Ytterbium(III) nitrate

Names
Other names

Ytterbium trinitrate, Ytterbium nitrate

Identifiers

CAS Number

* 13768-67-7 Y
* monohydrate: 35725-34-9

3D model (JSmol)

* Interactive image

ChemSpider |

* 32748884
* monohydrate: 29434727

EC Number |

* 237-384-6

PubChem CID

* monohydrate: 91886286
* pentahydrate: 16211525
* hexahydrate: 203097

InChI

* InChI=1S/HNO3.Yb/c2-1(3)4;/h(H,2,3,4);

Key: IKWXNJJIPMAOHU-UHFFFAOYSA-N

SMILES

* N(=O)(=O)O.[Yb]

Properties

Chemical formula

| Yb(NO3)3
Molar mass | 359.06
Appearance  | Colorless solid[1]

Solubility in water

| Soluble
Hazards
GHS pictograms |
GHS Signal word | Warning

GHS hazard statements

| H272, H315, H319, H335

GHS precautionary statements

| P210, P220, P221, P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P370+378, P403+233, P405, P501
Related compounds

Related compounds

| Terbium(III) nitrate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Tracking categories (test):

* SizeSet

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO3)3.[2] The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.[3][4]

## Contents

* 1 Synthesis
* 2 Physical properties
* 3 Chemical properties
* 4 Application
* 5 References

## Synthesis

Reaction of ytterbium and nitric oxide in ethyl acetate:

Yb+3N2O4 → Yb(NO3)3+3NO↑

Reaction of ytterbium hydroxide and nitric acid:

Yb(OH)3+3HNO3 → Yb(NO3)3+3H2O↑

## Physical properties

Ytterbium(III) nitrate forms colorless hygroscopic crystals.

Soluble in water and ethanol.

Forms crystalline hydrates of the composition Yb(NOA3)A3⋅nHA2O, where n = 4, 5, 6.[5]

## Chemical properties

The hydrated ytterbium nitrate thermally decomposes to form YbONO3 and decomposes to ytterbium oxide upon further heating.

## Application

Ytterbium(III) nitrate hydrate is used for nanoscale coatings of carbon composites.[6]

Also used to obtain metallic ytterbium and as a chemical reagent.

Used as a component for the production of ceramics and glass.

## References

1. ↑ Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3621. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Ytterbium+(III)+nitrate&pg=PA3621. Retrieved 19 August 2021.
2. ↑ Лидин, Ростислав; Молочко, Вадим; Андреева, Лариса (2 February 2019) (in ru). Константы неорганических веществ. Справочник. Litres. p. 69. ISBN 978-5-04-077039-7. https://books.google.com/books?id=-cQ0DwAAQBAJ&dq=нитрат+иттербия&pg=PA69. Retrieved 19 August 2021.
3. ↑ "Ytterbium(III) nitrate pentahydrate". Sigma Aldrich. https://www.sigmaaldrich.com/RU/ru/product/aldrich/209147.
4. ↑ Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. https://books.google.com/books?id=6IuZAwAAQBAJ&dq=Ytterbium+(III)+nitrate&pg=PA226. Retrieved 19 August 2021.
5. ↑ "Ytterbium(III) nitrate pentahydrate" (in en). pubchem.ncbi.nlm.nih.gov. https://pubchem.ncbi.nlm.nih.gov/compound/Ytterbium_III_-nitrate-pentahydrate.
6. ↑ "12901 Ytterbium(III) nitrate hydrate, 99.9% (REO)". Alfa Aesar. https://www.alfa.com/en/catalog/012901/.

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* t
* e

Ytterbium compounds

Yb(II)|

* YbCl2

Yb(III)|

* YbBr3
* YbCl3
* YbF3
* Yb2O3
* Yb2(SO4)3

Other|

* YbRh2Si2

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Salts and covalent derivatives of the nitrate ion

HNO3 |  |  |  | He

|
|
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LiNO3 | Be(NO3)2 | B(NO3)−4 | C  | NO−3,
NH4NO3 | O  | FNO3 | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si  | P  | S  | ClONO2 | Ar
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3,
Fe(NO3)2 | Co(NO3)2,
Co(NO3)3 | Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | Se  | Br  | Kr
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In  | Sn  | Sb(NO3)3 | Te  | I  | Xe(NO3)2
CsNO3 | Ba(NO3)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt  | Au  | Hg2(NO3)2,
Hg(NO3)2 | Tl(NO3)3,
TlNO3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po  | At  | Rn
FrNO3 | Ra(NO3)2 |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(NO3)3 | Ce(NO3)3,
Ce(NO3)4 | Pr  | Nd(NO3)3 | Pm  | Sm  | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy  | Ho  | Er  | Tm  | Yb  | Lu
Ac(NO3)3 | Th(NO3)4 | Pa  | UO2(NO3)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

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*[CID]: Compound ID
*[H272]: May intensify fire: oxidizer
*[H315]: Causes skin irritation
*[H319]: Causes serious eye irritation
*[H335]: May cause respiratory irritation
*[P210]: Keep away from heat/sparks/open flames/hot surfaces – No smoking
*[P220]: Keep/Store away from clothing/…/combustible materials
*[P221]: Take any precaution to avoid mixing with combustibles
*[P261]: Avoid breathing dust/fume/gas/mist/vapours/spray
*[P264]: Wash … thoroughly after handling
*[P271]: Use only outdoors or in a well-ventilated area
*[P280]: Wear protective gloves/protective clothing/eye protection/face protection
*[P302+352]: IF ON SKIN: Wash with soap and water
*[P304+340]: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
*[P305+351+338]: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
*[P312]: Call a POISON CENTER or doctor/physician if you feel unwell
*[P321]: Specific treatment (see … on this label)
*[P332+313]: If skin irritation occurs: Get medical advice/attention
*[P337+313]: Get medical advice/attention
*[P362]: Take off contaminated clothing and wash before reuse
*[P370+378]: In case of fire: Use … for extinction
*[P403+233]: Store in a well ventilated place. Keep container tightly closed
*[P405]: Store locked up
*[P501]: Dispose of contents/container to …
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