Vinylferrocene

Vinylferrocene is the organometallic compound with the formula (C5H5)Fe(C5H4CH=CH2). It is a derivative of ferrocene, with a vinyl group attached to one cyclopentadienyl ligand. As the ferrocene analogue of styrene, it is the precursor to some polyferrocenes.[1] It is an orange, air-stable oily solid that is soluble in nonpolar organic solvents.

Vinylferrocene can be prepared by the dehydration of α-hydroxylethylferrocene, which is obtained from acetylferrocene.[2] It can also be made by a Wittig reaction of ferrocenecarboxaldehyde.[3]

## References

1. ↑ Cass, Anthony E. G.; Davis, Graham; Francis, Graeme D.; Hill, H. Allen O.; Aston, William J.; Higgins, I. John; Plotkin, Elliot V.; Scott, Lesley D. L. et al. (1984). "Ferrocene-mediated enzyme electrode for amperometric determination of glucose". Analytical Chemistry 56 (4): 667–671. doi:10.1021/ac00268a018. PMID 6721151.
2. ↑ Rausch, Marvin D.; Siegel, Armand (1968). "Organometallic π-complexes. XIV. Vinylmetallocenes". Journal of Organometallic Chemistry 11: 317–324. doi:10.1016/0022-328X(68)80054-3.
3. ↑ "Solvent-free synthesis of ferrocenylethene derivatives". J. Organomet. Chem. 625: 128–132. 2001. doi:10.1016/S0022-328X(00)00927-X.

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