Methane leak

Short description: Unintended escape of methane from containment

Methane plume over Turkmenistan, 2020 image from the Sentinel-5 Precursor satellite

A methane leak is a significant natural gas leak. The term is used for a class of methane emissions, which can come from an industrial facility or pipeline.

Satellite data enables the identification of super-emitter events (synonymous with ultra-emitters, see "Mitigation of Ultra-Emitters") that produce methane plumes. Over 1,000 methane leaks of this type were found worldwide in 2022.[1] As with other gas leaks, a leak of methane is a safety hazard: coalbed methane in the form of fugitive gas emission has always been a danger to miners.[2] Methane leaks also have a serious environmental impact. Natural gas contain methane, ethane, and other gases, which from the safety and environmental point of view raise major issues with atmospheric composition and human health.

As a greenhouse gas and climate change contributor, methane ranks second, following carbon dioxide.[3] Fossil fuel exploration, transportation and production is responsible for about 40% of human-caused methane emissions.[1] Smaller leaks than can be spotted from space comprise long tail of emissions. They can be identified from planes flying at 900 meters (3,000 ft).[4] According to Fatih Birol of the International Energy Agency, "Methane emissions are still far too high, especially as methane cuts are among the cheapest options to limit near-term global warming".[1]

## Contents

* 1 Examples of methane leaks
* 2 Mitigation of Ultra-Emitters
* 3 Leakage from Abandoned Oil and Gas Wells
* 4 Methane Detection Sensors
* 4.1 Optical Sensors
* 4.2 Calorimetric Sensors
* 4.3 Pyroelectric Sensors
* 4.4 Semiconducting Metal Oxide Sensors
* 4.5 Electrochemical Sensors
* 5 Units
* 6 References

## Examples of methane leaks

Individual methane leaks are reported as specific events with a large quantity of gas released. An example followed the 2022 Nord Stream pipeline sabotage. Following early reports that the escape might exceed 105 tonnes, The International Methane Emissions Observatory of the United Nations Environment Programme analyzed the release. In February 2023 it put the mass of methane gas in the range 7.5 to 23.0 x 104 tonnes. In terms of overall human-made methane emissions, these figures are under 0.1% of the annual total.[5][6]

Satellite data detection has shown that methane super emitter sites in Turkmenistan, USA and Russia are responsible for the biggest number of events from fossil fuel facilities. Estimated emissions from oil and gas ultra-emitters rank highest for Turkmenistan with 1.3 megatons (Mt) of methane per year, followed by Russia, the United States, Iran, Kazakhstan, and Algeria.[7] Equipment failures are normally responsible for the releases, which can last for weeks.[8]

The Aliso Canyon gas leak of 2015 has been quantified as at least 1.09 x 105 tonnes of methane.[9] Satellite data for the Raspadskaya coal mine, Kemerovo Oblast, Russia indicated in 2022 an hourly methane leakage rate of 87 tonnes;[10] this compares to 60 tonnes per hour of natural gas leaking from the Aliso Canyon incident, considered among the worst recorded leak events.[11]

Spain's Technical University of Valencia, in a study published in 2022, found that a super emitter event at a gas and oil platform in the Gulf of Mexico released around 4 x 104 tonnes of methane during a 17-day time period in December 2021 (hourly rate around 98 tonnes).[12] Another major event in 2022 was a leak of 427 tonnes an hour in August, near Turkmenistan's Caspian coast and a major pipeline.[8]

## Mitigation of Ultra-Emitters

Ultra-emitters of methane are characterized by producing more than 25 tons/hour of CH4 from oil and gas activities, and are in the top 1% of methane emitters in the world.[7] Reducing emissions from these sites can be done by enforcing leak detection and by reducing venting during routine maintenance.[7]

Ultra-emitters are common and particularly large in Russia, Iran, and Kazakhstan, representing 10-20% of annual reported emissions across the globe.[7] The U.S. is found to house 5% of annual worldwide emissions, but this number excludes emissions from drilling in the Permian basin, which accounts for 10% of U.S. natural gas production.[7] Drilling in the Permian basin creates about 2.7 Mt a year of emissions, which is 35% of U.S. oil and gas production emissions.[7]

Spending for mitigation of ultra-emitters is funded by the International Energy Agency (IEA), Environmental Protection Agency (EPA), and International Institute for Applied Systems Analysis (IIASA).[7] Emissions from ultra-emitters are expected to be more cost-effective to mitigate than average-sized sources due to efficiency and leak efforts.[7]

## Leakage from Abandoned Oil and Gas Wells

The geographic area of Lubbock has been a site of ongoing emissions research to assess the extent and environmental implications of methane leakage from abandoned wells.[13] Lubbock is located within the Permian Basin in West Texas, United States, and includes an estimate of 1781 drilling wells.[13] Aeromagnetic surveys are used to detect active and abandoned wells and are able to detect those with no visible aboveground markers.[13] Regular monitoring and repair initiatives targeting emissions from storage tanks can be particularly impactful in mitigating vented emissions.[13] Even with efforts to accurately measure the greenhouse gas emissions associated with the abandoned wells, emissions data is still relatively uncertain due to gas characterization and source concerns.[13]

## Methane Detection Sensors

Usage of methane gas detection sensors vary based on region, environmental conditions, and purpose of measurements. Types of sensors include optical sensors, calorimetric sensors, pyroelectric sensors, semiconducting oxide sensors, and electrochemical sensors.

### Optical Sensors

Optical sensors detect changes in light waves that interact with the receptor. They are optimal in regions where there could be electromagnetic interference and at high altitudes where oxygen content is low.[14] They are also non-destructive and result in little to no environmental harm. However, they have high costs in large settings and low selectivity.[14]

### Calorimetric Sensors

Calorimetric sensors measure the heat produced from a reaction and compare the value to reactant concentration.[14] These sensors are low cost and have a simple design. They are able to operate in harsh conditions but are susceptible to cracking and accelerated degradation.[14] They also require high power consumption to operate and have low detection accuracy.

### Pyroelectric Sensors

Pyroelectric sensors convert thermal energy into electrical energy based on pyroelectricity.[14] They have good sensitivity and responsivity, can operate without oxygen, and have a wide measuring range. Among the limitations of pyroelectric sensors are cost and difficulty in manufacturing, but the most detrimental is the immobility of the sensor once positioned.[14]

### Semiconducting Metal Oxide Sensors

Semiconducting metal oxide sensors measure methane by detecting the absorption of gas on the surface of a metal oxide, which changes its conductivity.[14] These instruments are low cost, lightweight, and have a long lifespan. They may not be used as widely due to their poor selectivity, sensitivity to changes in temperature and humidity, and significant additive dependence.[14]

### Electrochemical Sensors

Electrochemical sensors oxidize or reduce the gas detected at an electrode and measure the current to find methane gas concentration.[14] These instruments are low cost, non-hazardous, and have low volatility. They also have good selectivity specifically for methane gas and can detect small leaks. They may have slow response time or be susceptible to degradation or loss of electrodes, however these sensors have returned promising results in the accuracy of small methane leak detection.[14]

## Units

Quantitative reports of methane leaks often use the standard cubic foot (scf) of the United States customary system. Applied to natural gas, a complex mixture of uncertain proportions, and depending on pressure and temperature conditions, the accuracy of calculations converting scf to metric units of mass is subject to limitations. A conversion figure given is 5 x 104 scf of natural gas as 1.32 short tons (1.20 t).[15]

For detection sensitivity, quantitative criteria are typically stated in units of standard cubic feet per hour (scf/h, "skiff", US), or thousand standard cubic feet per day (Mscf/d); or with metric units kilograms per hour (kg/hr), cubic meters per day (m3/d).[16] File:Tracking methane with EMIT and AVIRIS-3 (SVS5389).webm To describe the mass balance of methane in the atmosphere, mass rates are described in units of Tg/yr, i.e. teragrams per year where a teragram is 106 tonnes (megagrams).[17] The methane leak from the Permian Basin, a significant region of the Mid-Continent Oil Producing Area, was estimated for 2018/9 from satellite data as 2.7 Tg/yr. Quoted in terms of the proportion of the mass of extracted gas, the leakage comes to 3.7%.[18] The 2021 Carbon Mapper project, a collaboration of the Jet Propulsion Laboratory and academia, detected 533 methane super-emitters in the Permian Basin.[19]

## References

1. ↑ 1.0 1.1 1.2 Carrington, Damian (6 March 2023). "Revealed: 1,000 super-emitting methane leaks risk triggering climate tipping points". The Guardian. https://www.theguardian.com/environment/2023/mar/06/revealed-1000-super-emitting-methane-leaks-risk-triggering-climate-tipping-points.
2. ↑ US EPA, OAR (2015-12-08). "About Coal Mine Methane" (in en). https://www.epa.gov/cmop/about-coal-mine-methane.
3. ↑ "Methane | Vital Signs" (in en). https://climate.nasa.gov/vital-signs/methane/?intent=121.
4. ↑ "In Plane Sight: How to measure methane leaks". 30 November 2021. https://www.climateinvestment.com/news/in-plane-sight-how-to-measure-methane-leaks.
5. ↑ McVeigh, Karen; Oltermann, Philip (28 September 2022). "Nord Stream gas leaks may be biggest ever, with warning of 'large climate risk'". The Guardian. https://www.theguardian.com/environment/2022/sep/28/nord-stream-methane-gas-leaks-may-be-biggest-ever-with-warning-large-climate-risk.
6. ↑ "UNEP finds Nord Stream gas leak may be the highest methane emission event, but still a drop in the ocean" (in en). 20 February 2023. https://www.unep.org/technical-highlight/unep-finds-nord-stream-gas-leak-may-be-highest-methane-emission-event-still.
7. ↑ 7.0 7.1 7.2 7.3 7.4 7.5 7.6 7.7 Lauvaux, T.; Giron, C.; Mazzolini, M.; d'Aspremont, A.; Duren, R.; Cusworth, D.; Shindell, D.; Ciais, P. (2022-02-04). "Global assessment of oil and gas methane ultra-emitters". Science 375 (6580): 557–561. doi:10.1126/science.abj4351. PMID 35113691. Bibcode: 2022Sci...375..557L. https://www.science.org/doi/10.1126/science.abj4351.
8. ↑ 8.0 8.1 "How secretive methane leaks are driving climate change" (in en). UNEP. 19 July 2022. https://www.unep.org/news-and-stories/story/how-secretive-methane-leaks-are-driving-climate-change.
9. ↑ "Aliso Canyon Natural Gas Leak, California Air Resources Board". https://ww2.arb.ca.gov/our-work/programs/aliso-canyon-natural-gas-leak/about.
10. ↑ Fountain, Henry (14 June 2022). "One Site, 95 Tons of Methane an Hour". The New York Times. https://www.nytimes.com/2022/06/14/climate/methane-emissions-russia-coal-mine.html.
11. ↑ Milman, Oliver (26 February 2016). "LA gas leak: worst in US history spewed as much pollution as 600,000 cars". The Guardian. https://www.theguardian.com/environment/2016/feb/26/los-angeles-aliso-canyon-gas-leak-methane-largest-us-history.
12. ↑ "Methane emissions detected over offshore platform in the Gulf of Mexico" (in en). https://www.esa.int/Applications/Observing_the_Earth/Methane_emissions_detected_over_offshore_platform_in_the_Gulf_of_Mexico.
13. ↑ 13.0 13.1 13.2 13.3 13.4 Opara, Stanley U.; Okere, Chinedu J. (2024-07-01). "A review of methane leakage from abandoned oil and gas wells: A case study in Lubbock, Texas, within the Permian Basin". Energy Geoscience 5 (3). doi:10.1016/j.engeos.2024.100288. ISSN 2666-7592. https://linkinghub.elsevier.com/retrieve/pii/S2666759224000039.
14. ↑ 14.00 14.01 14.02 14.03 14.04 14.05 14.06 14.07 14.08 14.09 Aldhafeeri, Tahani; Tran, Manh-Kien; Vrolyk, Reid; Pope, Michael; Fowler, Michael (2020-07-06). "A Review of Methane Gas Detection Sensors: Recent Developments and Future Perspectives" (in en). Inventions 5 (3): 28. doi:10.3390/inventions5030028. ISSN 2411-5134.
15. ↑ "Conversion of volume of natural gas to mass of natural gas". 12 January 2021. https://cimarron.com/conversion-of-volume-of-natural-gas-to-mass-of-natural-gas/.
16. ↑ "Understanding Methane Detection Sensitivity, Bridger Photonics". https://www.bridgerphotonics.com/blog/understanding-methane-detection-sensitivity.
17. ↑ Khalil, M. A. K. (29 June 2013) (in en). Atmospheric Methane: Sources, Sinks, and Role in Global Change. Springer Science & Business Media. p. 173. ISBN 978-3-642-84605-2. https://books.google.com/books?id=tbXtCAAAQBAJ&pg=PA173.
18. ↑ Gramling, Carolyn (22 April 2020). "Permian Basin is leaking twice as much methane as once thought, Science News". https://www.sciencenews.org/article/permian-basin-oil-region-leaking-twice-methane-once-thought.
19. ↑ "Hidden Menace: Massive methane leaks speed up climate change" (in en). AP News. 28 July 2022. https://apnews.com/article/science-texas-trending-news-climate-and-environment-0eb6880f7c4532a845155a3bd44c2e4b.

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