Sodium hexafluorophosphate

Names
IUPAC name

sodium hexafluorophosphate

Identifiers

CAS Number

* 21324-39-0 Y

3D model (JSmol)

* Interactive image

ChEBI |

* CHEBI:172377

ChEMBL |

* ChEMBL3327018

ChemSpider |

* 4321427 Y

EC Number |

* 244-333-1

PubChem CID

* 5147921

InChI

* InChI=1S/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1 Y

Key: KMADQUOCJBLXRP-UHFFFAOYSA-N Y

* InChI=1/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1

Key: KMADQUOCJBLXRP-UHFFFAOYAE

SMILES

* F[P-](F)(F)(F)(F)F.[Na+]

Properties

Chemical formula

| Na[PF6]
Molar mass | 167.95395 g/mol
Hazards
Safety data sheet | Oxford MSDS
GHS pictograms |
GHS Signal word | Danger

GHS hazard statements

| H302, H312, H314, H332

GHS precautionary statements

| P260, P261, P264, P270, P271, P280, P301+312, P301+330+331, P302+352, P303+361+353, P304+312, P304+340, P305+351+338, P310, P312, P321, P322, P330, P363, P405, P501
Related compounds

Other anions

| sodium tetrafluoroborate

Other cations

| lithium hexafluorophosphate; ammonium hexafluorophosphate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Y verify (what is YN ?)
Infobox references

Tracking categories (test):

* SizeSet

Sodium hexafluorophosphate is an inorganic compound with the chemical formula Na[PF6].

In 2015 it has been utilised as a component of non-aqueous electrolyte in rechargeable sodium-ion batteries.[2] NaPF6 can be prepared by the reaction

PCl5 \+ NaCl + 6 HF → NaPF6 \+ 6 HCl

## Further reading

* Woyski, M. M.; Shenk, W. J.; Pellon, E. R. (1950). "Hexafluophosphates of Sodium, Ammonium, and Potassium". Inorganic Syntheses. 3. 111–117. doi:10.1002/9780470132340.ch29. ISBN 978-0-470-13234-0.

## References

1. ↑ "Sodium hexafluorophosphate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/5147921#section=Safety-and-Hazards.
2. ↑ Wang, Chueh-Han; Yeh, Ju-Wen; Wongittharom, Nithinai; Wang, Yi-Chen; Tseng, Chung-Jen; Lee, Sheng-Wei; Chang, Wen-Sheng; Chang, Jeng-Kuei (January 15, 2015). "Rechargeable Na/Na0.44MnO2 cells with ionic liquid electrolytes containing various sodium solutes". Journal of Power Sources 274: 1016–1023. doi:10.1016/j.jpowsour.2014.10.143. Bibcode: 2015JPS...274.1016W. https://www.sciencedirect.com/science/article/abs/pii/S0378775314017625. Retrieved November 2, 2021.

* v
* t
* e

Sodium compounds

* NaAlO2
* NaBH4
* NaBH3(CN)
* NaBO2
* NaBiO3
* NaBr
* NaBrO
* NaBrO3
* NaCH3COO
* NaC6H5CO2
* NaC6H4(OH)CO2
* NaCN
* NaCl
* NaClO
* NaClO2
* NaClO3
* NaClO4
* NaF
* Na2FeO4
* NaH
* NaHCO3
* NaH2PO4
* NaHSO3
* NaHSO4
* NaI
* NaIO3
* NaIO4
* Na5IO6
* NaMnO4
* NaN3
* NaNH2
* NaNO2
* NaNO3
* NaOCN
* NaO2
* NaO3
* NaOH
* NaPO2H2
* NaReO4
* NaSCN
* NaSH
* NaTcO4
* NaVO3
* Na2CO3
* Na2C2O4
* Na2CrO4
* Na2Cr2O7
* Na2GeO3
* Na2MnO4
* Na3MnO4
* Na2MoO4
* Na2MoS4
* Na2N2O2
* Na2O
* Na2O2
* Na2O(UO3)2
* Na2PO3F
* Na2S
* Na2SO3
* Na2SO4
* Na2S2O3
* Na2S2O4
* Na2S2O5
* Na2S2O6
* Na2S2O7
* Na2S2O8
* Na2S4O6
* Na2Se
* Na2SeO3
* Na2SeO4
* Na2SiO3
* Na2Si2O5
* Na4SiO4
* Na2Te
* Na2TeO3
* Na2TeO4
* Na2Po
* Na2Ti3O7
* Na2U2O7
* Na2WO4
* Na2Zn(OH)4
* Na3N
* Na3P
* Na3PO4
* Na3VO4
* Na4Fe(CN)6
* Na4P3O7
* Na5P3O10

Chemical formulas

* v
* t
* e

Hexafluorophosphates

* HPF6
* NH4PF6
* BMIM-PF6
* [Fe(C5H5)2]PF6
* LiPF6
* (C6H5)3CPF6
* AgPF6
* KPF6
* NaPF6
* NnBu4PF6
* [Cu(MeCN)4]PF6

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Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Sodium_hexafluorophosphate&oldid=812206"
*[CID]: Compound ID
*[H302]: Harmful if swallowed
*[H312]: Harmful in contact with skin
*[H314]: Causes severe skin burns and eye damage
*[H332]: Harmful if inhaled
*[P260]: Do not breathe dust/fume/gas/mist/vapours/spray
*[P261]: Avoid breathing dust/fume/gas/mist/vapours/spray
*[P264]: Wash … thoroughly after handling
*[P270]: Do not eat, drink or smoke when using this product
*[P271]: Use only outdoors or in a well-ventilated area
*[P280]: Wear protective gloves/protective clothing/eye protection/face protection
*[P301+312]: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
*[P301+330+331]: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
*[P302+352]: IF ON SKIN: Wash with soap and water
*[P303+361+353]: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
*[P304+312]: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell
*[P304+340]: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
*[P305+351+338]: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
*[P310]: Immediately call a POISON CENTER or doctor/physician
*[P312]: Call a POISON CENTER or doctor/physician if you feel unwell
*[P321]: Specific treatment (see … on this label)
*[P322]: Specific measures (see … on this label)
*[P330]: Rinse mouth
*[P363]: Wash contaminated clothing before reuse
*[P405]: Store locked up
*[P501]: Dispose of contents/container to …
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