Vinyl formate

Identifiers

CAS Number

* 692-45-5 Y

3D model (JSmol)

* Interactive image

ChemSpider |

* 193133

EC Number |

* 211-730-6

PubChem CID

* 222465

UNII |

* LFS2HF6ZYT

InChI

* InChI=1S/C3H4O2/c1-2-5-3-4/h2-3H,1H2

Key: GFJVXXWOPWLRNU-UHFFFAOYSA-N

SMILES

* C=COC=O

Properties

Chemical formula

| C3H4O2
Molar mass | 72.063 g·mol−1
Appearance  | colorless liquid
Density | 0.963 g/cm3
Boiling point |  46.8–47.0 °C (116.2–116.6 °F; 319.9–320.1 K)

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Vinyl formate is an organic compound with the formula CH
2=CHO
2CH. It is the ester formally derived from formic acid and vinyl alcohol. Although rare commercially, it occurs naturally.[1][2] It can be prepared by transvinylation, say by treating vinyl versatate with formic acid in the presence of a mercury(II) catalyst..[3]

## References

1. ↑ Dan, T.; Wang, D.; Jin, R.L.; Zhang, H.P.; Zhou, T.T.; Sun, T.S. (2017). "Characterization of volatile compounds in fermented milk using solid-phase microextraction methods coupled with gas chromatography-mass spectrometry". Journal of Dairy Science 100 (4): 2488–2500. doi:10.3168/jds.2016-11528. PMID 28161169.
2. ↑ Dekeirsschieter, Jessica; Stefanuto, Pierre-Hugues; Brasseur, Catherine; Haubruge, Eric; Focant, Jean-François (2012). "Enhanced Characterization of the Smell of Death by Comprehensive Two-Dimensional Gas Chromatography-Time-of-Flight Mass Spectrometry (GCXGC-TOFMS)". PLOS ONE 7 (6): e39005. doi:10.1371/journal.pone.0039005. PMID 22723918. Bibcode: 2012PLoSO...739005D.
3. ↑ Mondal, M.A.S.; Van Der Meer, R.; German, A.L.; Heikens, D. (1974). "A novel synthesis of vinyl esters from vinylversatate-10". Tetrahedron 30 (23–24): 4205–4207. doi:10.1016/S0040-4020(01)97407-1.

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*[CID]: Compound ID