Nitrogen triiodide

| Nitrogen triiodide | Nitrogen triiodide

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Names
IUPAC names

Nitrogen triiodide[1]
Triiodoazane[1]
Triiodidonitrogen[1]

Other names

Nitrogen iodide
Ammonia triiodide
Touch Powder
Triiodine nitride
Triiodine mononitride
Triiodamine[citation needed]
Triiodoamine[citation needed]
Iodine nitride

Identifiers

CAS Number

* 13444-85-4 Y

3D model (JSmol)

* Interactive image

ChemSpider |

* 55511 Y

PubChem CID

* 61603

InChI

* InChI=1S/I3N/c1-4(2)3 Y

Key: FZIONDGWZAKCEX-UHFFFAOYSA-N Y

* InChI=1/I3N/c1-4(2)3

Key: FZIONDGWZAKCEX-UHFFFAOYAL

SMILES

* IN(I)I

Properties

Chemical formula

| NI3
Molar mass | 394.719 g/mol
Appearance  | dark solid
Boiling point |  sublimes at −20 °C

Solubility in water

| Insoluble
Solubility | organic solvents,[2] such as diethyl ether
Hazards
Main hazards | Extremely explosive and unstable
NFPA 704 (fire diamond)  |

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Y verify (what is YN ?)
Infobox references

Tracking categories (test):

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Nitrogen triiodide is an inorganic compound with the formula NI3. It is an extremely sensitive contact explosive: small quantities explode with a loud, sharp snap when touched even lightly, releasing a purple cloud of iodine vapor; it can even be detonated by alpha radiation. NI3 has a complex structural chemistry that is difficult to study because of the instability of the derivatives. Although nitrogen is more electronegative than iodine, the compound was so named due to its analogy to the compound nitrogen trichloride.[citation needed]

## Contents

* 1 Structure of NI3 and its derivatives
* 2 Decomposition and explosiveness
* 3 References
* 4 External links

## Structure of NI3 and its derivatives

Nitrogen triiodide was first characterized by Raman spectroscopy in 1990 when it was prepared by an ammonia-free route. Boron nitride reacts with iodine monofluoride in trichlorofluoromethane at −30 °C to produce pure NI3 in low yield:[3]

BN + 3 IF → NI3 \+ BF3

NI3 is pyramidal (C3v molecular symmetry), as are the other nitrogen trihalides and ammonia.[4]

The material that is usually called "nitrogen triiodide" is prepared by the reaction of iodine with ammonia. When this reaction is conducted at low temperatures in anhydrous ammonia, the initial product is NI3 · (NH3)5, but this material loses some ammonia upon warming to give the 1:1 adduct NI3 · NH3. This adduct was first reported by Bernard Courtois in 1812, and its formula was finally determined in 1905 by Oswald Silberrad.[5] Its solid state structure consists of chains of -NI2-I-NI2-I-NI2-I-.[6] Ammonia molecules are situated between the chains. When kept cold in the dark and damp with ammonia, NI3 · NH3 is stable.

## Decomposition and explosiveness

File:Detonating Nitrogen triiodide.webm

The instability of NI3 and NI3 · NH3 can be attributed to the large steric strain caused by the three large iodine atoms being held in proximity to each other around the relatively tiny nitrogen atom. This results in a very low activation energy for its decomposition, a reaction made even more favorable due to the great stability of N2. Nitrogen triiodide has no practical commercial value due to its extreme shock sensitivity, making it impossible to store, transport, and utilize for controlled explosions. Whereas pure nitroglycerin is powerful and also greatly shock-sensitive (although not nearly as much so as nitrogen triiodide, which can be set off with the touch of a feather), it was only due to phlegmatizers that nitroglycerin's shock sensitivity was reduced and it became safer to handle and transport in the form of dynamite.

The decomposition of NI3 proceeds as follows to give nitrogen gas and iodine:

2 NI3 (s) → N2 (g) + 3 I2 (g) (−290 kJ/mol)

However, the dry material is a contact explosive, decomposing approximately as follows:[4]

8 NI3 · NH3 → 5 N2 \+ 6 NH4I \+ 9 I2

Consistent with this equation, these explosions leave orange-to-purple stains of iodine, which can be removed with sodium thiosulfate solution. An alternate method of stain removal is to simply allow the iodine time to sublime. Small amounts of nitrogen triiodide are sometimes synthesized as a demonstration to high school chemistry students or as an act of "chemical magic."[7] To highlight the sensitivity of the compound, it is usually detonated by touching it with a feather, but even the slightest air current, laser light, or other movement can cause detonation. Nitrogen triiodide is also notable for being the only known chemical explosive that detonates when exposed to alpha particles and nuclear fission products.[8]

## References

1. ↑ 1.0 1.1 1.2 per analogiam, see NF3 names, IUPAC Red Book 2005, p. 314
2. ↑ 4\. Analytical techniques. acornusers.org
3. ↑ Tornieporth-Oetting, I.; Klapötke, T. (1990). "Nitrogen Triiodide". Angewandte Chemie International Edition 29 (6): 677–679. doi:10.1002/anie.199006771.
4. ↑ 4.0 4.1 Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5.
5. ↑ Silberrad, O. (1905). "The Constitution of Nitrogen Triiodide". Journal of the Chemical Society, Transactions 87: 55–66. doi:10.1039/CT9058700055. https://zenodo.org/record/1429707.
6. ↑ Hart, H.; Bärnighausen, H.; Jander, J. (1968). "Die Kristallstruktur von Stickstofftrijodid‐1‐Ammoniak NJ3 · NH3". Z. Anorg. Allg. Chem. 357 (4–6): 225–237. doi:10.1002/zaac.19683570410.
7. ↑ Ford, L. A.; Grundmeier, E. W. (1993). Chemical Magic. Dover. p. 76. ISBN 0-486-67628-5. https://archive.org/details/chemicalmagic00ford_0/page/76.
8. ↑ Bowden, F. P. (1958). "Initiation of Explosion by Neutrons, α-Particles, and Fission Products". Proceedings of the Royal Society of London A 246 (1245): 216–219. doi:10.1098/rspa.1958.0123. Bibcode: 1958RSPSA.246..216B.

## External links

* See the explosion
* Nitrogen Tri-Iodide – explains why the compound is explosive
* Nitrogen Tri-Iodide Detonation on Youtube

HI |  |  |  | He

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|
|
|

LiI | BeI2 | BI3 | CI4 | NI3 | I2O4,
I2O5,
I4O9 | IF,
IF3,
IF5,
IF7 | Ne
NaI | MgI2 | AlI3 | SiI4 | PI3,
P2I4 | S  | ICl,
ICl3 | Ar
KI | CaI2 | Sc  | TiI4 | VI3 | CrI3 | MnI2 | FeI2 | CoI2 | NiI2 | CuI | ZnI2 | Ga2I6 | GeI2,
GeI4 | AsI3 | Se  | IBr | Kr
RbI | SrI2 | YI3 | ZrI4 | NbI5 | Mo  | Tc  | Ru  | Rh  | Pd  | AgI | CdI2 | InI3 | SnI4,
SnI2 | SbI3 | TeI4 | I  | Xe
CsI | BaI2 |  | HfI4 | TaI5 | W  | Re  | Os  | Ir  | Pt  | AuI | Hg2I2,
HgI2 | TlI | PbI2 | BiI3 | Po  | AtI | Rn
Fr  | RaI2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La  | Ce  | Pr  | Nd  | Pm  | SmI2 | Eu  | Gd  | TbI3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac  | ThI4 | Pa  | UI3,
UI4 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | EsI3 | Fm  | Md  | No  | Lr

* v
* t
* e

Salts and covalent derivatives of the nitride ion

NH3 |  |  |  | He(N2)11

|
|
|
|

Li3N | Be3N2 | BN | β-C3N4
g-C3N4 | N2 | NxOy | NF3 | Ne
Na3N | Mg3N2 | AlN | Si3N4 | PN
P3N5 | SxNy

S4N4 | NCl3 | Ar
K3N | Ca3N2 | ScN | TiN | VN | CrN
Cr2N | MnxNy | FexNy | CoN | Ni3N | CuN | Zn3N2 | GaN | Ge3N4 | As  | Se  | NBr3 | Kr
Rb3N | Sr3N2 | YN | ZrN | NbN | β-Mo2N | Tc  | Ru  | Rh  | PdN | Ag3N | CdN | InN | Sn  | Sb  | Te  | NI3 | Xe
Cs3N | Ba3N2 |  | Hf3N4 | TaN | WN | Re  | Os  | Ir  | Pt  | Au  | Hg3N2 | TlN | Pb  | BiN | Po  | At  | Rn
Fr3N | Ra3N |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La  | CeN | Pr  | Nd  | Pm  | Sm  | Eu  | GdN | Tb  | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac  | Th  | Pa  | UN | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

* v
* t
* e

Nitrogen species

* Hydrides:
* NH3
* NH4+
* NH2− MNH2
* N3−
* NH2OH
* N2H4
* N3–
* Organic:
* -NH2
* -CHR=NHR
* -CONHR2
* HCN
* CN−
* C2N2
* H2NCN
* CH2N2
* Oxides:
* N2O
* NO
* NO2
* N2O3
* N2O4
* N2O5
* H2N2O2
* H4N2O4
* HNO2
* HNO3
* HONO3
* HN2O2−
* N2O22−
* NO2−
* ONOO−
* NO3−
* NO43−
* O2NOO−
* NO+
* NO2+
* Halides:
* NF3
* NCl3
* NBr3
* NI3
* FN3
* ClN3
* BrN3
* NH2Cl
* NHCl2

Chemical formulas

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