Sulfur trifluoride

Names
Other names

sulfur(III) fluoride
trifluorosulfur radical

Identifiers

CAS Number

* 30937-38-3 Y

3D model (JSmol)

* Interactive image

InChI

* InChI=1S/F3S/c1-4(2)3

Key: PSCXEUSWZWRCMQ-UHFFFAOYSA-N

SMILES

* F[S](F)F

Properties

Chemical formula

| F3S
Molar mass | 89.06 g·mol−1
Related compounds

Related compounds

| SF2, SF4, SF6, S2F10

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Y verify (what is YN ?)
Infobox references

Sulfur trifluoride is the inorganic chemical compound with the formula SF3. It is a radical.[1][2]

## Structure and synthesis

Sulfur trifluoride is predicted to be pyramidal.[3][4]

SF3 is generated by irradiation of crystals SF+3BF−4 with gamma rays.[1]

## SF−3

A derivative formally derived from SF−3 is the coordination complex Ir(Cl)(CO)(F)(SF3)(Et3P)2 obtained by oxidative addition of sulfur tetrafluoride to Ir(Cl)(CO)(PEt3)2 (Et = C2H5).[5][6]

## References

1. ↑ 1.0 1.1 Morton, J. R.; Preston, K. F.; Strach, S. J. (1978). "The EPR spectrum of SF3 Trapped in SF3BF4 Crystals". The Journal of Chemical Physics 69 (4): 1392. doi:10.1063/1.436766. Bibcode: 1978JChPh..69.1392M.
2. ↑ Deng, Jianming; Wang, Chaoyang; Li, Qian-shu; Xie, Yaoming; King, R. Bruce; Schaefer, Henry F. (2011). "Trifluorosulfane Ligand as an Analogue of the Nitrosyl Ligand: Highly Exothermic Fluorine Transfer Reactions from Sulfur to Metal in the Chemistry of SF3 Metal Carbonyls of the First Row Transition Metals". Inorganic Chemistry 50 (7): 2824–2835. doi:10.1021/ic101994k. PMID 21366337.
3. ↑ Irikura, Karl K. (1995). "Structure and thermochemistry of sulfur fluorides SFn (n = 1–5) and their ions SF+n (n = 1–5)". The Journal of Chemical Physics 102 (13): 5357–5367. doi:10.1063/1.469263. Bibcode: 1995JChPh.102.5357I. https://zenodo.org/record/1232101.SF+''n''+(''n''+=+1–5)&rft.jtitle=The+Journal+of+Chemical+Physics&rft.aulast=Irikura&rft.aufirst=Karl+K.&rft.au=Irikura, Karl+K.&rft.date=1995&rft.volume=102&rft.issue=13&rft.pages=5357–5367&rft_id=info:doi/10.1063/1.469263&rft_id=info:bibcode/1995JChPh.102.5357I&rft_id=https://zenodo.org/record/1232101&rfr_id=info:sid/en.wikibooks.org:Chemistry:Sulfur_trifluoride">
4. ↑ Woon, David E.; Dunning, Thom H. (2009). "Theory of Hypervalency: Recoupled Pair Bonding in SFn (n = 1−6)". The Journal of Physical Chemistry A 113 (27): 7915–7926. doi:10.1021/jp901949b. PMID 19499905. Bibcode: 2009JPCA..113.7915W.
5. ↑ Cockman, Russell W.; Ebsworth, E. A. V.; Holloway, John H. (1987). "Complexes of iridium(III) containing the novel sulfur trifluoride ligand". Journal of the American Chemical Society 109 (7): 2194–2195. doi:10.1021/ja00241a055.
6. ↑ Gao, Xiaozhen; Li, Nan; King, R. Bruce (December 2014). "Formation of Difluorosulfane Complexes of the Third Row Transition Metals by Sulfur-to-Metal Fluorine Migration in Trifluorosulfane Metal Complexes: The Anomaly of Trifluorosulfane Iridium Tricarbonyl". Inorganic Chemistry 53 (23): 12635–12642. doi:10.1021/ic502375q. PMID 25397720.

* v
* t
* e

Sulfur compounds

* Al2S3
* As2S2
* As2S3
* As2S5
* As4S4
* Au2S
* Au2S3
* B2S3
* BaS
* BeS
* Bi2S3
* Br2S
* Br2S2
* CS2
* C3S2
* C6S6
* CaS
* CdS
* CeS
* SCl2
* S2Cl2
* CoS
* Cr2S3
* CuS
* D2S
* Dy2S3
* Er2S3
* EuS
* SF4
* S2F10
* SF6
* FeS2
* GaS
* H2S
* HfS2
* HgS
* InS
* I2S
* LaS
* LiS
* MgS
* MoS3
* NiS
* SO2
* SO3
* P4S7
* PbS
* PbS2
* PtS
* ReS2
* SrS
* TlS
* SV
* SeS2
* S2U
* WS2
* Sb2S3
* Sb2S5
* Sm2S3
* Y2S3
* Ag2SO4
* SOBr2
* CSTe
* C2H4S
* C2H6S3
* C4H4S
* CaSO4
* C32H66S2
* CuFeS2
* H2SO4
* H2SO3
* F2OS
* NaHS
* K2SO3
* O3S3Sb4
* Yb2(SO4)3
* AlKO8S2
* CHCl3S
* KSCN
* CdSO3
* PSCl3
* SOCl2
* Cs2O4S
* Re2S7
* Na2S
* K2S
* H2S2O7
* H2SO5
* NH5S
* HgSO4
* K2SO4
* RaSO4
* SnSO4
* SrSO4
* Zr(SO4)2
* Ti(SO4)2
* Tm2(SO4)3
* AlNa(SO4)2
* Er2(SO4)3
* Eu2(SO4)3
* CHNS
* Co(SCN)2
* C2H3SN
* PSI3
* ZrS2
* SiS
* CSSe

Chemical formulas

* v
* t
* e

Salts and covalent derivatives of the fluoride ion

HF |  |  |  | He

|
|
|
|

LiF | BeF2 | BF
BF3
B2F4 | CF4
other compounds | NF3
FN3
N2F2
N2F4
NF5§  | F2O
F2O2
other compounds | F2 | Ne
NaF | MgF2 | AlF
AlF3 | SiF4 | P2F4
PF3
PF5 | S2F2
SF2
SF4
SF6 | ClF
ClF3
ClF5 | Ar
KF | CaF
CaF2 | ScF3 | TiF2
TiF3
TiF4 | VF2
VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5
CrF6§  | MnF2 | FeF2
FeF3 | CoF2
CoF3 | NiF2 | CuF
CuF2 | ZnF2 | GaF2
GaF3 | GeF2
GeF4 | AsF3
AsF5 | Se2F2
SeF4
SeF6 | BrF
BrF3
BrF5 | KrF2
RbF | SrF
SrF2 | YF3 | ZrF3
ZrF4 | NbF4
NbF5 | MoF2
MoF3
MoF4
MoF5
MoF6 | TcF4
TcF6 | RuF3
RuF5
RuF6 | RhF3
RhF5
RhF6 | PdF2 | AgF | CdF2 | InF
InF2
InF3 | SnF2
SnF4 | SbF3
SbF5 | Te3F2
TeF4
TeF6 | IF
IF3</br>IF5</br>IF7 | XeF2
XeF4
XeF6
CsF | BaF2 |  | HfF4 | TaF5 | WF2
WF3
WF4
WF5
WF6 | Re3F9
ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6 | IrF2
IrF3
IrF4
IrF5
IrF6 | PtF2
PtF4
PtF5
PtF6 | AuF
AuF3
Au2F10
AuF5•F2 | Hg2F2
HgF2
HgF4 | TlF | PbF2
PbF4 | BiF3
BiF5 | PoF2
PoF4
PoF6 | AtF  | RnF2
FrF | RaF2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
LaF3 | CeF3
CeF4 | PrF3 | NdF2,
NdF3 | PmF3 | SmF2,
SmF3 | EuF2,
EuF3 | GdF3 | TbF3 | DyF2,
DyF3 | HoF3 | ErF3 | TmF2
TmF3 | YbF2
YbF3 | LuF3
AcF3 | ThF4 | PaF5 | UF3
UF4
UF5
UF6 | NpF4
NpF6 | PuF3
PuF6 | AmF2
AmF3 | CmF3 | BkF3 | CfF3 | EsF3 | Fm  | Md  | No  | LrF3

§ means the substance has not been made.

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Sulfur trifluoride. Read more

|

Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Sulfur_trifluoride&oldid=496738"
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template