Organotin chemistry

Short description: Branch of organic chemistry

Organotin compounds are those with tin linked to hydrocarbons. The compound on the picture is trimethyltin chloride, an example of an organotin compound.

Organotin chemistry is the scientific study of the synthesis and properties of organotin compounds or stannanes, which are organometallic compounds containing tin–carbon bonds. The first organotin compound was diethyltin diiodide ((CH
3CH

2SnI
2), discovered by Edward Frankland in 1849.[1] The area grew rapidly in the 1900s, especially after the discovery of the Grignard reagents, which are useful for producing Sn–C bonds. The area remains rich with many applications in industry and continuing activity in the research laboratory.[2]

## Contents

* 1 Structure
* 1.1 Organic derivatives of tin(IV)
* 1.1.1 Organotin halides
* 1.1.2 Organotin hydrides
* 1.1.3 Organotin oxides and hydroxides
* 1.1.4 Hypercoordinated stannanes
* 1.1.5 Triorganotin cations
* 1.2 Tin radicals (organic derivatives of tin(III))
* 1.3 Organic derivatives of tin(II)
* 1.4 Organic derivatives of tin(I)
* 2 Preparation
* 3 Reactions
* 4 Applications and toxicity
* 5 See also
* 6 References
* 7 External links

## Structure

Organotin compounds are generally classified according to their oxidation states. Tin(IV) compounds are much more common and more useful.

### Organic derivatives of tin(IV)

The tetraorgano derivatives are invariably tetrahedral. Compounds of the type SnRR'R''R''' have been resolved into individual enantiomers.[3]

#### Organotin halides

Organotin chlorides have the formula R
4-nSnCl
n for values of n up to 3. Bromides, iodides, and fluorides are also known, but are less important. These compounds are known for many R groups. They are always tetrahedral. The tri- and dihalides form adducts with good Lewis bases such as pyridine. The fluorides tend to associate such that dimethyltin difluoride forms sheet-like polymers. Di- and especially tri-organotin halides, e.g. tributyltin chloride, exhibit toxicities approaching that of hydrogen cyanide.[4]

#### Organotin hydrides

Organotin hydrides have the formula R
4-nSnH
n for values of n up to 3. The parent member of this series, stannane (SnH
4), is an unstable colourless gas. Stability is correlated with the number of organic substituents. Tributyltin hydride is used as a source of hydride radical in some organic reactions.[5]

#### Organotin oxides and hydroxides

Main article: Chemistry:Stannoxane

Organotin oxides and hydroxides are common products from the hydrolysis of organotin halides. Unlike the corresponding derivatives of silicon and germanium, tin oxides and hydroxides often adopt structures with penta- and even hexacoordinated tin centres, especially for the diorgano- and monoorgano derivatives. The group SnIV
–O–SnIV
is called a stannoxane (which is a tin analogue of ethers), and the group SnIV
–O–H is also called a stannanol (which is a tin analogue of alcohols).[6] Structurally simplest of the oxides and hydroxides are the triorganotin derivatives. A commercially important triorganotin hydroxide is the acaricide cyhexatin (also called Plictran, tricyclohexyltin hydroxide and tricyclohexylstannanol), (C

11)
3SnOH. Such triorganotin hydroxides exist in equilibrium with the distannoxanes:

2 R
3SnOH ⇌ R
3SnOSnR
3 \+ H

With only two organic substituents on each Sn centre, the diorganotin oxides and hydroxides are structurally more complex than the triorgano derivatives.[7] The simple tin geminal diols (R
2Sn(OH)
2, the tin analogues of geminal diols R
2C(OH)
2) and monomeric stannanones (R
2Sn=O, the tin analogues of ketones R
2C=O) are unknown. Diorganotin oxides (R
2SnO) are polymers except when the organic substituents are very bulky, in which case cyclic trimers or, in the case where R is CH(Si(CH

2 dimers, with Sn

3 and Sn

2 rings. The distannoxanes exist as dimers with the formula [R
2SnX]

2 wherein the X groups (e.g., chloride –Cl, hydroxide –OH, carboxylate RCO
2–) can be terminal or bridging (see Table). The hydrolysis of the monoorganotin trihalides has the potential to generate stannanoic acids, RSnO
2H. As for the diorganotin oxides/hydroxides, the monoorganotin species form structurally complex because of the occurrence of dehydration/hydration, aggregation. Illustrative is the hydrolysis of butyltin trichloride to give [(CH
3(CH

3Sn)
12O
14(OH)
6]2+.

* Idealized structure of trimeric diorganotin oxide.

* Ball-and-stick model for (((CH

3C)
2SnO)

* Structure of diorganotin oxide, highlighting the extensive intermolecular bonding.

#### Hypercoordinated stannanes

Unlike carbon(IV) analogues but somewhat like silicon compounds, tin(IV) can also be coordinated to five and even six atoms instead of the regular four. These hypercoordinated compounds usually have electronegative substituents. Numerous examples of hypercoordinated compounds are provided by the organotin oxides and associated carboxylates and related pseudohalide derivatives.[7] The organotin halides for adducts, e.g. (CH

2SnCl
2([[Chemistry:

2'−
Bipyridine|bipyridine]]).

The all-organic penta- and hexaorganostannates(IV) have even been characterized,[8] while in the subsequent year a six-coordinated tetraorganotin compound was reported.[9] A crystal structure of room-temperature stable (in argon) all-carbon pentaorganostannate(IV) was reported as the lithium salt with this structure:[10]

In this distorted trigonal bipyramidal structure the carbon to tin bond lengths (2.26 Å apical, 2.17 Å equatorial) are longer than regular C-Sn bonds (2.14 Å) reflecting its hypercoordinated nature.

#### Triorganotin cations

Some reactions of triorganotin halides implicate a role for R
3Sn+
intermediates. Such cations are analogous to carbocations. They have been characterized crystallographically when the organic substituents are large, such as 2,4,6-triisopropylphenyl.[11]

### Tin radicals (organic derivatives of tin(III))

Tin radicals, with the formula R
3Sn, are called stannyl radicals.[2] They are a type of tetrel radical, and are invoked as intermediates in certain atom-transfer reactions. For example, tributyltin hydride (tris(n-butyl)stannane) serves as a useful source of "hydrogen atoms" because of the stability of the tributytin radical.[12]

### Organic derivatives of tin(II)

Organotin(II) compounds are somewhat rare. Compounds with the empirical formula SnR
2 are somewhat fragile and exist as rings or polymers when R is not bulky. The polymers, called polystannanes, have the formula (SnR

100px

In principle, compounds of tin(II) might be expected to form a tin analogues of alkenes with a formal double bond between two tin atoms (R
2Sn=SnR
2) or between a tin atom and a carbon group atom (e.g. R
2Sn=CR
2 and R
2Sn=SiR
2). Indeed, compounds with the formula R
2Sn=SnR
2, called distannenes or distannylenes, which are tin analogues of ethylenes R
2C=CR
2, are known for certain organic substituents. The Sn centres in stannenes are trigonal. But, contrary to the C centres in alkenes which are trigonal planar, the Sn centres in stannenes tend to be highly pyramidal. Monomeric compounds with the formula SnR
2, tin analogues of carbenes CR
2 are also known in a few cases. One example is Sn(SiR

2, where R is the very bulky CH(Si(CH

2. Such species reversibly dimerize to the distannylene upon crystallization:[13]

2 R
2Sn ⇌ R
2Sn=SnR

Stannenes, compounds with tin-carbon double bonds, are exemplified by derivatives of stannabenzene. Stannoles, structural analogs of cyclopentadiene, exhibit little C-Sn double bond character.

### Organic derivatives of tin(I)

Compounds of Sn(I) are rare and only observed with very bulky ligands. One prominent family of cages is accessed by pyrolysis of the 2,6-diethylphenyl-substituted tristannylene [Sn(C6H3-2,6-Et2)2]3, which affords the cubane-type cluster and a prismane. These cages contain Sn(I) and have the formula [Sn(C6H3-2,6-Et2)]n where n = 8, 10 and Et stands for ethyl group.[14] A stannyne contains a tin atom to carbon group atom triple bond (e.g. R–Sn≡C–R and R–Sn≡Si–R), and a distannyne a triple bond between two tin atoms (R–Sn≡Sn–R). Distannynes only exist for extremely bulky substituents. Unlike alkynes, the C–Sn≡Sn–C core of these distannynes are nonlinear, although they are planar. The Sn-Sn distance is 3.066(1) Å, and the Sn-Sn-C angles are 99.25(14)°. Such compounds are prepared by reduction of bulky aryltin(II) halides.[15]

White (smallest) balls: H
Grey balls: C
Magenta (largest) balls: Sn
Structure of an Ar
10Sn
10 "prismane", a compound containing Sn(I) (Ar = 2,6-diethylphenyl).

## Preparation

Organotin compounds can be synthesised by numerous methods.[16] Classic is the reaction of a Grignard reagent with tin halides for example tin tetrachloride. An example is provided by the synthesis of tetraethyltin:[17]

4 CH
3CH
2MgBr + SnCl
4 → (CH
3CH

4Sn + 4 MgClBr

The symmetrical tetraorganotin compounds, especially tetraalkyl derivatives, can then be converted to various mixed chlorides by redistribution reactions (also known as the "Kocheshkov comproportionation" in the case of organotin compounds):

3 R
4Sn + SnCl
4 → 4 R
3SnCl

4Sn + SnCl
4 → 2 R
2SnCl

4Sn + 3 SnCl
4 → 4 RSnCl

A related method involves redistribution of tin halides with organoaluminium compounds.[2]: 45–47

In principle, alkyltin halides can be formed from direct insertion of the metal into the carbon-halogen bond. However, such reactions are temperamental, typically requiring a very weak carbon-halogen bond (e.g. an alkyl iodide or an allyl halide) or crown-complexed alkali metal salt catalyst. Lewis acids or an ionic solvent may also promote the reaction.[2]: 51–52

The mixed organo-halo tin compounds can be converted to the mixed organic derivatives, as illustrated by the synthesis of dibutyldivinyltin:[18]

2SnCl
2 \+ 2 CH
2=CHMgBr → Bu
2Sn(CH=CH

2 \+ 2 MgBrCl

The organotin hydrides are generated by reduction of the mixed alkyl chlorides. For example, treatment of dibutyltin dichloride with lithium aluminium hydride gives the dibutyltin dihydride, a colourless distillable oil:[19]

2 Bu
2SnCl
2 \+ Li[AlH
4] → 2 Bu
2SnH
2 \+ Li[AlCl

The Wurtz-like coupling of alkyl sodium compounds with tin halides yields tetraorganotin compounds.

Hydrostannylation involves the metal-catalyzed addition of tin hydrides across unsaturated substrates.[20]

Alternatively, stannides attack organic electrophiles to give organostannanes, e.g.:[2]: 49

LiSnMe3 \+ CCl4 → C(SnMe3)4 \+ LiCl.

## Reactions

Important reactions, discussed above, usually combine organotin halides and pseudohalides with nucleophiles. All-alkyl organotin compounds generally do not hydrolyze except in concentrated acid; the major exception being tin acetylides.[21] An organostannane addition is nucleophilic addition of an allyl-, allenyl-, or propargylstannanes to aldehydes and imines,[citation needed] whereas hydrostannylation conveniently reduces only unpolarized multiple bonds.[22]

Organotin hydrides are unstable to strong base, disproportionating to hydrogen gas and distannanes.[2]: 295 The latter equilibrate with the corresponding radicals only in the continued presence of base, or if strongly sterically hindered.[2]: 299, 334–335 Conversely, mineral acids cleave distannanes to the organotin halide and more hydrogen gas.[2]: 300

In "pure" organic synthesis, organotin reactions are unpopular, because organotin wastes are difficult to separate from the desired product and toxic even in extremely low concentrations. Strategies to remove the wastes include forming insoluble iodides or fluorides or covalently affixing the tin compounds to a solid polymer surface.[23]

Nevertheless, the Stille reaction is considered is a key coupling technique. In the Stille reaction, sp2-hybridized organic halides (e.g. vinyl chloride CH
2=CHCl) catalyzed by palladium:

–X + R2
–Sn(R3

3 Pd catalyst———→ R1
–R2
\+ X–Sn(R3

Organotin compounds are also used extensively in radical chemistry (e.g. radical cyclizations, Barton–McCombie deoxygenation, Barton decarboxylation, etc.).

## Applications and toxicity

* Organotin compounds
* Tetrabutyltin colorless oil, precursor to the other butyl-tin compounds

* Tributyltin oxide, a colorless to pale yellow liquid used in wood preservation

* Triphenyltin acetate, an off-white crystalline solid, used as an insecticide and a fungicide

* Triphenyltin chloride, a highly toxic white solid, used as a biocide

* Trimethyltin chloride, a toxic white solid, once used as a biocide

* Triphenyltin hydroxide, an off-white powder, used as a fungicide

* Azocyclotin, a white solid, used as a long-acting acaricide for control of spider mites on plants

* Cyhexatin, a white solid, used as an acaricide and miticide

* Hexamethylditin used as an intermediate in chemical synthesis

* Tetraethyltin, boiling point 63–65° at 12 mmHg is a catalyst.[24] The "Et" symbol stands for ethyl group.

Diagram illustrating the mechanisms of organotin poisoning in humans Diagram illustrating the processes of organotin poisoning in humans

Organotin compounds, mainly diorganotin dithiolates (formula R
2Sn(SR')
2), heat-stabilize polyvinyl chloride during production. The plastic dehydrochlorinates and exhibits undesirable brittleness if heated unstabilized. The stabilizers work by reducing allylic chlorides to allylic mercaptans and absorbing catalytic hydrogen chloride. This application consumes about 20,000 tons of tin each year.[2]: 384–385

Diorganotin carboxylates, e.g., dibutyltin dilaurate, catalyze the formation of polyurethanes, vulcanization of silicones, and certain transesterifications in industry.[2]

n-Butyltin trichloride feeds chemical vapor deposition of tin dioxide layers during glass bottle manufacture.

Trialkyltin compounds are strong biocides. Tributyltin and triphenyltin derivatives are comparably toxic to hydrogen cyanide. Depending on the organic groups, trialkyltins can be powerful bactericides and fungicides, but they are phytotoxic and therefore cannot be used in agriculture.

Tributyltins are e.g. antifungal agents in textiles and paper, wood pulp and paper mill systems, breweries, and industrial cooling systems. Triphenyltin derivatives are used as active components of antifungal paints and agricultural fungicides. Other triorganotins are miticides and acaricides. Tributyltin oxide has been extensively used as a wood preservative.[2]

Reflecting their high bioactivity, "tributyltins" were once used in marine anti-fouling paint.[2] Concerns[25] over off-target toxicity and bioaccumulation (some reports describe biological effects to marine life at a concentration of 1 nanogram per liter) led to a worldwide ban by the International Maritime Organization. As anti-fouling compounds, organotin compounds have been replaced by dichlorooctylisothiazolinone.[26]

Monoorgano, diorgano- and tetraorganotin compounds are far less dangerous than triorganotin compounds,[4] although DBT may be immunotoxic.[27]

The ototoxicity of organotin compounds in humans is not conclusively known,[28]: 4 but the United States Occupational Safety and Health Administration and National Institute for Occupational Safety and Health include them in an advisory list of metal-based ototoxicants alongside lead and mercury.[29]: 2 In guinea pigs, trimethyltin chloride was acutely and persistently ototoxic at 2 mg/kg, but in rats no such effect occurred.[28]: 4–8

## See also

* Organostannane addition
* Tributyltin azide
* Carbastannatranes

## References

1. ↑ Caseri, Walter (2014). "Initial Organotin Chemistry". Journal of Organometallic Chemistry 751: 20–24. doi:10.1016/j.jorganchem.2013.08.009.
2. ↑ 2.00 2.01 2.02 2.03 2.04 2.05 2.06 2.07 2.08 2.09 2.10 2.11 Davies, Alwyn George. (2004) Organotin Chemistry, 2nd Edition Weinheim: Wiley-VCH. ISBN 978-3-527-31023-4
3. ↑ Gielen, Marcel (1973). "From kinetics to the synthesis of chiral tetraorganotin compounds". Acc. Chem. Res. 6 (6): 198–202. doi:10.1021/ar50066a004.
4. ↑ 4.0 4.1 G. G. Graf (2005). "Ullmann's Encyclopedia of Industrial Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a27_049.
5. ↑ Jasch, Hannelore; Heinrich, Markus R. (2012). "Tin hydrides and functional group transformations". Encyclopedia of Radicals in Chemistry, Biology and Materials. Wiley. doi:10.1002/9781119953678.rad086.
6. ↑ "Stannanol | H4OSn | ChemSpider". http://www.chemspider.com/Chemical-Structure.25933968.html.
7. ↑ 7.0 7.1 Chandrasekhar, Vadapalli; Nagendran, Selvarajan; Baskar, Viswanathan (2002). "Organotin assemblies containing Sn/O bonds". Coordination Chemistry Reviews 235: 1–52. doi:10.1016/S0010-8545(02)00178-9.
8. ↑ Reich, Hans J.; Phillips, Nancy H. (1986). "Lithium-Metalloid Exchange Reactions. Observation of Lithium Pentaalkyl/aryl Tin Ate Complexes". J. Am. Chem. Soc. 108 (8): 2102–2103. doi:10.1021/ja00268a067.
9. ↑ V. G. Kumar Das; Lo Kong Mun; Chen Wei; Thomas C. W. Mak (1987). "Synthesis, Spectroscopic Study, and X-ray Crystal Structure of Bis[3-(2-pyridyl)-2-thienyl-C,N]diphenyltin(IV): The First Example of a Six-Coordinate Tetraorganotin Compound". Organometallics 6: 10–14. doi:10.1021/om00144a003.
10. ↑ Masaichi Saito; Sanae Imaizumi; Tomoyuki Tajima; Kazuya Ishimura; Shigeru Nagase (2007). "Synthesis and Structure of Pentaorganostannate Having Five Carbon Substituents". J. Am. Chem. Soc. 129 (36): 10974–10975. doi:10.1021/ja072478+. PMID 17705378.
11. ↑ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
12. ↑ T. V. RajanBabu, P. C. B. Page B. R. Buckley "Tri-n-butylstannane" in e-EROS Encyclopedia of Reagents for Organic Synthesis, 2004. doi:10.1002/047084289X.rt181.pub2
13. ↑ Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils, ed., Inorganic Chemistry, San Diego/Berlin: Academic Press/De Gruyter, ISBN 0-12-352651-5
14. ↑ Sita, Lawrence R. (1994). "Heavy-Metal Organic Chemistry: Building with Tin". Acc. Chem. Res. 27 (7): 191–197. doi:10.1021/ar00043a002.
15. ↑ Power, Philip P. (2007). "Bonding and Reactivity of Heavier Group 14 Element Alkyne Analogues". Organometallics 26 (18): 4362–4372. doi:10.1021/om700365p.
16. ↑ Sander H.L. Thoonen; Berth-Jan Deelman; Gerard van Koten (2004). "Synthetic aspects of tetraorganotins and organotin(IV) halides". Journal of Organometallic Chemistry (689): 2145–2157. http://dspace-test.library.uu.nl/keur/chem/2005-0426-063436/13093.pdf.
17. ↑ Der Kerk, G. J. M. Van; Luijten, J. G. A. (1956). "Tetraethyltin". Org. Synth. 36: 86ff. doi:10.15227/orgsyn.036.0086.
18. ↑ Seyferth, Dietmar (1959). "Di-n-butyldivinyltin". Org. Synth. 39: 10. doi:10.15227/orgsyn.039.0010.
19. ↑ "Organometallic Syntheses: Nontransition-Metal Compounds" John Eisch, Ed. Academic Press: New York, 1981. ISBN 0122349504.
20. ↑ Smith, Nicholas D.; Mancuso, John; Lautens, Mark (2000). "Metal-Catalyzed Hydrostannations". Chemical Reviews 100 (8): 3257–3282. doi:10.1021/cr9902695. PMID 11749320.
21. ↑ Eisch 1981, pp. 156, 169.
22. ↑ Elschenbroich, Christoph (2006). Organometallics (3rd ed.). Wiley. ISBN 978-3-527-29390-2.
23. ↑ Jasch & Heinrich 2012, pp. 1, 3–4.
24. ↑ Organic Syntheses, Coll. Vol. 4, p.881 (1963); Vol. 36, p.86 (1956). Link
25. ↑ Gajda, M.; Jancso, A. (2010). "Organotins, Formation, Use, Speciation and Toxicology". Metal Ions in Life Sciences (Cambridge: RSC publishing) 7, Organometallics in environment and toxicology: 111–151. doi:10.1039/9781849730822-00111. ISBN 978-1-84755-177-1.
26. ↑ Silva, Vânia; Silva, Cátia; Soares, Pedro; Garrido, E. Manuela; Borges, Fernanda; Garrido, Jorge (2020). "Isothiazolinone Biocides: Chemistry, Biological, and Toxicity Profiles". Molecules 25 (4): 991. doi:10.3390/molecules25040991. PMID 32102175.
27. ↑ C Gumy (2008). "Dibutyltin Disrupts Glucocorticoid Receptor Function and Impairs Glucocorticoid-Induced Suppression of Cytokine Production". PLOS ONE 3 (10). doi:10.1371/journal.pone.0003545. PMID 18958157. Bibcode: 2008PLoSO...3.3545G.
28. ↑ 28.0 28.1 "Tin, Organic compounds (as Sn)", Ototoxicity of industrial chemicals alone or in combination with noise, Université de Montréal School of Public Health, 2010-11-23, https://espum.umontreal.ca/fileadmin/espum/documents/DSEST/Ototoxicite_EN/25.pdf, retrieved 2026-02-11
29. ↑ Preventing Hearing Loss Caused by Chemical (Ototoxicity) and Noise Exposure, National Institute for Occupational Safety and Health, 2018, https://www.cdc.gov/niosh/docs/2018-124/pdfs/2018-124.pdf, retrieved 2026-02-11

## External links

* National Pollutant Inventory Fact Sheet for organotins
* Industry information site
* Organotin chemistry in synthesis

* v
* t
* e

Health issues of plastics and polyhalogenated compounds (PHCs)

Plasticizers: Phthalates|

* DIBP
* DBP
* BBP (BBzP)
* DIHP
* DEHP (DOP)
* DIDP
* DINP

Miscellaneous plasticizers|

* Organophosphates
* Adipates (DEHA
* DOA)

Monomers|

* Bisphenol A (BPA, in Polycarbonates)
* Vinyl chloride (in PVC)

Miscellaneous additives incl. PHCs|

* PBDEs
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* Organotins
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* Perfluorooctanoic acid

Health issues|

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Pollution|

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Regulations|

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* e

Compounds of carbon with other elements in the periodic table

| CH |  |  |  | He

|
|
|
|

CLi | CBe | CB | CC | CN | CO | CF | Ne
CNa | CMg | CAl | CSi | CP | CS | CCl | CAr
CK | CCa | CSc |  | CTi | CV | CCr | CMn | CFe | CCo | CNi | CCu | CZn | CGa | CGe | CAs | CSe | CBr | CKr
CRb | CSr | CY |  | CZr | CNb | CMo | CTc | CRu | CRh | CPd | CAg | CCd | CIn | CSn | CSb | CTe | CI | CXe
CCs | CBa | CLa |  | CHf | CTa | CW | CRe | COs | CIr | CPt | CAu | CHg | CTl | CPb | CBi | CPo  | CAt  | Rn
Fr  | CRa | Ac |  | Rf  | Db  | CSg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
|  | CCe | CPr | CNd | CPm | CSm | CEu | CGd | CTb | CDy | CHo | CEr | CTm | CYb | CLu
|  | CTh | CPa | CU | CNp | CPu | CAm | CCm | CBk | CCf | CEs | Fm | Md | No | Lr

Legend|

* Chemical bonds to carbon
* Core organic chemistry
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* Bond unknown

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