Palladium(II,IV) fluoride

Names
Other names

palladium(II) hexafluoropalladate(IV)

Identifiers

CAS Number

* 12021-58-8 Y

3D model (JSmol)

* Interactive image

PubChem CID

* 57434144

InChI

* InChI=1S/6FH.2Pd/h6*1H;;/q;;;;;;+2;+4/p-6

Key: LRWQWDMZTSEXJX-UHFFFAOYSA-H

SMILES

* [Pd+2].[F-][Pd+4]([F-])([F-])([F-])([F-])[F-]

Properties

Chemical formula

| F3Pd
Molar mass | 163.42 g·mol−1
Appearance  | black solid

Magnetic susceptibility (χ)

| +1760.0·10−6 cm3/mol
Structure

Crystal structure

| rhombohedral

Coordination geometry

| octahedral
Related compounds

Other cations

| Nickel(III) fluoride

Related compounds

| Palladium(II) fluoride
Palladium(IV) fluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Y verify (what is YN ?)
Infobox references

Palladium(II,IV) fluoride, also known as palladium trifluoride, is a chemical compound of palladium and fluorine. It has the empirical formula PdF3, but is better described as the mixed-valence compound palladium(II) hexafluoropalladate(IV), PdII[PdIVF6], and is often written as Pd[PdF6] or Pd2F6.[1][2]

## Contents

* 1 Synthesis
* 2 Structure and properties
* 3 See also
* 4 References

## Synthesis

Pd[PdF6] is the most stable product of the reaction of fluorine and metallic palladium.[1]

2 Pd + 3 F2 → Pd[PdF6]

## Structure and properties

Pd[PdF6] is paramagnetic, and both Pd(II) and Pd(IV) occupy octahedral sites in the crystal structure.[2][3] The PdII-F distance is 2.17 Å, whereas the PdIV-F distance is 1.90 Å.[4]

Coordination environments of PdII and PdIV, showing different distances to F atoms

## See also

* Palladium fluoride

## References

1. ↑ 1.0 1.1 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.
2. ↑ 2.0 2.1 Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. p. 788. ISBN 978-0-13-175553-6.
3. ↑ Hepworth, M. A.; Jack, K. H.; Peacock, R. D.; Westland, G. J. (1957). "The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium". Acta Crystallogr. 10: 63–69. doi:10.1107/S0365110X57000158.
4. ↑ Tressaud, A.; Bartlett, N. (2001). "Preparation, Magnetic Properties, and Pressure-Induced Transitions of Some MIIMIVF6 (MII=Ni, Pd, Cu; MIV=Pd, Pt, Sn) Complex Fluorides". J. Solid State Chem. 162 (2): 333–340. doi:10.1006/jssc.2001.9331. Bibcode: 2001JSSCh.162..333T.

* v
* t
* e

Palladium compounds

Pd(0)|

* Pd(P(C6H5)3)4

| Organopalladium(0) compounds|

* Pd2((C6H5C2H2)2CO)3

|

Pd(II)|

* Pd(OCOCH3)2
* Pd((COCH3)2CH)2
* PdBr2
* PdCl2
* Pd(CN)2
* PdF2
* PdI2
* Pd(NO3)2
* PdO
* Na2PdCl4
* Fe(C5H4P(C6H5)2)2PdCl2
* Pd(P(C6H5)3)2Cl2

| Organopalladium(II) compounds|

* ((CH2)2CHPdCl)2
* (C5H5)Pd(C3H5)

|

Pd(II,IV)|

* Pd2F6

Pd(IV)|

* PdF4

* v
* t
* e

Salts and covalent derivatives of the fluoride ion

HF |  |  |  | He

|
|
|
|

LiF | BeF2 | BF
BF3
B2F4 | CF4
other compounds | NF3
FN3
N2F2
N2F4
NF5§  | F2O
F2O2
other compounds | F2 | Ne
NaF | MgF2 | AlF
AlF3 | SiF4 | P2F4
PF3
PF5 | S2F2
SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF
CaF2 | ScF3 | TiF2
TiF3
TiF4 | VF2
VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5
CrF6§  | MnF2 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF2
GaF3 | GeF2
GeF4 | AsF3
AsF5 | Se2F2
SeF4
SeF6 | BrF
BrF3
BrF5 | KrF2
RbF | SrF
SrF2 | YF3 | ZrF3
ZrF4 | NbF4
NbF5 | MoF2
MoF3
MoF4
MoF5
MoF6 | TcF4
TcF6 | RuF3
RuF5
RuF6 | RhF3
RhF5
RhF6 | PdF2 | AgF | CdF2 | InF
InF2
InF3 | SnF2
SnF4 | SbF3
SbF5 | Te3F2
TeF4
TeF6 | IF
IF3</br>IF5</br>IF7 | XeF2
XeF4
XeF6
CsF | BaF2 |  | HfF4 | TaF5 | WF2
WF3
WF4
WF5
WF6 | Re3F9
ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF2
IrF3
IrF4
IrF5
IrF6 | PtF2
PtF4
PtF5
PtF6 | AuF
AuF3
Au2F10
AuF5•F2 | Hg2F2
HgF2
HgF4 | TlF | PbF2
PbF4 | BiF3
BiF5 | PoF2
PoF4
PoF6 | AtF  | RnF2
FrF | RaF2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
LaF3 | CeF3
CeF4 | PrF3 | NdF2,
NdF3 | PmF3 | SmF2,
SmF3 | EuF2,
EuF3 | GdF3 | TbF3 | DyF2,
DyF3 | HoF3 | ErF3 | TmF2
TmF3 | YbF2
YbF3 | LuF3
AcF3 | ThF4 | PaF5 | UF3
UF4
UF5
UF6 | NpF4
NpF6 | PuF3
PuF6 | AmF2
AmF3 | CmF3 | BkF3 | CfF3 | EsF3 | Fm  | Md  | No  | LrF3

§ means the substance has not been made.

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Palladium(II,IV) fluoride. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Palladium(II,IV)_fluoride&oldid=543723"
*[CID]: Compound ID
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template