 16156-36-8
Methyl trifluoromethyl sulfide[84] | CH3SCF3 | 11.5  |  | 116  | 421-16-9
Chlorine trifluoride | ClF3 | 11.75  | −76.34  | 92.5  | 7790-91-2
1-bromoheptafluoropropane[83] | CF3CF2CF2Br  | 12  |  | 249  | 422-85-5
Tert-butyl fluoride[111] | (CH3)3CF  | 12  |  | 76  | 353-61-7
Bis(trifluoromethyl)diazomethane  | (CF3)2CN2 | 12  | −132  | 178.04  | 371-77-7
1,1,1,2,2,3,3,4,4-Nonafluorobutane[3] | CF3CF2CF2CF2H  | 12  |  | 220  | 375-17-7
2-Fluoro-2-methylpropane  | CH3(CH3)CFCH3 | 12.1  |  | 76  | 353-61-7
Trichlorofluorosilane | SiCl3F  | 12.25  |  | 153.5  | 14965-52-7
Chloroethane | CH3CH2Cl  | 12.27  | −138  | 64.5  | 75-00-3
Pentafluoroiodoethane[112] | CF3CF2I  | 12.5  | −92  | 246  | 354-64-3
Cyclobutane | C4H8 | 12.5  | −90.7  | 56  | 287-23-0
1,1-difluoro-N-(pentafluoro-λ6-sulfanyl)methanimine[93] | F5SN=CF2 | 12.5±0.5  |  | 191  |
2-diazo-1,1,1,3,3,3-hexafluoropropane[113] | (CF3)2CN2 | 12.5±0.5  |  | 178  | 684-23-1
Silylphosphine[114] | SiH3PH2 | 12.7  |  | 64  | 14616-47-8
Cyanogen chloride | ClCN  | 13  | −6.55  | 61.5  | 506-77-4
trans-1-Bromo-1,2-difluoroethylene[97] | CBrF=CFH  | 13  |  | 143  | 358-99-6
Trifluoromethyl phosphine[3] | CF3PH2 | 13.1  |  | 102  | 420-52-0
2,2,2-Trifluorodiazoethane[115] | CF3CHNN  | 13.2  |  | 91  | 371-67-5
2-Chloro-1,1,1,2-tetrafluoropropane HCFC-244bb[116] | CF3CClFCH3 | 13.23  |  | 150.5  | 421-73-8
Pentafluoroethyl sulfur pentafluoride[117] | C2F5SF5 | 13.5  |  | 246  |
Phosphorus(III) dichloride fluoride  | PCl2F  | 13.85  | −144  | 121  | 15597-63-4
2-Chloro-1,1,1,3,3,3-hexafluoropropane[60] | CF3CHClCF3 | 14  | −120.8  | 186.5  | 51346-64-6
2-Chloro-3,3,3-trifluoroprop-1-ene[79] | CH2=CClCF3 | 14  |  | 130.5  | 2730-62-3
2-(Pentafluorothio)-3,3-difluorooxaziridine[118] | SF5(-NCF2O-)  | 14.0  |  | 207  | 73002-62-7
Difluoro(difluorochloromethyl)amine  | CClF2NF2 | 14.14  |  | 137.5  | 13880-71-2
Nitrosyl bromide | ONBr  | 14.5  |  | 110  | 13444-87-6
Hexafluoroisobutylene[3] | (CF3)2C=CH2 | 14.5  |  | 164  | 382-10-5
N,N-Difluoroethylamine[62] | CH3CH2NF2 | 14.9  | −150.3  | 81  | 758-18-9
Disulfur difluoride | FSSF  | 15  | −133  | 102  | 13709-35-8
cis-1-Chloro-2-fluoroethene[79] | CHCl=CHF  | 15  |  | 80.5  | 2268-31-7
(Z)-1-chloro-2,3,3,3-tetrafluoropropene[79] | CHCl=CFCF3 | 15  |  | 148.5  | 111512-60-8
1,1,1,3,3-Pentafluoropropane[3] | CF3CH2CHF2 | 15.14  | −102.10  | 134  | 460-73-1
Trifluoromethyl phosphorodifluoroperoxoate[87] | CF3OOP(O)F2 | 15.5  | −88.6  | 167  | 39125-42-3
(Trifluoroacetyl)sulfur pentafluoride[68] | CF3C(O)SF5 | 15.6  | −112  | 224  | 82390-51-0
Vinyl bromide | CH2=CHBr  | 15.8  | −137.8  | 107  | 593-60-2
Bis(fluorocarbonyl) peroxide[119][15] | CF(O)OOCFO  | 15.9  | −42.5  | 126  | 692-74-0
1-Chloro-1,1,2-trifluoroethane  | CClF2CH2F  | 16  |  | 118.5  | 421-04-5
cis-1-Bromo-1,2-difluoroethylene[97] | CBrF=CHF  | 16  |  | 143  |
1-Fluoro-2-methylpropane[111] | CH2FCHCH3CH3 | 16  |  | 76  | 359-00-2
Difluoromethyl 1,1,2-trifluoroethyl ether  | CHF2OCF2CH2F  | 16.14  |  | 150  | 69948-24-9
1-Chloro-1-fluoroethane[3] | CHClFCH3 | 16.15  |  | 82.5  | 1615-75-4
Fluorotrimethylsilane  | (CH3)3SiF  | 16.4  | −74.3  | 92  | 420-56-4
Bis(trifluoromethyl)nitramine[71] | (CF3)2NNO2 | 16.4  |  | 198  |
Hexafluoroacetone imine[120] | CF3C(=NH)CF3 | 16.5±  | −47  | 165  | 1645-75-6
Dichloro(trifluoromethyl)amine[3] | CF3NCl2 | 16.6  |  | 154  | 13880-73-4
Ethylamine | CH3CH2NH2 | 16.6  | −81  | 45  | 75-04-7
1,1,1-Trifluorobutane[121] | CF3CH2CH2CH3 | 16.74  | −114.79  | 112  | 460-34-4
Bismuthine | BiH3 | 17  | −67  | 212  | 18288-22-7
2,2,3,3-Tetrafluorobutane[74] | CH3CF2CF2CH3 | 17  |  | 130  | 421-74-9
tris(trifluoromethyl)phosphine[122] | (CF3)3P  | 17  |  | 238  | 432-04-2
Tungsten hexafluoride | WF6 | 17.1  | 1.9  | 294  | 7783-82-6
1-Chloro-1,2,2-trifluoroethane  | CHClFCHF2 | 17.3  |  | 99.5  | 431-07-2
Ethyl nitrite | C2H5NO2 | 17.5  |  | 75  | 109-95-5
Tetraborane(10)  | B4H10 | 18  | −120  | 54  | 18283-93-7
trifluoro-(sulfinylamino)methane[123] | CF3N=S=O  | 18  |  | 131  | 10564-49-5
F-2,3-dihydro-1,4-dioxin[124] (2,2,3,3,5,6-Hexafluoro-2,3-dihydro-1,4-dioxine)  | -CF2CF2OCF=CFO-  | 18.5  |  | 158  | 56625-38-8
Bromofluoromethane | CH2BrF  | 19 (CRC=23)  |  | 113  | 373-52-4
Bis(trifluoromethyl)arsine[65] | (CF3)2AsH  | 19  |  | 214  |
1,1-Dichloro-2,2-difluoroethene  | CCl2=CF2 | 19  | −116  | 135  | 79-35-6
Perfluorovinylsulphur pentafluoride[125] | CF2=CFSF5 | 19  |  | 208  | 1186-51-2
Difluorotris(trifluoromethyl)phosphorane[122] | (CF3)3PF2 | 19  |  | 276  | 661-45-0
trans-1-Chloro-3,3,3-trifluoropropene[79] | CHCl=CHCF3 | 19  |  | 130.5  | 102687-65-0
Fluoroformic acid anhydride[126] | FC(O)OC(O)F  | 19.2  | −46.2  | 110  | 177036-04-3
Trifluorovinyl isocyanate[127] | CF2=CFNCO  | 19.5  |  | 123  | 41594-57-4
Hydrogen fluoride | HF  | 20  | −83.36  | 20  | 7664-39-3
Bis(trifluoromethyl)carbamoyl fluoride  | (CF3)2NC(O)F  | 20  |  | 199.03  | 359-54-6
Bromine monofluoride | BrF  | 20 dec  | −33  | 99  | 13863-59-7
Perbromyl fluoride | BrO3F  | 20 dec  | −110  | 147  | 25251-03-0
1-Chloro-1,1,2,2-tetrafluoropropane[128] | CF2ClCF2CH3 | 20  |  | 150.5  | 421-75-0
Perfluorooxaspiro[2.3]hexane[90] | C5F8O  | 18-21  |  | 228  |
pentafluoroethylsulfinyl fluoride[73] | C2F5S(O)F  | 20  |  | 186  | 20621-31-2
3-Methyl-1-butene  | CH2=CHCH(CH3)2 | 20.1  | −168.41  | 70  | 563-45-1
Acetaldehyde | CH3CHO  | 20.2  | −123.37  | 44  | 75-07-0
Chlorotetrafluoro(trifluoromethyl)sulfur  | CF3SClF4 | 20.2  |  | 212.5  | 42179-04-4
trans-Bis(trifluoromethyl)sulfur tetrafluoride[129] | CF3SF4CF3 | 20.5  |  | 246  | 42179-02-2
1,1-Dimethylcyclopropane  | (CH3)2CCH2CH2 | 21  | −109.0  | 70  | 1630-94-0
Acetyl fluoride  | CH3C(O)F  | 21  | −84  | 62  | 557-99-3
Perfluoro-N-methyloxazolidine  | CF3-NCF2OCF2CF2\-  | 21  |  | 237  |
Bis(trifluoromethyl)cyanoamine[71] | (CF3)2NCN  | 21  |  | 178  |
Bis(trifluoromethyl)sulfur difluoride[84] | (CF3)2SF2 | 21  |  | 198  | 30341-38-9
Methaneselenol[130] | CH3SeH  | 21  |  | 95  | 6486-05-1
Perfluoroethyldimethylamine[34] | C2F5(CF3)2N  | 21±1  |  | 271  | 815-28-1
cis-1,2-Dichloro-1,2-difluoroethene  | CClF=CClF  | 21.1  | −119.6  | 133  | 598-88-9
Trifluoromethyl trifluoromethanesulfonate[131] | CF3SO2OCF3 | 21.2  | −108.2  | 218  | 3582-05-6
Nitrogen dioxide | NO2 | 21.15  | −9.3  | 46  | 10102-44-0
Difluoroiodomethane | CHF2I  | 21.5  | −122  | 178  | 1493-03-4
Trifluoromethylcyclopropane[54] | C3H5CF3 | 21.6  |  | 110  | 381-74-8
1,1,1-Trifluoroacetone  | CF3C(O)CH3 | 21.9  | −78  | 112  | 421-50-1
trans-1,2-Dichloro-1,2-difluoroethene  | CClF=CClF  | 22  | −93.3  | 133  | 27156-03-2
Heptafluoroisopropyl hypochlorite[67] | (CF3)2CFOCl  | 22  |  | 220.5  | 22675-68-9
Perfluoroazoethane[36] | C2F5N=NC2F5 | 22  |  | 266  |
1,2,2-Trifluoropropane[132] | CH2FCF2CH3 | 22  |  | 98  | 811-94-9
Bis(trifluoromethyl)bromamine[71] | (CF3)2NBr  | 22  |  | 232  |
Perfluorocyclopentane  | CF2CF2CF2CF2CF2 | 22.5  | −80  | 250.04  | 376-77-2
Bis(trifluoromethyl)tellurium[133] | (CF3)2Te  | 22.5  | −123  |  | 55642-42-7
1,1,1,3,3-Pentafluorobutane  | CF3CH3CF2CH3 | 22.6  | −34.1  | 149  | 406-58-6
octafluoro-1,4-dioxane[134] | (-CF2CF2OCF2CF2O-)  | 22.75±0.25  |  | 232  | 32981-22-9
Cyanic acid  | HNCO  | 23  | −86  | 43  | 420-05-3
2-Chloropropene | CH3CCl=CH2 | 23  | −137.4  | 76.5  | 557-98-2
1,2,2,2-Tetrafluoroethyl difluoromethyl ether  | CF3CHFOCHF2 | 23  |  | 168  | 57041-67-5
1,1,1,2,3-Pentafluoropropane[135] | CF3CHFCH2F  | 23  |  | 134  | 431-31-2
2,2,3,3,4,4,5-Heptafluoro oxolane[136] | -CF2CF2CF2CHFO-  | 23  |  | 179  |
Pentafluoroethyl iminosulfur difluoride[75] | CF3CF2N=SF2 | 23±1  |  | 203  |
Methoxyacetylene[137] | CH3OC≡CH  | 23±0.5  |  | 56  | 6443-91-0
Carbonyl fluoride iodide  | COFI  | 23.4  |  | 174  | 1495-48-3
1,2,2,2-Tetrafluoroethyl difluoromethyl ether[3] | CF3CHFOCHF2 | 23.4  |  | 168  | 57041-67-5
Propylsilane[63] | CH3CH2CH2SiH3 | 23.5±  |  | 78  | 13154-66-0
Trichlorofluoromethane | CCl3F  | 23.77  | −110.48  | 137.5  | 75-69-4
1-Chloro-1,3,3,3-tetrafluoropropene[60] | CF3CH=CFCl  | 24  |  | 148.5  | 460-71-9
1,1,2,2-Tetrafluoro-1-nitro-2-nitrosoethane[138] | NO2CF2CF2NO  | 24.2  |  | 176  | 679-08-3
Germyl methyl ether[139] | GeH3OCH3 | 24.3  |  | 107  | 5910-93-0
Dibromodifluoromethane[3] | CBr2F2 | 24.45  | −141.5  | 210  | 75-61-6
Heptafluoro-N-propyl isocyanate[20] | C3F7NCO  | 24.5  |  | 211  | 87050-96-2
Trifluoromethyl fluoroacetate  | FCH2COOCF3 | 24.5  |  | 146.04  | 425-24-1
1,1,1,4,4,4-Hexafluorobutane[140] | CF3CH2CH2CF3 | 24.6  |  | 166  | 407-59-0
Chloroheptafluorocyclobutane  | C4ClF7 | 25  | −39.1  | 216.5  | 377-41-3
Dimethylphosphine | (CH3)2PH  | 25  |  | 62  | 676-59-5
Ethyl phosphine[141] | CH3CH2PH2 | 25  |  | 62  | 593-68-0
Perfluorocyclopentene[142] | (CF2)3(CF)2 | 25  |  | 212  | 559-40-0
2-Fluorobutane[143] | CH3CHFCH2CH3 | 25  | −121  | 76  | 359-01-3

Number of entries: Script error: No such module "Table row counter".

## Known as gas

The following list has substances known to be gases, but with an unknown boiling point.

* Fluoroamine
* Trifluoromethyl trifluoroethyl trioxide CF3OOOCF2CF3 boils between 10 and 20°[144]
* Bis-trifluoromethyl carbonate boils between −10 and +10°[37] possibly +12, freezing −60°[145]
* Difluoroaminosulfinyl fluoride F2NS(O)F is a gas but decomposes over several hours[146]
* Trifluoromethylsulfinyl chloride CF3S(O)Cl[73]
* Nitrosyl cyanide ?−20° blue-green gas 4343-68-4[147]
* Thiazyl chloride NSCl greenish yellow gas; trimerises.[91]

## Possible

This list includes substances that may be gases. However reliable references are not available.

* cis-1-Fluoro-1-propene
* trans-1-Chloropropene ?
* cis-1-Chloropropene ?
* Perfluoro-1,2-butadiene[148]
* Perfluoro-1,2,3-butatriene −5[149] polymerizes[150]
* Perfluoropent-2-ene
* Perfluoropent-1-ene 29-30°[151]
* Trifluoromethanesulfenylfluoride CF3SF
* N-Sulfinyltrifluoromethaneamine CF3NSO 18°
* (Chlorofluoromethyl)silane 373-67-1 274.37 K (1.22 °C)[3]
* Difluoromethylsilane 420-34-8 237.56 K (−35.59 °C)[3]
* Trifluoromethyl sulfenic trifloromethyl ester[152]
* Pentafluoro(penta-fluorethoxy)sulfur 900001-56-6 15°
* Ethenol 557-75-5 10.5° = vinyl alcohol (tautomerizes)
* 1,1,1,2,2,3,4,4,4-nonafluorobutane 2-10° melt −129°[60]
* trans-2H-Heptafluoro-2-butene
* Pentafluoroethylhypochlorite around −10°[67]
* Trifluoromethyl pentafluoroethyl sulfide 6° 33547-10-3 [3]
* 1,1,1-Trifluoro-N-(trifluoromethoxy)methanamine 671-63-6 0.6°[3]
* 1-Chloro-1,1,2,2,3,3-hexafluoropropane 422-55-9 16.7[3]
* 1-Chloro-1,1,2,3,3,3-hexafluoropropane 359-58-0 17.15[3]
* 2-Chloro-1,1,1,2,3,3-hexafluoropropane 51346-64-6 16.7°[3]
* 3-Chloro-1,1,1,2,2,3-hexafluoropropane 422-57-1 16.7°[3]
* Trifluormethyl 1,2,2,2-tetrafluoroethyl ether 2356-62-9 11°[3]
* 2-Chloro-1,1,1,3,3-pentafluoropropane HFC-235da 134251-06-2 8°[3]
* 1,1,2,3,3-Pentafluoropropane 24270-66-4 −3.77
* 2,2,3,3,4,5,5-Heptafluoro oxolane[136]
* (Heptafluoropropyl)carbonimidic difluoride 378-00-7
* Pentafluoroethyl carbonimidic difluoride 428-71-7
* (Trifluoromethyl)carbonimidic difluoride 371-71-1 CF3N=CF2
* Perfluoro[N-methyl-(propylenamine)] 680-23-9
* Perfluoro-N,N-dimethylvinylamine 13821-49-3
* 3,3,4-Trifluoro-2,4-bis-trifluoromethyl-[1,2]oxazetidine 714-52-3
* Bis(trifluoromethyl) 2,2-difluoro-vinylamine 13747-23-4
* Bis(trifluoromethyl) 1,2-difluoro-vinylamine 13747-24-5
* 1,1,2-Trifluoro-3-(trifluoromethyl)cyclopropane 2967-53-5
* Bis(trifluoromethyl) 2-fluoro-vinylamine 25211-47-6
* 2-Fluoro-1,3-butadiene 381-61-3
* Trifluormethylcyclopropane 381-74-8
* cis-1-Fluoro-1-butene 66675-34-1
* trans-1-Fluoro-1-butene 66675-35-2
* 2-Fluoro-1-butene
* 3-Fluoro-1-butene
* trans-1-Fluoro-2-butene
* cis-2-fluoro-2-butene
* trans-2-fluoro-2-butene
* 1-Fluoro-2-methyl-1-propene
* 3-Fluoro-2-methyl-1-propene
* Perfluoro-2-methyl-1,3-butadiene 384-04-3
* 1,1,3,4,4,5,5,5-Octafluoro-1,2-pentadiene 21972-01-0

## Near misses

This list includes substances that boil just above standard condition temperatures. Numbers are boiling temperatures in °C.

* 1,1,2,2,3-Pentafluoropropane 25–26 °C[153][3]
* Dimethoxyborane 25.9 °C
* 1,4-Pentadiene 25.9 °C
* 2-Bromo-1,1,1-trifluoroethane 26 °C
* 1,2-Difluoroethane 26 °C
* Hydrogen cyanide 26 °C
* Trimethylgermane 26.2 °C[99]
* 1,H-Pentafluorocyclobut-1-ene[142]
* 1,H:2,H-hexafluorocyclobutane[142]
* Tetramethylsilane 26.7 °C
* Chlorosyl trifluoride 27 °C
* 2,2-Dichloro-1,1,1-trifluoroethane 27.8 °C
* Perfluoroethyl 2,2,2-trifluoroethyl ether 27.89 °C
* Perfluoroethyl ethyl ether 28 °C
* Perfluorocyclopentadiene C5F6 28 °C[154]
* 2-Butyne 29 °C
* Digermane 29 °C
* Perfluoroisopropyl methyl ether 29 °C
* Trifluoromethanesulfonyl chloride 29–32 °C[155]
* Perfluoropentane 29.2 °C
* Rhenium(VI) fluoride 33.8 °C
* Chlorodimethylsilane 34.7 °C
* Dimethylarsine 36 °C
* Polonium hydride 36.1 °C[156]
* Spiro[2.2]pentane 39 °C
* Ruthenium(VIII) oxide 40 °C
* 1,3-Difluoropropane 40-42 °C
* Nickel carbonyl 42.1 °C
* 1,2-Difluoropropane 43 °C
* Trimethylphosphine 43 °C

## Unstable substances

* Gallane liquid decomposes at 0 °C.
* Nitroxyl and diazene are simple nitrogen compounds known to be gases but they are too unstable and short lived to be condensed.
* Methanetellurol CH3TeH 25284-83-7 unstable at room temperature.[157]
* Sulfur pentafluoride isocyanide isomerises to sulfur pentafluoride cyanide.[158]

## References

* Template:CRC96

1. ↑ PubChem. "Deuterium" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/24523.
2. ↑ PubChem. "Tritium" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/24824.
3. ↑ 3.00 3.01 3.02 3.03 3.04 3.05 3.06 3.07 3.08 3.09 3.10 3.11 3.12 3.13 3.14 3.15 3.16 3.17 3.18 3.19 3.20 3.21 3.22 3.23 3.24 3.25 3.26 3.27 3.28 3.29 3.30 3.31 3.32 3.33 3.34 3.35 3.36 3.37 3.38 3.39 3.40 3.41 3.42 3.43 3.44 3.45 3.46 3.47 3.48 3.49 3.50 3.51 Yaws, Carl L. (2015) (in en). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics. Gulf Professional Publishing. p. 3. ISBN 9780128011461. https://books.google.com/books?id=GutDBAAAQBAJ&pg=PA4.
4. ↑ Journal of Heterocyclic Chemistry. - 1964. - Vol. 1, No. 1. - pp. 59-60
5. ↑ Russo, Antonio; DesMarteau, Darryl D. (June 1993). "Difluorodioxirane". Angewandte Chemie International Edition in English 32 (6): 905–907. doi:10.1002/anie.199309051.
6. ↑ Corbridge, D. E. C. (2016) (in en). Phosphorus: Chemistry, Biochemistry and Technology, Sixth Edition. CRC Press. p. 1265. ISBN 9781439840894. https://books.google.com/books?id=YWzRBQAAQBAJ&pg=PA1263.
7. ↑ DesMarteau, Darryl D. (January 1972). "Fluoroperoxytrifluoromethane, CF3OOF. Preparation from trifluoromethyl hydroperoxide and fluorine in the presence of cesium fluoride". Inorganic Chemistry 11 (1): 193–195. doi:10.1021/ic50107a047.
8. ↑ Journal of Fluorine Chemistry. - 2013. - Vol. 155. - pp. 29-31 full citation needed
9. ↑ & Warnell, Joseph Leo"époxydes fluoro-carbonés" FR patent 1322597A, issued 1963-03-29
10. ↑ Downs, A. J. (1962). "846. Thiocarbonyl fluoride". Journal of the Chemical Society (Resumed): 4361. doi:10.1039/JR9620004361.
11. ↑ Meyers, M. D.; Frank, S. (August 1966). "Difluorocyanamide". Inorganic Chemistry 5 (8): 1455–1457. doi:10.1021/ic50042a040.
12. ↑ "Trifluoroacetyl fluoride" (in en). https://webbook.nist.gov/cgi/cbook.cgi?ID=C354347&Mask=4.
13. ↑ Advances in Inorganic Chemistry and Radiochemistry. - 1961. - Vol. 3. - p. 406
14. ↑ Shreeve, Jean'ne M.; Duncan, Leonard Clinton; Cady, George H. (October 1965). "Difluoroaminooxyperfluoromethane, CF3ONF2". Inorganic Chemistry 4 (10): 1516–1517. doi:10.1021/ic50032a045.
15. ↑ 15.0 15.1 15.2 Stephenson, Richard Montgomery (2012) (in en). Handbook of the Thermodynamics of Organic Compounds. Springer Science & Business Media. p. 7. ISBN 9789400931732. https://books.google.com/books?id=X9PsCAAAQBAJ&pg=PA7.
16. ↑ Fraser, George W.; Shreeve, Jean'ne M. (October 1965). "Difluoraminocarbonyl Fluoride". Inorganic Chemistry 4 (10): 1497–1498. doi:10.1021/ic50032a034.
17. ↑ Landolt-Bornstein Numerical Data and Functional Relationships in Science and Technology. Group IV, Volume 20: Vapor Pressure of Chemicals. Subvolume A: Vapor Pressure and Antoine Constants for Hydrocarbons, and Sulfur, Selenium, Tellurium, and Halogen Containing Organic Compounds. - 1999. - p. 197
18. ↑ Journal of the American Chemical Society. - 1965. - Vol. 87, No. 2. - pp. 231-233
19. ↑ Advances in Inorganic Chemistry and Radiochemistry. - 1961. - Vol. 3. - p. 226
20. ↑ 20.0 20.1 20.2 Barr, D. A.; Haszeldine, R. N. (1956). "663. Perfluoroalkyl derivatives of nitrogen. Part III. Heptafluoronitrosopropane, perfluoro-2-n-propyl-1 : 2-oxazetidine, perfluoro-(methylene-n-propylamine), and related compounds". Journal of the Chemical Society (Resumed): 3416. doi:10.1039/JR9560003416.
21. ↑ (in en) Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 18: Four Carbon-Heteroatom Bonds. Georg Thieme Verlag. 2014. p. 1147. ISBN 9783131719119. https://books.google.com/books?id=Kh-GAwAAQBAJ&pg=PA1147.
22. ↑ Bivens D.B., Minor B.H. Fluoroethers and other next generation fluids / International Journal of Refrigeration. - 1998. - Vol. 21, No. 7. - p. 570
23. ↑ Advances in Inorganic Chemistry and Radiochemistry. - 1970. - Vol. 13. - p. 368
24. ↑ Bivens D.B., Minor B.H. Fluoroethers and other next generation fluids / International Journal of Refrigeration. - 1998. - Vol. 21, No. 7. - p. 569
25. ↑ Inorganic Chemistry. - 1972. - Vol. 11, No. 6. - p. 1259-1264
26. ↑ Ruff, O.; Giese, M. (4 March 1936). "Die Fluorierung des Silbercyanids. (I.)" (in de). Berichte der Deutschen Chemischen Gesellschaft (A and B Series) 69 (3): 598–603. doi:10.1002/cber.19360690325.
27. ↑ Inorganic Chemistry. - 1963. - Vol. 2, No. 1. - p. 230
28. ↑ 28.0 28.1 28.2 Holmes, Robert R.; Storey, Raymond N. (December 1966). "Pentacoordinated Molecules. VIII. Preparation and Nuclear Magnetic Resonance Study of PH2F3 and PHF4". Inorganic Chemistry 5 (12): 2146–2150. doi:10.1021/ic50046a015.
29. ↑ Journal of the American Chemical Society. - 1960. - Vol. 82, No. 24. - p. 6219
30. ↑ Journal of the American Chemical Society. - 1959. - Vol. 81, No. 3. - p. 607
31. ↑ Bivens D.B., Minor B.H. Fluoroethers and other next generation fluids / International Journal of Refrigeration. - 1998. - Vol. 21, No. 7. - p. 568
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35. ↑ Aymonino, P. J. (1965). "Trifluoromethyl fluoroformate". Chemical Communications (12): 241. doi:10.1039/C19650000241.
36. ↑ 36.0 36.1 Chambers, W. J.; Tullock, C. W.; Coffman, D. D. (June 1962). "The Synthesis and Chemistry of Fluoroazoalkanes". Journal of the American Chemical Society 84 (12): 2337–2343. doi:10.1021/ja00871a014. Bibcode: 1962JAChS..84.2337C.
37. ↑ 37.0 37.1 US Patent 3226418
38. ↑ Atkinson, B. (1952). "508. The mercury-photosensitised reactions of tetrafluoroethylene" (in en). Journal of the Chemical Society (Resumed): 2684–2694. doi:10.1039/jr9520002684. ISSN 0368-1769. http://xlink.rsc.org/?DOI=jr9520002684.
39. ↑ HAUPTFLEISCH, John O. (2009). "SYNTHESIS OF TRIFLUORONITROMETHANE, CF3NO2: PHOTOCHEMICAL SCALE-UP AND A NEW THERMOGENERATION METHOD WITH A REFINED PURIFICATION TECHNIQUE". University of Alabama. p. 28. https://ir.ua.edu/bitstream/handle/123456789/694/file_1.pdf?sequence=1&isAllowed=y.
40. ↑ Dresdner, R. D; Merritt, Jack; Royal, Joyce P. (August 1965). "Photochemical Fluorinations of C2N2 and RfN=-SF2 with N2F4". Inorganic Chemistry 4 (8): 1228–1230. doi:10.1021/ic50030a033.
41. ↑ Bohon, Robert L. (1 December 1969). "Separation of Tris(difluoroamino)fluoromethane and Bis(difluoroamino)fluoromethane with Crystalline Zeolites". Industrial & Engineering Chemistry Product Research and Development 8 (4): 443–445. doi:10.1021/i360032a024.
42. ↑ Macintyre, Jane E. (1992-07-23) (in en). Dictionary of Inorganic Compounds. CRC Press. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Fluorine+fluorosulfate&pg=PA3156.
43. ↑ Gholivand, Khodayar; Schatte, Gabriele; Willner, Helge (1987-07-01). "Properties of triazadienyl fluoride, N3F". Inorganic Chemistry 26 (13): 2137–2140. doi:10.1021/ic00260a025. ISSN 0020-1669.
44. ↑ Fedele, Laura; Bobbo, Sergio; Groppo, Fabio; Brown, J. Steven; Zilio, Claudio (12 May 2011). "Saturated Pressure Measurements of 2,3,3,3-Tetrafluoroprop-1-ene (R1234yf) for Reduced Temperatures Ranging from 0.67 to 0.93". Journal of Chemical & Engineering Data 56 (5): 2608–2612. doi:10.1021/je2000952.
45. ↑ Emeléus, H. J. (2013) (in en). The Chemistry of Fluorine and Its Compounds. Elsevier. p. 25. ISBN 9781483273044. https://books.google.com/books?id=9SkSBQAAQBAJ&pg=PA25.
46. ↑ Smith, James Everett; Cady, George H. (June 1970). "Reactions of fluoroxypentafluoroselenium". Inorganic Chemistry 9 (6): 1442–1445. doi:10.1021/ic50088a029.
47. ↑ Mitra, Grihapati; Cady, George H. (June 1959). "Preparation and Properties of Pentafluoroselenium Hypofluorite (F 5 SeOF) and Bis-(pentafluoroselenium) Peroxide (F 5 SeOOSeF 5 )" (in en). Journal of the American Chemical Society 81 (11): 2646–2648. doi:10.1021/ja01520a012. ISSN 0002-7863. Bibcode: 1959JAChS..81.2646M. https://pubs.acs.org/doi/abs/10.1021/ja01520a012.
48. ↑ Blackley, W. D.; Reinhard, R. R. (February 1965). "A New Stable Radical, Bis(trifluoromethyl) Nitroxide". Journal of the American Chemical Society 87 (4): 802–805. doi:10.1021/ja01082a019. Bibcode: 1965JAChS..87..802B.
49. ↑ Lösking, Oliver; Willner, Helge (September 1989). "Sulfur Cyanide Pentafluoride SF5CN". Angewandte Chemie International Edition in English 28 (9): 1255–1256. doi:10.1002/anie.198912551.
50. ↑ "Cyanopentafluorosulfur (CF5NS)". Landolt-Börnstein Substance/Property Index. https://lb.chemie.uni-hamburg.de/static/RN/1_1489-60-7 ... 1518-72-5.php?content=116/KW9HikLm.
51. ↑ 51.0 51.1 Haynes, W. M. (2014) (in en). CRC Handbook of Chemistry and Physics 95ed. CRC Press. ISBN 97814822-08689. https://books.google.com/books?id=bNDMBQAAQBAJ.
52. ↑ Griffin, C. E.; Haszeldine, R. N. (1960). "279. Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers". Journal of the Chemical Society (Resumed): 1398. doi:10.1039/JR9600001398.
53. ↑ Template:CRC96
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55. ↑ Wold, Aaron; Ruff, John K. (2009) (in en). Inorganic Syntheses Volume 14. John Wiley & Sons. p. 45. ISBN 9780470132807. https://books.google.com/books?id=m751CWmh0zEC&pg=PA45.
56. ↑ 56.0 56.1 Salvi-Narkhede, M.; Wang, Bao-Huai; Adcock, James L.; Alexander Van Hook, W. (October 1992). "Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2OCF2OCF2, and c-CF2CF2CF2O), and of CHF2Br and CF3CFHCF3" (in en). The Journal of Chemical Thermodynamics 24 (10): 1065–1075. doi:10.1016/S0021-9614(05)80017-5.
57. ↑ Lin, Peter (2003-04-15), John Wiley & Sons, Ltd, ed. (in en), Trifluoroacetaldehyde, Chichester, UK: John Wiley & Sons, Ltd, doi:10.1002/047084289x.rn00213, ISBN 978-0-471-93623-7, https://onlinelibrary.wiley.com/doi/10.1002/047084289X.rn00213, retrieved 2023-11-26
58. ↑ "2-Chloro-1,1-difluoroethene | C2HClF2 | ChemSpider". http://www.chemspider.com/Chemical-Structure.9283.html.
59. ↑ Logothetis, A. L.; Sausen, G. N.; Shozda, R. J. (February 1963). "The Preparation of Difluoroamino Sulfur Pentafluoride". Inorganic Chemistry 2 (1): 173–175. doi:10.1021/ic50005a044.
60. ↑ 60.0 60.1 60.2 60.3 60.4 60.5 Miller, William T.; Fried, John H.; Goldwhite, Harold (June 1960). "Substitution and Addition Reactions of the Fluoroölefins. IV. Reactions of Fluoride Ion with Fluoroölefins". Journal of the American Chemical Society 82 (12): 3091–3099. doi:10.1021/ja01497a028. Bibcode: 1960JAChS..82.3091M.
61. ↑ Advances in Inorganic Chemistry and Radiochemistry. - 1974. - Vol. 16. - p. 168
62. ↑ 62.0 62.1 Frazer, J.W. (November 1960). "Preparation of N,N-difluoromethylamine and N,N-difluoroethylamine". Journal of Inorganic and Nuclear Chemistry 16 (1–2): 63–66. doi:10.1016/0022-1902(60)80088-7.
63. ↑ 63.0 63.1 Griffiths, S.T.; Wilson, R.R. (September 1958). "The spontaneous ignition of alkyl silanes". Combustion and Flame 2 (3): 244–252. doi:10.1016/0010-2180(58)90045-2. Bibcode: 1958CoFl....2..244G.
64. ↑ 64.0 64.1 Sargeant, Peter B.; Krespan, Carl G. (January 1969). "Fluorocyclopropanes. II. Synthesis, properties, and reactions of perfluorocyclopropene" (in en). Journal of the American Chemical Society 91 (2): 415–419. doi:10.1021/ja01030a035. ISSN 0002-7863. Bibcode: 1969JAChS..91..415S. https://pubs.acs.org/doi/abs/10.1021/ja01030a035.
65. ↑ 65.0 65.1 Dictionary of organometallic compounds. - 2nd supplement. - Chapman and Hall Ltd, 1986. - p. 19
66. ↑ Duncan, Leonard C.; Cady, George H. (June 1964). "The Preparation and Properties of Trifluoromethoxy Sulfur Pentafluoride [CF3OSF5] and cis-Bis(trifluoromethoxy)tetrafluorosulfur(VI) [(CF3O)2SF4]". Inorganic Chemistry 3 (6): 850–852. doi:10.1021/ic50016a015.
67. ↑ 67.0 67.1 67.2 Gould, Douglas E.; Anderson, Lowell Ray; Young, David Edward; Fox, William B. (March 1969). "Perhaloalkyl hypochlorites and pentafluorosulfur hypochlorite. I. Preparation and properties". Journal of the American Chemical Society 91 (6): 1310–1313. doi:10.1021/ja01034a008. Bibcode: 1969JAChS..91.1310G.
68. ↑ 68.0 68.1 De Marco, Ronald A.; Fox, W. B. (September 1982). "(Trifluoroacetyl)sulfur pentafluoride". The Journal of Organic Chemistry 47 (19): 3772–3773. doi:10.1021/jo00140a039.
69. ↑ Anderson, Lowell Ray; Fox, William B. (September 1970). "New preparation for trifluoromethyl fluoroformyl peroxide and bis(trifluoromethyl) trioxide". Inorganic Chemistry 9 (9): 2182–2183. doi:10.1021/ic50091a045.
70. ↑ UNITED STATES PATENT 2,617,817 PERFLUOROALKYL ISOCYANATES Arthur H. Ahlbrecht, 11 November 1952
71. ↑ 71.0 71.1 71.2 71.3 Ang, H. G.; Syn, Y. C. (1974) (in en). Advances in Inorganic Chemistry and Radiochemistry. Academic Press. ISBN 9780080578651. https://books.google.com/books?id=qi0vujzNSz4C&pg=PA8.
72. ↑ Emeléus, H. J.; Heal, H. G. (1949). "363. The ethoxyfluorosilanes". J. Chem. Soc.: 1696–1699. doi:10.1039/JR9490001696.
73. ↑ 73.0 73.1 73.2 73.3 Ratcliffe, Charles T.; Shreeve, Jean'ne M. (September 1968). "Some perfluoroalkylsulfinyl halides. New preparations of trifluoromethylsulfur trifluoride". Journal of the American Chemical Society 90 (20): 5403–5408. doi:10.1021/ja01022a013. Bibcode: 1968JAChS..90.5403R.
74. ↑ 74.0 74.1 74.2 74.3 Burns, T. H. S.; Bracken, A. (1972). "Exploratory and Newer Compounds" (in en). Modern Inhalation Anesthetics. Springer Berlin Heidelberg. pp. 418–439. doi:10.1007/978-3-642-65055-0_19. ISBN 9783642650574.
75. ↑ 75.0 75.1 Smith, William C.; Tullock, Charles W.; Smith, Ronald D.; Engelhardt, Vaughn A. (February 1960). "Chemistry of Sulfur Tetrafluoride. III. Organoiminosulfur Difluorides". Journal of the American Chemical Society 82 (3): 551–555. doi:10.1021/ja01488a013. Bibcode: 1960JAChS..82..551S.
76. ↑ Jin, Anding; Mack, Hans-Georg; Waterfeld, Alfred; Dakkouri, Marwan; Oberhammer, Heinz (November 1992). "Perfluoro-1,2-dioxolane. A new synthesis and its gas-phase structure" (in en). Journal of Molecular Structure 274 (1): 163–170. doi:10.1016/0022-2860(92)80155-B. Bibcode: 1992JMoSt.274..163J.
77. ↑ "3M Novec 4710 Insulating Gas". 2022. https://multimedia.3m.com/mws/media/1132124O/3m-novec-4710-insulating-gas.pdf.
78. ↑ Emeléus, H. J.; Wilkins, C. J. (1944). "122. Some new ethyl and phenyl silicon fluorides". J. Chem. Soc.: 454–456. doi:10.1039/JR9440000454.
79. ↑ 79.0 79.1 79.2 79.3 79.4 Sicard, Alexandre J.; Baker, R. Tom (2020-09-09). "Fluorocarbon Refrigerants and their Syntheses: Past to Present" (in en). Chemical Reviews 120 (17): 9164–9303. doi:10.1021/acs.chemrev.9b00719. ISSN 0009-2665. PMID 32809811. https://pubs.acs.org/doi/10.1021/acs.chemrev.9b00719.
80. ↑ H. G. Ang; Y. C. Syn (1974). "The chemistry of bis(trifluoromethyl)amine compounds" (in en). Advances in Inorganic Chemistry and Radiochemistry. Academic Press. p. 29. ISBN 9780080578651. https://books.google.com/books?id=qi0vujzNSz4C&pg=PA29.
81. ↑ (Banus) Mason, Joan (1969). "Trifluoromethyl thionitrite". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 1587. doi:10.1039/J19690001587.
82. ↑ Lavrukhina, Avgusta Konstantinovna; Pozdni︠a︡kov, Aleksandr Aleksandrovich (1970) (in en). Analytical Chemistry of Technetium, Promethium, Astatine and Francium. Ann Arbor-Humphrey Science Publishers. ISBN 978-0-250-39923-9. https://books.google.com/books?id=5-6FAAAAIAAJ.
83. ↑ 83.0 83.1 83.2 Hauptschein, Murray; Nodiff, Edward A.; Grosse, Aristid V. (March 1952). "Perfluoroalkyl Halides Prepared from Silver Perfluoro-fatty Acid Salts. II. Perfluoroalkyl Bromides and Chlorides". Journal of the American Chemical Society 74 (5): 1347–1350. doi:10.1021/ja01125a511. Bibcode: 1952JAChS..74.1347H.
84. ↑ 84.0 84.1 84.2 Macintyre, Jane E. (1994) (in en). Dictionary of Inorganic Compounds, Supplement 2. CRC Press. p. 25. ISBN 9780412491009. https://books.google.com/books?id=yV-Kj-ubc0IC&pg=PA25.
85. ↑ Davis, Ralph Anderson; Kroon, James L.; Rausch, Douglas A. (May 1967). "Pentafluoroguanidine". The Journal of Organic Chemistry 32 (5): 1662–1663. doi:10.1021/jo01280a103.
86. ↑ "1,1,2,2-Tetrafluoropropane | C3H4F4 | ChemSpider". http://www.chemspider.com/Chemical-Structure.148999.html.
87. ↑ 87.0 87.1 87.2 Macintyre, Jane E. (1994) (in en). Dictionary of Inorganic Compounds, Supplement 2. CRC Press. ISBN 9780412491009. https://books.google.com/books?id=yV-Kj-ubc0IC&pg=PA18.
88. ↑ Young, D.E.; Anderson, L.R.; Gould, D.E.; Fox, W.B. (January 1969). "Perfluoroalkyl chloroformates and chlorosulfates". Tetrahedron Letters 10 (9): 723–726. doi:10.1016/S0040-4039(01)87792-3.
89. ↑ Burns, T. H. S.; Bracken, A. (1972). "Exploratory and Newer Compounds" (in en). Modern Inhalation Anesthetics. Springer Berlin Heidelberg. p. 413. doi:10.1007/978-3-642-65055-0_19. ISBN 9783642650574.
90. ↑ 90.0 90.1 90.2 De Pasquale, Ralph J.; Padgett, Calvin D.; Patton, Jerry R. (May 1973). "PERFLUOROCARBON EPOXIDES Part I TECHNICAL REPORT AFML-TR-73-144". PCR, Inc.. http://www.dtic.mil/dtic/tr/fulltext/u2/912520.pdf.
91. ↑ 91.0 91.1 Alange, G. G. (1969). Some reactions of tetrasulphur tetranitride and trithiazyl trichloride (Doctoral thesis). Durham University.
92. ↑ , Carl J.; William W. Wilson & Karl O. Christe"Synthesis of pentafluorotellurium hypofluorite"  patent US4462975A, issued 1984-07-31
93. ↑ 93.0 93.1 93.2 Tullock, C. W.; Coffman, D. D.; Muetterties, E. L. (February 1964). "Synthesis and Chemistry of SF5Cl". Journal of the American Chemical Society 86 (3): 357–361. doi:10.1021/ja01057a013. Bibcode: 1964JAChS..86..357T.
94. ↑ Burg, Anton B.; Mahler, Walter (August 1957). "A New Synthesis of Bis-Trifluoromethyl-Phosphine, (CF3)2PH". Journal of the American Chemical Society 79 (15): 4242. doi:10.1021/ja01572a072.
95. ↑ "1,1,4,4-Tetrafluoro-1,3-butadiene | C4H2F4 | ChemSpider". http://www.chemspider.com/Chemical-Structure.120032.html.
96. ↑ Schmuck, Arno; Seppelt, Konrad (February 1987). "Sulfur Pentafluoride Cyanate, F5S-O-C≡N". Angewandte Chemie International Edition in English 26 (2): 134–135. doi:10.1002/anie.198701341.
97. ↑ 97.0 97.1 97.2 Demiel, Arye (July 1965). "Structure and Stability of the Bromofluoroethylenes. II. The Geometric Isomers of 1-Bromo-1,2-difluoro- and 1,2-Dibromo-1,2-difluoroethylene". The Journal of Organic Chemistry 30 (7): 2121–2126. doi:10.1021/jo01018a002.
98. ↑ Dědek, V.; Chvátal, Z. (May 1986). "Addition of 1,2-dibromo-1-chlorotrifluoroethane to chlorotrifluoroethylene induced by uv-radiation. Synthesis of perfluoro-1,3-butadiene and perfluoro-1,3,5-hexatriene" (in en). Journal of Fluorine Chemistry 31 (4): 363–379. doi:10.1016/S0022-1139(00)81263-4. Bibcode: 1986JFluC..31..363D.
99. ↑ 99.0 99.1 Anderson, H. H. (October 1962). "Boiling Points and Boiling Point Numbers of Organogermanium Compounds" (in en). Journal of Chemical & Engineering Data 7 (4): 565–567. doi:10.1021/je60015a041. ISSN 0021-9568.
100. ↑ (in en) Advances in Organometallic Chemistry. Academic Press. 1964. p. 154. ISBN 9780080580029. https://archive.org/details/advancesinorgano0041unse.
101. ↑ Parsons, Theran D.; Baker, Everett D.; Burg, Anton B.; Juvinall, Gordon L. (January 1961). "A Trifluoromethylboron Compound, CF3BF2". Journal of the American Chemical Society 83 (1): 250–251. doi:10.1021/ja01462a053. Bibcode: 1961JAChS..83..250P.
102. ↑ Rahm, Martin; Bélanger-Chabot, Guillaume; Haiges, Ralf; Christe, Karl O. (2014-07-01). "Nitryl Cyanide, NCNO 2" (in en). Angewandte Chemie International Edition 53 (27): 6893–6897. doi:10.1002/anie.201404209. PMID 24861214. Bibcode: 2014ACIE...53.6893R.
103. ↑ Spanier, Edward J.; MacDiarmid, Alan G. (February 1963). "The Synthesis of Germylsilane from Silane and Germane in a Silent Electric Discharge" (in en). Inorganic Chemistry 2 (1): 215–216. doi:10.1021/ic50005a055. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic50005a055.
104. ↑ "(2E)-1,1,1,4,4,4-Hexafluoro-2-butene | C4H2F6 | ChemSpider". http://www.chemspider.com/Chemical-Structure.4647246.html.
105. ↑ Teal, Gordon K.; Kraus, Charles A. (October 1950). "Compounds of Germanium and Hydrogen. III. Monoalkylgermanes. IV. Potassium Germanyl. V. Electrolysis of Sodium Germanyl". Journal of the American Chemical Society 72 (10): 4706–4709. doi:10.1021/ja01166a100. ISSN 0002-7863. Bibcode: 1950JAChS..72.4706T.
106. ↑ Jander, J.; Haszeldine, R. N. (1954). "Addition of free radicals to unsaturated systems. Part VI. Free-radical addition to the nitroso-group". Journal of the Chemical Society (Resumed): 696. doi:10.1039/JR9540000696.
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108. ↑ (in en) Houben-Weyl Methods of Organic Chemistry Vol. E 10b/2, 4th Edition Supplement: Organo-Fluorine Compounds - Synthesis of Fluorinated Compounds II, Transformations of Fluorinated Compounds. Georg Thieme Verlag. 2014. p. 23. ISBN 9783131815644. https://books.google.com/books?id=HzSGAwAAQBAJ&pg=PA23.
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110. ↑ Talbott, Richard L. (May 1968). "Fluorocarbon peroxides. Novel peroxides prepared from bis(fluoroformyl) peroxide". The Journal of Organic Chemistry 33 (5): 2095–2099. doi:10.1021/jo01269a084.
111. ↑ 111.0 111.1 Toropov, Andrey; Toropova, Alla (December 2004). "Nearest neighboring code and hydrogen bond index in labeled hydrogen-filled graph and graph of atomic orbitals: application to model of normal boiling points of haloalkanes". Journal of Molecular Structure: THEOCHEM 711 (1–3): 173–183. doi:10.1016/j.theochem.2004.10.003.
112. ↑ "Pentafluoroethyl iodide | C2F5I". http://www.chemspider.com/Chemical-Structure.9259.html.
113. ↑ W. J. Middleton; D. M. Gale (1988). "Bis(Trifluoromethyl)diazomethane". Organic Syntheses. http://www.orgsyn.org/demo.aspx?prep=cv6p0161. ;  Collective Volume, 6, pp. 161
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115. ↑ Gilman, Henry; Jones, R. G. (August 1943). "2,2,2-Trifluoroethylamine and 2,2,2-Trifluorodiazoethane". Journal of the American Chemical Society 65 (8): 1458–1460. doi:10.1021/ja01248a005. Bibcode: 1943JAChS..65.1458G.
116. ↑ Yang, Zhi-qiang; Kou, Lian-gang; Mao, Wei; Lu, Jing; Zhang, Wei; Lu, Jian (20 December 2013). "Experimental Study of Saturated Pressure Measurements for 2,3,3,3-Tetrafluoropropene (HFO-1234yf) and 2-Chloro-1,1,1,2-Tetrafluoropropane (HCFC-244bb)". Journal of Chemical & Engineering Data 59 (1): 157–160. doi:10.1021/je400970y.
117. ↑ Hoffmann, Friedrich W.; Simmons, Thomas C.; Beck, R. B.; Holler, H. V.; Katz, T.; Koshar, R. J.; Larsen, E. R.; Mulvaney, J. E. et al. (July 1957). "Fluorocarbon Derivatives. I. Derivatives of Sulfur Hexafluoride". Journal of the American Chemical Society 79 (13): 3424–3429. doi:10.1021/ja01570a029. Bibcode: 1957JAChS..79.3424H.
118. ↑ Sekiya, Akira; DesMarteau, Darryl D. (May 1980). "Synthesis and properties of 2-(pentafluorothio)-3,3-difluorooxaziridine". Inorganic Chemistry 19 (5): 1330–1333. doi:10.1021/ic50207a045.
119. ↑ Arvia, A. J.; Aymonino, P. J.; Waldow, C. H.; Schumacher, H. J. (7 March 1960). "Bis-monofluorcarbonyl-peroxyd". Angewandte Chemie 72 (5): 169. doi:10.1002/ange.19600720505. Bibcode: 1960AngCh..72..169A.
120. ↑ Knunyants, I. L.; Yakobson, G. G. (2012) (in en). Syntheses of Fluoroorganic Compounds. Springer Science & Business Media. ISBN 9783642702075. https://books.google.com/books?id=m6zxCAAAQBAJ&pg=PA46.
121. ↑ "trifluorbutane | C4H7F3 | ChemSpider". http://www.chemspider.com/Chemical-Structure.10675046.html.
122. ↑ 122.0 122.1 Görg, Michaela; Röschenthaler, Gerd-Volker; Kolomeitsev, Alexander A. (July 1996). "Facile syntheses of tris(trifluoromethyl)phosphine and difluorotris (trifluoromethyl) phosphorane" (in en). Journal of Fluorine Chemistry 79 (1): 103–104. doi:10.1016/0022-1139(96)03471-9. Bibcode: 1996JFluC..79..103G.
123. ↑ Lustig, Max (August 1966). "Some Perfluoroalkyliminosulfur Derivatives". Inorganic Chemistry 5 (8): 1317–1319. doi:10.1021/ic50042a004.
124. ↑ Krespan, Carl G.; Dixon, David A. (June 1991). "Perhalodioxins and perhalodihydrodioxins". The Journal of Organic Chemistry 56 (12): 3915–3923. doi:10.1021/jo00012a026.
125. ↑ Case, J. R.; Ray, N. H.; Roberts, H. L. (1961). "394. Sulphur chloride pentafluoride: reaction with fluoro-olefins". Journal of the Chemical Society (Resumed): 2070. doi:10.1039/JR9610002070.
126. ↑ Pernice, Holger; Willner, Helge; Bierbrauer, Karina; Burgos Paci, Maximiliano; Argüello, Gustavo A. (18 October 2002). "Fluoroformic Acid Anhydride, FC(O)OC(O)F". Angewandte Chemie International Edition 41 (20): 3832–3834. doi:10.1002/1521-3773(20021018)41:20<3832::AID-ANIE3832>3.0.CO;2-M. PMID 12386862.
127. ↑ Middleton, William J. (November 1973). "Perfluorovinyl isocyanates". The Journal of Organic Chemistry 38 (22): 3924–3928. doi:10.1021/jo00962a022.
128. ↑ "1-Chloro-1,1,2,2-tetrafluoropropane | C3H3ClF4 | ChemSpider". http://www.chemspider.com/Chemical-Structure.61220.html.
129. ↑ Clifford, A. F.; El-Shamy, H. K.; Emeléus, H. J.; Haszeldine, R. N. (1953). "483. Organometallic and organometalloidal fluorine compounds. Part VIII. The electrochemical fluorination of dimethyl sulphide and carbon disulphide". J. Chem. Soc.: 2372–2375. doi:10.1039/JR9530002372.
130. ↑ Amouroux, David; Donard, Olivier F. X. (1996-07-01). "Maritime emission of selenium to the atmosphere in Eastern Mediterranean seas" (in en). Geophysical Research Letters 23 (14): 1777–1780. doi:10.1029/96GL01271. Bibcode: 1996GeoRL..23.1777A.
131. ↑ Kobayashi, Yoshiro; Yoshida, Tsutomu; Kumadaki, Itsumaro (January 1979). "Trifluoromethyl trifluoromethanesulfonate (CF3SO2OCF3)". Tetrahedron Letters 20 (40): 3865–3866. doi:10.1016/S0040-4039(01)95545-5.
132. ↑ "1,2,2-Trifluoropropane | C3H5F3 | ChemSpider". http://www.chemspider.com/Chemical-Structure.10675014.html.
133. ↑ Naumann, Dieter (2001). "On Perfluoroalkyl Tellurium Compounds" (in en). Phosphorus, Sulfur, and Silicon and the Related Elements 171 (1): 113–133. doi:10.1080/10426500108046630. ISSN 1042-6507. http://www.tandfonline.com/doi/abs/10.1080/10426500108046630.
134. ↑ "2,2,3,3,5,5,6,6-Octafluoro-1,4-dioxane | C4F8O2 | ChemSpider". http://www.chemspider.com/Chemical-Structure.10329211.html.
135. ↑ "1,1,1,2,3-Pentafluoropropane | C3H3F5 | ChemSpider". http://www.chemspider.com/Chemical-Structure.144295.html.
136. ↑ 136.0 136.1 Burdon, J.; Chivers, G. E.; Mooney, E. F.; Tatlow, J. C. (1969). "Partial fluorination of tetrahydrofuran with cobalt trifluoride" (in en). Journal of the Chemical Society C: Organic (13): 1739. doi:10.1039/j39690001739. ISSN 0022-4952.
137. ↑ Jones, E. R. H.; Eglinton, Geoffrey; Whiting, M. C.; Shaw, B. L.. "Ethoxyacetylene". Organic Syntheses 34: 48. doi:10.15227/orgsyn.034.0046. Fn. 10.
138. ↑ Birchall, J. M.; Bloom, A. J.; Haszeldine, R. N.; Willis, C. J. (1962). "584. Perfluoroalkyl derivatives of nitrogen. Part X. The reaction of nitric oxide with tetrafluoroethylene, and formation of a nitrosopolymer". Journal of the Chemical Society (Resumed): 3021. doi:10.1039/JR9620003021.
139. ↑ Gibbon, G. A.; Wang, Jin Tsai; Van Dyke, Charles H. (November 1967). "Preparation and properties of germyl methyl ether and germylmethyl methyl ether" (in en). Inorganic Chemistry 6 (11): 1989–1994. doi:10.1021/ic50057a012. ISSN 0020-1669.
140. ↑ Baker, Max T; Ruzicka, Jan A; Tinker, John H (April 1999). "One step synthesis of 1,1,1,4,4,4-hexafluorobutane from succinonitrile" (in en). Journal of Fluorine Chemistry 94 (2): 123–126. doi:10.1016/S0022-1139(98)00311-X. Bibcode: 1999JFluC..94..123B.
141. ↑ Wagner, Ross I.; Freeman, LeVern D.; Goldwhite, H.; Rowsell, D. G. (March 1967). "Phosphiran". Journal of the American Chemical Society 89 (5): 1102–1104. doi:10.1021/ja00981a013. Bibcode: 1967JAChS..89.1102W.
142. ↑ 142.0 142.1 142.2 Burns, T. H. S.; Bracken, A. (1972). "Exploratory and Newer Compounds" (in en). Modern Inhalation Anesthetics. Springer Berlin Heidelberg. pp. 416–417. doi:10.1007/978-3-642-65055-0_19. ISBN 9783642650574.
143. ↑ "2-Fluorobutane | C4H9F | ChemSpider". http://www.chemspider.com/Chemical-Structure.2282432.html.
144. ↑ Thompson, Phillip Gerhard. (August 1967). "Bis(perfluoroalkyl) trioxides". Journal of the American Chemical Society 89 (17): 4316–4319. doi:10.1021/ja00993a012. Bibcode: 1967JAChS..89.4316T.
145. ↑ Varetti, E. L.; Aymonino, P. J. (1967). "New photochemical routes to perfluoromethyl carbonate". Chemical Communications (14): 680. doi:10.1039/C19670000680.
146. ↑ De Marco, Ronald A.; Shreeve, Jean'ne M. (May 2002). "Reactions of the fluorimide-potassium fluoride adduct HNF2.KF, with sulfinyl and perfluoroalkylsulfinyl fluorides. Preparation of perfluoroalkyl perfluoroalkylthiosulfonates". Inorganic Chemistry 12 (8): 1896–1899. doi:10.1021/ic50126a040.
147. ↑ Horsewood, Peter; Kirby, Gordon W. (1980). "Preparation and dienophilic reactions of nitrosyl cyanide". Journal of the Chemical Society, Perkin Transactions 1: 1587. doi:10.1039/P19800001587.
148. ↑ "Specialty Gases. Rare Gases. Fluorocarbons". Electronic Fluorocarbons LLC. 2 May 2014. https://www.efgases.com/wp-content/uploads/EFC_Brochure_v3.pdf.
149. ↑ Martin, E. L.; Sharkey, W. H. (October 1959). "1,1,4,4-Tetrafluoro-1,2,3-butatriene". Journal of the American Chemical Society 81 (19): 5256–5258. doi:10.1021/ja01528a056. Bibcode: 1959JAChS..81.5256M.
150. ↑ Ehm, Christian; Lentz, Dieter (21 January 2011). "Cyclic dimers of tetrafluorobutatriene". Theoretical Chemistry Accounts 129 (3–5): 507–515. doi:10.1007/s00214-011-0890-3.
151. ↑ "perfluoropent-1-ene | C5F10 | ChemSpider". http://www.chemspider.com/Chemical-Structure.71329.html.
152. ↑ Ulic, S. E.; von Ahsen, S.; Willner, H. (August 2004). "Photoisomerization of Matrix-Isolated Bis(trifluoromethyl) Sulfoxide: Formation of the Sulfenic Ester CF3SOCF3". Inorganic Chemistry 43 (17): 5268–5274. doi:10.1021/ic049800r. PMID 15310204.
153. ↑ "1,1,2,2,3-Pentafluoropropane 411078". https://www.sigmaaldrich.com/catalog/product/aldrich/411078.
154. ↑ Banks, R. E.; Harrison, A. C.; Haszeldine, R. N. (1966). "Polyfluorocyclopentadienes. Part II. The thermal dimer of perfluorocyclopentadiene: perfluoro(tricyclo[5,2,1,02,6]deca-3,8-diene)". Journal of the Chemical Society C: Organic: 2102. doi:10.1039/J39660002102.
155. ↑ "Trifluoromethanesulfonyl chloride 164798". https://www.sigmaaldrich.com/catalog/product/aldrich/164798.
156. ↑ Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils (1985) (in German). Lehrbuch der Anorganischen Chemie (102 ed.). Walter de Gruyter. p. 627.
157. ↑ Hamada, K.; Morishita, H. (January 1977). "The Synthesis and the Raman and Infrared Spectra of Methanetellurol" (in en). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 7 (4): 355–366. doi:10.1080/00945717708069709. ISSN 0094-5714.
158. ↑ Thrasher, Joseph S.; Madappat, Krishnan V. (September 1989). "Sulfur-Pentafluoride Isocyanide, SF5NC". Angewandte Chemie International Edition in English 28 (9): 1256–1258. doi:10.1002/anie.198912561.

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