Isotope hydrology

Short description: Field of geochemistry and hydrology

Isotope hydrology[1] is a field of geochemistry and hydrology that uses naturally occurring stable and radioactive isotopic techniques to evaluate the age and origins of surface and groundwater and the processes within the atmospheric hydrologic cycle.[2] Isotope hydrology applications are highly diverse, and used for informing water-use policy, mapping aquifers, conserving water supplies, assessing sources of water pollution, investigating surface-groundwater interaction, refining groundwater flow models, and increasingly are used in eco-hydrology to study human impacts on all dimensions of the hydrological cycle and ecosystem services.

## Contents

* 1 Details
* 2 Applications
* 3 Current use
* 4 See also
* 5 References
* 6 External links

## Details

Water molecules carry unique isotopic "fingerprints", based in part on differing ratios of the oxygen and hydrogen isotopes that constitute the water molecule. Isotopes are atoms of the same element that have a different number of neutrons in their nuclei.

Air, freshwater and seawater contain mostly oxygen-16 ( 16O). Oxygen-18 (18O) occurs in approximately one oxygen atom in every five hundred and has a slightly higher mass than oxygen-16, as it has two extra neutrons. From a simple energy and bond breakage standpoint this results in a preference for evaporating the lighter 16O containing water and leaving more of the 18O water behind in the liquid state (called isotope fractionation). Thus seawater tends to contain more 18O than rain and snow.

Dissolved ions in surface and groundwater water also contain useful isotopes for hydrological investigations. Dissolved species like sulfate and nitrate contain differing ratios of 34-S to 32-S or 15-N to 14-N, and are often diagnostic of pollutant sources. Natural radioisotopes like tritium (3-H) and radiocarbon (14-C) are also used as natural clocks to determine the residence times of water in aquifers, rivers, and the oceans.

## Applications

The most commonly used isotope application in hydrology uses hydrogen and oxygen isotopes to evaluate sources or age of water, ice or snow. Isotopes in ice cores help to reveal conditions of past climate. Higher average global temperature would provide more energy and thus increase the atmospheric 18O content of rain or snow, so that lower than modern amounts of 18O in groundwater or ice layer imply the water or ice represents a period of cooler climatic eras or even ice ages.[3]

Another application involves the separation of groundwater flow and baseflow from streamflow in the field of catchment hydrology (i.e. a method of hydrograph separation). Since precipitation in each rain or snowfall event has a specific isotopic signature, and subsurface water can be identified by well sampling, the composite signature in the stream is an indicator the proportion of the streamflow comes from overland flow and what portion comes from subsurface flow.[4][5]

Stable isotopes in the water molecule are also useful in tracing the sources (or proportion of sources) of water that plants use.[6][7][8]

## Current use

The isotope hydrology program at the International Atomic Energy Agency works to aid developing states to create a detailed portrait of Earth's water resources.[9]

In Ethiopia, Libya, Chad, Egypt and Sudan, the International Atomic Energy Agency used radioisotope techniques to help local water policy identify and conserve fossil water.

The International Atomic Energy Agency maintains a publicly accessible global network and isotopic database for Earth's rainfall and rivers.[10]

## See also

* Baseflow
* Hydrograph
* Water chemistry analysis

## References

1. ↑ Gat, Joel (2010). Isotope hydrology: a study of the water cycle. World Scientific.
2. ↑ Gleeson, Tom (2016). "The global volume and distribution of modern groundwater". Nature 9 (2): 161–167. doi:10.1038/ngeo2590. Bibcode: 2016NatGe...9..161G.
3. ↑ Masters, G. & P. Ela. 2008. Global Atmospheric Change. Chapter in: Introduction to Environmental Engineering and Science. 3rd ed. Prentice Hall.
4. ↑ Kendall and McDonnell, 1998. Isotope Tracers in Catchment Hydrology. Elsevier
5. ↑ Tetzlaff, Doerthe; Buttle, James; Carey, Sean K.; van Huijgevoort, Marjolein H. J.; Laudon, Hjalmar; McNamara, James P.; Mitchell, Carl P. J.; Spence, Chris et al. (2015-12-15). "A preliminary assessment of water partitioning and ecohydrological coupling in northern headwaters using stable isotopes and conceptual runoff models: Water Partitioning in Northern Headwaters" (in en). Hydrological Processes 29 (25): 5153–5173. doi:10.1002/hyp.10515. PMID 27656040.
6. ↑ Evaristo, Jaivime; Jasechko, Scott; McDonnell, Jeffrey J. (2015). "Global separation of plant transpiration from groundwater and streamflow". Nature 525 (7567): 91–94. doi:10.1038/nature14983. PMID 26333467. Bibcode: 2015Natur.525...91E.
7. ↑ Good, Stephen P.; Noone, David; Bowen, Gabriel (2015-07-10). "Hydrologic connectivity constrains partitioning of global terrestrial water fluxes" (in en). Science 349 (6244): 175–177. doi:10.1126/science.aaa5931. ISSN 0036-8075. PMID 26160944. Bibcode: 2015Sci...349..175G.
8. ↑ Langs, Lindsey E.; Petrone, Richard M.; Pomeroy, John W. (2020-12-30). "A δ 18 O and δ 2 H stable water isotope analysis of subalpine forest water sources under seasonal and hydrological stress in the Canadian Rocky Mountains" (in en). Hydrological Processes 34 (26): 5642–5658. doi:10.1002/hyp.13986. ISSN 0885-6087. Bibcode: 2020HyPr...34.5642L. https://onlinelibrary.wiley.com/doi/10.1002/hyp.13986.
9. ↑ International Atomic Energy Agency
10. ↑ "Global Network for Isotopes in Precipitation". http://www-naweb.iaea.org/napc/ih/IHS_resources_isohis.html.

## External links

* Isotope Hydrology at the IAEA
* Environmental isotopes in the hydrological cycle: Principles and applications

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