Zirconium(IV) acetate

Identifiers
Properties

Chemical formula

| C24H40O32Zr6
Molar mass | 1387.896 g·mol−1
Appearance  | white solid

Solubility in water

| soluble
Related compounds

Related compounds

| zirconium dioxide, zirconium(IV) chloride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Zirconium acetate usually refers to the chemical formula Zr

4(OH)
4(O
2CCH

12. It forms by the reaction of zirconyl chloride and acetate. Claims of Zr(O
2CCH

4[1] have been superseded by experiments using X-ray crystallography.[2]

The species Zr

4(OH)
4(O
2CCH

12 is a common precursor to metal-organic frameworks (MOFs).[3]

## References

1. ↑ Pavlov, V. L.; Lysenko, Yu. A.; Kalinichenko, A. A. Synthesis and properties of zirconium tetraacetate.Script error: The function "in_lang" does not exist. Zhurnal Neorganicheskoi Khimii, 1972. 17(12). ISSN 0044-457X
2. ↑ Hennig, Christoph; Weiss, Stephan; Kraus, Werner; Kretzschmar, Jerome; Scheinost, Andreas C. (2017). "Solution Species and Crystal Structure of Zr(IV) Acetate". Inorganic Chemistry 56 (5): 2473–2480. doi:10.1021/acs.inorgchem.6b01624. PMID 28199091.
3. ↑ Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni; Guillou, Nathalie; Lamberti, Carlo; Bordiga, Silvia; Lillerud, Karl Petter (2008). "A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability". Journal of the American Chemical Society 130 (42): 13850–13851. doi:10.1021/ja8057953. PMID 18817383.

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Zirconium compounds

Zr(II)|

* ZrB2
* ZrH2
* ZrSi2

Zr(III)|

* ZrN
* ZrCl3

Zr(IV)|

* ZrBr4
* ZrC
* ZrCl4
* ZrF4
* ZrI4
* Zr(NO3)4
* ZrOCl2
* Zr(OH)4
* ZrO2
* ZrS2
* Zr(SO4)2
* ZrSiO4
* Zr(WO4)2

| Organozirconium(IV)|

* Zr(acac)4

|

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Acetyl halides and salts of the acetate ion

AcOH |  |  |  | He
LiOAc | Be(OAc)2
BeAcOH | B(OAc)3 | AcOAc
ROAc | NH4OAc | AcOOH | FAc | Ne
NaOAc | Mg(OAc)2 | Al(OAc)3
ALSOL
Al(OAc)2OH
Al2SO4(OAc)4 | Si  | P  | S  | ClAc | Ar
KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO(OAc)3 | Cr(OAc)2
Cr(OAc)3 | Mn(OAc)2
Mn(OAc)3 | Fe(OAc)2
Fe(OAc)3 | Co(OAc)2,
Co(OAc)3 | Ni(OAc)2 | Cu(OAc)2 | Zn(OAc)2 | Ga(OAc)3 | Ge  | As(OAc)3 | Se  | BrAc | Kr
RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb  | Mo(OAc)2 | Tc  | Ru(OAc)2
Ru(OAc)3
Ru(OAc)4 | Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In  | Sn(OAc)2
Sn(OAc)4 | Sb(OAc)3 | Te  | IAc | Xe
CsOAc | Ba(OAc)2 |  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt(OAc)2 | Au  | Hg2(OAc)2,
Hg(OAc)2 | TlOAc
Tl(OAc)3 | Pb(OAc)2
Pb(OAc)4 | Bi(OAc)3 | Po  | At  | Rn
Fr  | Ra  |  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
La(OAc)3 | Ce(OAc)x | Pr  | Nd  | Pm  | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb  | Dy(OAc)3 | Ho(OAc)3 | Er  | Tm  | Yb(OAc)3 | Lu(OAc)3
Ac  | Th  | Pa  | UO2(OAc)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No  | Lr

https://doi.org/10.1021/acs.inorgchem.6b01624 Copyright © 2017 American Chemical Society RIGHTS & PERMISSIONS Subscribed Access Article Views 3592 Altmetric 5 Citations 57 LEARN ABOUT THESE METRICS Share

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RIS PDF (2 MB) OpenURL UNIV ILLINOIS URBANA-CHAMPAIGNSupporting Info (2)»Supporting Information SUBJECTS:Cluster chemistry, Go to Inorganic Chemistry Inorganic Chemistry Abstract

Complex formation and the coordination of zirconium with acetic acid were investigated with Zr K-edge extended X-ray absorption fine structure spectroscopy (EXAFS) and single-crystal diffraction. Zr K-edge EXAFS spectra show that a stepwise increase of acetic acid in aqueous solution with 0.1 M Zr(IV) leads to a structural rearrangement from initial tetranuclear hydrolysis species [Zr4(OH)8(OH2)16]8+ to a hexanuclear acetate species Zr6(O)4(OH)4(CH3COO)12.

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